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Unique mononuclear Mn-II complexes of an end-off compartmental Schiff base ligand: experimental and theoretical studies on their bio-relevant catalytic promiscuity
(Royal Soc Chemistry, Cambridge, 2016)
Three new mononuclear manganese(II) complexes, namely [Mn(HL)(2)]center dot 2ClO(4) (1), [Mn(HL)(N(CN)(2)) (H2O)(2)]center dot ClO4 (2) and [Mn(HL)(SCN)(2)] (3) [LH = 4-tert-butyl-2,6-bis-[(2-pyridin-2-yl-ethylimino)-met ...
Investigation of antitumor potential of Ni(II) complexes with tridentate PNO acylhydrazones of 2-(diphenylphosphino)benzaldehyde and monodentate pseudohalides
(Springer, New York, 2016)
Square-planar azido Ni(II) complex with condensation product of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent was synthesized and its crystal structure was determined. Cytotoxic activity of the azido complex and ...
Organobentonite: Characterization and Adsorptive Properties towards Phenol and its Derivatives
(International Institute for the Science of Sintering, Beograd, 2016)
Bentonite from Mecji Do locality in Serbia was modified with hexadecyltrimethylammonium bromide (HDTMA-Br), and the sample was denoted as HDTMA-MD. The characterization of the material included X-Ray diffraction, elemental ...
Modelling cholesterol effects on the dynamics of the hypothalamic-pituitary-adrenal (HPA) axis
(Oxford Univ Press, Oxford, 2016)
A mathematical model of the hypothalamic-pituitary-adrenal (HPA) axis with cholesterol as a dynamical variable was derived to investigate the effects of cholesterol, the primary precursor of all steroid hormones, on the ...
Expression and characterization of a thermostable organic solvent-tolerant laccase from Bacillus licheniformis ATCC 9945a
(Elsevier, 2016)
Bacterial laccases have proven advantages over fungal and plant counterparts in terms of wider pH optimum, higher stability and broader biocatalytic scope. In this work, Bacillus licheniformis ATCC 9945a laccase is produced ...
Electrochemical lithiation/delithiation kinetics and capacity of phosphate tungsten bronze and its chemically pre-lithiated derivatives in aqueous solutions
(Springer, 2016)
Monophosphate bronze (PW8O26, WPB) was synthesized by low-temperature (650 °C) heating of 12-tungstophosphoric acid (WPA). Its lithiated derivative with a low lithium content (Li3-WPB) was synthesized by heating lithium ...
Influence of a Low Content of PEO Segment on the Thermal, Surface and Morphological Properties of Triblock and Diblock PCL Copolymers
(Springer, Dordrecht, 2016)
Two series, one of triblock (PCL/PEO/PCL) and the other of diblock (PCL/PEO) copolymers were prepared by ring-opening polymerization of epsilon-caprolactone catalized with tin(II) octoate and by using dihydroxy or monohydroxy ...
Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond
(Royal Soc Chemistry, Cambridge, 2016)
Information about the strength of donor-acceptor interactions in push-pull alkenes is valuable, as this so-called "push-pull effect'' influences their chemical reactivity and dynamic behaviour. In this paper, we discuss ...
Ni(II) complex with bishydrazone ligand: synthesis, characterization, DNA binding studies and pro-apoptotic and pro-differentiation induction in human cancerous cell lines
(Royal Soc Chemistry, Cambridge, 2016)
A new Ni(II) complex, [Ni(L)(H2O)] (1), with diethyl 3,3'-(2,2'-(1,1'-(pyridine-2,6-diyl) bis(ethan-1-yl-1-ylidene)) bis(hydrazin-1-yl-2-ylidene)) bis(3-oxopropanoate) ligand (H2L) was synthesized as a potential chemotherapeutic ...