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Poly(urethane-dimethylsiloxane) copolymers displaying a range of soft segment contents, noncytotoxic chemistry, and nonadherent properties toward endothelial cells
(Wiley-Blackwell, Hoboken, 2015)
Polyurethane copolymers based on ,-dihydroxypropyl poly(dimethylsiloxane) (PDMS) with a range of soft segment contents were prepared by two-stage polymerization, and their microstructures, thermal, thermomechanical, and ...
Autocatalator as the source of instability in the complex non-linear neuroendocrine model
(Oxford : Pergamon-Elsevier Science Ltd, 2015)
The mathematical analogy between properties of simple and complex models of non-linear reactions was used to determine reaction steps in the complex model, necessary to generate instability region and appropriate type of ...
Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts
(Elsevier, 2015)
Experimental results of non-thermal plasma (NTP) utilization for degradation of 4-chlorphenol (4CP) with screening of toxicity were presented in this study. Degradation of 4CP was tested in the presence of homogeneous ...
Electrochemical and Crystallographic Aspects of Lead Granular Growth
(Springer, New York, 2015)
Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, ...
Phenolic Compounds from Atriplex littoralis and Their Radiation-Mitigating Activity
(American Chemical Society (ACS), 2015)
From the aerial parts of Atriplex littoralis, three new flavonoid glycosides named atriplexins I-III (1-3), a known flavonoid glycoside, spinacetin 3-O-beta-D-glucopyranoside (4), arbutin (5), and 4-hydroxybenzyl-beta-D- ...
Origin of Fluorine/Sulfur Gauche Effect of beta-Fluorinated Thiol, Sulfoxide, Sulfone, and Thionium Ion
(American Chemical Society (ACS), 2015)
The well-known gauche preference in FCCX systems, where X is an electronegative element from Period 2, is widely exploited in synthetic, medicinal, and material chemistry. It is rationalized on the basis of sigma(C-H)->sigma*(C-F) ...
Energy decomposition analysis of gauche preference in 2-haloethanol, 2-haloethylamine (halogen = F, Cl), their protonated forms and anti preference in 1-chloro-2-fluoroethane
(Royal Soc Chemistry, Cambridge, 2015)
2-Haloethanol and 2-haloethylamine (halogen = F, Cl) prefer gauche conformation. This preference is significantly increased upon protonation. Commonly used explanations are based on intramolecular hydrogen bonding and ...
Nature of the Water/Aromatic Parallel Alignment Interactions
(Wiley, Hoboken, 2015)
The water/aromatic parallel alignment interactions are interactions where the water molecule or one of its OH bonds is parallel to the aromatic ring plane. The calculated energies of the interactions are significant, up ...
Resistance to common organophosphate and carbamate insecticides in Aphis pomi (Hemiptera: Aphididae)
(Edp Sciences S A, Les Ulis Cedex A, 2015)
Introduction. Aphis pomi (De Geer) has developed resistance to organophosphate and carbamate insecticides, as a result of long-term application of these insecticides in conventional apple orchards. For many years, the only ...
Magnetic Anisotropy in "Scorpionate" First-Row Transition-Metal Complexes: A Theoretical Investigation
(Wiley-VCH Verlag Gmbh, Weinheim, 2015)
In this work we have analyzed in detail the magnetic anisotropy in a series of hydrotris(pyrazolyl)borate (Tp(-)) metal complexes, namely [VTpCl](+), [CrTpCl](+), [MnTpCl](+), [FeTpCl], [CoTpCl], and [NiTpCl], and their ...