Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
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Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
Source:Organic Letters, 2007, 9, 24, 5063-5066
- Amer Chemical Soc, Washington