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Carbon-air electrode with regenerative short time overload capacity: Part 1. Effect of manganese dioxide
(Springer Nature, 1973)
To increase the overload capacity of the carbon-air electrode in alkaline electrolyte, without seriously changing the electrode potential during short-time overload periods, small amounts of MnO2 were added to carbon and ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...
Criteria for the determination of the stereochemistry of steroidal indolizidines
(Elsevier, 1974)
E/F-Indolizidine steroids, which represent a structural unit of Solanum alkaloids, have been synthesized and used to evaluate criteria (IR—Bohlmann bands,1a-c —hydrogenbond,2a-e NMR,3a-c mass spectra,4 kinetic studies of ...
Pulsating potential electrolysis in the deposition of copper
(Elsevier, 1973)
A very low impedance circuit was constructed in order to provide a pulsating cathodic potential for a copper electrode immersed in a copper sulphate solution of the type used in copper refining. The increase in surface ...
Rotating two-ring electrodes as a tool for electrochemical investigations of gas-evolving reactions
(Elsevier, 1972)
It is shown that two concentric ring electrodes located on a rotating disc surface can be used as an instrument for chemical and electrochemical analysis of gas-evolving reactions up to rates of gas evolution from the inner ...
Acceleration of electrocatalytic reactions by pulsation of potential: Oxidation of formic acid on Pt and Pt/Pbads electrodes
(Pergamon Press, 1978)
Pulsating potential electrolysis has been applied to one typical electrocatalytic reaction ie, the oxidation of formic acid on platinum and platinum partially covered by lead adatoms electrodes. It has been found that much ...
An apparatus for simultaneous determination of electrical conductivity and thermogravimetric curves of solid systems
(Springer, 1975)
A new apparatus for measurement of electrical conductivity during thermogravimetric analysis is described. Results of an investigation of the water-zeolite system in the interval -200° up to +450° prove the suitability of ...
Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions
(Pergamon Press, 1978)
The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
An analysis of elementary processes of water desorption from zeolites of type a Part II. Zeolites with bivalent counterions
(Elsevier, 1976)
DSC and EGA were used to follow the process of water desorption from synthetic MgA, ZnA and CdA zeolites. Applying a semi-empirical algorithm the complex experimental curves were resolved into elementary ones. It turned ...