CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrilic)
    • Serbian (Latin)
  • Login
View Item 
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Fulleropyrrolidines derived from dioxa- and trioxaalkyl-tethered diglycines

Thumbnail
2015
1827.pdf (1.034Mb)
Authors
Kop, Tatjana
Bjelaković, Mira
Dordevic, Jelena
Zekic, Andrijana
Milić, Dragana
Article (Published version)
Metadata
Show full item record
Abstract
Two different alpha,omega-diglicynes linked by linear polyoxaalkyl chains in the presence of formaldehyde underwent Prato reaction to the fullerene C-60. The shorter linker templated formation of only cis-bisadducts, while the longer one afforded a mixture of four bisadducts (all cis and the equatorial) and difullerene dumbbell compound. Their structures were confirmed by the extensive analysis of the spectral data and molecular symmetry, as well. All compounds expressed an ability to arrange into hierarchically ordered supramolecular aggregates, the form of which depended both on the addition pattern and the spacer structure. The attenuated electron-accepting affinity, examined by cyclic voltammetry was in agreement with diminished delocalization of the pi-electronic system. In addition, all compounds exerted a notable radical scavenging activity.
Source:
RSC Advances, 2015, 5, 115, 94599-94606
Publisher:
  • Royal Soc Chemistry, Cambridge
Projects:
  • Design, synthesis and investigations of fullerene based nanomolecular machines (RS-172002)

DOI: 10.1039/c5ra17392b

ISSN: 2046-2069

WoS: 000364906600010

Scopus: 2-s2.0-84946945297
[ Google Scholar ]
1
1
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/1829
Collections
  • Radovi istraživača / Researchers' publications
Institution
IHTM

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutionsAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB