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Circular dichroism of some cyclopropane ring containing 1,3-cyclo-5,10-seco-steroidal ketones

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1982
Authors
Lorenc, Ljubinka
Dabović, Milan
Juranić, Ivan
Mihailović, Mihailo Lj.
Snatzke, G
Tóth, G
Article (Published version)
,
Elsevier
Metadata
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Abstract
Circular dichroism of the rearranged keto steroids 3 and 4, containing a condensed three and nine-membered ring system, shows that the conformation of the nine-membered ring is the same in solution as in the crystal; reduction of the kto group does not change this situation. CD also indicates that epimerization at C(5) in the pair 7 8 and the pair 11 12 leaves the cyclononanone ring conformation unchanged. © 1982.
Source:
Tetrahedron, 1982, 38, 21, 3163-3168
Publisher:
  • Elsevier
Projects:
  • Serbian Research Fund
  • Serbian Academy of Sciences and Arts
  • Deutsche Furschungsgemeinschaft
  • Funds der Chemischen Industrie
  • Alexander von Humboldt Foundation (Germany)

DOI: 10.1016/0040-4020(82)80053-7

ISSN: 0040-4020

Scopus: 2-s2.0-49049137738
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/2696
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IHTM

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