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Electrocatalytic optimization of faradaic yields in the chlorate cell process
(Elsevier, 1984)
It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well ...
Treatment of electrostatic effects within the molecular mechanics method. 1
(American Chemical Society (ACS), 1983)
A model of intramolecular electrostatic effects (called the induced dipole moment and energy (IDME) method) was derived by extending the method originally proposed by Del Re for calculating dipole moments and charge ...
Fundamental aspects of pulsating current metal electrodeposition VIII: The effect of pause-to-pulse ratio on microthrowing power of metal deposition
(Elsevier, 1984)
The effect of a pulsating current on the microthrowing power of metal deposits in the early stage of deposition was investigated by scanning electron microscopy. It is shown that at the same average current density the ...
Electrocatalysis of oxygen on single crystal gold electrodes
(Elsevier, 1989)
Oxide formation and oxygen reduction on gold have been investigated with single crystal electrode surfaces of various orientations. Both reactions show sensitivity to the surface orientation, presence of steps, their density ...
Photoelectrochemical microscopy of oxide films on metals: Ti/TiO2 interface
(Elsevier, 1988)
Thin electrochemically grown oxide films on polycrystalline titanium substrates were examined by photoelectrochemical and electron diffraction techniques. Photoelectrochemical microscopy, based on illumination by a focused ...
Structural effects in electrocatalysis. Oxygen reduction on the Au (100) single crystal electrode
(Elsevier, 1984)
The kinetics of O2 reduction on the Au (100) single crystal electrode have been examined in alkaline electrolytes using the rotating dise method. A comparison has been made with the Au (110) and Au (111) surfaces. The ...
The surface structure of RuO2: A leed, auger and XPS study of the (110) and (100) faces
(Elsevier, 1988)
The (110) and the (100) surfaces of RuO2 show well defined LEED patterns. The surface lattice dimensions agree within 5% with the values predicted from X-ray diffraction. Both surfaces undergo a series of reversible surface ...
Oxygen reduction on a ruthenium electrode in acid electrolytes
(Elsevier, 1986)
The kinetics and mechanism of O2 reduction on an Ru electrode in acid electrolytes have been measured by using a disc—ring method. The reaction proceeds through a “parallel” mechanism with the exchange of approximately ...
Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces
(Elsevier, 1984)
The electrocrystallization of thin anodic films on metal electrodes continues
provoke interest since the original work of Bewick et al. [1]. These
studies have been focused on the film formation on mercury [1--3] ...
Two‐dimensional NMR spectra of sesquiterpenes. I—NOESY study of caryophyllenes from Inula spiraeifolia
(John Wiley & Sons Ltd., 1987)
The application of two‐dimensional NOE NMR spectroscopy (NOESY) for the stereochemical assignment of isomeric 14‐acetoxy‐13‐hydroxy‐ and 13‐acetoxy‐14‐hydroxy‐5,6‐caryophyllen‐7‐ones, and their acetylation products, is ...