TY  - JOUR
AU  - Trmčić, Milena
AU  - Vulović, Bojan
AU  - Zlatar, Matija
AU  - Saičić, Radomir N.
PY  - 2024
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7041
AB  - Hemiacetals of cyclopropanone can be isolated and stocked, contrary to their highly reactive parent ketone.  However, they are not readily converted to cyclopropanone, which limits their use as its synthetic equivalents.  2,2,2-trifluoroethoxy hemiacetals are expected to be better cyclopropanone surrogates, however, they have  never been prepared, so far. We show that oxyallyl cations with a heteroatom in the -position can be  intercepted with 2,2,2-trifluoroethanol, with formation of cyclopropanone trifluoroethoxy hemiacetals stable  enough to be isolated, purified and characterized. These species can serve as synthetic equivalents of  cyclopropanone under mild conditions.
PB  - ARKAT USA, Inc.
T2  - ARKIVOC - Online Journal of Organic Chemistry
T1  - Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation
VL  - 2024
IS  - 2
DO  - 10.24820/ark.5550190.p012.123
ER  - 

@article{
author = "Trmčić, Milena and Vulović, Bojan and Zlatar, Matija and Saičić, Radomir N.",
year = "2024",
abstract = "Hemiacetals of cyclopropanone can be isolated and stocked, contrary to their highly reactive parent ketone.  However, they are not readily converted to cyclopropanone, which limits their use as its synthetic equivalents.  2,2,2-trifluoroethoxy hemiacetals are expected to be better cyclopropanone surrogates, however, they have  never been prepared, so far. We show that oxyallyl cations with a heteroatom in the -position can be  intercepted with 2,2,2-trifluoroethanol, with formation of cyclopropanone trifluoroethoxy hemiacetals stable  enough to be isolated, purified and characterized. These species can serve as synthetic equivalents of  cyclopropanone under mild conditions.",
publisher = "ARKAT USA, Inc.",
journal = "ARKIVOC - Online Journal of Organic Chemistry",
title = "Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation",
volume = "2024",
number = "2",
doi = "10.24820/ark.5550190.p012.123"
}

Trmčić, M., Vulović, B., Zlatar, M.,& Saičić, R. N.. (2024). Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation. in ARKIVOC - Online Journal of Organic Chemistry
ARKAT USA, Inc.., 2024(2).
https://doi.org/10.24820/ark.5550190.p012.123

Trmčić M, Vulović B, Zlatar M, Saičić RN. Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation. in ARKIVOC - Online Journal of Organic Chemistry. 2024;2024(2).
doi:10.24820/ark.5550190.p012.123 .

Trmčić, Milena, Vulović, Bojan, Zlatar, Matija, Saičić, Radomir N., "Preparation of cyclopropanone 2,2,2-trifluoroethoxy hemiacetals via oxyallyl cation" in ARKIVOC - Online Journal of Organic Chemistry, 2024, no. 2 (2024),
https://doi.org/10.24820/ark.5550190.p012.123 . .

TY  - JOUR
AU  - Stjepanovic, Mihailo
AU  - Janković, Aleksandar
AU  - Vulović, Bojan
AU  - Matović, Radomir
AU  - Saičić, Radomir
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7160
AB  - The synthesis of an angular triquinane, which could serve as a suit­able platform for the synthesis of several natural products (panaginsene, sil­phi­nene, senoxydene) is described. The synthesis is based on two consecutive cyc­lo­pentene annulations, where alkenes were used as latent carbonyl function­alities (via Wacker reaction), and cyclopentenone annulation was effected by aldol condensation.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Synthetic study on the angular triquinanes: Scientific paper
VL  - 88
IS  - 10
SP  - 975
EP  - 983
DO  - 10.2298/JSC230627046S
ER  - 

@article{
author = "Stjepanovic, Mihailo and Janković, Aleksandar and Vulović, Bojan and Matović, Radomir and Saičić, Radomir",
year = "2023",
abstract = "The synthesis of an angular triquinane, which could serve as a suit­able platform for the synthesis of several natural products (panaginsene, sil­phi­nene, senoxydene) is described. The synthesis is based on two consecutive cyc­lo­pentene annulations, where alkenes were used as latent carbonyl function­alities (via Wacker reaction), and cyclopentenone annulation was effected by aldol condensation.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Synthetic study on the angular triquinanes: Scientific paper",
volume = "88",
number = "10",
pages = "975-983",
doi = "10.2298/JSC230627046S"
}

Stjepanovic, M., Janković, A., Vulović, B., Matović, R.,& Saičić, R.. (2023). Synthetic study on the angular triquinanes: Scientific paper. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 88(10), 975-983.
https://doi.org/10.2298/JSC230627046S

Stjepanovic M, Janković A, Vulović B, Matović R, Saičić R. Synthetic study on the angular triquinanes: Scientific paper. in Journal of the Serbian Chemical Society. 2023;88(10):975-983.
doi:10.2298/JSC230627046S .

Stjepanovic, Mihailo, Janković, Aleksandar, Vulović, Bojan, Matović, Radomir, Saičić, Radomir, "Synthetic study on the angular triquinanes: Scientific paper" in Journal of the Serbian Chemical Society, 88, no. 10 (2023):975-983,
https://doi.org/10.2298/JSC230627046S . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Trmčić, Milena
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2019
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3819
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3388
AB  - Unsaturated oxyallyl cations with a suitably positioned alkene bond undergo 5-exo-cyclization with the formation of vinylcyclopentane derivatives. Alkyne analogues provide allenes. The reaction proceeds with a moderate to excellent level of stereoselectivity and allows for asymmetric induction in the reaction with chiral substrate.
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation
VL  - 21
IS  - 23
SP  - 9618
EP  - 9621
DO  - 10.1021/acs.orglett.9b03791
ER  - 

@article{
author = "Vulović, Bojan and Trmčić, Milena and Matović, Radomir and Saičić, Radomir N.",
year = "2019",
abstract = "Unsaturated oxyallyl cations with a suitably positioned alkene bond undergo 5-exo-cyclization with the formation of vinylcyclopentane derivatives. Alkyne analogues provide allenes. The reaction proceeds with a moderate to excellent level of stereoselectivity and allows for asymmetric induction in the reaction with chiral substrate.",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation",
volume = "21",
number = "23",
pages = "9618-9621",
doi = "10.1021/acs.orglett.9b03791"
}

Vulović, B., Trmčić, M., Matović, R.,& Saičić, R. N.. (2019). Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation. in Organic Letters
American Chemical Society (ACS)., 21(23), 9618-9621.
https://doi.org/10.1021/acs.orglett.9b03791

Vulović B, Trmčić M, Matović R, Saičić RN. Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation. in Organic Letters. 2019;21(23):9618-9621.
doi:10.1021/acs.orglett.9b03791 .

Vulović, Bojan, Trmčić, Milena, Matović, Radomir, Saičić, Radomir N., "Cyclization Reactions of Oxyallyl Cation. A Method for Cyclopentane Ring Formation" in Organic Letters, 21, no. 23 (2019):9618-9621,
https://doi.org/10.1021/acs.orglett.9b03791 . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Kolarski, Dusan
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Gruden, Maja
AU  - Saičić, Radomir N.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1847
AB  - 1,6-Diynes with a t-butylcarbonate group in the propargylic position undergo gold(I)-catalyzed dominocyclization which affords alpha-hydroxycyclohexenones. The described sequence can be applied on functionalized, highly oxygenated substrates, as examplified in the synthesis of (-)-gabosine H and its epimer.
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H
VL  - 18
IS  - 15
SP  - 3886
EP  - 3889
DO  - 10.1021/acs.orglett.6b01898
ER  - 

@article{
author = "Vulović, Bojan and Kolarski, Dusan and Bihelović, Filip and Matović, Radomir and Gruden, Maja and Saičić, Radomir N.",
year = "2016",
abstract = "1,6-Diynes with a t-butylcarbonate group in the propargylic position undergo gold(I)-catalyzed dominocyclization which affords alpha-hydroxycyclohexenones. The described sequence can be applied on functionalized, highly oxygenated substrates, as examplified in the synthesis of (-)-gabosine H and its epimer.",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H",
volume = "18",
number = "15",
pages = "3886-3889",
doi = "10.1021/acs.orglett.6b01898"
}

Vulović, B., Kolarski, D., Bihelović, F., Matović, R., Gruden, M.,& Saičić, R. N.. (2016). Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H. in Organic Letters
American Chemical Society (ACS)., 18(15), 3886-3889.
https://doi.org/10.1021/acs.orglett.6b01898

Vulović B, Kolarski D, Bihelović F, Matović R, Gruden M, Saičić RN. Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H. in Organic Letters. 2016;18(15):3886-3889.
doi:10.1021/acs.orglett.6b01898 .

Vulović, Bojan, Kolarski, Dusan, Bihelović, Filip, Matović, Radomir, Gruden, Maja, Saičić, Radomir N., "Gold(I)-Catalyzed Domino Cyclizations of Diynes for the Synthesis of Functionalized Cyclohexenone Derivatives. Total Synthesis of (-)-Gabosine H and (-)-6-epi-Gabosine H" in Organic Letters, 18, no. 15 (2016):3886-3889,
https://doi.org/10.1021/acs.orglett.6b01898 . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Maric, Ivana
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2050
AB  - Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis of vinyldihydropyran by cooperative catalysis
VL  - 81
IS  - 12
SP  - 1335
EP  - 1343
DO  - 10.2298/JSC161102103V
ER  - 

@article{
author = "Vulović, Bojan and Maric, Ivana and Matović, Radomir and Saičić, Radomir N.",
year = "2016",
abstract = "Delta(5)-Unsaturated aldehydes with a suitably positioned allylic halide, or phosphate, leaving group undergo doubly-catalyzed cyclization to give dihydropyran derivatives. The cyclization proceeds under the synergetic action of diazabicycloundecene and Pd(PPh3)(4). This type of transformation was also accomplished with an aryl ketone.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis of vinyldihydropyran by cooperative catalysis",
volume = "81",
number = "12",
pages = "1335-1343",
doi = "10.2298/JSC161102103V"
}

Vulović, B., Maric, I., Matović, R.,& Saičić, R. N.. (2016). Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 81(12), 1335-1343.
https://doi.org/10.2298/JSC161102103V

Vulović B, Maric I, Matović R, Saičić RN. Synthesis of vinyldihydropyran by cooperative catalysis. in Journal of the Serbian Chemical Society. 2016;81(12):1335-1343.
doi:10.2298/JSC161102103V .

Vulović, Bojan, Maric, Ivana, Matović, Radomir, Saičić, Radomir N., "Synthesis of vinyldihydropyran by cooperative catalysis" in Journal of the Serbian Chemical Society, 81, no. 12 (2016):1335-1343,
https://doi.org/10.2298/JSC161102103V . .

TY  - JOUR
AU  - Novkovic, L
AU  - Trmcic, M
AU  - Rodić, Marko V.
AU  - Bihelović, Filip
AU  - Zlatar, Matija
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1796
AB  - Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.
PB  - Royal Soc Chemistry, Cambridge
T2  - RSC Advances
T1  - Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen
VL  - 5
IS  - 120
SP  - 99577
EP  - 99584
DO  - 10.1039/c5ra13476e
ER  - 

@article{
author = "Novkovic, L and Trmcic, M and Rodić, Marko V. and Bihelović, Filip and Zlatar, Matija and Matović, Radomir and Saičić, Radomir N.",
year = "2015",
abstract = "Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "RSC Advances",
title = "Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen",
volume = "5",
number = "120",
pages = "99577-99584",
doi = "10.1039/c5ra13476e"
}

Novkovic, L., Trmcic, M., Rodić, M. V., Bihelović, F., Zlatar, M., Matović, R.,& Saičić, R. N.. (2015). Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen. in RSC Advances
Royal Soc Chemistry, Cambridge., 5(120), 99577-99584.
https://doi.org/10.1039/c5ra13476e

Novkovic L, Trmcic M, Rodić MV, Bihelović F, Zlatar M, Matović R, Saičić RN. Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen. in RSC Advances. 2015;5(120):99577-99584.
doi:10.1039/c5ra13476e .

Novkovic, L, Trmcic, M, Rodić, Marko V., Bihelović, Filip, Zlatar, Matija, Matović, Radomir, Saičić, Radomir N., "Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen" in RSC Advances, 5, no. 120 (2015):99577-99584,
https://doi.org/10.1039/c5ra13476e . .

TY  - JOUR
AU  - Matović, Radomir
AU  - Bihelović, Filip
AU  - Gruden-Pavlović, Maja
AU  - Saičić, Radomir N.
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1400
AB  - The total synthesis of desmethylabyssomicin C analogue 1 was accomplished using diastereotopos-selective ring closing metathesis and Nozaki-Hiyama-Kishi cyclization as the key steps. The synthetic analogue retained its antibacterial activity against methicillin-resistant S. aureus strains, whereas its cytotoxicity decreased for three orders of magnitude, as compared to atrop-abyssomicin C.
PB  - Royal Soc Chemistry, Cambridge
T2  - Organic & Biomolecular Chemistry
T1  - Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C
VL  - 12
IS  - 39
SP  - 7682
EP  - 7685
DO  - 10.1039/c4ob01436g
ER  - 

@article{
author = "Matović, Radomir and Bihelović, Filip and Gruden-Pavlović, Maja and Saičić, Radomir N.",
year = "2014",
abstract = "The total synthesis of desmethylabyssomicin C analogue 1 was accomplished using diastereotopos-selective ring closing metathesis and Nozaki-Hiyama-Kishi cyclization as the key steps. The synthetic analogue retained its antibacterial activity against methicillin-resistant S. aureus strains, whereas its cytotoxicity decreased for three orders of magnitude, as compared to atrop-abyssomicin C.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Organic & Biomolecular Chemistry",
title = "Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C",
volume = "12",
number = "39",
pages = "7682-7685",
doi = "10.1039/c4ob01436g"
}

Matović, R., Bihelović, F., Gruden-Pavlović, M.,& Saičić, R. N.. (2014). Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C. in Organic & Biomolecular Chemistry
Royal Soc Chemistry, Cambridge., 12(39), 7682-7685.
https://doi.org/10.1039/c4ob01436g

Matović R, Bihelović F, Gruden-Pavlović M, Saičić RN. Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C. in Organic & Biomolecular Chemistry. 2014;12(39):7682-7685.
doi:10.1039/c4ob01436g .

