Briggs-Rauscher (BR) oscillatory reaction is a chemical system very sensitive to different analyte addition. Changes in oscillatory dynamics, by analyte addition, could be successfully used for the determination of analyte concentration, as well as for its antioxidative/antiradical activity assessment. In this work, the BR reaction is used as a system detector for distinguishing solid unsolvable materials, such as phosphate tungsten bronze (PWB) and phosphate molybdenum bronze (PMoB), obtained by thermal treatment. The addition of different masses of PWB in BR reaction decreases its oscillation time, while the addition of different masses of PMoB had no effects on the BR oscillation time. Additionally, the BR oscillation time is the linear function of added PWB mass. The mechanism of bronzes action is investigated by using pH and electric conductivity measurements, as well as inductively coupled plasma and the cyclic voltammetry measurements, and it can be ascribed to PWB better cataly...tic activity then PMoB, under BR reaction condition. This work extends the practical aspect of the BR reaction for testing solid (insoluble) materials, and opening the possibility of using oscillatory reactions in material science and catalysis, in general.
TY - JOUR
AU - Pagnacco, Maja
AU - Maksimović, Jelena
AU - Mudrinić, Tihana
AU - Mojović, Zorica
AU - Nedić, Zoran P.
PY - 2019
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/3058
AB - Briggs-Rauscher (BR) oscillatory reaction is a chemical system very sensitive to different analyte addition. Changes in oscillatory dynamics, by analyte addition, could be successfully used for the determination of analyte concentration, as well as for its antioxidative/antiradical activity assessment. In this work, the BR reaction is used as a system detector for distinguishing solid unsolvable materials, such as phosphate tungsten bronze (PWB) and phosphate molybdenum bronze (PMoB), obtained by thermal treatment. The addition of different masses of PWB in BR reaction decreases its oscillation time, while the addition of different masses of PMoB had no effects on the BR oscillation time. Additionally, the BR oscillation time is the linear function of added PWB mass. The mechanism of bronzes action is investigated by using pH and electric conductivity measurements, as well as inductively coupled plasma and the cyclic voltammetry measurements, and it can be ascribed to PWB better catalytic activity then PMoB, under BR reaction condition. This work extends the practical aspect of the BR reaction for testing solid (insoluble) materials, and opening the possibility of using oscillatory reactions in material science and catalysis, in general.
PB - Elsevier
T2 - Journal of Electroanalytical Chemistry
T1 - Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes
VL - 849
SP - 113369
DO - 10.1016/j.jelechem.2019.113369
ER -
@article{
author = "Pagnacco, Maja and Maksimović, Jelena and Mudrinić, Tihana and Mojović, Zorica and Nedić, Zoran P.",
year = "2019",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3058",
abstract = "Briggs-Rauscher (BR) oscillatory reaction is a chemical system very sensitive to different analyte addition. Changes in oscillatory dynamics, by analyte addition, could be successfully used for the determination of analyte concentration, as well as for its antioxidative/antiradical activity assessment. In this work, the BR reaction is used as a system detector for distinguishing solid unsolvable materials, such as phosphate tungsten bronze (PWB) and phosphate molybdenum bronze (PMoB), obtained by thermal treatment. The addition of different masses of PWB in BR reaction decreases its oscillation time, while the addition of different masses of PMoB had no effects on the BR oscillation time. Additionally, the BR oscillation time is the linear function of added PWB mass. The mechanism of bronzes action is investigated by using pH and electric conductivity measurements, as well as inductively coupled plasma and the cyclic voltammetry measurements, and it can be ascribed to PWB better catalytic activity then PMoB, under BR reaction condition. This work extends the practical aspect of the BR reaction for testing solid (insoluble) materials, and opening the possibility of using oscillatory reactions in material science and catalysis, in general.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes",
volume = "849",
pages = "113369",
doi = "10.1016/j.jelechem.2019.113369"
}
Pagnacco M, Maksimović J, Mudrinić T, Mojović Z, Nedić ZP. Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes. Journal of Electroanalytical Chemistry. 2019;849:113369
Pagnacco, M., Maksimović, J., Mudrinić, T., Mojović, Z.,& Nedić, Z. P. (2019). Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes.
Journal of Electroanalytical ChemistryElsevier., 849, 113369.
https://doi.org/10.1016/j.jelechem.2019.113369
Pagnacco Maja, Maksimović Jelena, Mudrinić Tihana, Mojović Zorica, Nedić Zoran P., "Briggs-Rauscher reaction as a novel electrochemical detector for phosphate tungsten and phosphate molybdenum bronzes" 849 (2019):113369,
https://doi.org/10.1016/j.jelechem.2019.113369 .
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