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The electrocatalytic properties of the oxides of noble metals in the electro-oxidation of some organic molecules
(Elsevier, 1997)
The electro-oxidation of organic compounds on gold and silver electrodes can occur either in a potential range more negative than that where the metal oxides are formed or within the more positive range where the surface ...
The electro-oxidation of glycerol on the gold(100)-oriented single-crystal surface and poly crystalline surface in 0.1 M NaOH
(Elsevier, 1991)
Studies of chemical and electrochemical reactions at well-defined surfaces provide additional data on surface reactivity and guidelines for the understanding and design of catalytic materials. In this work, the oxidation ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Kinetic and mechanistic study of methanol oxidation on a Pt(111) surface in alkaline media
(Elsevier, 1996)
A comparative study of methanol oxidation on a Pt(111) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. The surface activity was directly correlated to the OHad species ...
Structural effects in electrocatalysis: oxygen reduction on platinum low index single-crystal surfaces in perchloric acid solutions
(Elsevier, 1994)
Oxygen reduction has been studied in 0.1 M HClO4 on the platinum low index surfaces, employing a hanging meniscus rotating-disk technique. A special cleaning procedure has been developed to remove impurities from the surface ...
Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
(Elsevier, 1992)
The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
(Elsevier, 1997)
Electrochemical reduction of carbon dioxide is still of great interest in the fields of theoretical and applied electrochemistry. Ruthenium is one of the metals with an intermediate hydrogen evolution overpotential which ...
Structural effects in electrocatalysis. Ethylene glycol oxidation on platinum single-crystal surfaces
(Elsevier, 1991)
The oxidation of ethylene glycol (EG) has been studied on platinum single-crystal surfaces in 0.1 M NaOH. A strong structural dependence of the reaction kinetics was found for all 12 single-crystal orientations investigated. ...
Investigation of phase-transformation kinetics in electrodeposited Cu + Cd alloys using anodic linear sweep voltammetry
(Elsevier, 1993)
The anodic linear sweep voltammetry technique was used for a quantitative assessment of the phase composition of Cu + Cd alloys obtained by electrochemical deposition. Current peaks obtained in the voltammograms were ...