Matović, Radomir, Bihelović, Filip, Gruden-Pavlović, Maja, Saičić, Radomir N., "Total synthesis and biological evaluation of atrop-O-benzyl-desmethylabyssomicin C" in Organic & Biomolecular Chemistry, 12, no. 39 (2014):7682-7685,
https://doi.org/10.1039/c4ob01436g . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Gruden-Pavlović, Maja
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1524
AB  - Organocatalyzed Tsuji-Trost cyclization of 3b proceeds with asymmetric induction and allows for stereoselective synthesis of (+)-allokainic acid. The stereochemical outcome of the cyclization was predicted by calculations.
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates
VL  - 16
IS  - 1
SP  - 34
EP  - 37
DO  - 10.1021/ol4028557
ER  - 

@article{
author = "Vulović, Bojan and Gruden-Pavlović, Maja and Matović, Radomir and Saičić, Radomir N.",
year = "2014",
abstract = "Organocatalyzed Tsuji-Trost cyclization of 3b proceeds with asymmetric induction and allows for stereoselective synthesis of (+)-allokainic acid. The stereochemical outcome of the cyclization was predicted by calculations.",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates",
volume = "16",
number = "1",
pages = "34-37",
doi = "10.1021/ol4028557"
}

Vulović, B., Gruden-Pavlović, M., Matović, R.,& Saičić, R. N.. (2014). Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates. in Organic Letters
American Chemical Society (ACS)., 16(1), 34-37.
https://doi.org/10.1021/ol4028557

Vulović B, Gruden-Pavlović M, Matović R, Saičić RN. Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates. in Organic Letters. 2014;16(1):34-37.
doi:10.1021/ol4028557 .

Vulović, Bojan, Gruden-Pavlović, Maja, Matović, Radomir, Saičić, Radomir N., "Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates" in Organic Letters, 16, no. 1 (2014):34-37,
https://doi.org/10.1021/ol4028557 . .

TY  - JOUR
AU  - Bihelović, Filip
AU  - Karadžić, Ivanka
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1214
AB  - Enantioselective synthesis of a marine antibiotic (-)-atrop-abyssomicin C was accomplished in 21 steps, in 1.8% overall yield (4%, based on the recovered starting material). The key steps of the synthesis are the formation of the functionalized cyclohexane core by an organocatalyzed Tsuji-Trost reaction, the formation of a tricyclic spirotetronate unit by a gold-catalyzed reaction sequence and the highly efficient eleven-membered ring closure by a Nozaki-Hiyama-Kishi reaction. Biological tests showed all abyssomicin derivatives to possess strong antibacterial activity against methicillin resistant S. aureus strains; however, they also proved to be cytotoxic, both to malignant and to normal somatic cells.
PB  - Royal Soc Chemistry, Cambridge
T2  - Organic & Biomolecular Chemistry
T1  - Total synthesis and biological evaluation of (-)-atrop-abyssomicin C
VL  - 11
IS  - 33
SP  - 5413
EP  - 5424
DO  - 10.1039/c3ob40692j
ER  - 

@article{
author = "Bihelović, Filip and Karadžić, Ivanka and Matović, Radomir and Saičić, Radomir N.",
year = "2013",
abstract = "Enantioselective synthesis of a marine antibiotic (-)-atrop-abyssomicin C was accomplished in 21 steps, in 1.8% overall yield (4%, based on the recovered starting material). The key steps of the synthesis are the formation of the functionalized cyclohexane core by an organocatalyzed Tsuji-Trost reaction, the formation of a tricyclic spirotetronate unit by a gold-catalyzed reaction sequence and the highly efficient eleven-membered ring closure by a Nozaki-Hiyama-Kishi reaction. Biological tests showed all abyssomicin derivatives to possess strong antibacterial activity against methicillin resistant S. aureus strains; however, they also proved to be cytotoxic, both to malignant and to normal somatic cells.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Organic & Biomolecular Chemistry",
title = "Total synthesis and biological evaluation of (-)-atrop-abyssomicin C",
volume = "11",
number = "33",
pages = "5413-5424",
doi = "10.1039/c3ob40692j"
}

Bihelović, F., Karadžić, I., Matović, R.,& Saičić, R. N.. (2013). Total synthesis and biological evaluation of (-)-atrop-abyssomicin C. in Organic & Biomolecular Chemistry
Royal Soc Chemistry, Cambridge., 11(33), 5413-5424.
https://doi.org/10.1039/c3ob40692j

Bihelović F, Karadžić I, Matović R, Saičić RN. Total synthesis and biological evaluation of (-)-atrop-abyssomicin C. in Organic & Biomolecular Chemistry. 2013;11(33):5413-5424.
doi:10.1039/c3ob40692j .

Bihelović, Filip, Karadžić, Ivanka, Matović, Radomir, Saičić, Radomir N., "Total synthesis and biological evaluation of (-)-atrop-abyssomicin C" in Organic & Biomolecular Chemistry, 11, no. 33 (2013):5413-5424,
https://doi.org/10.1039/c3ob40692j . .

TY  - JOUR
AU  - Marjanovic, Jasna
AU  - Divjakovic, Vladimir
AU  - Matović, Radomir
AU  - Ferjančić, Zorana
AU  - Saičić, Radomir N.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1215
AB  - The stereodivergent synthesis of two hyacinthacine analogues, which relies on an organocatalyzed aldol addition, is described. The aldol addition of dioxanone to an -N-carbobenzyloxy-substituted chiral aldehyde, promoted by both (R)- and (S)-proline, proceeds in reasonable yields with acceptable diastereomeric ratios. The success of the reaction may be due to the use of an acyclic aldehyde acceptor, which allows reagent control of the stereochemical outcome of the key aldolization step in both the matched and mismatched cases.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - European Journal of Organic Chemistry
T1  - Double Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1)
VL  - 2013
IS  - 25
SP  - 5555
EP  - 5560
DO  - 10.1002/ejoc.201300716
ER  - 

@article{
author = "Marjanovic, Jasna and Divjakovic, Vladimir and Matović, Radomir and Ferjančić, Zorana and Saičić, Radomir N.",
year = "2013",
abstract = "The stereodivergent synthesis of two hyacinthacine analogues, which relies on an organocatalyzed aldol addition, is described. The aldol addition of dioxanone to an -N-carbobenzyloxy-substituted chiral aldehyde, promoted by both (R)- and (S)-proline, proceeds in reasonable yields with acceptable diastereomeric ratios. The success of the reaction may be due to the use of an acyclic aldehyde acceptor, which allows reagent control of the stereochemical outcome of the key aldolization step in both the matched and mismatched cases.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "European Journal of Organic Chemistry",
title = "Double Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1)",
volume = "2013",
number = "25",
pages = "5555-5560",
doi = "10.1002/ejoc.201300716"
}

Marjanovic, J., Divjakovic, V., Matović, R., Ferjančić, Z.,& Saičić, R. N.. (2013). Double Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1). in European Journal of Organic Chemistry
Wiley-V C H Verlag Gmbh, Weinheim., 2013(25), 5555-5560.
https://doi.org/10.1002/ejoc.201300716

Marjanovic J, Divjakovic V, Matović R, Ferjančić Z, Saičić RN. Double Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1). in European Journal of Organic Chemistry. 2013;2013(25):5555-5560.
doi:10.1002/ejoc.201300716 .

Marjanovic, Jasna, Divjakovic, Vladimir, Matović, Radomir, Ferjančić, Zorana, Saičić, Radomir N., "Double Asymmetric Induction in Organocatalyzed Aldol Reactions: Total Synthesis of (+)-2-epi-Hyacinthacine A(2) and (-)-3-epi-Hyacinthacine A(1)" in European Journal of Organic Chemistry, 2013, no. 25 (2013):5555-5560,
https://doi.org/10.1002/ejoc.201300716 . .

TY  - JOUR
AU  - Trmcic, Milena V.
AU  - Matović, Radomir
AU  - Tovilović, Gordana
AU  - Ristic, Biljana Z.
AU  - Trajković, Vladimir
AU  - Ferjančić, Zorana
AU  - Saičić, Radomir N.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/981
AB  - The design, synthesis and biological evaluation of a novel C, D-spirolactone analogue of paclitaxel is described. This is the first paclitaxel analogue without an oxetane D-ring that shows a significant cytotoxic effect (activity one order of magnitude lower than paclitaxel). More importantly, its cytotoxicity is a result of a different mechanism of action, involving mTOR inhibition-dependent autophagy instead of G(2)/M cell cycle arrest-dependent apoptosis.
PB  - Royal Soc Chemistry, Cambridge
T2  - Organic & Biomolecular Chemistry
T1  - A novel C,D-spirolactone analogue of paclitaxel: autophagy instead of apoptosis as a previously unknown mechanism of cytotoxic action for taxoids
VL  - 10
IS  - 25
SP  - 4933
EP  - 4942
DO  - 10.1039/c2ob25514f
ER  - 

@article{
author = "Trmcic, Milena V. and Matović, Radomir and Tovilović, Gordana and Ristic, Biljana Z. and Trajković, Vladimir and Ferjančić, Zorana and Saičić, Radomir N.",
year = "2012",
abstract = "The design, synthesis and biological evaluation of a novel C, D-spirolactone analogue of paclitaxel is described. This is the first paclitaxel analogue without an oxetane D-ring that shows a significant cytotoxic effect (activity one order of magnitude lower than paclitaxel). More importantly, its cytotoxicity is a result of a different mechanism of action, involving mTOR inhibition-dependent autophagy instead of G(2)/M cell cycle arrest-dependent apoptosis.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Organic & Biomolecular Chemistry",
title = "A novel C,D-spirolactone analogue of paclitaxel: autophagy instead of apoptosis as a previously unknown mechanism of cytotoxic action for taxoids",
volume = "10",
number = "25",
pages = "4933-4942",
doi = "10.1039/c2ob25514f"
}

Trmcic, M. V., Matović, R., Tovilović, G., Ristic, B. Z., Trajković, V., Ferjančić, Z.,& Saičić, R. N.. (2012). A novel C,D-spirolactone analogue of paclitaxel: autophagy instead of apoptosis as a previously unknown mechanism of cytotoxic action for taxoids. in Organic & Biomolecular Chemistry
Royal Soc Chemistry, Cambridge., 10(25), 4933-4942.
https://doi.org/10.1039/c2ob25514f

Trmcic MV, Matović R, Tovilović G, Ristic BZ, Trajković V, Ferjančić Z, Saičić RN. A novel C,D-spirolactone analogue of paclitaxel: autophagy instead of apoptosis as a previously unknown mechanism of cytotoxic action for taxoids. in Organic & Biomolecular Chemistry. 2012;10(25):4933-4942.
doi:10.1039/c2ob25514f .

Trmcic, Milena V., Matović, Radomir, Tovilović, Gordana, Ristic, Biljana Z., Trajković, Vladimir, Ferjančić, Zorana, Saičić, Radomir N., "A novel C,D-spirolactone analogue of paclitaxel: autophagy instead of apoptosis as a previously unknown mechanism of cytotoxic action for taxoids" in Organic & Biomolecular Chemistry, 10, no. 25 (2012):4933-4942,
https://doi.org/10.1039/c2ob25514f . .

TY  - JOUR
AU  - Ferjančić, Zorana
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1056
AB  - A synthetic sequence has been developed for the preparation of 9,10- di-O-diacetyl-4-desmethylene-4β-(3-butenyl)-4α-hydroxy-5-O-mesyltaxicin I- -1,2-carbonate 3, an intermediate in an attempted synthesis of a cyclobutane paclitaxel analogue. A series of reactions of 3 were investigated, including the protection of the sterically hindered C-4α-hydroxy group and the oxidative cleavage of the terminal double bond. Cyclization of 13 to the cyclobutane-containing intermediate failed due to the unexpected instability of the dimethylsilane protecting group under basic conditions.
AB  - Razvijena je sintetička sekvenca za dobijanje 9,10-di-O-acetil-4-desmetilen-4β-(3-butenil)-4α-hidroksi-5-O-meziltaksicin I-1,2-karbonata (3), intermedijera u pokušanoj sintezi ciklobutanskog analoga paklitaksela. Ispitivana je mogućnost dalje hemijske transformacije jedinjenja 3, kao što je zaštita sterno izrazito zaštićene C-4α hidroksilne grupe i oksidativna fragmentacija terminalne dvostruke veze. Ciklizacija jedinjenja 13 nije dala željeni rezultat - intermedijer sa ciklobutanovim prstenom, što je posledica neočekivane nestabilnosti DMS-zaštitne grupe u baznim reakcionim uslovima.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Synthetic studies towards D-modified paclitaxel analogues
T1  - Sintetičke studije analoga paklitaksela sa modifikovanim D-prstenom
VL  - 77
IS  - 11
SP  - 1529
EP  - 1539
DO  - 10.2298/JSC120626094F
ER  - 

@article{
author = "Ferjančić, Zorana and Matović, Radomir and Saičić, Radomir N.",
year = "2012",
abstract = "A synthetic sequence has been developed for the preparation of 9,10- di-O-diacetyl-4-desmethylene-4β-(3-butenyl)-4α-hydroxy-5-O-mesyltaxicin I- -1,2-carbonate 3, an intermediate in an attempted synthesis of a cyclobutane paclitaxel analogue. A series of reactions of 3 were investigated, including the protection of the sterically hindered C-4α-hydroxy group and the oxidative cleavage of the terminal double bond. Cyclization of 13 to the cyclobutane-containing intermediate failed due to the unexpected instability of the dimethylsilane protecting group under basic conditions., Razvijena je sintetička sekvenca za dobijanje 9,10-di-O-acetil-4-desmetilen-4β-(3-butenil)-4α-hidroksi-5-O-meziltaksicin I-1,2-karbonata (3), intermedijera u pokušanoj sintezi ciklobutanskog analoga paklitaksela. Ispitivana je mogućnost dalje hemijske transformacije jedinjenja 3, kao što je zaštita sterno izrazito zaštićene C-4α hidroksilne grupe i oksidativna fragmentacija terminalne dvostruke veze. Ciklizacija jedinjenja 13 nije dala željeni rezultat - intermedijer sa ciklobutanovim prstenom, što je posledica neočekivane nestabilnosti DMS-zaštitne grupe u baznim reakcionim uslovima.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Synthetic studies towards D-modified paclitaxel analogues, Sintetičke studije analoga paklitaksela sa modifikovanim D-prstenom",
volume = "77",
number = "11",
pages = "1529-1539",
doi = "10.2298/JSC120626094F"
}

Ferjančić, Z., Matović, R.,& Saičić, R. N.. (2012). Synthetic studies towards D-modified paclitaxel analogues. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 77(11), 1529-1539.
https://doi.org/10.2298/JSC120626094F

Ferjančić Z, Matović R, Saičić RN. Synthetic studies towards D-modified paclitaxel analogues. in Journal of the Serbian Chemical Society. 2012;77(11):1529-1539.
doi:10.2298/JSC120626094F .

Ferjančić, Zorana, Matović, Radomir, Saičić, Radomir N., "Synthetic studies towards D-modified paclitaxel analogues" in Journal of the Serbian Chemical Society, 77, no. 11 (2012):1529-1539,
https://doi.org/10.2298/JSC120626094F . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/658
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Corrigendum to: Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings (vol 65, pg 10485, 2009)
VL  - 66
IS  - 17
SP  - 3275
EP  - 3275
DO  - 10.1016/j.tet.2010.03.013
ER  - 

@article{
author = "Vulović, Bojan and Bihelović, Filip and Matović, Radomir and Saičić, Radomir N.",
year = "2010",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Corrigendum to: Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings (vol 65, pg 10485, 2009)",
volume = "66",
number = "17",
pages = "3275-3275",
doi = "10.1016/j.tet.2010.03.013"
}

Vulović, B., Bihelović, F., Matović, R.,& Saičić, R. N.. (2010). Corrigendum to: Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings (vol 65, pg 10485, 2009). in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 66(17), 3275-3275.
https://doi.org/10.1016/j.tet.2010.03.013

Vulović B, Bihelović F, Matović R, Saičić RN. Corrigendum to: Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings (vol 65, pg 10485, 2009). in Tetrahedron. 2010;66(17):3275-3275.
doi:10.1016/j.tet.2010.03.013 .

Vulović, Bojan, Bihelović, Filip, Matović, Radomir, Saičić, Radomir N., "Corrigendum to: Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings (vol 65, pg 10485, 2009)" in Tetrahedron, 66, no. 17 (2010):3275-3275,
https://doi.org/10.1016/j.tet.2010.03.013 . .

TY  - JOUR
AU  - Vulović, Bojan
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2009
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1031
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2774
AB  - A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings
VL  - 65
IS  - 50
SP  - 10485
EP  - 10494
DO  - 10.1016/j.tet.2009.10.006
ER  - 

@article{
author = "Vulović, Bojan and Bihelović, Filip and Matović, Radomir and Saičić, Radomir N.",
year = "2009",
abstract = "A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings",
volume = "65",
number = "50",
pages = "10485-10494",
doi = "10.1016/j.tet.2009.10.006"
}

Vulović, B., Bihelović, F., Matović, R.,& Saičić, R. N.. (2009). Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 65(50), 10485-10494.
https://doi.org/10.1016/j.tet.2009.10.006

Vulović B, Bihelović F, Matović R, Saičić RN. Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. in Tetrahedron. 2009;65(50):10485-10494.
doi:10.1016/j.tet.2009.10.006 .

Vulović, Bojan, Bihelović, Filip, Matović, Radomir, Saičić, Radomir N., "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings" in Tetrahedron, 65, no. 50 (2009):10485-10494,
https://doi.org/10.1016/j.tet.2009.10.006 . .

TY  - JOUR
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Vulović, Bojan
AU  - Saičić, Radomir N.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/343
AB  - Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
VL  - 9
IS  - 24
SP  - 5063
EP  - 5066
DO  - 10.1021/ol7023554
ER  - 

@article{
author = "Bihelović, Filip and Matović, Radomir and Vulović, Bojan and Saičić, Radomir N.",
year = "2007",
abstract = "Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings",
volume = "9",
number = "24",
pages = "5063-5066",
doi = "10.1021/ol7023554"
}

Bihelović, F., Matović, R., Vulović, B.,& Saičić, R. N.. (2007). Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings. in Organic Letters
American Chemical Society (ACS)., 9(24), 5063-5066.
https://doi.org/10.1021/ol7023554

Bihelović F, Matović R, Vulović B, Saičić RN. Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings. in Organic Letters. 2007;9(24):5063-5066.
doi:10.1021/ol7023554 .

Bihelović, Filip, Matović, Radomir, Vulović, Bojan, Saičić, Radomir N., "Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings" in Organic Letters, 9, no. 24 (2007):5063-5066,
https://doi.org/10.1021/ol7023554 . .

TY  - JOUR
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Vulović, Bojan
AU  - Saičić, Radomir N.
PY  - 2007
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/894
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2773
AB  - Page 5064. Two references pertinent to the described work have been omitted in ref 13:  For the first example of combining organocatalysis and transition metal catalysis, see:  (e) Jellerichs, B. G.; Kong, J.-R.; Krische, M. J. J. Am. Chem. Soc. 2003, 125, 7758. For a recent application of double catalysis to a highly efficient asymmetric allylation of aldehydes, see:  (f) Mukherjee, S.; List, B. J. Am. Chem. Soc. 2007, 129, 11336.11/28/2007
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Erratum: Organocatalyzed Cyclizations of pi-allylpalladium complexes: A new method for the construction of five- and six-membered rings (vol 9, pg 5064, 2007)
VL  - 9
IS  - 26
SP  - 5649
EP  - 5649
DO  - 10.1021/ol702760g
ER  - 

@article{
author = "Bihelović, Filip and Matović, Radomir and Vulović, Bojan and Saičić, Radomir N.",
year = "2007",
abstract = "Page 5064. Two references pertinent to the described work have been omitted in ref 13:  For the first example of combining organocatalysis and transition metal catalysis, see:  (e) Jellerichs, B. G.; Kong, J.-R.; Krische, M. J. J. Am. Chem. Soc. 2003, 125, 7758. For a recent application of double catalysis to a highly efficient asymmetric allylation of aldehydes, see:  (f) Mukherjee, S.; List, B. J. Am. Chem. Soc. 2007, 129, 11336.11/28/2007",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Erratum: Organocatalyzed Cyclizations of pi-allylpalladium complexes: A new method for the construction of five- and six-membered rings (vol 9, pg 5064, 2007)",
volume = "9",
number = "26",
pages = "5649-5649",
doi = "10.1021/ol702760g"
}

