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Electrochemical deposition of Ni–W alloys from ammonia–citrate electrolyte
(Elsevier, 2003)
Ammonia-citrate electrolyte is one of the solutions that are used in practice for electroplating Ni-W alloys. In this contribution, a systematic effort was made to clarify some controversies about the mechanism of the ...
Identification of intermetallic compounds in thin layers of electrodeposited Cu–Cd alloys using electrochemical techniques
(USA :Taylor & Francis INC, 1991)
An attempt was made to analyse the phase structure of thin layers of electrodeposited Cu–Cd alloys using anodic linear sweep voltammetry combined with a potentiostatic pulse technique (ALSV–PPT). The results were compared ...
Oxygen reduction on iron-V. Processes in boric acid-borate buffer solutions in the 7.4-9.8 pH range
(Elsevier, 1991)
O2 and H2O2 reduction was studied on Puratronic iron (99.995%) in borate buffer solutions of various pH ranging from 7.4 to 9.8. In solutions of pH < 9.3 the E-j curves are of quite irregular shapes and the limiting current ...
Oxygen reduction on a ruthenium electrode in acid electrolytes
(Elsevier, 1986)
The kinetics and mechanism of O2 reduction on an Ru electrode in acid electrolytes have been measured by using a disc—ring method. The reaction proceeds through a “parallel” mechanism with the exchange of approximately ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Fundamental aspects of pulsating current metal electrodeposition IX: The prevention of spongy deposit formation on inert substrates
(Elsevier, 1984)
It is shown that spongy deposits are obtained under d.c. conditions and that compact deposits are obtained in pulsating current (PC) deposition with high pause-to-pulse ratios at the same average current density and ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
The electrocatalytic properties of the oxides of noble metals in the electro-oxidation of some organic molecules
(Elsevier, 1997)
The electro-oxidation of organic compounds on gold and silver electrodes can occur either in a potential range more negative than that where the metal oxides are formed or within the more positive range where the surface ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
Surface properties of RuO2 + IrO2 mixed oxide electrodes
(Elsevier, 1986)
The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV ...