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The solvent effect on the conformational equilibrium of 1,3-dichloro-5-methylcylclohexane
(Elsevier, 1985)
The conformational equilibrium has been measured for r-1,c-3-dichloro-t-5-methylcyclohexane(2) in six solvents from the 500 MHz and 400 MHz 1H NMR spectra. The room-temperature and low-temperature C1H couplings are used ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part I. Theory
(Elsevier, 1987)
A general scheme of oxygen reduction is given and analysis of the disk-ring measurements is performed. Expressions for the diagnostic criteria for such a scheme have been derived and their implications are discussed. The ...
Optical and electrochemical study of cation adsorption on oxide layers on gold and platinum electrodes
(Elsevier, 1985)
It has been shown that the adsorption of Bi3+ and Tl+ cations occurs on oxide layers of Au and Pt electrodes in acid solutions. The initial stages of oxide formation and reduction are inhibited. The effect increases with ...
Circular dichroism of some cyclopropane ring containing 1,3-cyclo-5,10-seco-steroidal ketones
(Elsevier, 1982)
Circular dichroism of the rearranged keto steroids 3 and 4, containing a condensed three and nine-membered ring system, shows that the conformation of the nine-membered ring is the same in solution as in the crystal; ...
Synthesis, structure, and reactions of secosteroids containing a medium-sized ring. Part 17. Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 3-tosylates
(Royal Society of Chemistry, 1980)
Kinetic measurements of the solvolysis of (Z)-3α- and (Z)-3β-, and (E)-3α- and (E)-3β-tosyloxy-5,10-secocholest-1(10)-en-5-ones in buffered aqueous acetone (90 : 10 v/v) reveal that the (Z)-3α-, (E)-3α-, and (E)-3β-tosylates ...
Treatment of electrostatic effects within the molecular mechanics method. 1
(American Chemical Society (ACS), 1983)
A model of intramolecular electrostatic effects (called the induced dipole moment and energy (IDME) method) was derived by extending the method originally proposed by Del Re for calculating dipole moments and charge ...
Mass spectrometric analysis of the carbon content in the plasma of a horizontal electric arc burning in a graphite tube / Massenspektrometrische Analyse des Kohlenstoffgehaltes im Plasma einer horizontalen Bogenentladung in einem Graphitrohr
(Springer Science and Business Media LLC, 1981)
The carbon content in the plasma of a horizontal electric arc in a graphite tube, burning in air, in the presence of an inhomogeneous magnetic field has been determined. The modifications with one and two rotating arc ...
Free-radical oxidative transformations of androst-4-ene-3β,9α,17β-triol 3,17-diacetate
(Tetrahedron, 1988)
The oxidation of androst-4-ene-3β,9α,17β-triol 3,17-diacetate (2) with lead tetraacetate resulted mainly In β-fragmentation of the C(9)-C(10) bond to give a mixture of 10α- and 10β-acetoxy-Δ4-unsaturated 9,10-seco-steroidal ...
The effect of anions on the electrochemical behaviour of aluminium
(Elsevier, 1983)
Aluminum has been known to exhibit widely different electrochemical properties in different aqueous electrolytes. Thus, OH- ions in strongly alkaline solutions reveal its strong affinity to water by dissolving its protective ...
Structural effects in electrocatalysis: oxidation of formic acid and hydrogen adsorption on platinum single-crystal stepped surfaces
(Elsevier, 1986)
The oxidation of formic acid and hydrogen adsorption have been measured on platinum single-crystal stepped surfaces with five orientations. A pronounced structural sensitivity of both reactions has been found. They show a ...