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Increased yield of enzymatic synthesis by chromatographic selection of different N-glycoforms of yeast invertase
(Wiley, 2020)
Invertases are glycosidases applied for synthesis of alkyl glycosides that are important and effective surfactants. Stability of invertases in the environment with increased content of organic solvent is crucial for increase ...
Controlling Pd-Catalyzed N-Arylation and Dimroth Rearrangement in the Synthesis of N,1-Diaryl-1H-tetrazol-5-amines
(American Chemical Society (ACS), 2021)
The Pd-catalyzed N-arylation method for the synthesis of eighteen N,1-diaryl-1H-tetrazol-5-amine derivatives is reported. By running the reactions at 35 °C, compounds were isolated as single isomers since the undesired ...
Insight into the Origin of Pyrocatechol Inhibition on Oscillating Bray-Liebhafsky Reaction: Combined Experimental and Theoretical Study
(Chemical Society of Japan, 2020)
The pyrocatechol inhibitory effect on the oscillatory Bray-Liebhafsky (BL) reaction is reported. Obtained results are compared with those available in the literature (R. Cervellati et al, Helvetica Chimica Acta 2001) for ...
Soil erodibility in European mountain beech forests
(Canadian Science Publishing, 2021)
Forests in Europe are currently not endangered by soil erosion. However, this can change with climate change orwith intensified forest management practices. Using a newly established network of plots in beech forests across ...
Self-Assembly and Biorecognition of a Spirohydantoin Derived from α-Tetralone: Interplay between Chirality and Intermolecular Interactions
(John Wiley and Sons Inc., 2020)
A racemic spirohydantoin derivative with two aromatic substituents, a tetralin and a 4-methoxybenzyl unit, was synthesized and its crystal structure was determined. To define the relationship between molecular stereochemistry ...
Nanocrystal dispersion of DK-I-56–1, a poorly soluble pyrazoloquinolinone positive modulator of α6 GABAA receptors: Formulation approach toward improved in vivo performance
(Elsevier, 2020)
DK-I-56–1 (7‑methoxy‑2-(4‑methoxy‑d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one), a recently developed deuterated pyrazoloquinolinone, has been recognized as a lead candidate for treatment of various neuropsychiatric ...
Bisaurones-enzymatic production and biological evaluation
(Royal Society of Chemistry, 2020)
The Trametes versicolor laccase catalyzed oxidation of chalcone butein afforded four dimers of aurone sulfuretin (i.e. two regioisomeric pairs of diasteromers, 1-4) as the major products. The formation of the dimers was ...
Synthesis, characterization and SAR studies of bis(imino)pyridines as antioxidants, acetylcholinesterase inhibitors and antimicrobial agents
(Elsevier, 2020)
In this study we synthesized a series of sixteen bis(imino)pyridines (BIPs) starting from 2,6-diaminopyridine and various aromatic aldehydes, and evaluated their antioxidant, antibacterial, antifungal and acetylcholinesterase ...
Role of aromatic amino acids in amyloid self-assembly
(Elsevier, 2020)
Amyloids are proteins of a cross-β structure found as deposits in several diseases and also in normal tissues (nails, spider net, silk). Aromatic amino acids are frequently found in amyloid deposits. Although they are not ...
A novel nonenzymatic hydrogen peroxide amperometric sensor based on AgNp@GNR nanocomposites modified screen-printed carbon electrode
(Elsevier, 2020)
A nonenzymatic hydrogen-peroxide sensor was developed by utilization of silver nanoparticles and graphenenanoribbons. The mentioned composite was inflicted on a screen-printed carbon electrode which provides disposable,r ...