Bihelović, F., Matović, R., Vulović, B.,& Saičić, R. N.. (2007). Erratum: Organocatalyzed Cyclizations of pi-allylpalladium complexes: A new method for the construction of five- and six-membered rings (vol 9, pg 5064, 2007). in Organic Letters
American Chemical Society (ACS)., 9(26), 5649-5649.
https://doi.org/10.1021/ol702760g

Bihelović F, Matović R, Vulović B, Saičić RN. Erratum: Organocatalyzed Cyclizations of pi-allylpalladium complexes: A new method for the construction of five- and six-membered rings (vol 9, pg 5064, 2007). in Organic Letters. 2007;9(26):5649-5649.
doi:10.1021/ol702760g .

Bihelović, Filip, Matović, Radomir, Vulović, Bojan, Saičić, Radomir N., "Erratum: Organocatalyzed Cyclizations of pi-allylpalladium complexes: A new method for the construction of five- and six-membered rings (vol 9, pg 5064, 2007)" in Organic Letters, 9, no. 26 (2007):5649-5649,
https://doi.org/10.1021/ol702760g . .

TY  - JOUR
AU  - Elheshi, Ahmed Mohamed
AU  - Maslak, Veselin
AU  - Saičić, Radomir N.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4299
AB  - Homoallylic radicals, generated from the corresponding xanthates, react with terminal alkynes to give cyclopentene derivatives in moderate yields.
AB  - Хомоалилни радикали, настали из одговарајућих ксантата, реагују са терминалним 
алкинима и дају деривате циклопентена у умереним приносима.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Radical reactions of xanthates: Annulation of the cyclopentene ring
T1  - Radikalske reakcije ksantata : anelacija ciklopentenovog prstena
VL  - 72
IS  - 12
SP  - 1173
EP  - 1179
DO  - 10.2298/JSC0712173E
ER  - 

@article{
author = "Elheshi, Ahmed Mohamed and Maslak, Veselin and Saičić, Radomir N.",
year = "2007",
abstract = "Homoallylic radicals, generated from the corresponding xanthates, react with terminal alkynes to give cyclopentene derivatives in moderate yields., Хомоалилни радикали, настали из одговарајућих ксантата, реагују са терминалним 
алкинима и дају деривате циклопентена у умереним приносима.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Radical reactions of xanthates: Annulation of the cyclopentene ring, Radikalske reakcije ksantata : anelacija ciklopentenovog prstena",
volume = "72",
number = "12",
pages = "1173-1179",
doi = "10.2298/JSC0712173E"
}

Elheshi, A. M., Maslak, V.,& Saičić, R. N.. (2007). Radical reactions of xanthates: Annulation of the cyclopentene ring. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 72(12), 1173-1179.
https://doi.org/10.2298/JSC0712173E

Elheshi AM, Maslak V, Saičić RN. Radical reactions of xanthates: Annulation of the cyclopentene ring. in Journal of the Serbian Chemical Society. 2007;72(12):1173-1179.
doi:10.2298/JSC0712173E .

Elheshi, Ahmed Mohamed, Maslak, Veselin, Saičić, Radomir N., "Radical reactions of xanthates: Annulation of the cyclopentene ring" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1173-1179,
https://doi.org/10.2298/JSC0712173E . .

TY  - JOUR
AU  - Ferjančić, Zorana
AU  - Matović, Radomir
AU  - Čeković, Živorad
AU  - Jiang, Yi
AU  - Snyder, James P.
AU  - Trajković, Vladimir
AU  - Saičić, Radomir N.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2772
AB  - A C,D-seco-paclitaxel derivative 26 was prepared from taxine and tested for biological activity. Chemical reactivity of the seco-compounds proved to be substantially modified, with respects to taxoids. The corresponding C,D-seco-taxoid does not show tubulin stabilizing activity or cytotoxicity. Explanation of these observations based on molecular modeling is provided. (c) 2006 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Synthesis, biology, and modeling of a C-4 carbonyl C,D-seco-taxoid
VL  - 62
IS  - 36
SP  - 8503
EP  - 8514
DO  - 10.1016/j.tet.2006.06.080
ER  - 

@article{
author = "Ferjančić, Zorana and Matović, Radomir and Čeković, Živorad and Jiang, Yi and Snyder, James P. and Trajković, Vladimir and Saičić, Radomir N.",
year = "2006",
abstract = "A C,D-seco-paclitaxel derivative 26 was prepared from taxine and tested for biological activity. Chemical reactivity of the seco-compounds proved to be substantially modified, with respects to taxoids. The corresponding C,D-seco-taxoid does not show tubulin stabilizing activity or cytotoxicity. Explanation of these observations based on molecular modeling is provided. (c) 2006 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Synthesis, biology, and modeling of a C-4 carbonyl C,D-seco-taxoid",
volume = "62",
number = "36",
pages = "8503-8514",
doi = "10.1016/j.tet.2006.06.080"
}

Ferjančić, Z., Matović, R., Čeković, Ž., Jiang, Y., Snyder, J. P., Trajković, V.,& Saičić, R. N.. (2006). Synthesis, biology, and modeling of a C-4 carbonyl C,D-seco-taxoid. in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 62(36), 8503-8514.
https://doi.org/10.1016/j.tet.2006.06.080

Ferjančić Z, Matović R, Čeković Ž, Jiang Y, Snyder JP, Trajković V, Saičić RN. Synthesis, biology, and modeling of a C-4 carbonyl C,D-seco-taxoid. in Tetrahedron. 2006;62(36):8503-8514.
doi:10.1016/j.tet.2006.06.080 .

Ferjančić, Zorana, Matović, Radomir, Čeković, Živorad, Jiang, Yi, Snyder, James P., Trajković, Vladimir, Saičić, Radomir N., "Synthesis, biology, and modeling of a C-4 carbonyl C,D-seco-taxoid" in Tetrahedron, 62, no. 36 (2006):8503-8514,
https://doi.org/10.1016/j.tet.2006.06.080 . .

