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Study on the assessment of humification processes during biodegradation of heavy residual fuel oil
(Elsevier, 2021)
The aim of this study was to investigate the creation of humic substances during biodegradation of heavy residual fuel oil, because there are indications that substances similar to humic substances are generated during ...
Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
(Wiley, 2019)
α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until ...
Organocatalytic, Organic Oxidant Promoted, Enamine C−H Oxidation/Cyclopropanation Reaction
(Wiley, 2021)
Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions ...
Toxicity investigation of CeO2 nanoparticles coated with glucose and exopolysaccharides levan and pullulan on the bacterium Vibrio fischeri and aquatic organisms Daphnia magna and Danio rerio
(Elsevier, 2021)
Cerium oxide nanoparticles (nCeO2) have widespread applications, but they can be hazardous to the environment. Some reports indicate the toxic effect of nCeO2 on tested animals, but literature data are mainly contradictory. ...
Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction
(Springer Science and Business Media LLC, 2020)
The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the ...
Carbohydrate – Protein aromatic ring interactions beyond CH/π interactions: A Protein Data Bank survey and quantum chemical calculations
(Elsevier, 2020)
The geometries of the contacts between monosaccharides and aromatic rings of amino acids found in X-ray crystallography structures, in the Protein Data Bank (PDB), were analyzed, while the energies of the interactions were ...
Activation of Oxone® with plasma deposited mixed cobalt and alumina oxide for the dye degradation
(Elsevier, 2020)
The aim of this work is to examine the possibility of the formation of cobalt doped Al2O3 coatings on aluminum substrate by plasma electrolytic oxidation process (PEO) and application of the obtained material as catalyst ...
Polyurethane networks based on polycaprolactone and hyperbranched polyester: Structural, thermal and mechanical investigation
(Elsevier, 2019)
A series of environmentally friendly polyurethane (PU) networks based on polycaprolactone as soft segment (SS) and Boltorn® aliphatic hyperbranched polyester of the second pseudo generation as crosslinking agent was prepared ...
Characterisation of the binding of dihydro-alpha-lipoic acid to fibrinogen and the effects on fibrinogen oxidation and fibrin formation
(Elsevier, 2020)
A reduced form of the alpha-lipoic acid, dihydro-alpha-lipoic acid (DHLA) is a potent, naturally occurring antioxidant which can be consumed as food constituent or as supplement at doses up to 600 mg/day. DHLA has inhibitory ...
Role of aromatic amino acids in amyloid self-assembly
(Elsevier, 2020)
Amyloids are proteins of a cross-β structure found as deposits in several diseases and also in normal tissues (nails, spider net, silk). Aromatic amino acids are frequently found in amyloid deposits. Although they are not ...