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Structure-reactivity relationship in the solvolysis of 5,10-secosteroidal 5-p-nitrobenzoates
(Pergamon Press, 1979)
The solvolysis of (Z)- and (E)-3β-acyloxy-5,10-seco-1(10)-cholesten-5β-ol p-nitrobenzoates 4 and 5 has been investigated and compared with the solvolytic reactivity of the epimeric (Z)- and (E)-5α-p-nitrobenzoates 1 and ...
Transannular solvolysis reactions in seco-steroids containing a ten-membered ring.
(Pergamon Press, 1970)
Homoallylic interaction in steroidal cyclodecenyl systems
(Pergamon Press, 1974)
New approach to the aromatization of ring B in 19-norsteroids and to the synthesis of equilenin-type compounds
(Royal Society of Chemistry, 1978)
When 7α-acetoxy-3,3 : 17,17-bis(ethylenedioxy)-5,10-epoxy-5β, 10β-oestran-6-one (2), formed by lead tetra-acetate acetoxylation of the parent compound (1), is heated with alkali, it undergoes ring B aromatization to give ...
Non-faradaic electrocatalysis. Part I. Acceleration of ester hydrolysis in the electrochemical double layer
(Elsevier Sequoia S.A., Lausanne, 1979)
Pulsation of potential of a gold electrode in the double-layer region, between the p.z.c. and a several hundred millivolts more positive value, was found to increase the rate of hydrolysis of tertiary butyl acetate. The ...
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
Analysis of the organic matter of oil shales by nuclear magnetic resonance
(Pergamon Press, 1978)
13C NMR spectroscopy was applied in the investigation of the structure of the organic matter in oil shales. By using Proton Enhanced Nuclear Induction Spectroscopy, a fair resolution of aliphatic and aromatic carbon signals ...
Reflectance study of cation adsorption on oxide layers of gold and platinum electrodes
(Elsevier Sequoia S.A., Lausanne, 1979)
Carbon air electrode with regenerative short time overload capacity. II. Effects of duroquinone and 2-amino-1.4 naphthoquinone
(Switzerland : Springer Nature, 1975)
The short time overload capacity of the carbon-air electrode in a strongly alkaline electrolyte can be increased by addition of organic redox substances such as duroquinone (DQ) or 2-amino-1.4-naphthoquinone (ANQ). DQ, ...
The effect of the plasma composition on characteristics of the d.c. arc—IV: Influence of lithium on an arc in nitrogen
(Elsevier, 1971)
The radial temperature distribution of the arc burning in nitrogen was measured when a large quantity of Li2CO3 evaporates in the arc. In comparison to the radial temperature distribution of the arc burning in nitrogen ...