TY  - JOUR
AU  - Ferjančić, Zorana
AU  - Matović, Radomir
AU  - Čeković, Živorad
AU  - Saičić, Radomir N.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/259
AB  - The reaction of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I (2) with BF3·Et2O/Bu4NBr can give rise to 4 different products. Each of these products can be obtained selectively, under the appropriate reaction conditions.
AB  - U reakciji α-4(20)-epoksi-5-O-meziltriacetiltaksicina I (2) sa bortrifluorid eteratom i tetrabutilamonijum-bromidom mogu nastati 4 različita proizvoda, u zavisnosti od reakcionih uslova. Svaki od ova 4 proizvoda se može dobiti selektivno, pod odgovarajućim reakcionim uslovima.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Reactions of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I induced by Bf3·Et2O/Bu4NBr
T1  - Reakcije α-4(20)-epoksi-5-O-meziltriacetiltaksicina I sa tetrabutilamonijum-bromidom u prisustvu bortrifluorid-eterata
VL  - 71
IS  - 7
SP  - 705
EP  - 711
DO  - 10.2298/JSC0607705F
ER  - 

@article{
author = "Ferjančić, Zorana and Matović, Radomir and Čeković, Živorad and Saičić, Radomir N.",
year = "2006",
abstract = "The reaction of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I (2) with BF3·Et2O/Bu4NBr can give rise to 4 different products. Each of these products can be obtained selectively, under the appropriate reaction conditions., U reakciji α-4(20)-epoksi-5-O-meziltriacetiltaksicina I (2) sa bortrifluorid eteratom i tetrabutilamonijum-bromidom mogu nastati 4 različita proizvoda, u zavisnosti od reakcionih uslova. Svaki od ova 4 proizvoda se može dobiti selektivno, pod odgovarajućim reakcionim uslovima.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Reactions of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I induced by Bf3·Et2O/Bu4NBr, Reakcije α-4(20)-epoksi-5-O-meziltriacetiltaksicina I sa tetrabutilamonijum-bromidom u prisustvu bortrifluorid-eterata",
volume = "71",
number = "7",
pages = "705-711",
doi = "10.2298/JSC0607705F"
}

Ferjančić, Z., Matović, R., Čeković, Ž.,& Saičić, R. N.. (2006). Reactions of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I induced by Bf3·Et2O/Bu4NBr. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 71(7), 705-711.
https://doi.org/10.2298/JSC0607705F

Ferjančić Z, Matović R, Čeković Ž, Saičić RN. Reactions of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I induced by Bf3·Et2O/Bu4NBr. in Journal of the Serbian Chemical Society. 2006;71(7):705-711.
doi:10.2298/JSC0607705F .

Ferjančić, Zorana, Matović, Radomir, Čeković, Živorad, Saičić, Radomir N., "Reactions of α-4(20)-epoxy-5-O-mesyltriacetyltaxicine I induced by Bf3·Et2O/Bu4NBr" in Journal of the Serbian Chemical Society, 71, no. 7 (2006):705-711,
https://doi.org/10.2298/JSC0607705F . .

TY  - JOUR
AU  - Matović, Radomir
AU  - Ivkovic, Aleksandar
AU  - Manojlović, Marija
AU  - Tokic-Vujosevic, Zorana
AU  - Saičić, Radomir N.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2771
AB  - The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.
PB  - American Chemical Society (ACS)
T2  - Journal of Organic Chemistry
T1  - Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C
VL  - 71
IS  - 25
SP  - 9411
EP  - 9419
DO  - 10.1021/jo061790j
ER  - 

@article{
author = "Matović, Radomir and Ivkovic, Aleksandar and Manojlović, Marija and Tokic-Vujosevic, Zorana and Saičić, Radomir N.",
year = "2006",
abstract = "The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.",
publisher = "American Chemical Society (ACS)",
journal = "Journal of Organic Chemistry",
title = "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C",
volume = "71",
number = "25",
pages = "9411-9419",
doi = "10.1021/jo061790j"
}

Matović, R., Ivkovic, A., Manojlović, M., Tokic-Vujosevic, Z.,& Saičić, R. N.. (2006). Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C. in Journal of Organic Chemistry
American Chemical Society (ACS)., 71(25), 9411-9419.
https://doi.org/10.1021/jo061790j

Matović R, Ivkovic A, Manojlović M, Tokic-Vujosevic Z, Saičić RN. Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C. in Journal of Organic Chemistry. 2006;71(25):9411-9419.
doi:10.1021/jo061790j .

Matović, Radomir, Ivkovic, Aleksandar, Manojlović, Marija, Tokic-Vujosevic, Zorana, Saičić, Radomir N., "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C" in Journal of Organic Chemistry, 71, no. 25 (2006):9411-9419,
https://doi.org/10.1021/jo061790j . .

TY  - JOUR
AU  - Ferjančić, Zorana
AU  - Matović, Radomir
AU  - Čeković, Živorad
AU  - Snyder, James P.
AU  - Saičić, Radomir N.
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2770
AB  - A C,D-seco-paclitaxel derivative 12 was prepared and tested for biological activity. The key step in the synthesis was a free radical fragmentation of the bicyclic tertiary alcohol 7 under the conditions of the hypobromite reaction. The compound 12 showed no activity in the tubulin test. (c) 2005 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron Letters
T1  - Synthesis, biological evaluation, and modeling of a C,D-seco-taxoid
VL  - 46
IS  - 30
SP  - 5049
EP  - 5052
DO  - 10.1016/j.tetlet.2005.05.071
ER  - 

@article{
author = "Ferjančić, Zorana and Matović, Radomir and Čeković, Živorad and Snyder, James P. and Saičić, Radomir N.",
year = "2005",
abstract = "A C,D-seco-paclitaxel derivative 12 was prepared and tested for biological activity. The key step in the synthesis was a free radical fragmentation of the bicyclic tertiary alcohol 7 under the conditions of the hypobromite reaction. The compound 12 showed no activity in the tubulin test. (c) 2005 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron Letters",
title = "Synthesis, biological evaluation, and modeling of a C,D-seco-taxoid",
volume = "46",
number = "30",
pages = "5049-5052",
doi = "10.1016/j.tetlet.2005.05.071"
}

Ferjančić, Z., Matović, R., Čeković, Ž., Snyder, J. P.,& Saičić, R. N.. (2005). Synthesis, biological evaluation, and modeling of a C,D-seco-taxoid. in Tetrahedron Letters
Oxford : Pergamon-Elsevier Science Ltd., 46(30), 5049-5052.
https://doi.org/10.1016/j.tetlet.2005.05.071

Ferjančić Z, Matović R, Čeković Ž, Snyder JP, Saičić RN. Synthesis, biological evaluation, and modeling of a C,D-seco-taxoid. in Tetrahedron Letters. 2005;46(30):5049-5052.
doi:10.1016/j.tetlet.2005.05.071 .

Ferjančić, Zorana, Matović, Radomir, Čeković, Živorad, Snyder, James P., Saičić, Radomir N., "Synthesis, biological evaluation, and modeling of a C,D-seco-taxoid" in Tetrahedron Letters, 46, no. 30 (2005):5049-5052,
https://doi.org/10.1016/j.tetlet.2005.05.071 . .

