Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated form...s. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.
Source:
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2015, 46, 4, 1760-1774
TY - JOUR
AU - Nikolić, Nebojša D.
AU - Ivanović, Evica
AU - Branković, Goran
AU - Lačnjevac, Uroš
AU - Stevanović, Sanja
AU - Stevanović, Jasmina
AU - Pavlović, Miomir
PY - 2015
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/1639
AB - Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.
PB - Springer, New York
T2 - Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
T1 - Electrochemical and Crystallographic Aspects of Lead Granular Growth
VL - 46
IS - 4
SP - 1760
EP - 1774
DO - 10.1007/s11663-015-0385-z
ER -
@article{
author = "Nikolić, Nebojša D. and Ivanović, Evica and Branković, Goran and Lačnjevac, Uroš and Stevanović, Sanja and Stevanović, Jasmina and Pavlović, Miomir",
year = "2015",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/1639",
abstract = "Lead granules synthesized by the potentiostatic regime of electrolysis were characterized by the scanning electron microscopy technique. Effect of the different parameters of electrolysis, such as solution composition, overpotential of electrodeposition, and quantity of the electricity, on lead granular growth has been systematically investigated. Aside from the electrochemical aspects of lead granular growth, crystallographic aspects of the obtained granules were also analyzed. In the dependence of the electrodeposition conditions, granules of various shapes were obtained. The granules, such as octahedrons and hexagons, as well as many various types of twinned particles: single-twinned, multiply-twinned, lamellar-twinned, and many other complicated shapes denoted as polyparticles, were synthesized through regulation of the parameters of electrolysis. Increasing both the concentration of Pb2+ ions and overpotential of the electrodeposition favored the formation of more complicated forms. Formation of granules of specified crystallographic characteristics was also correlated with the basic principle of metal electrocrystallization.",
publisher = "Springer, New York",
journal = "Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science",
title = "Electrochemical and Crystallographic Aspects of Lead Granular Growth",
volume = "46",
number = "4",
pages = "1760-1774",
doi = "10.1007/s11663-015-0385-z"
}
Nikolić, N. D., Ivanović, E., Branković, G., Lačnjevac, U., Stevanović, S., Stevanović, J.,& Pavlović, M. (2015). Electrochemical and Crystallographic Aspects of Lead Granular Growth.
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
Springer, New York., 46(4), 1760-1774.
https://doi.org/10.1007/s11663-015-0385-z
Nikolić ND, Ivanović E, Branković G, Lačnjevac U, Stevanović S, Stevanović J, Pavlović M. Electrochemical and Crystallographic Aspects of Lead Granular Growth. Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science. 2015;46(4):1760-1774
Nikolić Nebojša D., Ivanović Evica, Branković Goran, Lačnjevac Uroš, Stevanović Sanja, Stevanović Jasmina, Pavlović Miomir, "Electrochemical and Crystallographic Aspects of Lead Granular Growth" Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 46, no. 4 (2015):1760-1774,
https://doi.org/10.1007/s11663-015-0385-z .
