Bimetallic electrodes prepared by Rh nanoislands spontaneously deposited on polycrystalline palladium, Pd(poly), at submonolayer coverage were explored for ethanol oxidation in alkaline media. Characterization of obtained Rh/Pd(poly) nanostructures was performed ex situ by AFM imaging and by X-ray photoelectron spectroscopy. In situ characterization of the obtained electrodes and subsequent ethanol oxidation measurements were performed by cyclic voltammetry in 0.1 M KOH. Palladium surface with 50% Rh coverage exhibited the highest catalytic activity for ethanol oxidation in alkaline media. The origin of the enhanced catalysis of Rh/Pd(poly) surfaces with respect to bare Pd was explained by the electronic effect. Possible reaction pathways for ethanol oxidation were discussed taking into account the activity of obtained bimetallic electrodes for the oxidation of CO and acetaldehyde, as the most probable reaction intermediates.
TY - JOUR
AU - Maksic, A
AU - Smiljanić, Milutin
AU - Miljanic, S
AU - Rakočević, Zlatko Lj.
AU - Štrbac, Svetlana
PY - 2016
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/1852
AB - Bimetallic electrodes prepared by Rh nanoislands spontaneously deposited on polycrystalline palladium, Pd(poly), at submonolayer coverage were explored for ethanol oxidation in alkaline media. Characterization of obtained Rh/Pd(poly) nanostructures was performed ex situ by AFM imaging and by X-ray photoelectron spectroscopy. In situ characterization of the obtained electrodes and subsequent ethanol oxidation measurements were performed by cyclic voltammetry in 0.1 M KOH. Palladium surface with 50% Rh coverage exhibited the highest catalytic activity for ethanol oxidation in alkaline media. The origin of the enhanced catalysis of Rh/Pd(poly) surfaces with respect to bare Pd was explained by the electronic effect. Possible reaction pathways for ethanol oxidation were discussed taking into account the activity of obtained bimetallic electrodes for the oxidation of CO and acetaldehyde, as the most probable reaction intermediates.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Electrochimica Acta
T1 - Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution
VL - 209
SP - 323
EP - 331
DO - 10.1016/j.electacta.2016.05.096
ER -
@article{
author = "Maksic, A and Smiljanić, Milutin and Miljanic, S and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2016",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/1852",
abstract = "Bimetallic electrodes prepared by Rh nanoislands spontaneously deposited on polycrystalline palladium, Pd(poly), at submonolayer coverage were explored for ethanol oxidation in alkaline media. Characterization of obtained Rh/Pd(poly) nanostructures was performed ex situ by AFM imaging and by X-ray photoelectron spectroscopy. In situ characterization of the obtained electrodes and subsequent ethanol oxidation measurements were performed by cyclic voltammetry in 0.1 M KOH. Palladium surface with 50% Rh coverage exhibited the highest catalytic activity for ethanol oxidation in alkaline media. The origin of the enhanced catalysis of Rh/Pd(poly) surfaces with respect to bare Pd was explained by the electronic effect. Possible reaction pathways for ethanol oxidation were discussed taking into account the activity of obtained bimetallic electrodes for the oxidation of CO and acetaldehyde, as the most probable reaction intermediates.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution",
volume = "209",
pages = "323-331",
doi = "10.1016/j.electacta.2016.05.096"
}
Maksic A, Smiljanić M, Miljanic S, Rakočević ZL, Štrbac S. Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution. Electrochimica Acta. 2016;209:323-331
Maksic, A., Smiljanić, M., Miljanic, S., Rakočević, Z. Lj.,& Štrbac, S. (2016). Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution.
Electrochimica ActaPergamon-Elsevier Science Ltd, Oxford., 209, 323-331.
https://doi.org/10.1016/j.electacta.2016.05.096
Maksic A, Smiljanić Milutin, Miljanic S, Rakočević Zlatko Lj., Štrbac Svetlana, "Ethanol Oxidation on Rh/Pd(poly) in Alkaline Solution" 209 (2016):323-331,
https://doi.org/10.1016/j.electacta.2016.05.096 .
