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Selective borane reductions of progesterone
(Elsevier, 1967)
A number of selective reductions using borane end metal borohydrides has been described. In our studies of hydroboration of steroid conjugated ketones under different conditions and with different solvents we have found ...
An improved preparation of 3-α-acetoxy-11,20-diketo-(5β)-pregnane, the key intermediate in the synthesis of 11-oxygenated corticosteroids
(Elsevier, 1967)
Although microbiological methods of introducing oxygen at C-11 of the steroid molecule are effective, it is obvious that purely synthetic way of producing cortisone and its analogs from bile acids or hecogenin have never ...
Preparation and photolysis of 2-diazo-6-oximino- and 2,6-bisdiazo-4-tert. Butylcyclohexanone
(Elsevier, 1967)
Reaction mechanism of diazoketone photolysie is assumed
to involve the formation ofd-keto-carbene intermediates, final products being dependent on the molecular structure and
reaction medium. Numerous example8 of ...
The structure of glycerol acetals
(Elsevier, 1967)
It is known that the condensation of with polyols yields cyclic acetals. Thus, carbonyl compounds it is known that by condensation of benzaldehyde with glycerol, a mixture of 2-phenyl-5-hydroxy-1,3-dioxane and 2-phenyl-4 ...
The conversion of unbranched primary alkyl and arylalkyl amines to nitriles by means of lead tetraacetate
(Elsevier, 1965)
The only amino compounds oxidized so far with lead tetroacetate were primary aromatic amines, which gave mainly the corresponding azo compounds(1), and some tertiary aryldialkyl amines, which in glacial acetic acid in the ...
Reactions with lead tetraacetate. I. Oxidation of saturated aliphatic alcohols. Part 1
(Elsevier, 1963)
It was recently shown that various steroid alcohols could react with lead tetraacetate in non-polar solvents to give tetrahydrofuran and tetrahydropyran derivatives. cyclization occurring when the position of and the ...