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Hydrogen evolution on platinum in the presence of lead, cadmium and thallium adatoms
(Pergamon Press, 1979)
Hydrogen evolution on rotating platinum electrode has been measured in the presence of Pb, Tl and Cd adatoms. At low coverages of these adatoms (θM < 0.5) the mechanism of H2 evolution is the same as that for Pt, giving ...
Optical and electrochemical study of electrocatalysis by foreign metal adatoms. Oxidation of formic acid on rhodium
(Elsevier Sequoia S.A., 1979)
Specular reflectance spectroscopy, in conjunction with linear potential sweep voltammetry, has been used in studying catalytic effects of Pb and Cd adatoms on the oxidation of HCOOH on Rh. The intermediates formed in that ...
The polarographic and chronopotentiometric investigation of the copper(II)-ethylenedithioldiacetic acid system
(Elsevier, 1975)
The electrode process of the Cu(II)-ethylenedithioldiacetic acid chelatereduction occurs in two one-electron reduction steps. The reversibility of the first polarographic wave was confirmed by microcoulometry at constant ...
The lead tetraacetate reaction of alcohols containing a small ring. Part II. Cyclobutane‐methanols and cyclopropane‐ethanols
(Wiley, 1976)
The leadtetraacetate and lead tetraacetate/metal chloride oxidations of cyclobutane‐methanol, cyclopropane‐ethanol and the corresponding α, α‐diniethyl alcohols have been investigated and compared with the oxidative reactions ...
The possibility of separating hydrogen fluoride from its gaseous mixture with silicon tetrafluoride
(Elsevier, 1973)
We report in this paper investigations of the conditions necessary to effect the selective absorption of hydrogen fluoride from its gaseous mixture with silicon tetrafluoride when that mixture is brought into contact with ...
1H n.m.r. spectra of some bicyclic compounds: I—relative configurations of the diastereomeric endo‐α‐methyl‐5‐norbornene‐2‐methanols, the corresponding saturated analogues, and their cyclization ether products
(Wiley, 1977)
The configurational and conformational relationship at C‐2 and C‐α in the two racemic diastereomeric endo‐α‐methyl‐5‐norbornene‐2‐methanols and the corresponding saturated endo‐α‐methyl‐2‐norbornanemethanols were determined ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
Acceleration of electrocatalytic reactions by pulsation of potential: Oxidation of formic acid on Pt and Pt/Pbads electrodes
(Pergamon Press, 1978)
Pulsating potential electrolysis has been applied to one typical electrocatalytic reaction ie, the oxidation of formic acid on platinum and platinum partially covered by lead adatoms electrodes. It has been found that much ...
An apparatus for simultaneous determination of electrical conductivity and thermogravimetric curves of solid systems
(Springer, 1975)
A new apparatus for measurement of electrical conductivity during thermogravimetric analysis is described. Results of an investigation of the water-zeolite system in the interval -200° up to +450° prove the suitability of ...
The dissolution of iron under cathodic polarization
(Pergamon Press, 1979)
It has been shown that the dissolution rate for iron at cathodic potential is higher than expected on the grounds of the Wagner-Traud mixed potential theory. This observation cannot be explained by a parallel chemical ...