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What is the nature of bonding in [Fe(CO)3(NO)]− and [Fe(CO)4]2−?
(Springer Nature, 2020)
To shed new light on the electronic structure of [Fe(CO)3(NO)]¯ complex ion, DFT-based analysis of the nature of chemical bonding has been performed. For this purpose, the extended transition state energy decomposition ...
Synthesis and pharmacological evaluation of novel cis and trans 3‑substituted anilidopiperidines
(Springer Nature, 2020)
Background 4-Anilidopiperidine class of synthetic opioid analgesics, with it’s representative fentanyl, are by far the most potent and clinically significant for the treatment of the severe chronic and surgical pain. ...
Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum
(Elsevier, 2020)
Chemical vapour deposition (CVD) is a promising method for producing large-scale graphene (Gr). Nevertheless, microscopic inhomogeneity of Gr grown on traditional metal substrates such as copper or nickel results in a ...
Microstructure and biopharmaceutical performances of curcumin-loaded low-energy nanoemulsions containing eucalyptol and pinene: Terpenes’ role overcome penetration enhancement effect?
(Elsevier, 2020)
The objective of this work was to develop low-energy nanoemulsions for enhanced dermal delivery of curcumin, using monoterpene compounds eucalyptol (EUC) and pinene (PIN) as chemical penetration enhancers. Spontaneous ...
Polysaccharide-fullerene supramolecular hybrids: Synthesis, characterization and antioxidant activity
(Elsevier, 2020)
An efficient encapsulation of the fullerene into two hydrophobized and one native polysaccharide provided water soluble supramolecular hybrids. After covalent modification of polysaccharides by cholesterol, noncovalent ...
Fabrication and characterization of luminescent Pr3+ doped fluorapatite nanocrystals as bioimaging contrast agents
(Elsevier, 2020)
Fluorapatite doped with rare-earth elements has a wide-range of biomedical applications. Here, a new type of fluorapatite nanocrystals doped with praseodymium (FAP-Pr) with excitation-emission profiles in visible part of ...
Microstructure and cavitation erosion performance of nickel-Inconel 718 composite coatings produced with cold spray
(Elsevier, 2020)
The cold spray technique was employed in this study to produce pure nickel (Ni) and nickel-Inconel 718 powder deposits on duplex stainless steel substrates. High quality coatings were manufactured using nitrogen as the ...
Chemo- and biocatalytic esterification of marchantin A and cytotoxic activity of ester derivatives
(Elsevier, 2020)
Chemical and biocatalytic synthesis of seven previously undescribed marchantin A ester derivatives has been presented. Chemical synthesis afforded three peresterified bisbibenzyl products (TE1-TE3), while enzymatic method, ...
Comparative study of lignocellulosic biomass and its components as electrode modifiers for detection of lead and copper ions
(Elsevier, 2020)
Cellulose, xylan and lignin, as well as maize cell wall, were used as modifiers of carbon paste electrode. Comparative analysis of electrochemical performance of each modifier toward heavy metal detection was performed. A ...
Characterisation of the binding of dihydro-alpha-lipoic acid to fibrinogen and the effects on fibrinogen oxidation and fibrin formation
(Elsevier, 2020)
A reduced form of the alpha-lipoic acid, dihydro-alpha-lipoic acid (DHLA) is a potent, naturally occurring antioxidant which can be consumed as food constituent or as supplement at doses up to 600 mg/day. DHLA has inhibitory ...