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Methanol oxidation on Pd/Pt(poly) in alkaline solution
(Elsevier, 2015)
Bimetallic electrodes prepared by Pd nanoislands spontaneously deposited on polycrystalline platinum, Pt(poly), at submonolayer coverage were explored for methanol oxidation in alkaline media. Characterization of obtained ...
Chemical stability of the peroxide bond enables diversified synthesis of potent tetraoxane antimalarials
(American Chemical Society (ACS), 2008)
Of 17 prepared 1,2,4,5-tetraoxacyclohexanes stable to reductive and acidic conditions, 3 of them were more active than artemisinin against CQ and MFQ resistant strain TM91C235 and all compounds were more active in vitro ...
Porous carbon thin films for electrochemical capacitors
(Oxford : Pergamon-Elsevier Science Ltd, 2013)
Activation effects on carbon films, derived from commercial aromatic polyimide films (Kapton, DuPont), in CO2 atmosphere at 1203 K on capacitance properties were studied. Two thicknesses of polyimide films were used: 7 and ...
Crystallographic and ab Initio Study of Pyridine Stacking Interactions. Local Nature of Hydrogen Bond Effect in Stacking Interactions
(American Chemical Society (ACS), 2012)
Stacking interactions between pyridine molecules and the influence of simultaneous hydrogen bonds were studied by analyzing data in the Cambridge Structural Database (CSD) and by ab initio calculations. The results show ...
An exergy composite curves approach for the design of optimum multi-pressure organic Rankine cycle processes
(Oxford : Pergamon-Elsevier Science Ltd, 2014)
This work adopts the (ECCs) under bar (exergy composite curves) approach to explore the potential for ORC (organic Rankine cycle) process improvements. The method is used to explore different ORC configurations supported ...
Two nitro derivatives of azabenzo[a]pyrene N-oxide: Electronic properties and their relation to mutagenic activity
(Elsevier, 2015)
The equilibrium geometries, relative energies, IR and Raman spectra, vertical ionization potentials (IP), vertical electron affinities (EA), dipole moments (mu), electronic dipole polarizabilities (alpha), and molecular ...
Are Chelate Rings Aromatic? Calculations of Magnetic Properties of Acetylacetonato and o-Benzoquinonediimine Chelate Rings
(American Chemical Society (ACS), 2007)
The aromaticity of the chelate rings of acetylacetonato (acac) and o-benzoquinonediimine (bqdi) ligands was
investigated theoretically by calculating nucleus-independent chemical shifts (NICS). The calculations were ...
Organocatalyzed cyclizations of π-allylpalladium complexes: A new method for the construction of five- and six-membered rings
(American Chemical Society (ACS), 2007)
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
Structure sensitivity of dimethylamine deep oxidation over Pt/Al2O3 catalysts
(Elsevier, 2009)
The deep oxidation of dimethylamine (DMA) was studied over Pt/Al2O3 catalysts with small (1 nm) and large (7.8-15.5 nm) Pt crystallite sizes. The turnover frequency (TOF) was higher for the large than for the small Pt ...
Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3 catalysts Oxidation of mixture
(Elsevier, 2004)
The oxidation of n-hexane and toluene mixtures in air over Pt/Al2O3 catalysts with mean Pt crystallite sizes of 1.0 and 15.5 nm has been studied. Measurements were performed in an external recycle reactor at temperatures ...