Relić, Dubravka

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Authority KeyName Variants
orcid::0000-0002-0876-4561
  • Relić, Dubravka (38)
Projects
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Studying climate change and its influence on environment: impacts, adaptation and mitigation
Structure-properties relationships of natural and synthetic molecules and their metal complexes Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Improvement and development of hygienic and technological procedures in production of animal originating foodstuffs with the aim of producing high-quality and safe products competetive on the global market Osmotic dehydration of food - energy and ecological aspects of sustainable production
OTKA [K119269] Meteorological extremes and climatic change in Serbia
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200007 (University of Belgrade, Institute for Biological Research 'Siniša Stanković') Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200116 (University of Belgrade, Faculty of Agriculture) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200288 (Innovation Center of the Faculty of Chemistry)
Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine INTERREG/CARDS-PHARE Adriatic New Neighborhood Programme [06SER02/01/04]
INTERREG/CARDS-PHARE Adriatic New Neighbourhood Programme [06SER02/01/04] SIMCA project (INTER-REG/CARDS-PHARE Adriatic New Neighborhood Program) [06SER02/01/04]
SIMCA project (INTERREG/CARDS-PHARE Adriatic New Neighborhood Programme) [06SER02/01/04] This paper is supported by University of Rijeka research grant “Development and researchof prodrugs with antitumour effects”. We greatly appreciate access to equipment in possession of University of Rijeka within the project “Research Infrastructure for Campus-based Laboratories at University of Rijeka”,financed by European Regional Development Fund (ERDF).We thank EN-FIST Centre of Excellence, Trg of 13, 1000 Ljubljana, Slovenia for using SuperNova diffractometer and Slovenian Research Agency for financial support(P1-0175).

Author's Bibliography

To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries

Popović, Aleksandar R.; Anđelković, Boban D.; Đorđević, Dragana; Sakan, Sanja; Vujisić, Ljubodrag V.; Veličković, Sava; Relić, Dubravka

(Belgrade : Serbian chemical society, 2022)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Anđelković, Boban D.
AU  - Đorđević, Dragana
AU  - Sakan, Sanja
AU  - Vujisić, Ljubodrag V.
AU  - Veličković, Sava
AU  - Relić, Dubravka
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5231
AB  - In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.
PB  - Belgrade : Serbian chemical society
T2  - Journal of the Serbian Chemical Society
T1  - To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries
VL  - 87
IS  - 1
SP  - 27
EP  - 40
DO  - 10.2298/JSC210901090P
ER  - 
@article{
author = "Popović, Aleksandar R. and Anđelković, Boban D. and Đorđević, Dragana and Sakan, Sanja and Vujisić, Ljubodrag V. and Veličković, Sava and Relić, Dubravka",
year = "2022",
abstract = "In order to further define the potential use of FTIR-ATR spectroscopy, as a non-destructive and reliable technique, for the analysis of the characteristics of post stamps, certified originals of the Principality of Serbia stamps (“Prince Michael issues”) issued in 1866 and 1868 as well as their forgeries were ana­lyzed. Spectra enabling the comparison of the paper, dye and glue of stamps of so-called “Vienna issues”, having denominations of 10 (orange-yellow), 20 (pink) and 40 para (blue) and “Belgrade issues” (1 para-green and 2 para-reddish brown), as well as 24 expert-certified forgeries, were taken. It was shown that the applied technology was, in most of the cases, a fast and suitable technique for establishing clear differences between the spectral characteristics of the paper and dye used for the original stamps, and forgeries that were most probably made decades after the printing of the genuine stamps. The differences between print­ings of the same issues of the genuine stamps were also elaborated. It is pro­posed, for the first time in philatelic history, the possibility that “Vienna issues” stamps may have been printed on two different papers, and, having in mind the technology of printing in the 19th century, potentially, not even at the same time or in the same printing house.",
publisher = "Belgrade : Serbian chemical society",
journal = "Journal of the Serbian Chemical Society",
title = "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries",
volume = "87",
number = "1",
pages = "27-40",
doi = "10.2298/JSC210901090P"
}
Popović, A. R., Anđelković, B. D., Đorđević, D., Sakan, S., Vujisić, L. V., Veličković, S.,& Relić, D.. (2022). To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society
Belgrade : Serbian chemical society., 87(1), 27-40.
https://doi.org/10.2298/JSC210901090P
Popović AR, Anđelković BD, Đorđević D, Sakan S, Vujisić LV, Veličković S, Relić D. To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries. in Journal of the Serbian Chemical Society. 2022;87(1):27-40.
doi:10.2298/JSC210901090P .
Popović, Aleksandar R., Anđelković, Boban D., Đorđević, Dragana, Sakan, Sanja, Vujisić, Ljubodrag V., Veličković, Sava, Relić, Dubravka, "To Professor Petar Pfendt, In calidum, et plurium retributivus memoriae: FTIR-ATR analysis of post stamps of the Principality of Serbia issued in 1866 and 1868 and their forgeries" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):27-40,
https://doi.org/10.2298/JSC210901090P . .

Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition

Natić, Maja; Dabić Zagorac, Dragana; Gašić, Uroš; Dojčinović, Biljana; Ćirić, Ivanka; Relić, Dubravka; Todić, Slavica R.; Sredojević, Milica

(Elsevier, 2021)

TY  - JOUR
AU  - Natić, Maja
AU  - Dabić Zagorac, Dragana
AU  - Gašić, Uroš
AU  - Dojčinović, Biljana
AU  - Ćirić, Ivanka
AU  - Relić, Dubravka
AU  - Todić, Slavica R.
AU  - Sredojević, Milica
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4216
AB  - The phenolic and elemental profiles of Serbian autochthonous grape varieties ‘Smederevka’ and ‘Plovdina’ were studied and compared with some international varieties. Total phenolic content and radical scavenging activity were highest in seeds of ‘Plovdina’, and in ‘Smederevka’ skins, which also had the highest contents of ferulic, chlorogenic and caffeic acids (16.0, 1.44 and 0.98 mg/kg, respectively). Protocatechuic acid was quantified only in the seeds of these varieties. Untypically for Vitis vinifera L. species, the presence of malvidin 3,5-O-dihexoside was found in the skins of ‘Vranac’ and ‘Muscat Hamburg’. In ‘Plovdina’ skins among the anthocyanins, hexosides of peonidin and delphinidin were prevalent. ‘Plovdina’ grapes had lower quantities of Al, Ni and Na in comparison to the other varieties intended for white wine production. Significant correlations among the most abundant elements, such as K, P, Ca, Mg, S, Fe, Cu, and Zn, pointed to potential positive interactions. For elements that have toxicological reference values, the health risk assessment was calculated for adults and children, and suggested that all samples were safe for human consumption.
PB  - Elsevier
T2  - Food Bioscience
T1  - Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition
VL  - 40
SP  - 100889
DO  - 10.1016/j.fbio.2021.100889
ER  - 
@article{
author = "Natić, Maja and Dabić Zagorac, Dragana and Gašić, Uroš and Dojčinović, Biljana and Ćirić, Ivanka and Relić, Dubravka and Todić, Slavica R. and Sredojević, Milica",
year = "2021",
abstract = "The phenolic and elemental profiles of Serbian autochthonous grape varieties ‘Smederevka’ and ‘Plovdina’ were studied and compared with some international varieties. Total phenolic content and radical scavenging activity were highest in seeds of ‘Plovdina’, and in ‘Smederevka’ skins, which also had the highest contents of ferulic, chlorogenic and caffeic acids (16.0, 1.44 and 0.98 mg/kg, respectively). Protocatechuic acid was quantified only in the seeds of these varieties. Untypically for Vitis vinifera L. species, the presence of malvidin 3,5-O-dihexoside was found in the skins of ‘Vranac’ and ‘Muscat Hamburg’. In ‘Plovdina’ skins among the anthocyanins, hexosides of peonidin and delphinidin were prevalent. ‘Plovdina’ grapes had lower quantities of Al, Ni and Na in comparison to the other varieties intended for white wine production. Significant correlations among the most abundant elements, such as K, P, Ca, Mg, S, Fe, Cu, and Zn, pointed to potential positive interactions. For elements that have toxicological reference values, the health risk assessment was calculated for adults and children, and suggested that all samples were safe for human consumption.",
publisher = "Elsevier",
journal = "Food Bioscience",
title = "Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition",
volume = "40",
pages = "100889",
doi = "10.1016/j.fbio.2021.100889"
}
Natić, M., Dabić Zagorac, D., Gašić, U., Dojčinović, B., Ćirić, I., Relić, D., Todić, S. R.,& Sredojević, M.. (2021). Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition. in Food Bioscience
Elsevier., 40, 100889.
https://doi.org/10.1016/j.fbio.2021.100889
Natić M, Dabić Zagorac D, Gašić U, Dojčinović B, Ćirić I, Relić D, Todić SR, Sredojević M. Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition. in Food Bioscience. 2021;40:100889.
doi:10.1016/j.fbio.2021.100889 .
Natić, Maja, Dabić Zagorac, Dragana, Gašić, Uroš, Dojčinović, Biljana, Ćirić, Ivanka, Relić, Dubravka, Todić, Slavica R., Sredojević, Milica, "Autochthonous and international grape varieties grown in Serbia - Phenolic and elemental composition" in Food Bioscience, 40 (2021):100889,
https://doi.org/10.1016/j.fbio.2021.100889 . .
2
2

Problemi u životnoj sredini i po zdravlje prouzrokovani proizvodnjom energije u Srbiji

Đorđević, Dragana; Popović, Aleksandar; Sakan, Sanja; Mihajlidi-Zelić, Aleksandra; Relić, Dubravka

(Belgrade : Association of Chemists and Chemical Engineers of Serbia (UHTS), 2019)

TY  - CONF
AU  - Đorđević, Dragana
AU  - Popović, Aleksandar
AU  - Sakan, Sanja
AU  - Mihajlidi-Zelić, Aleksandra
AU  - Relić, Dubravka
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6853
AB  - Still, now the main energy production in Serbia (70%) is from low-caloric lignite of Kolubara and Kostolac basins which contain harmful elements: As, Be, Co, Mo, Mn, Ni, Pb, Se, Sb, V, U, Th, Ra, Rn etc. Six Serbian CFPPs generate about 6,000,000 t/year of ash enriched by toxic elements which are being deposited on fertile arable land and emitted in ambient air. About 1600 hectares of fertile soil is permanently contaminated with toxic elements from ash disposals endangering surface and underground waters. An increased carcinogenic risk was observed due to arsenic in ambient air, contained in 
the respiratory particles of the finest fraction. CFPPs are identified as their emission sources. In recent years, small hydropower plants have been installed on last mountains clean rivers in Serbia based on decades old echnical projects and old water data, which do not include the climate change factors. Our research has shown the consequence on Vlasina River, making it the swamp quality water and enhanced erosion processes. 
Particularly dangerous in mountainous areas is of landslides and torrential floods induced by enormous precipitation due to climate change. Problems of the water supply of Vlasotince municipality are already evident. Serbia has many other possibilities for clean and low carbon energy production: 1) biogas production from biomass with which Serbia is globally one of the richest countries, 2) in summer period Serbia is country with Mediterranean climate and solar energy is easy to use, 3) Serbia is rich with underground geothermal waters that are not used for domestic and public heating, 4) energy production from methane from farms and waste disposal, 5) wind energy etc. 
The most important approach must be towards energy efficiency in the public and domestic sector and to prosumers concept. With this approach, Serbia does not need any CFPPs and especially small hydro power plants.
PB  - Belgrade : Association of Chemists and Chemical Engineers of Serbia (UHTS)
C3  - International scientific conference Environmental impact of illegal construction, poor planning and design IMPEDE 2019, Conference Proceeings, 10 – 11 October 2019, Belgrade, Serbia
T1  - Problemi u životnoj sredini i po zdravlje prouzrokovani  proizvodnjom energije u Srbiji
SP  - 1
EP  - 8
UR  - https://hdl.handle.net/21.15107/rcub_cer_6853
ER  - 
@conference{
author = "Đorđević, Dragana and Popović, Aleksandar and Sakan, Sanja and Mihajlidi-Zelić, Aleksandra and Relić, Dubravka",
year = "2019",
abstract = "Still, now the main energy production in Serbia (70%) is from low-caloric lignite of Kolubara and Kostolac basins which contain harmful elements: As, Be, Co, Mo, Mn, Ni, Pb, Se, Sb, V, U, Th, Ra, Rn etc. Six Serbian CFPPs generate about 6,000,000 t/year of ash enriched by toxic elements which are being deposited on fertile arable land and emitted in ambient air. About 1600 hectares of fertile soil is permanently contaminated with toxic elements from ash disposals endangering surface and underground waters. An increased carcinogenic risk was observed due to arsenic in ambient air, contained in 
the respiratory particles of the finest fraction. CFPPs are identified as their emission sources. In recent years, small hydropower plants have been installed on last mountains clean rivers in Serbia based on decades old echnical projects and old water data, which do not include the climate change factors. Our research has shown the consequence on Vlasina River, making it the swamp quality water and enhanced erosion processes. 
Particularly dangerous in mountainous areas is of landslides and torrential floods induced by enormous precipitation due to climate change. Problems of the water supply of Vlasotince municipality are already evident. Serbia has many other possibilities for clean and low carbon energy production: 1) biogas production from biomass with which Serbia is globally one of the richest countries, 2) in summer period Serbia is country with Mediterranean climate and solar energy is easy to use, 3) Serbia is rich with underground geothermal waters that are not used for domestic and public heating, 4) energy production from methane from farms and waste disposal, 5) wind energy etc. 
The most important approach must be towards energy efficiency in the public and domestic sector and to prosumers concept. With this approach, Serbia does not need any CFPPs and especially small hydro power plants.",
publisher = "Belgrade : Association of Chemists and Chemical Engineers of Serbia (UHTS)",
journal = "International scientific conference Environmental impact of illegal construction, poor planning and design IMPEDE 2019, Conference Proceeings, 10 – 11 October 2019, Belgrade, Serbia",
title = "Problemi u životnoj sredini i po zdravlje prouzrokovani  proizvodnjom energije u Srbiji",
pages = "1-8",
url = "https://hdl.handle.net/21.15107/rcub_cer_6853"
}
Đorđević, D., Popović, A., Sakan, S., Mihajlidi-Zelić, A.,& Relić, D.. (2019). Problemi u životnoj sredini i po zdravlje prouzrokovani  proizvodnjom energije u Srbiji. in International scientific conference Environmental impact of illegal construction, poor planning and design IMPEDE 2019, Conference Proceeings, 10 – 11 October 2019, Belgrade, Serbia
Belgrade : Association of Chemists and Chemical Engineers of Serbia (UHTS)., 1-8.
https://hdl.handle.net/21.15107/rcub_cer_6853
Đorđević D, Popović A, Sakan S, Mihajlidi-Zelić A, Relić D. Problemi u životnoj sredini i po zdravlje prouzrokovani  proizvodnjom energije u Srbiji. in International scientific conference Environmental impact of illegal construction, poor planning and design IMPEDE 2019, Conference Proceeings, 10 – 11 October 2019, Belgrade, Serbia. 2019;:1-8.
https://hdl.handle.net/21.15107/rcub_cer_6853 .
Đorđević, Dragana, Popović, Aleksandar, Sakan, Sanja, Mihajlidi-Zelić, Aleksandra, Relić, Dubravka, "Problemi u životnoj sredini i po zdravlje prouzrokovani  proizvodnjom energije u Srbiji" in International scientific conference Environmental impact of illegal construction, poor planning and design IMPEDE 2019, Conference Proceeings, 10 – 11 October 2019, Belgrade, Serbia (2019):1-8,
https://hdl.handle.net/21.15107/rcub_cer_6853 .

Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area

Relić, Dubravka; Sakan, Sanja; Anđelković, Ivan; Popović, Aleksandar R.; Đorđević, Dragana

(MDPI, 2019)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Sakan, Sanja
AU  - Anđelković, Ivan
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2964
AB  - The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.
PB  - MDPI
T2  - Molecules
T1  - Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area
VL  - 24
IS  - 11
SP  - 1
EP  - 19
DO  - 10.3390/molecules24112139
ER  - 
@article{
author = "Relić, Dubravka and Sakan, Sanja and Anđelković, Ivan and Popović, Aleksandar R. and Đorđević, Dragana",
year = "2019",
abstract = "The pollution state and health risk assessment of potentially toxic elements (PTE) in soil and sediment samples of the petrochemical industry and its surrounding area are evaluated in this study. The pseudo-total contents of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were measured by inductively coupled plasma–optical emission spectrometry (ICP/OES) in analyzed samples. Instead of determining total content, we performed aqua regia of the samples. The silicate matrix remained, and the quantities of elements that are within the silicate matrix do not represent an environmental danger. The soils from the chlor–alkali plant are highly polluted by Hg (the enrichment factor values were above 6000), and by Cu, Cd, Pb, and Zn, while the sediment samples from the wastewater channel are polluted with Cr, Cd, and Hg. The measured element contents are used for calculating health risk criteria for a composite worker (a worker who is exposed, long-term, during the work day) and for residential people. Hg is the element that mainly contributes to non-carcinogenic risks within the petrochemical area. The highest value of total carcinogenic risk obtained in the sediment sample from the wastewater channel, and the metal that mostly contributes is Cr. The areas closest to the petrochemical industry have higher values of health risk criteria parameters and pollution indices. The areas that are located further to the north and south from the petrochemical industry are less burdened with the analyzed elements, which is significant because the closest city and village are situated in those directions.",
publisher = "MDPI",
journal = "Molecules",
title = "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area",
volume = "24",
number = "11",
pages = "1-19",
doi = "10.3390/molecules24112139"
}
Relić, D., Sakan, S., Anđelković, I., Popović, A. R.,& Đorđević, D.. (2019). Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules
MDPI., 24(11), 1-19.
https://doi.org/10.3390/molecules24112139
Relić D, Sakan S, Anđelković I, Popović AR, Đorđević D. Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area. in Molecules. 2019;24(11):1-19.
doi:10.3390/molecules24112139 .
Relić, Dubravka, Sakan, Sanja, Anđelković, Ivan, Popović, Aleksandar R., Đorđević, Dragana, "Pollution and health risk assessments of potentially toxic elements in soil and sediment samples in a petrochemical industry and surrounding area" in Molecules, 24, no. 11 (2019):1-19,
https://doi.org/10.3390/molecules24112139 . .
1
21
8
23

Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment

Popović, Aleksandar R.; Đinović-Stojanović, Jasna M.; Đorđević, Dragana; Relić, Dubravka; Vranic, Danijela V.; Milijasevic, Milan P.; Pezo, Lato

(Academic Press Inc Elsevier Science, San Diego, 2018)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đinović-Stojanović, Jasna M.
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
AU  - Vranic, Danijela V.
AU  - Milijasevic, Milan P.
AU  - Pezo, Lato
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2320
AB  - A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment
VL  - 67
SP  - 70
EP  - 76
DO  - 10.1016/j.jfca.2018.01.003
ER  - 
@article{
author = "Popović, Aleksandar R. and Đinović-Stojanović, Jasna M. and Đorđević, Dragana and Relić, Dubravka and Vranic, Danijela V. and Milijasevic, Milan P. and Pezo, Lato",
year = "2018",
abstract = "A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment",
volume = "67",
pages = "70-76",
doi = "10.1016/j.jfca.2018.01.003"
}
Popović, A. R., Đinović-Stojanović, J. M., Đorđević, D., Relić, D., Vranic, D. V., Milijasevic, M. P.,& Pezo, L.. (2018). Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 67, 70-76.
https://doi.org/10.1016/j.jfca.2018.01.003
Popović AR, Đinović-Stojanović JM, Đorđević D, Relić D, Vranic DV, Milijasevic MP, Pezo L. Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis. 2018;67:70-76.
doi:10.1016/j.jfca.2018.01.003 .
Popović, Aleksandar R., Đinović-Stojanović, Jasna M., Đorđević, Dragana, Relić, Dubravka, Vranic, Danijela V., Milijasevic, Milan P., Pezo, Lato, "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment" in Journal of Food Composition and Analysis, 67 (2018):70-76,
https://doi.org/10.1016/j.jfca.2018.01.003 . .
27
15
27

Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods

Relić, Dubravka; Heberger, Karoly; Sakan, Sanja; Skrbic, Biljana; Popović, Aleksandar R.; Đorđević, Dragana

(Oxford : Pergamon-Elsevier Science Ltd, 2018)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Heberger, Karoly
AU  - Sakan, Sanja
AU  - Skrbic, Biljana
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2324
AB  - This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Chemosphere
T1  - Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods
VL  - 198
SP  - 103
EP  - 110
DO  - 10.1016/j.chemosphere.2017.12.200
ER  - 
@article{
author = "Relić, Dubravka and Heberger, Karoly and Sakan, Sanja and Skrbic, Biljana and Popović, Aleksandar R. and Đorđević, Dragana",
year = "2018",
abstract = "This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Chemosphere",
title = "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods",
volume = "198",
pages = "103-110",
doi = "10.1016/j.chemosphere.2017.12.200"
}
Relić, D., Heberger, K., Sakan, S., Skrbic, B., Popović, A. R.,& Đorđević, D.. (2018). Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere
Oxford : Pergamon-Elsevier Science Ltd., 198, 103-110.
https://doi.org/10.1016/j.chemosphere.2017.12.200
Relić D, Heberger K, Sakan S, Skrbic B, Popović AR, Đorđević D. Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere. 2018;198:103-110.
doi:10.1016/j.chemosphere.2017.12.200 .
Relić, Dubravka, Heberger, Karoly, Sakan, Sanja, Skrbic, Biljana, Popović, Aleksandar R., Đorđević, Dragana, "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods" in Chemosphere, 198 (2018):103-110,
https://doi.org/10.1016/j.chemosphere.2017.12.200 . .
7
3
6

Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods

Relić, Dubravka; Heberger, Karoly; Sakan, Sanja; Skrbic, Biljana; Popović, Aleksandar R.; Đorđević, Dragana

(Oxford : Pergamon-Elsevier Science Ltd, 2018)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Heberger, Karoly
AU  - Sakan, Sanja
AU  - Skrbic, Biljana
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2934
AB  - This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Chemosphere
T1  - Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods
VL  - 198
SP  - 103
EP  - 110
DO  - 10.1016/j.chemosphere.2017.12.200
ER  - 
@article{
author = "Relić, Dubravka and Heberger, Karoly and Sakan, Sanja and Skrbic, Biljana and Popović, Aleksandar R. and Đorđević, Dragana",
year = "2018",
abstract = "This study aims to compare three extraction techniques of four sequential element extraction steps from soil and sediment samples that were taken from the location of the Pancevo petrochemical industry (Serbia). Elements were extracted using three different techniques: conventional, microwave and ultrasound extraction. A novel procedure sum of the ranking differences (SRD) - was able to rank the techniques and elements, to see whether this method is a suitable tool to reveal the similarities and dissimilarities in element extraction techniques, provided that a proper ranking reference is available. The concentrations of the following elements Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, Sn, Sr, V and Zn were determined through ICP OES. The different efficiencies and recovery values of element concentrations using each of the three extraction techniques were examined by the CRM BCR-701. By using SRD, we obtained a better separation between the different extraction techniques and steps when we rank their differences among the samples while lower separation was obtained according to analysed elements. Appling this method for ordering the elements could be useful for three purposes: (i) to find possible associations among the elements; (ii) to find possible elements that have outlier concentrations or (iii) detect differences in geochemical origin or behaviour of elements. Cross-validation of the SRD values in combination with cluster and principal component analysis revealed the same groups of extraction steps and techniques.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Chemosphere",
title = "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods",
volume = "198",
pages = "103-110",
doi = "10.1016/j.chemosphere.2017.12.200"
}
Relić, D., Heberger, K., Sakan, S., Skrbic, B., Popović, A. R.,& Đorđević, D.. (2018). Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere
Oxford : Pergamon-Elsevier Science Ltd., 198, 103-110.
https://doi.org/10.1016/j.chemosphere.2017.12.200
Relić D, Heberger K, Sakan S, Skrbic B, Popović AR, Đorđević D. Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods. in Chemosphere. 2018;198:103-110.
doi:10.1016/j.chemosphere.2017.12.200 .
Relić, Dubravka, Heberger, Karoly, Sakan, Sanja, Skrbic, Biljana, Popović, Aleksandar R., Đorđević, Dragana, "Ranking and similarity of conventional, microwave and ultrasound element sequential extraction methods" in Chemosphere, 198 (2018):103-110,
https://doi.org/10.1016/j.chemosphere.2017.12.200 . .
7
3
6

Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment

Popović, Aleksandar R.; Đinović-Stojanović, Jasna; Đorđević, Dragana; Relić, Dubravka; Vranić, Danijela; Milijašević, Milan P.; Pezo, Lato

(Academic Press Inc Elsevier Science, San Diego, 2018)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đinović-Stojanović, Jasna
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
AU  - Vranić, Danijela
AU  - Milijašević, Milan P.
AU  - Pezo, Lato
PY  - 2018
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3235
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3142
AB  - A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment
VL  - 67
SP  - 70
EP  - 76
DO  - 10.1016/j.jfca.2018.01.003
ER  - 
@article{
author = "Popović, Aleksandar R. and Đinović-Stojanović, Jasna and Đorđević, Dragana and Relić, Dubravka and Vranić, Danijela and Milijašević, Milan P. and Pezo, Lato",
year = "2018",
abstract = "A total of 138 samples of canned tuna, sardines and mackerel from the Serbian market were analyzed for toxic (As, Cd, Pb, Hg) element levels using ICPMS. The highest average contents of toxic elements were found to be 1.70 mg kg(-1) for arsenic and 0.026 mg kg(-1) for cadmium in sardine and 0.068 mg kg(-1) for mercury in tuna. The lead content was very similar (similar to 0.048 mg kg(-1)) of the three types of canned fish. None of the fish analyzed contained toxic elements in levels exceeding the maximum allowable levels currently in force. Human health risk assessment of As, Cd, Pb and Hg in canned fish were investigated. A risk assessment based on the measured levels of examined elements indicated that consumption of canned fish according to current eating habits in Serbia presents little risk to human health since the carcinogenic risk is within the acceptable range, 10(-4)-10(-6).",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment",
volume = "67",
pages = "70-76",
doi = "10.1016/j.jfca.2018.01.003"
}
Popović, A. R., Đinović-Stojanović, J., Đorđević, D., Relić, D., Vranić, D., Milijašević, M. P.,& Pezo, L.. (2018). Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 67, 70-76.
https://doi.org/10.1016/j.jfca.2018.01.003
Popović AR, Đinović-Stojanović J, Đorđević D, Relić D, Vranić D, Milijašević MP, Pezo L. Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment. in Journal of Food Composition and Analysis. 2018;67:70-76.
doi:10.1016/j.jfca.2018.01.003 .
Popović, Aleksandar R., Đinović-Stojanović, Jasna, Đorđević, Dragana, Relić, Dubravka, Vranić, Danijela, Milijašević, Milan P., Pezo, Lato, "Levels of toxic elements in canned fish from the Serbian markets and their health risks assessment" in Journal of Food Composition and Analysis, 67 (2018):70-76,
https://doi.org/10.1016/j.jfca.2018.01.003 . .
27
15
29

Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia

Relić, Dubravka; Popović, Aleksandar R.; Đorđević, Dragana; Čáslavský, Josef

(Springer, New York, 2017)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
AU  - Čáslavský, Josef
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2194
AB  - This study assessed the state of waters in Belgrade regarding pollution with musk compounds as the target contaminants. Eleven of these compounds were alicyclic, two were macrocyclic, and one was polycyclic. Solid-phase microextraction was used for the isolation of these compounds from waste, surface and underground waters and from processed water prepared for drinking, while comprehensive orthogonal two-dimensional gas chromatography with mass spectrometry was used as the final analytical method. In wastewater samples, galaxolide was detected in concentrations of 1.13 and 0.40 mu g/L, while in the Sava River and underground water its concentrations were 0.09 and 0.038 mu g/L. The lowest concentrations of the investigated musk compounds were detected in underground water samples, indicating that this is the cleanest water of all the analyzed sources with respect to musk compounds. Comparing the results of musk compound concentrations determined in surface river water samples and clean river water samples utilized for drinking, a lower concentration of these compounds was detected in the clean river water samples. The majority of musk compounds were found in waters utilized for drinking. Based on the concentration values, we conclude that the analyzed waters are moderately polluted with these compounds.
PB  - Springer, New York
T2  - Environmental Earth Sciences
T1  - Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia
VL  - 76
IS  - 3
DO  - 10.1007/s12665-017-6441-z
ER  - 
@article{
author = "Relić, Dubravka and Popović, Aleksandar R. and Đorđević, Dragana and Čáslavský, Josef",
year = "2017",
abstract = "This study assessed the state of waters in Belgrade regarding pollution with musk compounds as the target contaminants. Eleven of these compounds were alicyclic, two were macrocyclic, and one was polycyclic. Solid-phase microextraction was used for the isolation of these compounds from waste, surface and underground waters and from processed water prepared for drinking, while comprehensive orthogonal two-dimensional gas chromatography with mass spectrometry was used as the final analytical method. In wastewater samples, galaxolide was detected in concentrations of 1.13 and 0.40 mu g/L, while in the Sava River and underground water its concentrations were 0.09 and 0.038 mu g/L. The lowest concentrations of the investigated musk compounds were detected in underground water samples, indicating that this is the cleanest water of all the analyzed sources with respect to musk compounds. Comparing the results of musk compound concentrations determined in surface river water samples and clean river water samples utilized for drinking, a lower concentration of these compounds was detected in the clean river water samples. The majority of musk compounds were found in waters utilized for drinking. Based on the concentration values, we conclude that the analyzed waters are moderately polluted with these compounds.",
publisher = "Springer, New York",
journal = "Environmental Earth Sciences",
title = "Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia",
volume = "76",
number = "3",
doi = "10.1007/s12665-017-6441-z"
}
Relić, D., Popović, A. R., Đorđević, D.,& Čáslavský, J.. (2017). Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia. in Environmental Earth Sciences
Springer, New York., 76(3).
https://doi.org/10.1007/s12665-017-6441-z
Relić D, Popović AR, Đorđević D, Čáslavský J. Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia. in Environmental Earth Sciences. 2017;76(3).
doi:10.1007/s12665-017-6441-z .
Relić, Dubravka, Popović, Aleksandar R., Đorđević, Dragana, Čáslavský, Josef, "Occurrence of synthetic musk compounds in surface, underground, waste and processed water samples in Belgrade , Serbia" in Environmental Earth Sciences, 76, no. 3 (2017),
https://doi.org/10.1007/s12665-017-6441-z . .
1
18
7
14

Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia

Pantelić, Milica; Dabić Zagorac, Dragana; Ćirić, Ivanka Z.; Pergal, Marija; Relić, Dubravka; Todić, Slavica R.; Natić, Maja

(Academic Press Inc Elsevier Science, San Diego, 2017)

TY  - JOUR
AU  - Pantelić, Milica
AU  - Dabić Zagorac, Dragana
AU  - Ćirić, Ivanka Z.
AU  - Pergal, Marija
AU  - Relić, Dubravka
AU  - Todić, Slavica R.
AU  - Natić, Maja
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2059
AB  - This research was designed to determine phenolics content, radical scavenging activity and mineral composition of 22 grapevine leaves of diverse varietal origin. Samples were collected from two vineyards located in Central Serbia (Belgrade vineyard area) and Eastern Serbia (Mlava vineyard area). Leaf extracts were characterized mostly with phenolics acids, flavonols and flavan-3-ols. Ellagic acid and rutin were the most abundant components, found in the concentration up to 770 mg/kg and 450 mg/kg of dry weight, respectively. Total phenolic content was in the range from 27.5 to 76.0 g GAE/kg of dry weight while the radical scavenging activity ranged from 0.429 to 0.867 mmol TE/kg of dry weight. The most common element in all samples was IC (content ranging from 2.30 g/kg to 6.77 g/kg of dry weight), followed by Ca, Na, and B. A variation in the chemical composition was shown to be convenient way to differentiate among the grape leaves of diverse varietal origin. Clear separation was demonstrated between objects of different geographical origin by Principal Component Analysis. Serbian variety 'Petra', an interspecies hybrid with atypical composition, was detected as an outlier in comparison to other samples.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia
VL  - 62
SP  - 76
EP  - 83
DO  - 10.1016/j.jfca.2017.05.002
ER  - 
@article{
author = "Pantelić, Milica and Dabić Zagorac, Dragana and Ćirić, Ivanka Z. and Pergal, Marija and Relić, Dubravka and Todić, Slavica R. and Natić, Maja",
year = "2017",
abstract = "This research was designed to determine phenolics content, radical scavenging activity and mineral composition of 22 grapevine leaves of diverse varietal origin. Samples were collected from two vineyards located in Central Serbia (Belgrade vineyard area) and Eastern Serbia (Mlava vineyard area). Leaf extracts were characterized mostly with phenolics acids, flavonols and flavan-3-ols. Ellagic acid and rutin were the most abundant components, found in the concentration up to 770 mg/kg and 450 mg/kg of dry weight, respectively. Total phenolic content was in the range from 27.5 to 76.0 g GAE/kg of dry weight while the radical scavenging activity ranged from 0.429 to 0.867 mmol TE/kg of dry weight. The most common element in all samples was IC (content ranging from 2.30 g/kg to 6.77 g/kg of dry weight), followed by Ca, Na, and B. A variation in the chemical composition was shown to be convenient way to differentiate among the grape leaves of diverse varietal origin. Clear separation was demonstrated between objects of different geographical origin by Principal Component Analysis. Serbian variety 'Petra', an interspecies hybrid with atypical composition, was detected as an outlier in comparison to other samples.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia",
volume = "62",
pages = "76-83",
doi = "10.1016/j.jfca.2017.05.002"
}
Pantelić, M., Dabić Zagorac, D., Ćirić, I. Z., Pergal, M., Relić, D., Todić, S. R.,& Natić, M.. (2017). Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 62, 76-83.
https://doi.org/10.1016/j.jfca.2017.05.002
Pantelić M, Dabić Zagorac D, Ćirić IZ, Pergal M, Relić D, Todić SR, Natić M. Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia. in Journal of Food Composition and Analysis. 2017;62:76-83.
doi:10.1016/j.jfca.2017.05.002 .
Pantelić, Milica, Dabić Zagorac, Dragana, Ćirić, Ivanka Z., Pergal, Marija, Relić, Dubravka, Todić, Slavica R., Natić, Maja, "Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia" in Journal of Food Composition and Analysis, 62 (2017):76-83,
https://doi.org/10.1016/j.jfca.2017.05.002 . .
45
27
42

Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia

Pantelić, Milica; Dabić Zagorac, Dragana; Ćirić, Ivanka Z.; Pergal, Marija; Relić, Dubravka; Todić, Slavica R.; Natić, Maja

(Academic Press Inc Elsevier Science, San Diego, 2017)

TY  - JOUR
AU  - Pantelić, Milica
AU  - Dabić Zagorac, Dragana
AU  - Ćirić, Ivanka Z.
AU  - Pergal, Marija
AU  - Relić, Dubravka
AU  - Todić, Slavica R.
AU  - Natić, Maja
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2921
AB  - This research was designed to determine phenolics content, radical scavenging activity and mineral composition of 22 grapevine leaves of diverse varietal origin. Samples were collected from two vineyards located in Central Serbia (Belgrade vineyard area) and Eastern Serbia (Mlava vineyard area). Leaf extracts were characterized mostly with phenolics acids, flavonols and flavan-3-ols. Ellagic acid and rutin were the most abundant components, found in the concentration up to 770 mg/kg and 450 mg/kg of dry weight, respectively. Total phenolic content was in the range from 27.5 to 76.0 g GAE/kg of dry weight while the radical scavenging activity ranged from 0.429 to 0.867 mmol TE/kg of dry weight. The most common element in all samples was IC (content ranging from 2.30 g/kg to 6.77 g/kg of dry weight), followed by Ca, Na, and B. A variation in the chemical composition was shown to be convenient way to differentiate among the grape leaves of diverse varietal origin. Clear separation was demonstrated between objects of different geographical origin by Principal Component Analysis. Serbian variety 'Petra', an interspecies hybrid with atypical composition, was detected as an outlier in comparison to other samples.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia
VL  - 62
SP  - 76
EP  - 83
DO  - 10.1016/j.jfca.2017.05.002
ER  - 
@article{
author = "Pantelić, Milica and Dabić Zagorac, Dragana and Ćirić, Ivanka Z. and Pergal, Marija and Relić, Dubravka and Todić, Slavica R. and Natić, Maja",
year = "2017",
abstract = "This research was designed to determine phenolics content, radical scavenging activity and mineral composition of 22 grapevine leaves of diverse varietal origin. Samples were collected from two vineyards located in Central Serbia (Belgrade vineyard area) and Eastern Serbia (Mlava vineyard area). Leaf extracts were characterized mostly with phenolics acids, flavonols and flavan-3-ols. Ellagic acid and rutin were the most abundant components, found in the concentration up to 770 mg/kg and 450 mg/kg of dry weight, respectively. Total phenolic content was in the range from 27.5 to 76.0 g GAE/kg of dry weight while the radical scavenging activity ranged from 0.429 to 0.867 mmol TE/kg of dry weight. The most common element in all samples was IC (content ranging from 2.30 g/kg to 6.77 g/kg of dry weight), followed by Ca, Na, and B. A variation in the chemical composition was shown to be convenient way to differentiate among the grape leaves of diverse varietal origin. Clear separation was demonstrated between objects of different geographical origin by Principal Component Analysis. Serbian variety 'Petra', an interspecies hybrid with atypical composition, was detected as an outlier in comparison to other samples.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia",
volume = "62",
pages = "76-83",
doi = "10.1016/j.jfca.2017.05.002"
}
Pantelić, M., Dabić Zagorac, D., Ćirić, I. Z., Pergal, M., Relić, D., Todić, S. R.,& Natić, M.. (2017). Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 62, 76-83.
https://doi.org/10.1016/j.jfca.2017.05.002
Pantelić M, Dabić Zagorac D, Ćirić IZ, Pergal M, Relić D, Todić SR, Natić M. Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia. in Journal of Food Composition and Analysis. 2017;62:76-83.
doi:10.1016/j.jfca.2017.05.002 .
Pantelić, Milica, Dabić Zagorac, Dragana, Ćirić, Ivanka Z., Pergal, Marija, Relić, Dubravka, Todić, Slavica R., Natić, Maja, "Phenolic profiles, antioxidant activity and minerals in leaves of different grapevine varieties grown in Serbia" in Journal of Food Composition and Analysis, 62 (2017):76-83,
https://doi.org/10.1016/j.jfca.2017.05.002 . .
45
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44

Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade)

Đorđević, Dragana; Buha, J; Stortini, A M; Mihajlidi Zelić, Aleksandra; Relić, Dubravka; Barbante, C; Gambaro, Andrea

(Springer Heidelberg, Heidelberg, 2016)

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Buha, J
AU  - Stortini, A M
AU  - Mihajlidi Zelić, Aleksandra
AU  - Relić, Dubravka
AU  - Barbante, C
AU  - Gambaro, Andrea
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1978
AB  - This work presents characteristics of atmospheric aerosols of urban central Balkans area, using a size-segregated aerosol sampling method, calculation of mass distributions, SEM/EDX characterization, and ICP/MS analysis. Three types of mass distributions were observed: distribution with a pronounced domination of coarse mode, bimodal distribution, and distribution with minimum at 1 mu m describing the urban aerosol. SEM/EDX analyses have shown morphological difference and variation in the content of elements in samples. EDX spectra demonstrate that particles generally contain the following elements: Al, Ca, K, Fe, Mg, Ni, K, Si, S. Additionally, the presence of As, Br, Sn, and Zn found in air masses from southeast segment points out the anthropogenic activities most probably from mining activities in southeastern part of Serbia. The ratio Al/Si equivalent to the ratio of desert dust was associated with air masses coming from southeastern and southwestern segments, pointing to influences from North Africa and Middle East desert areas whereas the Al/Si ratio in other samples is significantly lower. In several samples, we found high values of aluminum in the nucleation mode. Samples with low share of crustal elements in the coarse mode are collected when Mediterranean air masses prevailed, while high share in the coarse mode was associated with continental air masses that could be one of the approaches for identification of the aerosol origin.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade)
VL  - 23
IS  - 1
SP  - 851
EP  - 859
DO  - 10.1007/s11356-015-5271-3
ER  - 
@article{
author = "Đorđević, Dragana and Buha, J and Stortini, A M and Mihajlidi Zelić, Aleksandra and Relić, Dubravka and Barbante, C and Gambaro, Andrea",
year = "2016",
abstract = "This work presents characteristics of atmospheric aerosols of urban central Balkans area, using a size-segregated aerosol sampling method, calculation of mass distributions, SEM/EDX characterization, and ICP/MS analysis. Three types of mass distributions were observed: distribution with a pronounced domination of coarse mode, bimodal distribution, and distribution with minimum at 1 mu m describing the urban aerosol. SEM/EDX analyses have shown morphological difference and variation in the content of elements in samples. EDX spectra demonstrate that particles generally contain the following elements: Al, Ca, K, Fe, Mg, Ni, K, Si, S. Additionally, the presence of As, Br, Sn, and Zn found in air masses from southeast segment points out the anthropogenic activities most probably from mining activities in southeastern part of Serbia. The ratio Al/Si equivalent to the ratio of desert dust was associated with air masses coming from southeastern and southwestern segments, pointing to influences from North Africa and Middle East desert areas whereas the Al/Si ratio in other samples is significantly lower. In several samples, we found high values of aluminum in the nucleation mode. Samples with low share of crustal elements in the coarse mode are collected when Mediterranean air masses prevailed, while high share in the coarse mode was associated with continental air masses that could be one of the approaches for identification of the aerosol origin.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade)",
volume = "23",
number = "1",
pages = "851-859",
doi = "10.1007/s11356-015-5271-3"
}
Đorđević, D., Buha, J., Stortini, A. M., Mihajlidi Zelić, A., Relić, D., Barbante, C.,& Gambaro, A.. (2016). Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade). in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 23(1), 851-859.
https://doi.org/10.1007/s11356-015-5271-3
Đorđević D, Buha J, Stortini AM, Mihajlidi Zelić A, Relić D, Barbante C, Gambaro A. Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade). in Environmental Science and Pollution Research. 2016;23(1):851-859.
doi:10.1007/s11356-015-5271-3 .
Đorđević, Dragana, Buha, J, Stortini, A M, Mihajlidi Zelić, Aleksandra, Relić, Dubravka, Barbante, C, Gambaro, Andrea, "Mass distributions and morphological and chemical characterization of urban aerosols in the continental Balkan area (Belgrade)" in Environmental Science and Pollution Research, 23, no. 1 (2016):851-859,
https://doi.org/10.1007/s11356-015-5271-3 . .
7
5
8

Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008)

Mihajlidi Zelić, Aleksandra; Đorđević, Dragana; Relić, Dubravka; Tosic, Ivana; Ignjatović, Ljubiša M.; Stortini, Maria A; Gambaro, Andrea

(De Gruyter Open Ltd, Warsaw, 2015)

TY  - JOUR
AU  - Mihajlidi Zelić, Aleksandra
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
AU  - Tosic, Ivana
AU  - Ignjatović, Ljubiša M.
AU  - Stortini, Maria A
AU  - Gambaro, Andrea
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1662
AB  - Size-segregated aerosol samples were collected using six stages High Volume Cascade Impactor. Aerosol mass and water soluble ions concentrations were determined. The Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to study the origin of air masses arriving to Belgrade in the investigated period. The obtained results of aerosol mass and water-soluble ion concentrations have been divided into six sub-data sets based on air mass categories. The highest average mass concentration of the fine mode (D-p  LT = 0.49 mu m) was found for air masses coming to Belgrade from the southeast and northwest directions, and of the coarse mode (3.0  LT  D-p  LT = 7.2 mu m) for air masses arriving from the northwest direction. The highest concentrations of SO42- were found in the fine particles transported to the investigated area by air masses from southeast direction. The analysis of contribution of marine aerosol components (Na+ and Cl-), the Correlation and Cluster Analysis indicated the influence of marine aerosol on urban aerosol of the central Balkans coming from the Western Mediterranean and northern direction. NH4+ and SO42- and K+ dominated in the fine mode for all air mass categories. PCA demonstrated the dominant impact of secondary aerosol formation processes on urban aerosols.
PB  - De Gruyter Open Ltd, Warsaw
T2  - Open Chemistry
T1  - Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008)
VL  - 13
IS  - 1
SP  - 245
EP  - 256
DO  - 10.1515/chem-2015-0010
ER  - 
@article{
author = "Mihajlidi Zelić, Aleksandra and Đorđević, Dragana and Relić, Dubravka and Tosic, Ivana and Ignjatović, Ljubiša M. and Stortini, Maria A and Gambaro, Andrea",
year = "2015",
abstract = "Size-segregated aerosol samples were collected using six stages High Volume Cascade Impactor. Aerosol mass and water soluble ions concentrations were determined. The Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to study the origin of air masses arriving to Belgrade in the investigated period. The obtained results of aerosol mass and water-soluble ion concentrations have been divided into six sub-data sets based on air mass categories. The highest average mass concentration of the fine mode (D-p  LT = 0.49 mu m) was found for air masses coming to Belgrade from the southeast and northwest directions, and of the coarse mode (3.0  LT  D-p  LT = 7.2 mu m) for air masses arriving from the northwest direction. The highest concentrations of SO42- were found in the fine particles transported to the investigated area by air masses from southeast direction. The analysis of contribution of marine aerosol components (Na+ and Cl-), the Correlation and Cluster Analysis indicated the influence of marine aerosol on urban aerosol of the central Balkans coming from the Western Mediterranean and northern direction. NH4+ and SO42- and K+ dominated in the fine mode for all air mass categories. PCA demonstrated the dominant impact of secondary aerosol formation processes on urban aerosols.",
publisher = "De Gruyter Open Ltd, Warsaw",
journal = "Open Chemistry",
title = "Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008)",
volume = "13",
number = "1",
pages = "245-256",
doi = "10.1515/chem-2015-0010"
}
Mihajlidi Zelić, A., Đorđević, D., Relić, D., Tosic, I., Ignjatović, L. M., Stortini, M. A.,& Gambaro, A.. (2015). Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008). in Open Chemistry
De Gruyter Open Ltd, Warsaw., 13(1), 245-256.
https://doi.org/10.1515/chem-2015-0010
Mihajlidi Zelić A, Đorđević D, Relić D, Tosic I, Ignjatović LM, Stortini MA, Gambaro A. Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008). in Open Chemistry. 2015;13(1):245-256.
doi:10.1515/chem-2015-0010 .
Mihajlidi Zelić, Aleksandra, Đorđević, Dragana, Relić, Dubravka, Tosic, Ivana, Ignjatović, Ljubiša M., Stortini, Maria A, Gambaro, Andrea, "Water-soluble inorganic ions in urban aerosols of the continental part of Balkans (Belgrade) during the summer - autumn (2008)" in Open Chemistry, 13, no. 1 (2015):245-256,
https://doi.org/10.1515/chem-2015-0010 . .
9
10
11

Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash

Popović, Aleksandar R.; Relić, Dubravka; Đorđević, Dragana

(Taylor & Francis Inc, Philadelphia, 2015)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Relić, Dubravka
AU  - Đorđević, Dragana
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1627
AB  - Statistical analysis of concentrations of trace and major elements obtained by five-step sequential extraction of samples of dump ash taken from a passive, previously filled cassette of "Nikola Tesla A" power plant dump located near Belgrade, Serbia, revealed the existence of magnesium alumosilicates, mixed silicates of potassium and magnesium, alumosilicates not containing magnesium, and compounds of aluminium, not containing silicon or magnesium that were dissolved in the fifth phase of extraction. Intraphase associations of major elements dissolved in the third phase were not established. Preferential intraphase and interphase binding of matrix and adsorbed and ion-exchangeable fractions of elements were established and discussed.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash
VL  - 37
IS  - 14
SP  - 1487
EP  - 1494
DO  - 10.1080/15567036.2011.626495
ER  - 
@article{
author = "Popović, Aleksandar R. and Relić, Dubravka and Đorđević, Dragana",
year = "2015",
abstract = "Statistical analysis of concentrations of trace and major elements obtained by five-step sequential extraction of samples of dump ash taken from a passive, previously filled cassette of "Nikola Tesla A" power plant dump located near Belgrade, Serbia, revealed the existence of magnesium alumosilicates, mixed silicates of potassium and magnesium, alumosilicates not containing magnesium, and compounds of aluminium, not containing silicon or magnesium that were dissolved in the fifth phase of extraction. Intraphase associations of major elements dissolved in the third phase were not established. Preferential intraphase and interphase binding of matrix and adsorbed and ion-exchangeable fractions of elements were established and discussed.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash",
volume = "37",
number = "14",
pages = "1487-1494",
doi = "10.1080/15567036.2011.626495"
}
Popović, A. R., Relić, D.,& Đorđević, D.. (2015). Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 37(14), 1487-1494.
https://doi.org/10.1080/15567036.2011.626495
Popović AR, Relić D, Đorđević D. Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2015;37(14):1487-1494.
doi:10.1080/15567036.2011.626495 .
Popović, Aleksandar R., Relić, Dubravka, Đorđević, Dragana, "Trace and Major Elements in Ash of "Nikola Tesla A" Power Plant (III)-Associations of Elements in Passive Cassette Ash" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 37, no. 14 (2015):1487-1494,
https://doi.org/10.1080/15567036.2011.626495 . .
1
2

Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis

Popović, Aleksandar R.; Đorđević, Dragana; Relić, Dubravka

(Taylor & Francis Inc, Philadelphia, 2015)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1777
AB  - Six combined samples of filter ash obtained by lignite combustion in the "Nikola Tesla A" Power Plant were subjected to a five-phase sequential extraction. In order to establish associations of extracted trace and major elements, obtained concentrations were subjected to intraphase and interphase correlation analysis. Statistical analysis revealed the pollution potential, association forms of trace and major elements with the inorganic matrix, binding pattern of adsorbed and ion-exchangeable fractions to the inorganic matrix, and changes in association forms occurred during and after lignite combustion.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis
VL  - 37
IS  - 9
SP  - 987
EP  - 996
DO  - 10.1080/15567036.2011.601793
ER  - 
@article{
author = "Popović, Aleksandar R. and Đorđević, Dragana and Relić, Dubravka",
year = "2015",
abstract = "Six combined samples of filter ash obtained by lignite combustion in the "Nikola Tesla A" Power Plant were subjected to a five-phase sequential extraction. In order to establish associations of extracted trace and major elements, obtained concentrations were subjected to intraphase and interphase correlation analysis. Statistical analysis revealed the pollution potential, association forms of trace and major elements with the inorganic matrix, binding pattern of adsorbed and ion-exchangeable fractions to the inorganic matrix, and changes in association forms occurred during and after lignite combustion.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis",
volume = "37",
number = "9",
pages = "987-996",
doi = "10.1080/15567036.2011.601793"
}
Popović, A. R., Đorđević, D.,& Relić, D.. (2015). Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 37(9), 987-996.
https://doi.org/10.1080/15567036.2011.601793
Popović AR, Đorđević D, Relić D. Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2015;37(9):987-996.
doi:10.1080/15567036.2011.601793 .
Popović, Aleksandar R., Đorđević, Dragana, Relić, Dubravka, "Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash-Statistical Analysis" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 37, no. 9 (2015):987-996,
https://doi.org/10.1080/15567036.2011.601793 . .

Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study

Sakan, Sanja; Dević, Gordana; Relić, Dubravka; Anđelković, Ivan; Sakan, Nenad; Đorđević, Dragana

(Springer, New York, 2015)

TY  - JOUR
AU  - Sakan, Sanja
AU  - Dević, Gordana
AU  - Relić, Dubravka
AU  - Anđelković, Ivan
AU  - Sakan, Nenad
AU  - Đorđević, Dragana
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1810
AB  - To effectively manage potential environmental and human health impacts of contaminated river sediments, it is important that information about the source (anthropogenic vs geogenic), variability and environmental risks associated with the contamination are well understood. The present study was carried out to assess the source and severity of contamination and to undertake a risk assessment for selected elements (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn) in river sediments in Serbia. The estimate of the anthropogenic component of contamination was derived by determining the total element content and the background values for elements in sediments, and the severity of pollution was assessed by calculating a number of pollution indices including the contamination factor, the enrichment factor, the index of geoaccumulation, the ecological risk factor, the potential ecological risk index, the pollution load index, the combined pollution index, the modified degree of contamination and the toxic unit factor. This analysis indicates that river sediments in Serbia are primarily polluted with Zn, Cu and Cd. The most contaminated river systems are the Ibar, Pek, West Morava and Great Morava rivers. Mining activities were found to have a significant influence on sediment. Multivariate analyses suggested anthropogenic origins for Pb, Zn, Cd, As, Ni and Cu, whilst Fe, V, Mn, Co and Cr appear to have a mixed origin (both lithogenic and anthropogenic sources). A geochemical approach, with a calculation of pollution indices and statistical methods, is recognised as useful for the risk management of trace elements in sediments around the world.
PB  - Springer, New York
T2  - Environmental Earth Sciences
T1  - Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study
VL  - 73
IS  - 10
SP  - 6625
EP  - 6638
DO  - 10.1007/s12665-014-3886-1
ER  - 
@article{
author = "Sakan, Sanja and Dević, Gordana and Relić, Dubravka and Anđelković, Ivan and Sakan, Nenad and Đorđević, Dragana",
year = "2015",
abstract = "To effectively manage potential environmental and human health impacts of contaminated river sediments, it is important that information about the source (anthropogenic vs geogenic), variability and environmental risks associated with the contamination are well understood. The present study was carried out to assess the source and severity of contamination and to undertake a risk assessment for selected elements (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn) in river sediments in Serbia. The estimate of the anthropogenic component of contamination was derived by determining the total element content and the background values for elements in sediments, and the severity of pollution was assessed by calculating a number of pollution indices including the contamination factor, the enrichment factor, the index of geoaccumulation, the ecological risk factor, the potential ecological risk index, the pollution load index, the combined pollution index, the modified degree of contamination and the toxic unit factor. This analysis indicates that river sediments in Serbia are primarily polluted with Zn, Cu and Cd. The most contaminated river systems are the Ibar, Pek, West Morava and Great Morava rivers. Mining activities were found to have a significant influence on sediment. Multivariate analyses suggested anthropogenic origins for Pb, Zn, Cd, As, Ni and Cu, whilst Fe, V, Mn, Co and Cr appear to have a mixed origin (both lithogenic and anthropogenic sources). A geochemical approach, with a calculation of pollution indices and statistical methods, is recognised as useful for the risk management of trace elements in sediments around the world.",
publisher = "Springer, New York",
journal = "Environmental Earth Sciences",
title = "Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study",
volume = "73",
number = "10",
pages = "6625-6638",
doi = "10.1007/s12665-014-3886-1"
}
Sakan, S., Dević, G., Relić, D., Anđelković, I., Sakan, N.,& Đorđević, D.. (2015). Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study. in Environmental Earth Sciences
Springer, New York., 73(10), 6625-6638.
https://doi.org/10.1007/s12665-014-3886-1
Sakan S, Dević G, Relić D, Anđelković I, Sakan N, Đorđević D. Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study. in Environmental Earth Sciences. 2015;73(10):6625-6638.
doi:10.1007/s12665-014-3886-1 .
Sakan, Sanja, Dević, Gordana, Relić, Dubravka, Anđelković, Ivan, Sakan, Nenad, Đorđević, Dragana, "Risk assessment of trace element contamination in river sediments in Serbia using pollution indices and statistical methods: a pilot study" in Environmental Earth Sciences, 73, no. 10 (2015):6625-6638,
https://doi.org/10.1007/s12665-014-3886-1 . .
22
19
25

Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization

Sakan, Sanja; Dević, Gordana; Relić, Dubravka; Anđelković, Ivan; Sakan, Nenad; Đorđević, Dragana

(Springer, Dordrecht, 2015)

TY  - JOUR
AU  - Sakan, Sanja
AU  - Dević, Gordana
AU  - Relić, Dubravka
AU  - Anđelković, Ivan
AU  - Sakan, Nenad
AU  - Đorđević, Dragana
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1757
AB  - In the present study, concentrations of heavy metals (Cd, Cu, Co, Mn, Cr, Ni, Pb, and Zn) were determined at 35 river sediments in Serbia. The anthropogenic heavy metals input and quantification of the metal enrichment degree in sediments were estimated by calculating geo-accumulation indices (I-geo) and enrichment factors (EF). These pollution indices have been calculated using different background values (continental crust and local background values) and different element used for normalization (Al and Fe), followed by result comparison. The EF values calculated with continental crust as background (minor to extremely severe enrichment) were higher than when regional background values were used (minor to moderate enrichment). Significant influence of background values on the I-geo values is observed. Values of geo-accumulation index ( LT 2) revealed that studied river sediments are remaining unpolluted to moderately polluted with Co, Mn, Cr, and Ni. Significant pollution in the sediments was observed for Cd, Cu, Pb, and Zn elements. The results of this study confirm the relevance of precise and accurate determining of local background concentrations while assessing sediment pollution. The values of EFs for studied elements were more influenced by the choice of background values than selection of element used for normalization. Our recommendation would be to use the local and regional background content in quantification of metal contamination in sediments, since these values differ and are site and region dependent.
PB  - Springer, Dordrecht
T2  - Environmental Geochemistry and Health
T1  - Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization
VL  - 37
IS  - 1
SP  - 97
EP  - 113
DO  - 10.1007/s10653-014-9633-4
ER  - 
@article{
author = "Sakan, Sanja and Dević, Gordana and Relić, Dubravka and Anđelković, Ivan and Sakan, Nenad and Đorđević, Dragana",
year = "2015",
abstract = "In the present study, concentrations of heavy metals (Cd, Cu, Co, Mn, Cr, Ni, Pb, and Zn) were determined at 35 river sediments in Serbia. The anthropogenic heavy metals input and quantification of the metal enrichment degree in sediments were estimated by calculating geo-accumulation indices (I-geo) and enrichment factors (EF). These pollution indices have been calculated using different background values (continental crust and local background values) and different element used for normalization (Al and Fe), followed by result comparison. The EF values calculated with continental crust as background (minor to extremely severe enrichment) were higher than when regional background values were used (minor to moderate enrichment). Significant influence of background values on the I-geo values is observed. Values of geo-accumulation index ( LT 2) revealed that studied river sediments are remaining unpolluted to moderately polluted with Co, Mn, Cr, and Ni. Significant pollution in the sediments was observed for Cd, Cu, Pb, and Zn elements. The results of this study confirm the relevance of precise and accurate determining of local background concentrations while assessing sediment pollution. The values of EFs for studied elements were more influenced by the choice of background values than selection of element used for normalization. Our recommendation would be to use the local and regional background content in quantification of metal contamination in sediments, since these values differ and are site and region dependent.",
publisher = "Springer, Dordrecht",
journal = "Environmental Geochemistry and Health",
title = "Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization",
volume = "37",
number = "1",
pages = "97-113",
doi = "10.1007/s10653-014-9633-4"
}
Sakan, S., Dević, G., Relić, D., Anđelković, I., Sakan, N.,& Đorđević, D.. (2015). Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization. in Environmental Geochemistry and Health
Springer, Dordrecht., 37(1), 97-113.
https://doi.org/10.1007/s10653-014-9633-4
Sakan S, Dević G, Relić D, Anđelković I, Sakan N, Đorđević D. Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization. in Environmental Geochemistry and Health. 2015;37(1):97-113.
doi:10.1007/s10653-014-9633-4 .
Sakan, Sanja, Dević, Gordana, Relić, Dubravka, Anđelković, Ivan, Sakan, Nenad, Đorđević, Dragana, "Evaluation of sediment contamination with heavy metals: the importance of determining appropriate background content and suitable element for normalization" in Environmental Geochemistry and Health, 37, no. 1 (2015):97-113,
https://doi.org/10.1007/s10653-014-9633-4 . .
49
37
54

Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia

Sakan, Sanja; Dević, Gordana; Relić, Dubravka; Anđelković, Ivan; Sakan, Nenad; Đorđević, Dragana

(Wiley-Blackwell, Hoboken, 2015)

TY  - JOUR
AU  - Sakan, Sanja
AU  - Dević, Gordana
AU  - Relić, Dubravka
AU  - Anđelković, Ivan
AU  - Sakan, Nenad
AU  - Đorđević, Dragana
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1651
AB  - The purpose of this study was to evaluate sediment heavy metals (Cd, Cu, Co, Mn, Cr, Ni, Pb and Zn) related to pollution in freshwater sediments in Serbia. The heavy metal enrichment determination in studied sediments was conducted by using total metal content with strong acidic digestion (HCl + HNO3 + HF), a calculated enrichment factor (EF), and application of correlation analysis and the box plot method. For identification of appropriate elemental normalisers for enrichment factor calculations, Fe, Al, Ti and Si were used. The significant variation in heavy metal distribution among samples collected in this large region, encompassing all Serbian watersheds, suggests the selective contamination of sediments by heavy metals. Values for EF indicate nil to moderate enrichment for most studied elements, except for Cd, Cu, and Zn at some sampling points, where the enrichment was, in some cases, even severe. The high content of heavy metals and EFs in Serbia is related to the human activities around the sampling sites. The results indicate that all elements used for normalisation in this paper can also be used to estimate the anthropogenic influence, with an exception of Co, which should be considered as an element for normalisation in future studies.
PB  - Wiley-Blackwell, Hoboken
T2  - Clean-Soil Air Water
T1  - Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia
VL  - 43
IS  - 6
SP  - 838
EP  - 845
DO  - 10.1002/clen.201400275
ER  - 
@article{
author = "Sakan, Sanja and Dević, Gordana and Relić, Dubravka and Anđelković, Ivan and Sakan, Nenad and Đorđević, Dragana",
year = "2015",
abstract = "The purpose of this study was to evaluate sediment heavy metals (Cd, Cu, Co, Mn, Cr, Ni, Pb and Zn) related to pollution in freshwater sediments in Serbia. The heavy metal enrichment determination in studied sediments was conducted by using total metal content with strong acidic digestion (HCl + HNO3 + HF), a calculated enrichment factor (EF), and application of correlation analysis and the box plot method. For identification of appropriate elemental normalisers for enrichment factor calculations, Fe, Al, Ti and Si were used. The significant variation in heavy metal distribution among samples collected in this large region, encompassing all Serbian watersheds, suggests the selective contamination of sediments by heavy metals. Values for EF indicate nil to moderate enrichment for most studied elements, except for Cd, Cu, and Zn at some sampling points, where the enrichment was, in some cases, even severe. The high content of heavy metals and EFs in Serbia is related to the human activities around the sampling sites. The results indicate that all elements used for normalisation in this paper can also be used to estimate the anthropogenic influence, with an exception of Co, which should be considered as an element for normalisation in future studies.",
publisher = "Wiley-Blackwell, Hoboken",
journal = "Clean-Soil Air Water",
title = "Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia",
volume = "43",
number = "6",
pages = "838-845",
doi = "10.1002/clen.201400275"
}
Sakan, S., Dević, G., Relić, D., Anđelković, I., Sakan, N.,& Đorđević, D.. (2015). Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia. in Clean-Soil Air Water
Wiley-Blackwell, Hoboken., 43(6), 838-845.
https://doi.org/10.1002/clen.201400275
Sakan S, Dević G, Relić D, Anđelković I, Sakan N, Đorđević D. Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia. in Clean-Soil Air Water. 2015;43(6):838-845.
doi:10.1002/clen.201400275 .
Sakan, Sanja, Dević, Gordana, Relić, Dubravka, Anđelković, Ivan, Sakan, Nenad, Đorđević, Dragana, "Environmental Assessment of Heavy Metal Pollution in Freshwater Sediment, Serbia" in Clean-Soil Air Water, 43, no. 6 (2015):838-845,
https://doi.org/10.1002/clen.201400275 . .
10
7
14

Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension

Đorđević, Dragana; Stortini, Angela Maria; Relić, Dubravka; Mihajlidi Zelić, Aleksandra; Huremovic, Jasna; Barbante, Carlo; Gambaro, Andrea

(Springer Heidelberg, Heidelberg, 2014)

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Stortini, Angela Maria
AU  - Relić, Dubravka
AU  - Mihajlidi Zelić, Aleksandra
AU  - Huremovic, Jasna
AU  - Barbante, Carlo
AU  - Gambaro, Andrea
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1436
AB  - Size segregated particulate samples of atmospheric aerosols in urban site of continental part of Balkans were collected during 6 months in 2008. Six stages impactor in the size ranges: Dp  LT = 0.49 mu m, 0.49 LT Dp  LT = 0.95 mu m, 0.95 LT Dp  LT = 1.5 mu m, 1.5 LT Dp  LT = 3.0 mu m, 3.0 LT Dp  LT = 7.2 mu m, and 7.2 LT Dp  LT = 10.0 mu m was applied for sampling. ICP-MS was used to quantify elements: Al, As, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Na, Ni, Mg, Mn, Pb, Sb, V, and Zn. Two main groups of elements were investigated: (1) K, V, Ni, Zn, Pb, As, and Cd with high domination in nuclei mode indicating the combustion processes as a dominant sources and (2) Al, Fe, Ca, Mg, Na, Cr, Ga, Co, and Li in coarse mode indicating mechanical processes as their main origin. The strictly crustal origin is for Mg, Fe, Ca, and Co while for As, Cd, K, V, Ni, Cu, Pb, and Zn dominates the anthropogenic influence. The PCA analysis has shown that main contribution is of resuspension (PC1, sigma(2)approximate to 30 %) followed by traffic (PC2, sigma(2)approximate to 20 %) that are together contributing around 50 % of elements in the investigated urban aerosol. The EF model shows that major origin of Cd, K, V, Ni, Cu, Pb, Zn, and As in the fine mode is from the anthropogenic sources while increase of their contents in the coarse particles indicates their deposition from the atmosphere and soil contamination. This approach is useful for the assessment of the local resuspension influence on element's contents in the aerosol and also for the evaluation of the historical pollution of soil caused by deposition of metals from the atmosphere.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension
VL  - 21
IS  - 18
SP  - 10949
EP  - 10959
DO  - 10.1007/s11356-014-2998-1
ER  - 
@article{
author = "Đorđević, Dragana and Stortini, Angela Maria and Relić, Dubravka and Mihajlidi Zelić, Aleksandra and Huremovic, Jasna and Barbante, Carlo and Gambaro, Andrea",
year = "2014",
abstract = "Size segregated particulate samples of atmospheric aerosols in urban site of continental part of Balkans were collected during 6 months in 2008. Six stages impactor in the size ranges: Dp  LT = 0.49 mu m, 0.49 LT Dp  LT = 0.95 mu m, 0.95 LT Dp  LT = 1.5 mu m, 1.5 LT Dp  LT = 3.0 mu m, 3.0 LT Dp  LT = 7.2 mu m, and 7.2 LT Dp  LT = 10.0 mu m was applied for sampling. ICP-MS was used to quantify elements: Al, As, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K, Li, Na, Ni, Mg, Mn, Pb, Sb, V, and Zn. Two main groups of elements were investigated: (1) K, V, Ni, Zn, Pb, As, and Cd with high domination in nuclei mode indicating the combustion processes as a dominant sources and (2) Al, Fe, Ca, Mg, Na, Cr, Ga, Co, and Li in coarse mode indicating mechanical processes as their main origin. The strictly crustal origin is for Mg, Fe, Ca, and Co while for As, Cd, K, V, Ni, Cu, Pb, and Zn dominates the anthropogenic influence. The PCA analysis has shown that main contribution is of resuspension (PC1, sigma(2)approximate to 30 %) followed by traffic (PC2, sigma(2)approximate to 20 %) that are together contributing around 50 % of elements in the investigated urban aerosol. The EF model shows that major origin of Cd, K, V, Ni, Cu, Pb, Zn, and As in the fine mode is from the anthropogenic sources while increase of their contents in the coarse particles indicates their deposition from the atmosphere and soil contamination. This approach is useful for the assessment of the local resuspension influence on element's contents in the aerosol and also for the evaluation of the historical pollution of soil caused by deposition of metals from the atmosphere.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension",
volume = "21",
number = "18",
pages = "10949-10959",
doi = "10.1007/s11356-014-2998-1"
}
Đorđević, D., Stortini, A. M., Relić, D., Mihajlidi Zelić, A., Huremovic, J., Barbante, C.,& Gambaro, A.. (2014). Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 21(18), 10949-10959.
https://doi.org/10.1007/s11356-014-2998-1
Đorđević D, Stortini AM, Relić D, Mihajlidi Zelić A, Huremovic J, Barbante C, Gambaro A. Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension. in Environmental Science and Pollution Research. 2014;21(18):10949-10959.
doi:10.1007/s11356-014-2998-1 .
Đorđević, Dragana, Stortini, Angela Maria, Relić, Dubravka, Mihajlidi Zelić, Aleksandra, Huremovic, Jasna, Barbante, Carlo, Gambaro, Andrea, "Trace elements in size-segregated urban aerosol in relation to the anthropogenic emission sources and the resuspension" in Environmental Science and Pollution Research, 21, no. 18 (2014):10949-10959,
https://doi.org/10.1007/s11356-014-2998-1 . .
18
14
17

Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia

Relić, Dubravka; Đorđević, Dragana; Sakan, Sanja; Anđelković, Ivan; Pantelić, Ana; Stanković, Ratomir; Popović, Aleksandar R.

(Springer, Dordrecht, 2013)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Đorđević, Dragana
AU  - Sakan, Sanja
AU  - Anđelković, Ivan
AU  - Pantelić, Ana
AU  - Stanković, Ratomir
AU  - Popović, Aleksandar R.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1206
AB  - In this paper, the main objective was fractionation of Cd, Cu, Ni, Pb, Zn, Ca, Fe, and K in certificate material and sediment samples gathered from and around the Petrochemical Industry using the conventional, microwave and ultrasonic sequential extraction. Microwave oven and ultrasound bath were used as an energy source for achieving faster extraction. Additional heating and boiling of samples were avoided by using lower power and shorter time for microwave and ultrasound extraction. Precision and accuracy of procedure were evaluated by using certificate material (BCR701). Acceptable accuracy of metals (87.0-111.3 %) was achieved for all three-step sequential of conventional extraction protocol. An accuracy of the fourth step has been verified with two certificate materials: BCR143R and 146R. The range of total extracted metal concentrations from sediments was similar for all three extraction techniques. A significant high percentage of Cd, Cu, and Zn were obtained after extraction of the exchangeable and acid soluble sediment fraction. Principal component analysis of values obtained after determination of risk assessment code using conventional and ultrasound sequential extraction show similarity of these values. Accuracy, recovery, and risk assessment code values imply that ultrasound sequential extraction is a more suitable, accelerated sequential extraction procedure (30 min per extraction step) than microwave extraction in applied conditions.
PB  - Springer, Dordrecht
T2  - Environmental Monitoring and Assessment
T1  - Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia
VL  - 185
IS  - 9
SP  - 7627
EP  - 7645
DO  - 10.1007/s10661-013-3124-4
ER  - 
@article{
author = "Relić, Dubravka and Đorđević, Dragana and Sakan, Sanja and Anđelković, Ivan and Pantelić, Ana and Stanković, Ratomir and Popović, Aleksandar R.",
year = "2013",
abstract = "In this paper, the main objective was fractionation of Cd, Cu, Ni, Pb, Zn, Ca, Fe, and K in certificate material and sediment samples gathered from and around the Petrochemical Industry using the conventional, microwave and ultrasonic sequential extraction. Microwave oven and ultrasound bath were used as an energy source for achieving faster extraction. Additional heating and boiling of samples were avoided by using lower power and shorter time for microwave and ultrasound extraction. Precision and accuracy of procedure were evaluated by using certificate material (BCR701). Acceptable accuracy of metals (87.0-111.3 %) was achieved for all three-step sequential of conventional extraction protocol. An accuracy of the fourth step has been verified with two certificate materials: BCR143R and 146R. The range of total extracted metal concentrations from sediments was similar for all three extraction techniques. A significant high percentage of Cd, Cu, and Zn were obtained after extraction of the exchangeable and acid soluble sediment fraction. Principal component analysis of values obtained after determination of risk assessment code using conventional and ultrasound sequential extraction show similarity of these values. Accuracy, recovery, and risk assessment code values imply that ultrasound sequential extraction is a more suitable, accelerated sequential extraction procedure (30 min per extraction step) than microwave extraction in applied conditions.",
publisher = "Springer, Dordrecht",
journal = "Environmental Monitoring and Assessment",
title = "Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia",
volume = "185",
number = "9",
pages = "7627-7645",
doi = "10.1007/s10661-013-3124-4"
}
Relić, D., Đorđević, D., Sakan, S., Anđelković, I., Pantelić, A., Stanković, R.,& Popović, A. R.. (2013). Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia. in Environmental Monitoring and Assessment
Springer, Dordrecht., 185(9), 7627-7645.
https://doi.org/10.1007/s10661-013-3124-4
Relić D, Đorđević D, Sakan S, Anđelković I, Pantelić A, Stanković R, Popović AR. Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia. in Environmental Monitoring and Assessment. 2013;185(9):7627-7645.
doi:10.1007/s10661-013-3124-4 .
Relić, Dubravka, Đorđević, Dragana, Sakan, Sanja, Anđelković, Ivan, Pantelić, Ana, Stanković, Ratomir, Popović, Aleksandar R., "Conventional, microwave, and ultrasound sequential extractions for the fractionation of metals in sediments within the Petrochemical Industry, Serbia" in Environmental Monitoring and Assessment, 185, no. 9 (2013):7627-7645,
https://doi.org/10.1007/s10661-013-3124-4 . .
21
16
21

Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments

Popović, Aleksandar R.; Đorđević, Dragana; Relić, Dubravka

(Taylor & Francis Inc, Philadelphia, 2013)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1285
AB  - Serbia obtains most of its energy from low-quality lignite, thus being one of the world's largest producers of coal ash per capita. In order to examine the distribution of trace and major elements in the ash and the pollution potential of the ash itself, six combined samples of filter ash, obtained by lignite combustion in the Nikola Tesla A Power Plant, were subjected to a five-phase sequential extraction. Analysis of obtained concentrations revealed the short- and long-term pollution capacity of different elements as well as the influence ionic strength of river water may have to the pollution of neighboring waters.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments
VL  - 35
IS  - 6
SP  - 529
EP  - 537
DO  - 10.1080/15567036.2011.590856
ER  - 
@article{
author = "Popović, Aleksandar R. and Đorđević, Dragana and Relić, Dubravka",
year = "2013",
abstract = "Serbia obtains most of its energy from low-quality lignite, thus being one of the world's largest producers of coal ash per capita. In order to examine the distribution of trace and major elements in the ash and the pollution potential of the ash itself, six combined samples of filter ash, obtained by lignite combustion in the Nikola Tesla A Power Plant, were subjected to a five-phase sequential extraction. Analysis of obtained concentrations revealed the short- and long-term pollution capacity of different elements as well as the influence ionic strength of river water may have to the pollution of neighboring waters.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments",
volume = "35",
number = "6",
pages = "529-537",
doi = "10.1080/15567036.2011.590856"
}
Popović, A. R., Đorđević, D.,& Relić, D.. (2013). Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 35(6), 529-537.
https://doi.org/10.1080/15567036.2011.590856
Popović AR, Đorđević D, Relić D. Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2013;35(6):529-537.
doi:10.1080/15567036.2011.590856 .
Popović, Aleksandar R., Đorđević, Dragana, Relić, Dubravka, "Associations and Pollution Potential of Selected Trace and Major Elements in Filter Lignite Ash from the "Nikola Tesla A" Power Plant (Obrenovac, Serbia) (I) - Leaching Experiments" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 35, no. 6 (2013):529-537,
https://doi.org/10.1080/15567036.2011.590856 . .
7
8
9

An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia

Relić, Dubravka; Đorđević, Dragana; Sakan, Sanja; Anđelković, Ivan; Pantelić, Ana; Stanković, R.; Radojičić, A.; Popović, Aleksandar R.

(EDP Sciences, 2013)

TY  - CONF
AU  - Relić, Dubravka
AU  - Đorđević, Dragana
AU  - Sakan, Sanja
AU  - Anđelković, Ivan
AU  - Pantelić, Ana
AU  - Stanković, R.
AU  - Radojičić, A.
AU  - Popović, Aleksandar R.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1370
AB  - We use conventional, microwave and ultrasound assisted sequential extraction, of defined time and power, techniques for extractions of Cd, Cu, Cr, Ni, Pb and Zn in sediments and certified material. We did not change the conditions of extractions through steps, cause we what to see is there difference in extraction results for the certified material and sediments. We use lower powers and time from microwave and ultrasound extraction in order to avoid additional heating and boiling of the samples. Steps 1-3 of the BCR (Community Bureau of Reference), excluding the hydrogen peroxide digestion in step 3, were completed in 16 h in the conventional, in 120 s with 90 W power of microwave and in 30 min of 42 kHz of an ultrasonic frequency. Digestion of organic matter with hydrogen peroxide was performed the same for all techniques. The fourth step, the pseudo-total content, was performed the same on samples remaining after performing the extraction of the previous three phases either conventionally, microwave-assisted or with ultrasound. The precision and accuracy of the proposed procedures were evaluated using a certified reference material BCR701. Acceptable accuracy for most of the metals was observed for all three steps of BCR protocol applying a 16 h total shaking period. Metals were determined with an acceptable accuracy after the pseudo-total step; expect Cr. Results obtained after the application of different techniques on sediments were comparable with ANOVA test for the 95 % of confidence level.
PB  - EDP Sciences
C3  - E3S Web of Conferences
T1  - An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia
VL  - 1
DO  - 10.1051/e3sconf/20130139002
ER  - 
@conference{
author = "Relić, Dubravka and Đorđević, Dragana and Sakan, Sanja and Anđelković, Ivan and Pantelić, Ana and Stanković, R. and Radojičić, A. and Popović, Aleksandar R.",
year = "2013",
abstract = "We use conventional, microwave and ultrasound assisted sequential extraction, of defined time and power, techniques for extractions of Cd, Cu, Cr, Ni, Pb and Zn in sediments and certified material. We did not change the conditions of extractions through steps, cause we what to see is there difference in extraction results for the certified material and sediments. We use lower powers and time from microwave and ultrasound extraction in order to avoid additional heating and boiling of the samples. Steps 1-3 of the BCR (Community Bureau of Reference), excluding the hydrogen peroxide digestion in step 3, were completed in 16 h in the conventional, in 120 s with 90 W power of microwave and in 30 min of 42 kHz of an ultrasonic frequency. Digestion of organic matter with hydrogen peroxide was performed the same for all techniques. The fourth step, the pseudo-total content, was performed the same on samples remaining after performing the extraction of the previous three phases either conventionally, microwave-assisted or with ultrasound. The precision and accuracy of the proposed procedures were evaluated using a certified reference material BCR701. Acceptable accuracy for most of the metals was observed for all three steps of BCR protocol applying a 16 h total shaking period. Metals were determined with an acceptable accuracy after the pseudo-total step; expect Cr. Results obtained after the application of different techniques on sediments were comparable with ANOVA test for the 95 % of confidence level.",
publisher = "EDP Sciences",
journal = "E3S Web of Conferences",
title = "An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia",
volume = "1",
doi = "10.1051/e3sconf/20130139002"
}
Relić, D., Đorđević, D., Sakan, S., Anđelković, I., Pantelić, A., Stanković, R., Radojičić, A.,& Popović, A. R.. (2013). An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia. in E3S Web of Conferences
EDP Sciences., 1.
https://doi.org/10.1051/e3sconf/20130139002
Relić D, Đorđević D, Sakan S, Anđelković I, Pantelić A, Stanković R, Radojičić A, Popović AR. An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia. in E3S Web of Conferences. 2013;1.
doi:10.1051/e3sconf/20130139002 .
Relić, Dubravka, Đorđević, Dragana, Sakan, Sanja, Anđelković, Ivan, Pantelić, Ana, Stanković, R., Radojičić, A., Popović, Aleksandar R., "An appraisal of conventional, microwave and ultrasound BCR extraction methods for the analysis of metals in sediments of Pančevo, Serbia" in E3S Web of Conferences, 1 (2013),
https://doi.org/10.1051/e3sconf/20130139002 . .
3
3

Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade)

Đorđević, Dragana; Stortini, A.M.; Relić, Dubravka; Mihajlidi Zelić, Aleksandra; Huremović, J.; Gambaro, Andrea

(EDP Sciences, 2013)

TY  - CONF
AU  - Đorđević, Dragana
AU  - Stortini, A.M.
AU  - Relić, Dubravka
AU  - Mihajlidi Zelić, Aleksandra
AU  - Huremović, J.
AU  - Gambaro, Andrea
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1376
AB  - This work focuses on the heavy metals contents of the size-segregated urban aerosol of the continental area of Balkans. The distribution of nano/micron heavy metals in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges Dp ≤0.49 μm, 0.49 ≤ Dp ≤0.95 μm, 0.95 ≤ Dp ≤1.5 μm, 1.5 ≤ Dp ≤3.0 μm, 3.0 ≤ Dp ≤7.2 μm and Dp ≥ 7.2 μm was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (mGM) and, for heavy metals analyzed by ICP/MS.
PB  - EDP Sciences
C3  - E3S Web of Conferences
T1  - Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade)
VL  - 1
DO  - 10.1051/e3sconf/20130103006
ER  - 
@conference{
author = "Đorđević, Dragana and Stortini, A.M. and Relić, Dubravka and Mihajlidi Zelić, Aleksandra and Huremović, J. and Gambaro, Andrea",
year = "2013",
abstract = "This work focuses on the heavy metals contents of the size-segregated urban aerosol of the continental area of Balkans. The distribution of nano/micron heavy metals in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges Dp ≤0.49 μm, 0.49 ≤ Dp ≤0.95 μm, 0.95 ≤ Dp ≤1.5 μm, 1.5 ≤ Dp ≤3.0 μm, 3.0 ≤ Dp ≤7.2 μm and Dp ≥ 7.2 μm was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (mGM) and, for heavy metals analyzed by ICP/MS.",
publisher = "EDP Sciences",
journal = "E3S Web of Conferences",
title = "Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade)",
volume = "1",
doi = "10.1051/e3sconf/20130103006"
}
Đorđević, D., Stortini, A.M., Relić, D., Mihajlidi Zelić, A., Huremović, J.,& Gambaro, A.. (2013). Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade). in E3S Web of Conferences
EDP Sciences., 1.
https://doi.org/10.1051/e3sconf/20130103006
Đorđević D, Stortini A, Relić D, Mihajlidi Zelić A, Huremović J, Gambaro A. Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade). in E3S Web of Conferences. 2013;1.
doi:10.1051/e3sconf/20130103006 .
Đorđević, Dragana, Stortini, A.M., Relić, Dubravka, Mihajlidi Zelić, Aleksandra, Huremović, J., Gambaro, Andrea, "Size-segregated concentration of heavy metals in an urban aerosol of the Balkans region (Belgrade)" in E3S Web of Conferences, 1 (2013),
https://doi.org/10.1051/e3sconf/20130103006 . .

Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)

Đorđević, Dragana; Mihajlidi Zelić, Aleksandra; Relić, Dubravka; Ignjatović, Ljubiša M.; Huremovic, J.; Stortini, A. M.; Gambaro, Andrea

(Oxford : Pergamon-Elsevier Science Ltd, 2012)

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Mihajlidi Zelić, Aleksandra
AU  - Relić, Dubravka
AU  - Ignjatović, Ljubiša M.
AU  - Huremovic, J.
AU  - Stortini, A. M.
AU  - Gambaro, Andrea
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1010
AB  - The distribution of nano/micron inorganic main ions in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges D(p)  LT = 0.49 mu m, 0.49  LT = D(p)  LT = 0.95 mu m, 0.95  LT = D(p)  LT = 1.5 mu m, 1.5  LT = D(p)  LT = 3.0 mu m, 3.0  LT = D(p)  LT = 7.2 mu m and D(p) >= 7.2 mu m was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (m(GM)) and, analyzed by ion chromatography for Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), PO(4)(3-) and SO(4)(2-). The mean random uncertainties associated with the determinations of Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-) and SO(4)(2-) were assessed. The absolute highest concentration is found for SO(4)(2-) (1555.8 +/- 973.6 ng m(-3)) in the range of D(p)  LT = 0.49 mu m with an average participation of 8.19% to the total mass of the particles. The highest coefficients of correlation were found between NH(4)(+) and SO(4)(2-). Principal component analysis, PCA, was used for the identification and evaluation of the contributions of the main emission sources to the contents of water soluble ions in the urban aerosol. The formation of (NH(4))(2)SO(4) was found to be the dominant process. The influences of local urban (traffic) and regional industrial sources (nearby city Pancevo) were identified and a contribution of marine aerosol was observed.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Atmospheric Environment
T1  - Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)
VL  - 46
SP  - 309
EP  - 317
DO  - 10.1016/j.atmosenv.2011.09.057
ER  - 
@article{
author = "Đorđević, Dragana and Mihajlidi Zelić, Aleksandra and Relić, Dubravka and Ignjatović, Ljubiša M. and Huremovic, J. and Stortini, A. M. and Gambaro, Andrea",
year = "2012",
abstract = "The distribution of nano/micron inorganic main ions in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges D(p)  LT = 0.49 mu m, 0.49  LT = D(p)  LT = 0.95 mu m, 0.95  LT = D(p)  LT = 1.5 mu m, 1.5  LT = D(p)  LT = 3.0 mu m, 3.0  LT = D(p)  LT = 7.2 mu m and D(p) >= 7.2 mu m was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (m(GM)) and, analyzed by ion chromatography for Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), PO(4)(3-) and SO(4)(2-). The mean random uncertainties associated with the determinations of Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-) and SO(4)(2-) were assessed. The absolute highest concentration is found for SO(4)(2-) (1555.8 +/- 973.6 ng m(-3)) in the range of D(p)  LT = 0.49 mu m with an average participation of 8.19% to the total mass of the particles. The highest coefficients of correlation were found between NH(4)(+) and SO(4)(2-). Principal component analysis, PCA, was used for the identification and evaluation of the contributions of the main emission sources to the contents of water soluble ions in the urban aerosol. The formation of (NH(4))(2)SO(4) was found to be the dominant process. The influences of local urban (traffic) and regional industrial sources (nearby city Pancevo) were identified and a contribution of marine aerosol was observed.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Atmospheric Environment",
title = "Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)",
volume = "46",
pages = "309-317",
doi = "10.1016/j.atmosenv.2011.09.057"
}
Đorđević, D., Mihajlidi Zelić, A., Relić, D., Ignjatović, L. M., Huremovic, J., Stortini, A. M.,& Gambaro, A.. (2012). Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade). in Atmospheric Environment
Oxford : Pergamon-Elsevier Science Ltd., 46, 309-317.
https://doi.org/10.1016/j.atmosenv.2011.09.057
Đorđević D, Mihajlidi Zelić A, Relić D, Ignjatović LM, Huremovic J, Stortini AM, Gambaro A. Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade). in Atmospheric Environment. 2012;46:309-317.
doi:10.1016/j.atmosenv.2011.09.057 .
Đorđević, Dragana, Mihajlidi Zelić, Aleksandra, Relić, Dubravka, Ignjatović, Ljubiša M., Huremovic, J., Stortini, A. M., Gambaro, Andrea, "Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)" in Atmospheric Environment, 46 (2012):309-317,
https://doi.org/10.1016/j.atmosenv.2011.09.057 . .
31
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38

Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade)

Buha, Jelena; Đorđević, Dragana; Relić, Dubravka; Mihajlidi Zelić, Aleksandra; Stortini, Angela Maria; Gambaro, Andrea

(American Chemical Society (ACS), 2012)

TY  - CONF
AU  - Buha, Jelena
AU  - Đorđević, Dragana
AU  - Relić, Dubravka
AU  - Mihajlidi Zelić, Aleksandra
AU  - Stortini, Angela Maria
AU  - Gambaro, Andrea
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1067
AB  - Size-segregated urban aerosol of Belgrade center (44049'14''N, 20027'44''E) was studied during the summer-autumn 2008. The representative location in traffic area Studentski trg was chosen for investigating physical and chemical characteristics of collected particles. Particle size distribution in the size range Dp = 0.49 m, 0.49 = Dp = 0.95 m, 0.95 = Dp = 1.5 m, 1.5 = Dp = 3.0 m, 3.0 = Dp = 7.2 m and Dp = 7.2 m were measured. Aerosol samples were submitted to gravimetric SEM analysis. The shape, size and chemical composition of the fine and coarse particles were analyzed. The imaging was carried out by SEM (Nova NanoSEM 230, FEI, USA). The same SEM was also used for the EDX measurements performed. The particles collected on fiber filters for SEM imaging were further on coated with 4 nm Pt layer to improve conductivity of the samples. The morphological and chemical composition suggested that the most abundant particles were carbonaceous soot but also microbes and natural and anthropogenic inorganic mineral materials. The chemical characterization was performed on a semi-quantitative level. The contents of the carbon were up to 70% or higher. In the samples were dominating next others elements: O, Mo, Si, Fe, Ca, Al, K, Mg.
PB  - American Chemical Society (ACS)
C3  - Abstracts of Papers of the American Chemical Society
T1  - Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade)
VL  - 244
SP  - 331-ENVR
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1402
ER  - 
@conference{
author = "Buha, Jelena and Đorđević, Dragana and Relić, Dubravka and Mihajlidi Zelić, Aleksandra and Stortini, Angela Maria and Gambaro, Andrea",
year = "2012",
abstract = "Size-segregated urban aerosol of Belgrade center (44049'14''N, 20027'44''E) was studied during the summer-autumn 2008. The representative location in traffic area Studentski trg was chosen for investigating physical and chemical characteristics of collected particles. Particle size distribution in the size range Dp = 0.49 m, 0.49 = Dp = 0.95 m, 0.95 = Dp = 1.5 m, 1.5 = Dp = 3.0 m, 3.0 = Dp = 7.2 m and Dp = 7.2 m were measured. Aerosol samples were submitted to gravimetric SEM analysis. The shape, size and chemical composition of the fine and coarse particles were analyzed. The imaging was carried out by SEM (Nova NanoSEM 230, FEI, USA). The same SEM was also used for the EDX measurements performed. The particles collected on fiber filters for SEM imaging were further on coated with 4 nm Pt layer to improve conductivity of the samples. The morphological and chemical composition suggested that the most abundant particles were carbonaceous soot but also microbes and natural and anthropogenic inorganic mineral materials. The chemical characterization was performed on a semi-quantitative level. The contents of the carbon were up to 70% or higher. In the samples were dominating next others elements: O, Mo, Si, Fe, Ca, Al, K, Mg.",
publisher = "American Chemical Society (ACS)",
journal = "Abstracts of Papers of the American Chemical Society",
title = "Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade)",
volume = "244",
pages = "331-ENVR",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1402"
}
Buha, J., Đorđević, D., Relić, D., Mihajlidi Zelić, A., Stortini, A. M.,& Gambaro, A.. (2012). Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade). in Abstracts of Papers of the American Chemical Society
American Chemical Society (ACS)., 244, 331-ENVR.
https://hdl.handle.net/21.15107/rcub_cherry_1402
Buha J, Đorđević D, Relić D, Mihajlidi Zelić A, Stortini AM, Gambaro A. Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade). in Abstracts of Papers of the American Chemical Society. 2012;244:331-ENVR.
https://hdl.handle.net/21.15107/rcub_cherry_1402 .
Buha, Jelena, Đorđević, Dragana, Relić, Dubravka, Mihajlidi Zelić, Aleksandra, Stortini, Angela Maria, Gambaro, Andrea, "Physical and chemical characteristic of urban aerosol of central Balkans (Belgrade)" in Abstracts of Papers of the American Chemical Society, 244 (2012):331-ENVR,
https://hdl.handle.net/21.15107/rcub_cherry_1402 .