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Structural effects in electrocatalysis
(Springer Science and Business Media LLC, 1982)
Studies of chemical reactions on well-defined surfaces provide fundamental data on surface reactivity and guidelines for the understanding and design of catalytic materials but few such studies have been done in electrocatalysis. ...
Characterization and methanol electrooxidation studies of Pt(111)/Os surfaces prepared by spontaneous deposition
(American Chemical Society (ACS), 2006)
Catalytic activity of the Pt(111)/Os surface toward methanol electrooxidation was optimized by exploring a wide range of Os coverage. Various methods of surface analyses were used, including electroanalytical, STM, and XPS ...
Electrosorption of hydrogen and sulfuric acid anions on single crystal platinum stepped surfaces. Part II. The [110] zone
(Elsevier, 1991)
Hydrogen and bisulphate adsorption at platinum single crystal surfaces from the [ITO] zone is
strongly dependent on the crystallographic orientation of the electrode surface, which is similar to that
found earlier for ...
Oscillatory phenomena in oxygen and hydrogen peroxide reduction on the Au(100) electrode surface in alkaline solutions
(Elsevier, 1992)
In this work we report preliminary data for oscillatory behavior found in oxygen and hydrogen peroxide reduction on a rotating gold electrode with (100) orientation in alkaline solutions.
Structural effects in electrocatalysis: oxidation of formic acid and hydrogen adsorption on platinum single-crystal stepped surfaces
(Elsevier, 1986)
The oxidation of formic acid and hydrogen adsorption have been measured on platinum single-crystal stepped surfaces with five orientations. A pronounced structural sensitivity of both reactions has been found. They show a ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
The electrocatalytic properties of the oxides of noble metals in the electro-oxidation of some organic molecules
(Elsevier, 1997)
The electro-oxidation of organic compounds on gold and silver electrodes can occur either in a potential range more negative than that where the metal oxides are formed or within the more positive range where the surface ...
Structural effects in electrocatalysis: Oxygen and hydrogen peroxide reduction on single crystal gold electrodes and the effects of lead ad-atoms
(Elsevier, 1982)
Structural effects in electrocatalysis have been clearly and definitely demonstrated for example in the oxidation of HCOOH, CH3OH and CH2O on platinum single crystal electrodes. In this note, we report considerable structural ...
Electrochemical Deposition and Dissolution of Alloys and Metal Composites—Fundamental Aspects
(Springer Science and Business Media LLC, 1995)
It is general experience in materials science that alloys can exhibit qualities that are unobtainable with the parent metals. This is true of electroplated deposits as well. Thus, such properties as hardness, tensile ...