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Resolving the origin of the multimode Jahn-Teller effect in metallophthalocyanines
(Royal Soc Chemistry, Cambridge, 2016)
A detailed Density Functional Theory (DFT) analysis was performed in order to study the multimode Jahn-Teller (JT) problem in the electronic ground state of manganese phthalocyanine (MnPc). A comparison with the magnesium ...
Study of the Properties of Urethane-Siloxane Copolymers Based on Poly(propylene oxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) Soft Segments
(American Chemical Society (ACS), 2016)
Segmented polyurethanes (PURs) were prepared from alpha,omega-dihydroxypoly(propylene oxide)-b-poly-(dimethylsiloxane)-b-poly(propyleneoxide) (PPO-PDMS) as the soft segment and 4,4'-diphenylmethane diisocyanate and ...
Excited States of Pt(PF3)(4) and Their Role in Focused Electron Beam Nanofabrication
(American Chemical Society (ACS), 2016)
Electron induced chemistry of metal-containing precursor molecules is central in focused electron beam induced deposition (FEBID). While some elementary processes leading to precursor decomposition were quantitatively ...
Smectite-chitosan-based electrodes in electrochemical detection of phenol and its derivatives
(Elsevier, 2016)
In this paper smectite-chitosan bionanocomposite (SM-C) based on smectite (SM) from Crni Timok (Black Timok) basin, Serbia, was synthesized and characterized using chemical analysis, XRD and FTIR. The SM-C obtained was ...
Oxidative stress and DNA damage in horses naturally infected with Theileria equi
(Elsevier Sci Ltd, Oxford, 2016)
The aim of this study was to determine the concentrations of oxidative stress parameters and DNA damage in horses infected by Theileria equi. Initial screening of 110 horses with duplex PCR enabled the selection of 30 ...
Photocatalytic Ability of Visible-Light-Responsive TiO2 Nanoparticles
(American Chemical Society (ACS), 2016)
The synthetic procedures for preparation of free-standing and attached to polymer support surface modified TiO2 nanoparticles (NPs) with absorption extended into the visible spectral region due to charge transfer complex ...
Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution
(Oxford : Pergamon-Elsevier Science Ltd, 2016)
Bimetallic electrodes prepared by Rh nanoislands spontaneously deposited on polycrystalline palladium, Pd(poly), at submonolayer coverage were explored for ethanol oxidation in alkaline media. Characterization of obtained ...
Mass transfer and concentration boundary layer in a particulate fluidized bed
(Elsevier, 2016)
The aim of this study was to analyze the concentration boundary layer for a comprehensive description of the mass transfer in systems with fluidized particles. Mass transfer from the wall of the column to the fluid in the ...
Ru layers electrodeposited onto highly stable Ti2AlC substrates as cathodes for hydrogen evolution in sulfuric acid solutions
(Elsevier, 2016)
In this work, the hydrogen evolution reaction (HER) was studied on Ru coated Ti2AlC electrodes in 1.0 mol dm(-3) H2SO4 at 25 degrees C. Ti2AlC was found to be a highly stable substrate in sulfuric acid solutions due to the ...
Heracleum orphanidis: chemical characterisation, and comparative evaluation of antioxidant and antimicrobial activities with specific interest in the influence on Pseudomonas aeruginosa PAO1
(Royal Soc Chemistry, Cambridge, 2016)
GC-FID and GC-MS were used to determine the chemical composition of the essential oil of the aerial parts of Heracleum orphanidis Boiss. Also, the HPLC-DAD/ESI-ToF-MS profile of the methanol extracts of aerial parts and ...