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Palladium(II) complexes with R2edda derived ligands, Part III: Diisobutyl (s,s)-2,2'-(1,2-ethanediyldiimino)di(4-methylpentanoate) and its palladium(II) complex: Synthesis and characterization
Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo III - diizobutil-(s,s)-2,2'-(1,2,-etandiildiimino)-di(4-metilpentanoat)-dihidrohlorid i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija
dc.creator | Zmejkovski, Bojana | |
dc.creator | Kaluđerović, Goran N. | |
dc.creator | Gómez-Ruiz, Santiago | |
dc.creator | Sabo, Tibor | |
dc.date.accessioned | 2019-01-30T17:19:31Z | |
dc.date.available | 2019-01-30T17:19:31Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/498 | |
dc.description.abstract | A new R2edda-type ester, diisobutyl (S,S)-2,2'-(1,2-ethane-diyldiimino) di(4-methylpentanoate) dihydrochloride, [(S,S)-H2iBu2eddl]Cl2, 1, and its palladium(II) complex, dichloro(diisobutyl (S,S)-2,2'-(1,2-ethanediyldiimino) di(4-methylpentanoate))palladium(II), [PdCl2{(S,S)-iBu2eddl}], 2, were synthesized and characterized by elemental analysis, as well as IR and NMR spectroscopy. It was found that complex 2 was obtained as mixture of two diastereoisomers, observed in NMR spectra. The crystal structure of compound 1 was determined by X-ray diffraction studies and is described. The isolated crystals consisted of one dicationic species [(S,S)-H2iBu2eddl]2+ and two Cl-. The crystal system was tetragonal with the space group P42. Hydrogen bonds significant for the manner of packing are N-H1N···Cl, 3.049(3) Å, 159(3)° and N-H2N···Cl, 3.100(3) Å, 164(3)°. An infinite chain was formed building a one layer structure, usual for these types of compounds. The C2 symmetry axis of the compound passes through the C1-C1i bond vector and lies perpendicular to the plane N2Cl2. | en |
dc.description.abstract | Novi estar R2edda-tipa diizobutil-(S,S)-2,2'-(1,2-etandiildiimino)-di(4-metilpen-tanoat)-dihidrohlorid [(S,S)-H2iBu2eddl]Cl2,1, i njegov kompleks paladijuma(II), dihlorodiizobutil-(S,S)-2,2'-(1,2-etandiildiimino)-di(4-metilpentanoat)-paladijum(II) [PdCl2{(S,S)-iBu2eddl}], 2, sintetisani su i okarakterisani uz pomoć elementalne analize, IR i NMR spektroskopije. Nađeno je da je kompleks 2 dobijen kao smeša dva dijastereoizomera, što je primećeno u NMR spektrima. Kristalna struktura 1 je rešena i opisana. Izolovani kristali se sastoje iz jedne dikatjonske vrste [(S,S)-H2iBu2eddl]2+ i dva Cl-. Kristalni sistem je tetragonalan sa prostornim grupom P42. Značajne vodonične veze za način pakovanja su N-H1N•••Cl, 3,049(3) Å, 159(3)°i N-H2N...Cl, 3,100(3) Å, 164(3)°. Time se formira beskonačan lanac i jednoslojna struktura, koji su uobičajeni za ove tipove struktura. Osa simetrije C2 jedinjenja prolazi kroz C1-C1i vektor veze i leži normalno na N2Cl2 ravan. PR Projekat Ministarstva nauke Republike Srbije, br. 142010. | sr |
dc.publisher | Serbian Chemical Society | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | palladium complexes | en |
dc.subject | crystal structure | en |
dc.subject | EDDP ligands | en |
dc.subject | characterization | en |
dc.title | Palladium(II) complexes with R2edda derived ligands, Part III: Diisobutyl (s,s)-2,2'-(1,2-ethanediyldiimino)di(4-methylpentanoate) and its palladium(II) complex: Synthesis and characterization | en |
dc.title | Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo III - diizobutil-(s,s)-2,2'-(1,2,-etandiildiimino)-di(4-metilpentanoat)-dihidrohlorid i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Гóмез-Руиз, Сантиаго; Змејковски, Бојана; Сабо, Тибор Ј.; Калуђеровић, Горан Н.; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део ИИИ - диизобутил-(с,с)-2,2'-(1,2,-етандиилдиимино)-ди(4-метилпентаноат)-дихидрохлорид и његов комплекс са паладијумом(ИИ) - синтеза и карактеризација; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део ИИИ - диизобутил-(с,с)-2,2'-(1,2,-етандиилдиимино)-ди(4-метилпентаноат)-дихидрохлорид и његов комплекс са паладијумом(ИИ) - синтеза и карактеризација; | |
dc.citation.volume | 74 | |
dc.citation.issue | 11 | |
dc.citation.spage | 1249 | |
dc.citation.epage | 1258 | |
dc.citation.other | 74(11): 1249-1258 | |
dc.citation.rank | M23 | |
dc.identifier.doi | 10.2298/JSC0911249Z | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs//bitstream/id/9141/496.pdf | |
dc.identifier.scopus | 2-s2.0-77349108581 | |
dc.identifier.wos | 000272469700007 | |
dc.type.version | publishedVersion |