TY  - JOUR
AU  - Tokic-Vujosevic, Z
AU  - Petrović, G
AU  - Rakić, B
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2769
AB  - Immunomodulator (-)-cytoxazone and its epimer (+)-epi-cytoxazone were synthesized starting from (D)-(-)-4-hydroxyphenylglycine. Homologation of the amino acid was achieved via the corresponding aldehyde, by a cyanohydrin reaction. The racemization of highly sensible amido aldehyde was efficiently suppressed when the oxidation of the parent aminoalcohol was performed by a modified Dess-Martin procedure.
PB  - Taylor & Francis
T2  - Synthetic Communications
T1  - Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach
VL  - 35
IS  - 3
SP  - 435
EP  - 447
DO  - 10.1081/SCC-200048953
ER  - 

@article{
author = "Tokic-Vujosevic, Z and Petrović, G and Rakić, B and Matović, Radomir and Saičić, Radomir N.",
year = "2005",
abstract = "Immunomodulator (-)-cytoxazone and its epimer (+)-epi-cytoxazone were synthesized starting from (D)-(-)-4-hydroxyphenylglycine. Homologation of the amino acid was achieved via the corresponding aldehyde, by a cyanohydrin reaction. The racemization of highly sensible amido aldehyde was efficiently suppressed when the oxidation of the parent aminoalcohol was performed by a modified Dess-Martin procedure.",
publisher = "Taylor & Francis",
journal = "Synthetic Communications",
title = "Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach",
volume = "35",
number = "3",
pages = "435-447",
doi = "10.1081/SCC-200048953"
}

Tokic-Vujosevic, Z., Petrović, G., Rakić, B., Matović, R.,& Saičić, R. N.. (2005). Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach. in Synthetic Communications
Taylor & Francis., 35(3), 435-447.
https://doi.org/10.1081/SCC-200048953

Tokic-Vujosevic Z, Petrović G, Rakić B, Matović R, Saičić RN. Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach. in Synthetic Communications. 2005;35(3):435-447.
doi:10.1081/SCC-200048953 .

Tokic-Vujosevic, Z, Petrović, G, Rakić, B, Matović, Radomir, Saičić, Radomir N., "Synthesis of (-)-cytoxazone and (+)-epi-cytoxazone: The chiral pool approach" in Synthetic Communications, 35, no. 3 (2005):435-447,
https://doi.org/10.1081/SCC-200048953 . .

TY  - JOUR
AU  - Maslak, Veselin
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2768
AB  - Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides, followed by acidic work-up, affords butanolides in moderate/good yields. With epihalohydrins the reaction is regioselective and occurs at the less substituted end of the epoxide; the gamma-haloalkyl-gamma-butanolides thus obtained can be further transformed into various products. (C) 2004 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides
VL  - 60
IS  - 40
SP  - 8957
EP  - 8966
DO  - 10.1016/j.tet.2004.07.007
ER  - 

@article{
author = "Maslak, Veselin and Matović, Radomir and Saičić, Radomir N.",
year = "2004",
abstract = "Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides, followed by acidic work-up, affords butanolides in moderate/good yields. With epihalohydrins the reaction is regioselective and occurs at the less substituted end of the epoxide; the gamma-haloalkyl-gamma-butanolides thus obtained can be further transformed into various products. (C) 2004 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides",
volume = "60",
number = "40",
pages = "8957-8966",
doi = "10.1016/j.tet.2004.07.007"
}

Maslak, V., Matović, R.,& Saičić, R. N.. (2004). Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides. in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 60(40), 8957-8966.
https://doi.org/10.1016/j.tet.2004.07.007

Maslak V, Matović R, Saičić RN. Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides. in Tetrahedron. 2004;60(40):8957-8966.
doi:10.1016/j.tet.2004.07.007 .

Maslak, Veselin, Matović, Radomir, Saičić, Radomir N., "Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides" in Tetrahedron, 60, no. 40 (2004):8957-8966,
https://doi.org/10.1016/j.tet.2004.07.007 . .

TY  - JOUR
AU  - Milićević, Selena
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2762
AB  - Optically pure (-)-cytoxazone was synthesized, starting from methyl p-methoxycinnamate, in six steps and in 31%, overall yield. The required anti-aminoalcohol configuration was established by combining Sharpless asymmetric aminohydroxylation with the configurational inversion of the intermediate amidoalcohol via ail oxazoline. The synthesis of (+)-epi-cytoxazone is also described. (C) 2003 Elsevier Ltd. All rights reserved.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron Letters
T1  - Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone
VL  - 45
IS  - 5
SP  - 955
EP  - 957
DO  - 10.1016/j.tetlet.2003.11.096
ER  - 

@article{
author = "Milićević, Selena and Matović, Radomir and Saičić, Radomir N.",
year = "2004",
abstract = "Optically pure (-)-cytoxazone was synthesized, starting from methyl p-methoxycinnamate, in six steps and in 31%, overall yield. The required anti-aminoalcohol configuration was established by combining Sharpless asymmetric aminohydroxylation with the configurational inversion of the intermediate amidoalcohol via ail oxazoline. The synthesis of (+)-epi-cytoxazone is also described. (C) 2003 Elsevier Ltd. All rights reserved.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron Letters",
title = "Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone",
volume = "45",
number = "5",
pages = "955-957",
doi = "10.1016/j.tetlet.2003.11.096"
}

Milićević, S., Matović, R.,& Saičić, R. N.. (2004). Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone. in Tetrahedron Letters
Oxford : Pergamon-Elsevier Science Ltd., 45(5), 955-957.
https://doi.org/10.1016/j.tetlet.2003.11.096

Milićević S, Matović R, Saičić RN. Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone. in Tetrahedron Letters. 2004;45(5):955-957.
doi:10.1016/j.tetlet.2003.11.096 .

Milićević, Selena, Matović, Radomir, Saičić, Radomir N., "Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone" in Tetrahedron Letters, 45, no. 5 (2004):955-957,
https://doi.org/10.1016/j.tetlet.2003.11.096 . .

TY  - JOUR
AU  - Ivkovic, A
AU  - Matović, Radomir
AU  - Saičić, Radomir N.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2767
AB  - The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a semiochemical of Periplaneta americana.
PB  - American Chemical Society (ACS)
T2  - Organic Letters
T1  - Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C
VL  - 6
IS  - 8
SP  - 1221
EP  - 1224
DO  - 10.1021/ol049875z
ER  - 

@article{
author = "Ivkovic, A and Matović, Radomir and Saičić, Radomir N.",
year = "2004",
abstract = "The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a semiochemical of Periplaneta americana.",
publisher = "American Chemical Society (ACS)",
journal = "Organic Letters",
title = "Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C",
volume = "6",
number = "8",
pages = "1221-1224",
doi = "10.1021/ol049875z"
}

Ivkovic, A., Matović, R.,& Saičić, R. N.. (2004). Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C. in Organic Letters
American Chemical Society (ACS)., 6(8), 1221-1224.
https://doi.org/10.1021/ol049875z

Ivkovic A, Matović R, Saičić RN. Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C. in Organic Letters. 2004;6(8):1221-1224.
doi:10.1021/ol049875z .

Ivkovic, A, Matović, Radomir, Saičić, Radomir N., "Ring-closing metathesis/fragmentation route to geometrically defined medium-ring cycloalkenes: Total synthesis of (+/-)-periplanone C" in Organic Letters, 6, no. 8 (2004):1221-1224,
https://doi.org/10.1021/ol049875z . .