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Reactions of transition metal carbonyl anions with 2-(1-bromoalkylidene)thiazolidin-4-ones: halogenophilic attack or deprotonation
(Oxford : Pergamon-Elsevier Science Ltd, 2011)
Bromophilic attack by the transition metal carbonyl anion, [Re(CO)(5)]Na (pK(a) = 21.1), on 2-(1-bromoalkylidene)thiazolidin-4-ones is significantly faster than abstraction of an acidic lactam hydrogen (pK(a) similar to ...
Configurational, LFDFT and NBO analysis of chromium(III) complexes of edta-type ligands
(Oxford : Pergamon-Elsevier Science Ltd, 2013)
A new hexadentate chromium(III) complex, Na[Cr(1,3-pd3ap)]center dot 3H(2)O, containing an unsymmetrical edta-type ligand, the 1,3-propanediamine-N,N,N'-triacetate-N'-3-propionate ion (1,3-pd3ap), has been prepared, ...
Effect of pH and human serum albumin on the cytotoxicity of a glucuronide prodrug of 9-aminocamptothecin
(Switzerland : Springer Nature, 2007)
Purpose: 9-aminocamptothecin glucuronide (9ACG) is a prodrug of 9-aminocamptothecin (9AC) that displays potent antitumor activity against human tumor xenografts in nude mice. Camptothecins exist in a pH dependent equilibrium ...
Fluctuations of the mass adsorbed on microcantilever sensor surface in liquid-phase chemical and biochemical detection
(Elsevier, 2012)
We present a simple mathematical model of adsorbed mass fluctuations in microcantilever sensors operating in liquids, taking into account the effects of the transfer process of analyte molecules from a solution to the ...
Halogen bonding in complexes of proteins and non-natural amino acids
(Elsevier Sci Ltd, Oxford, 2013)
In this work, we have analyzed the influence of halogen bonding to the stability of 44 complexes of proteins and non-natural amino acids. Fluorine- and chlorine-containing non-natural amino acids are more prevalent in the ...
Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands
(Ceska Republika : Akademie Ved Ceske Republiky, 2007)
The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands ...
Silver–silica transparent metal structures as bandpass filters for the ultraviolet range
(IOP Publishing, 2005)
We designed and produced silver–silicon dioxide multilayer thin-film bandpass filters for the ultraviolet range by applying the concept of 'transparent metals'. To calculate the transmission of the designed metallodielectric ...
The thermal stability of the external invertase isoforms from Saccharomyces cerevisiae correlates with the surface charge density
(Elsevier France-Editions Scientifiques Medicales Elsevier, Paris, 2012)
Understanding the effect of surface charge on the stability of proteins is one prerequisite for "tailoring" proteins with increased thermal stability. Here, we investigated the origin of the altered thermal stability ...
Fractal approach to surface roughness of TiO2/WO3 coatings formed by plasma electrolytic oxidation process
(Elsevier Science Sa, Lausanne, 2013)
In this study, we have shown that atomic force microscopy is a powerful technique to study the fractal parameters of TiO2/WO3 coatings prepared by plasma electrolytic oxidation (PEO) process. Since the surface roughness ...
Modeling of kinetics of pertechnetate removal by amino-functionalized glycidyl methacrylate copolymer
(Springer Verlag, 2012)
Technetium-99 comprises a significant health risk, since edible plants can bioaccumulate and convert it to more lipophilic species that cannot be excreted through urine. Batch kinetics of pertechnetate removal from aqueous ...