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Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands

Authorized Users Only
2007
Authors
Kaluđerović, Goran N.
Schmidt, Harry
Wagner, Christoph
Merzweiler, Kurt
Steinborn, Dirk
Article (Published version)
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Abstract
The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography.
Keywords:
Chelates / Coordination chemistry / Crystal structure / EDTA ligands / Palladium complexes / X-ray diffraction
Source:
Collection of Czechoslovak Chemical Communications, 2007, 72, 4, 560-568
Publisher:
  • Ceska Republika : Akademie Ved Ceske Republiky

DOI: 10.1135/cccc20070560

ISSN: 0010-0765; 1212-6950

WoS: 000246602000009

Scopus: 2-s2.0-34347334355
[ Google Scholar ]
8
6
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4304
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Kaluđerović, Goran N.
AU  - Schmidt, Harry
AU  - Wagner, Christoph
AU  - Merzweiler, Kurt
AU  - Steinborn, Dirk
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4304
AB  - The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography.
PB  - Ceska Republika : Akademie Ved Ceske Republiky
T2  - Collection of Czechoslovak Chemical Communications
T1  - Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands
VL  - 72
IS  - 4
SP  - 560
EP  - 568
DO  - 10.1135/cccc20070560
ER  - 
@article{
author = "Kaluđerović, Goran N. and Schmidt, Harry and Wagner, Christoph and Merzweiler, Kurt and Steinborn, Dirk",
year = "2007",
abstract = "The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography.",
publisher = "Ceska Republika : Akademie Ved Ceske Republiky",
journal = "Collection of Czechoslovak Chemical Communications",
title = "Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands",
volume = "72",
number = "4",
pages = "560-568",
doi = "10.1135/cccc20070560"
}
Kaluđerović, G. N., Schmidt, H., Wagner, C., Merzweiler, K.,& Steinborn, D.. (2007). Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands. in Collection of Czechoslovak Chemical Communications
Ceska Republika : Akademie Ved Ceske Republiky., 72(4), 560-568.
https://doi.org/10.1135/cccc20070560
Kaluđerović GN, Schmidt H, Wagner C, Merzweiler K, Steinborn D. Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands. in Collection of Czechoslovak Chemical Communications. 2007;72(4):560-568.
doi:10.1135/cccc20070560 .
Kaluđerović, Goran N., Schmidt, Harry, Wagner, Christoph, Merzweiler, Kurt, Steinborn, Dirk, "Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands" in Collection of Czechoslovak Chemical Communications, 72, no. 4 (2007):560-568,
https://doi.org/10.1135/cccc20070560 . .

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