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Cyclisation of alkoxy radicals. A semiempirical MNDO-PM3 study
(Royal Society of Chemistry, 1994)
The reactivity of the butoxy and 3-methylcyclohexyl radicals, as representatives of alkoxy radicals, was studied by MNDO-PM3 semiempirical MO method. In both cases it was found that the oxy radical underwent easily 1,5-H ...
Formation of allenes by reaction of 1,4-dibromobut-2-ene with dialkyl ketones and base
(Royal Society of Chemistry, 1991)
By reaction of 1,4-dibromo-(E)-but-2-ene with dialkyl ketones and sodium hydride the allenic ketones 3 were obtained as the main products, in addition to the symmetrical unsaturated 1,8-diketones 4.
The Influence of Sintering Conditions on the Microstructure and Magnetic Properties of Sintered SmCo5 Magnets
(Springer Science and Business Media LLC, 1999)
Since the magnetic features of the magnet of Sm-Co type are in direct connection with microstructure, it is indispensable to achieve, in the procedure of synthesis of these materials, the microstructure which ensures the ...
Non-sensitized photooxygenation of some steroidal isoxazolidines
(Pergamon press, 1991)
UV irradiation of the steroidal isoxazolidines 2a, 2b, and 2c in various solvents in the presence of molecular oxygen, results in oxidative cleavage of the epoxyimino bridge to give several products; the N-unsubstituted ...
Semisynthesis of Taxol (R): an improved procedure far the isolation of 10-deacetylbaccatin III
(Serbian Chemical Soc, Belgrade, 1999)
From the needles of domestic yew, (Taxus baccata), 10-deacetylbaccatin III (10-DAB) call be isolated in quantities of up to 297 mg per kg of fresh needles. Additional quantities of 10-DAB call be obtained from the extract ...
Free radical ring expansion and subsequent reactions of intermediary carbon radicals
(Serbian Chemical Society, 1996)
Alkyl radicals, derived from ethyl 1-(bromoalkyl)-2-oxocyclo-alkanecarboxylates or from the corresponding thiohydroxamic esters, undergo a ring expansion reaction and subsequent intermoleculaar addition/elimination reactions. ...
Chaerophyllum coloratum L.: Essential oils of ripe fruits and umbels
(Taylor & Francis, 1995)
Essential oils of ripe fruits and umbels of Chaerophyllum coloraturn L. (Apiaceae) were found by GC and GC/MS to contain very high percentage of (E)-Pfarnesene (79.21% and 68.40% respectively). © 1995 Allured Publishing Corp.
Hexaene H-85, a hexaene macrolide complex
(Switzerland : Springer Nature, 1991)
The hexaene macrolide antibiotics constitute the smallest group of the polyenes (12 ~ 15). Mediocidin, endomycin, hexaene H-85 and hexafungin each have a significant tetraene spectrum in addition to a hexaene spectrum ...
The influence of milling conditions on the properties of powder of intermetallic compound SmCo5 / Uticaj uslova mlevenja na svojstva intermetalnog jedinjenja SmCo5
(Kiev, Ukraine : Nauka dumka, 1996)
The dependence of magnetic properties of sintered magnetic materials, demands the quantification of the milling conditions. In this paper the part of the results of the investigation of the phase of milling of SmCo5 powder ...
Electrochemical and Surface Characterization of pH Sensor Based on Bisulfate-Doped Poly(pyrrole)
(Wiley, 1997)
Pyrrole was electrochemically polymerized on glassy carbon support in NaHSO4 solutions under different conditions (method applied, concentration of monomer, concentration of the main solution, thickness of the film). These ...