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New approach to the aromatization of ring B in 19-norsteroids and to the synthesis of equilenin-type compounds
(Royal Society of Chemistry, 1978)
When 7α-acetoxy-3,3 : 17,17-bis(ethylenedioxy)-5,10-epoxy-5β, 10β-oestran-6-one (2), formed by lead tetra-acetate acetoxylation of the parent compound (1), is heated with alkali, it undergoes ring B aromatization to give ...
The critical overpotential for zinc dendrite formation
(Kluwer Academic Publishers, 1979)
The critical overpotential for zinc dendrite growth is determined as 173 mV by the method described by Popov et al. [1]. It was shown that this procedure can be applied successfully to metal deposition processes when there ...
The polarographic behavior of metal ions in molten LiNO3-KNO3 eutectic in presence of complexon III
(Elsevier, 1973)
The possibility of using complexon III as a complexing substance in the polarography of salt metls (LiNO3-KNO3 eutectic) has been investigated. Complexon III was found to form complexes with Cd, Pb, Ni and Zn ions in the ...
Electric conductivity and viscosity of 1,4-benzenediol and hydroxybenzene solutions in concentrated sulphuric acid
(Elsevier, 1974)
Many authors have dealt with the formation of the complexes of 1,4-benzenediol and some metals in concentrated sulphuric acid. However, no data can be found in the literature either on the reaction of 1,4-benzenediol with ...
Rotating two-ring electrodes as a tool for electrochemical investigations of gas-evolving reactions
(Elsevier, 1972)
It is shown that two concentric ring electrodes located on a rotating disc surface can be used as an instrument for chemical and electrochemical analysis of gas-evolving reactions up to rates of gas evolution from the inner ...
Criteria for the determination of the stereochemistry of steroidal indolizidines
(Elsevier, 1974)
E/F-Indolizidine steroids, which represent a structural unit of Solanum alkaloids, have been synthesized and used to evaluate criteria (IR—Bohlmann bands,1a-c —hydrogenbond,2a-e NMR,3a-c mass spectra,4 kinetic studies of ...
Electron ground state in the semiconductor inversion layer and low frequency MIS capacitance
(Elsevier, 1976)
By varying the total energy and electrostatic energy functionals which represent an approximate self-consistent solution of Schrödinger's and Poisson's equation, the ground state of electrons is determined in a semiconductor ...
Complex plane analysis in electrode modulated specular reflectance studies
(AIP Publishing, 1973)
Optical specular reflection is finding extensive use for studies of electrode-electrolyte interfaces. The purpose of this Note is to call attention to the use of complex plane analysis to obtain kinetic information concerning ...
Study of the reactions of hexanitrocobaltates(III) with amino acids. VII. Geometrical isomerism and absolute configuration of dinitrobis(aminoacidato)cobaltate(III) ions
(Elsevier, 1971)
Dinitrobis(aminoacidato)cobaltate(III) salts with L-α-aminobutyric acid, aminoisobutyric acid, L-valine, L-norvaline, L-leucine, L-norleucine, and L-isoleucine were prepared and resolved into optical isomers. We report ...
Photochemically induced oxidation of some steroidal isoxazolidines by molecular oxygen
(Royal Society of Chemistry, 1977)
U.v. irradiation of the steroidal isoxazolidines 5α,10α-imino- oxy-5(10 → 1βH)abeo-5α-cholestan-3β-olacetate (1a) and the corresponding N-methyl and N-acetyl derivatives (1b) and (1c) in various solvents in the presence ...