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Synthesis and oxidative transformations of 5-hydroxy-5α-cholest-8-en-3β-yl acetate
(Serbian Chemical Society, 1997)
5-Hydroxy-5α-cholest-8-en-3β-yl acetate (8) (prepared in 6 steps starting from 7-dehydrocholesteryl acetate (1) was transformed with ruthenium tetroxide to 5-hydroxy-8,9-dioxo-8,9-seco-5α-cholestan-3β-yl acetate (9). ...