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ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Oxygen reduction on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in alkaline solution. A rotating disc-ring study
(Elsevier, 1992)
The kinetics of oxygen reduction have been studied on Au (100) and vicinal Au (910) and Au (11, 1, 1) faces in 0.1 M NaOH by a rotating disc-ring method. A very high activity of these surfaces for O2 reduction was demonstrated. ...
The roles of the ruthenium concentration profile, the stabilizing component and the substrate on the stability of oxide coatings
(Elsevier, 1992)
Electrocatalytic oxide coatings with variable concentration profiles of RuO2 as the active component were obtained through a combination of separately applied layers of RuO2, TiO2, IrO2, RuO2 + TiO2 and RuO2 + IrO2 on ...
Electrochemical indication of surface reconstruction of (NO), (311) and (111) gold faces in alkaline solutions
(Elsevier, 1993)
The specific adsorption of OH- anion and the changes in the surface atomic structures of (100), (311) and (111) gold faces with charge density are discussed on the basis of cyclic voltammograms and differential capacity-potential ...
Structural effects in electrocatalysis. Oxidation of D-glucose on single crystal platinum electrodes in alkaline solution
(Elsevier, 1991)
Electrochemical oxidation of D-glucose has been studied in 0.1 M NaOH on single crystal platinum electrodes with thirteen different orientations. The reaction rate depends strongly on the crystallographic orientation of ...
Electrosorption of hydrogen and sulfuric acid anions on single crystal platinum stepped surfaces. Part II. The [110] zone
(Elsevier, 1991)
Hydrogen and bisulphate adsorption at platinum single crystal surfaces from the [ITO] zone is
strongly dependent on the crystallographic orientation of the electrode surface, which is similar to that
found earlier for ...
Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
(Elsevier, 1997)
Electrochemical reduction of carbon dioxide is still of great interest in the fields of theoretical and applied electrochemistry. Ruthenium is one of the metals with an intermediate hydrogen evolution overpotential which ...
Structural effects in electrocatalysis. Ethylene glycol oxidation on platinum single-crystal surfaces
(Elsevier, 1991)
The oxidation of ethylene glycol (EG) has been studied on platinum single-crystal surfaces in 0.1 M NaOH. A strong structural dependence of the reaction kinetics was found for all 12 single-crystal orientations investigated. ...
Anodic oxidation of small organic molecules on silver modified glassy carbon electrodes
(Elsevier, 1991)
Small organic molecules (HCOOH, C,H,(OH),, CH,OH, CH,O, etc.) have become more interesting with the possibility of their application in fuel cells. Therefore, the anodic oxidation of such molecules has been studied on a ...