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Fundamental aspects of pulsating current metal electrodeposition VIII: The effect of pause-to-pulse ratio on microthrowing power of metal deposition
(Elsevier, 1984)
The effect of a pulsating current on the microthrowing power of metal deposits in the early stage of deposition was investigated by scanning electron microscopy. It is shown that at the same average current density the ...
Electrocatalytic optimization of faradaic yields in the chlorate cell process
(Elsevier, 1984)
It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well ...
Structural effects in electrocatalysis. Oxygen reduction on the Au (100) single crystal electrode
(Elsevier, 1984)
The kinetics of O2 reduction on the Au (100) single crystal electrode have been examined in alkaline electrolytes using the rotating dise method. A comparison has been made with the Au (110) and Au (111) surfaces. The ...
Photoelectrochemical microscopy of oxide films on metals: Ti/TiO2 interface
(Elsevier, 1988)
Thin electrochemically grown oxide films on polycrystalline titanium substrates were examined by photoelectrochemical and electron diffraction techniques. Photoelectrochemical microscopy, based on illumination by a focused ...
Electrocatalysis of oxygen on single crystal gold electrodes
(Elsevier, 1989)
Oxide formation and oxygen reduction on gold have been investigated with single crystal electrode surfaces of various orientations. Both reactions show sensitivity to the surface orientation, presence of steps, their density ...
Two‐dimensional NMR spectra of sesquiterpenes. I—NOESY study of caryophyllenes from Inula spiraeifolia
(John Wiley & Sons Ltd., 1987)
The application of two‐dimensional NOE NMR spectroscopy (NOESY) for the stereochemical assignment of isomeric 14‐acetoxy‐13‐hydroxy‐ and 13‐acetoxy‐14‐hydroxy‐5,6‐caryophyllen‐7‐ones, and their acetylation products, is ...
The behaviour of mixed metal sulphide/silver suphide sensing materials in solutions of silver ions
(Analytica Chimica Acta, 1985)
Hydrophobized graphite electrodes activated with CuS/Ag2S can be used to measure silver ion activities as effectively as silver sulphide electrodes, whereas electrodes activatd with PbS/Ag2S or CdS/Ag2S are useless for ...
Anodic deposition of colloidal gold
(Elsevier, 1984)
Colloidal gold solutions were prepared following classical recipes. When electrolysed between graphite electrodes, gold was found to deposit at the anode. The rate of deposition was dependent on the anode potential, on the ...
The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride
(Wiley, 1985)
Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, ...
Treatment of electrostatic effects within the molecular mechanics method. 1
(American Chemical Society (ACS), 1983)
A model of intramolecular electrostatic effects (called the induced dipole moment and energy (IDME) method) was derived by extending the method originally proposed by Del Re for calculating dipole moments and charge ...