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Structural effects in electrocatalysis: oxygen reduction on platinum low index single-crystal surfaces in perchloric acid solutions
(Elsevier, 1994)
Oxygen reduction has been studied in 0.1 M HClO4 on the platinum low index surfaces, employing a hanging meniscus rotating-disk technique. A special cleaning procedure has been developed to remove impurities from the surface ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Elsevier, 2021)
Hydrated iridium oxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...
Electrochemical indication of surface reconstruction of (NO), (311) and (111) gold faces in alkaline solutions
(Elsevier, 1993)
The specific adsorption of OH- anion and the changes in the surface atomic structures of (100), (311) and (111) gold faces with charge density are discussed on the basis of cyclic voltammograms and differential capacity-potential ...
Structural effects in electrocatalysis. Oxygen reduction on the Au (100) single crystal electrode
(Elsevier, 1984)
The kinetics of O2 reduction on the Au (100) single crystal electrode have been examined in alkaline electrolytes using the rotating dise method. A comparison has been made with the Au (110) and Au (111) surfaces. The ...
Electrochemical deposition of Ni–W alloys from ammonia–citrate electrolyte
(Elsevier, 2003)
Ammonia-citrate electrolyte is one of the solutions that are used in practice for electroplating Ni-W alloys. In this contribution, a systematic effort was made to clarify some controversies about the mechanism of the ...
Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes
(Elsevier, 2019)
Briggs-Rauscher (BR) oscillatory reaction is a chemical system very sensitive to different analyte addition. Changes in oscillatory dynamics, by analyte addition, could be successfully used for the determination of analyte ...
An electrochemical illustration of the mathematical modelling of chlorine impact and acidification in electrochemical tumour treatment and its application on an agar-agar gel system
(Elsevier, 2003)
Electrochemical treatment (EchT) of tumours, which is also known as electrochemical therapy, implies that tumour tissue is treated with a direct current through the use of electrodes. This was shown earlier when the major ...