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Neuroprotective arylpiperazine dopaminergic/serotonergic ligands suppress experimental autoimmune encephalomyelitis in rats
(Wiley, Hoboken, 2015)
Arylpiperazine-based dopaminergic/serotonergic ligands exert neuroprotective activity. We examined the effect of arylpiperazine D-2/5-HT1A ligands, N-{4-[2-(4-phenyl-piperazin-1-yl)-ethyl}-phenyl]- picolinamide (6a) and ...
Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity
(Wiley-V C H Verlag Gmbh, Weinheim, 2015)
A series of heteropentanuclear oxalate-bridged Ru(NO)-Ln (4d-4f) metal complexes of the general formula (nBu(4)N)(5)[Ln{RuCl3(-ox)(NO)}(4)], where Ln=Y (2), Gd (3), Tb (4), Dy (5) and ox=oxalate anion, were obtained by ...
Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen
(Royal Soc Chemistry, Cambridge, 2015)
Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in ...
Fulleropyrrolidines derived from dioxa- and trioxaalkyl-tethered diglycines
(Royal Soc Chemistry, Cambridge, 2015)
Two different alpha,omega-diglicynes linked by linear polyoxaalkyl chains in the presence of formaldehyde underwent Prato reaction to the fullerene C-60. The shorter linker templated formation of only cis-bisadducts, while ...
Fulleropeptide esters as potential self-assembled antioxidants
(Beilstein-Institut, Frankfurt Am Main, 2015)
The potential use of amphiphilic fullerene derivatives as a bionanomaterial was investigated by cyclic voltammetry (CV), scanning electron microscopy (SEM), and the ferrous ion oxidation-xylenol orange (FOX) method. Despite ...
Anion-pi interactions in protein-porphyrin complexes
(Royal Soc Chemistry, Cambridge, 2015)
In this work, we have analyzed the influence of anion-pi interactions on the stability of high resolution protein-porphyrin complex crystal structures. The anion-pi interactions are distance and orientation dependent. ...
Expression of cellobiose dehydrogenase from Phanerochaete chrysosporium in yeast Saccharomyces cerevisiae for directed evolution
(Wiley-Blackwell, Hoboken, 2015)
Effect of surface modified TiO2 nanoparticles on thermal, barrier and mechanical properties of long oil alkyd resin-based coatings
(Budapest University of Technology, 2015)
Novel soy alkyd-based nanocomposites (NCs) were prepared using TiO2 nanoparticles (NPs) surface modified with different gallates, and for the first time with imine obtained from 3,4-dihydroxybenzaldehyde and oleylamine ...
Energy decomposition analysis of gauche preference in 2-haloethanol, 2-haloethylamine (halogen = F, Cl), their protonated forms and anti preference in 1-chloro-2-fluoroethane
(Royal Soc Chemistry, Cambridge, 2015)
2-Haloethanol and 2-haloethylamine (halogen = F, Cl) prefer gauche conformation. This preference is significantly increased upon protonation. Commonly used explanations are based on intramolecular hydrogen bonding and ...
A theoretical study on borenium ion affinities toward ammonia, formaldehyde and chloride anions
(Royal Soc Chemistry, Cambridge, 2015)
Various borenium ion affinities toward three ligands (L' = NH3, HCHO and Cl-) have been evaluated by DFT calculations in the gas-phase and in solvent (CH2Cl2). The gas-phase results have been rationalized on the basis of ...