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Unusual mode of reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditions
dc.creator | Džambaski, Zdravko | |
dc.creator | Toljic, Dorde | |
dc.creator | Bondžić, Bojan | |
dc.creator | Marković, Rade | |
dc.creator | Baranac-Stojanović, Marija | |
dc.date.accessioned | 2019-01-30T17:35:58Z | |
dc.date.available | 2019-01-30T17:35:58Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1263 | |
dc.description.abstract | The reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditions, using Ac2O, TFAA, SOCl2 and SOBr2 as initiators, has been examined. Almost all reactions proceeded with absolute regioselectivity yielding alpha-substituted sulfides or vinyl-chloro derivatives. The mechanism for the formation of the latter products was postulated and proved experimentally. | en |
dc.publisher | Oxford : Pergamon-Elsevier Science Ltd | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS// | |
dc.rights | restrictedAccess | |
dc.source | Tetrahedron | |
dc.subject | Pummerer reaction | en |
dc.subject | 2-Alkylidene-4-oxothiazolidine S-oxide | en |
dc.subject | Regioselectivity | en |
dc.subject | Density functional calculations | en |
dc.title | Unusual mode of reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditions | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Тољиц, Дорде; Марковиц, Раде; Джамбаски, Здравко; Бонджић, Бојан; Баранац-Стојановиц, Марија; | |
dc.citation.volume | 69 | |
dc.citation.issue | 46 | |
dc.citation.spage | 9819 | |
dc.citation.epage | 9825 | |
dc.citation.other | 69(46): 9819-9825 | |
dc.citation.rank | M21 | |
dc.identifier.doi | 10.1016/j.tet.2013.09.004 | |
dc.identifier.scopus | 2-s2.0-84885181662 | |
dc.identifier.wos | 000326768800035 | |
dc.type.version | publishedVersion |