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Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within ...
The effect of hydrogen codeposition on the morphology of copper electrodeposits. 1. The concept of effective overpotential
(Elsevier, 2006)
The effect of hydrogen codeposition on the morphology of copper electrodeposits was studied. The dependences of the overall current and the volume of evolved hydrogen on the quantity of electricity used were plotted and ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Elsevier, 2021)
Hydrated iridium oxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
Catalytic effects of monolayers of metals deposited at underpotentials: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was recently shown that the monolayers of some metals deposited at underpotentials
on gold can substantially increase the rates of some redox reactions 1 , and the
rate of oxygen reduction:. This note reports the ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Electrochemical indication of surface reconstruction of (NO), (311) and (111) gold faces in alkaline solutions
(Elsevier, 1993)
The specific adsorption of OH- anion and the changes in the surface atomic structures of (100), (311) and (111) gold faces with charge density are discussed on the basis of cyclic voltammograms and differential capacity-potential ...
The roles of the ruthenium concentration profile, the stabilizing component and the substrate on the stability of oxide coatings
(Elsevier, 1992)
Electrocatalytic oxide coatings with variable concentration profiles of RuO2 as the active component were obtained through a combination of separately applied layers of RuO2, TiO2, IrO2, RuO2 + TiO2 and RuO2 + IrO2 on ...
Anodic deposition of colloidal gold
(Elsevier, 1984)
Colloidal gold solutions were prepared following classical recipes. When electrolysed between graphite electrodes, gold was found to deposit at the anode. The rate of deposition was dependent on the anode potential, on the ...