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The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride

Authorized Users Only
1985
Authors
Andrejević Vladimir
Bjelaković, Mira
Mihailović, Milan M.
Mihailović, Milhailo Lj.
Article (Published version)
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Abstract
Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.
Keywords:
1,2‐epoxycycloalkanes / Reduction / alcohols / LiAlH4 / AlCl3
Source:
Helvetica Chimica Acta, 1985, 68, 7, 2030-2032
Publisher:
  • Wiley

DOI: 10.1002/hlca.19850680727

ISSN: 0018-019X; 1522-2675

Scopus: 2-s2.0-84987472492
[ Google Scholar ]
9
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4185
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Andrejević Vladimir
AU  - Bjelaković, Mira
AU  - Mihailović, Milan M.
AU  - Mihailović, Milhailo Lj.
PY  - 1985
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4185
AB  - Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.
PB  - Wiley
T2  - Helvetica Chimica Acta
T1  - The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride
VL  - 68
IS  - 7
SP  - 2030
EP  - 2032
DO  - 10.1002/hlca.19850680727
ER  - 
@article{
author = "Andrejević Vladimir and Bjelaković, Mira and Mihailović, Milan M. and Mihailović, Milhailo Lj.",
year = "1985",
abstract = "Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.",
publisher = "Wiley",
journal = "Helvetica Chimica Acta",
title = "The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride",
volume = "68",
number = "7",
pages = "2030-2032",
doi = "10.1002/hlca.19850680727"
}
Andrejević Vladimir, Bjelaković, M., Mihailović, M. M.,& Mihailović, M. Lj.. (1985). The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride. in Helvetica Chimica Acta
Wiley., 68(7), 2030-2032.
https://doi.org/10.1002/hlca.19850680727
Andrejević Vladimir, Bjelaković M, Mihailović MM, Mihailović ML. The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride. in Helvetica Chimica Acta. 1985;68(7):2030-2032.
doi:10.1002/hlca.19850680727 .
Andrejević Vladimir, Bjelaković, Mira, Mihailović, Milan M., Mihailović, Milhailo Lj., "The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride" in Helvetica Chimica Acta, 68, no. 7 (1985):2030-2032,
https://doi.org/10.1002/hlca.19850680727 . .

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