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Structural effects in electrocatalysis: oxidation of formic acid and hydrogen adsorption on platinum single-crystal stepped surfaces
(Elsevier, 1986)
The oxidation of formic acid and hydrogen adsorption have been measured on platinum single-crystal stepped surfaces with five orientations. A pronounced structural sensitivity of both reactions has been found. They show a ...
Surface properties of RuO2 + IrO2 mixed oxide electrodes
(Elsevier, 1986)
The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV ...
Oxygen reduction on the Au (311) electrode surface in alkaline electrolyte
(Elsevier, 1988)
Oxygen reduction was studied for the first time using a single crystal electrode in a rotating disc-ring arrangement. The Au (311) surface shows a complex behaviour, with a very high activity in certain potential regions. ...
Electrosorption of hydrogen and sulphuric acid anions on single-crystal platinum stepped surfaces. Part I. The [110] zone
(Elsevier, 1988)
The adsorption of hydrogen and sulphuric acid anions has been studied on single-crystal platinum stepped surfaces from the [110] zone. Both processes depend on the orientation of the electrode surface. The multiple states ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part II. Applications
(Elsevier, 1987)
The criteria obtained for a new reaction scheme of O2 reduction have been applied to experimental data from several laboratories. The possibilities and merits of a new scheme have been analysed. Some results, not fully ...
Oxygen reduction on a ruthenium electrode in alkaline electrolytes
(Elsevier, 1986)
The kinetics of oxygen reduction have been studied on a ruthenium electrode in alkaline solutions using the rotating disc and rotating disc-ring methods. The reaction kinetics and mechanism were found to depend on the ...
Structural effects in electrocatalysis: Oxygen and hydrogen peroxide reduction on single crystal gold electrodes and the effects of lead ad-atoms
(Elsevier, 1982)
Structural effects in electrocatalysis have been clearly and definitely demonstrated for example in the oxidation of HCOOH, CH3OH and CH2O on platinum single crystal electrodes. In this note, we report considerable structural ...
Oxygen reduction on iron. Part III. An analysis of the rotating disk-ring electrode measurements in near neutral solutions
(Elsevier, 1989)
The kinetics of oxygen reduction were studied on iron in borate and bicarbonate buffered solutions, pH 9.8, using the rotating disk-ring method. Under these conditions O2 reduction occurs both on the oxidized surface and ...
Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
(Elsevier, 1987)
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the ...
Determination of the kinetic parameters of the oxygen reduction reaction using the rotating ring-disk electrode. Part I. Theory
(Elsevier, 1987)
A general scheme of oxygen reduction is given and analysis of the disk-ring measurements is performed. Expressions for the diagnostic criteria for such a scheme have been derived and their implications are discussed. The ...