Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.
TY - JOUR
AU - Andrejević Vladimir
AU - Bjelaković, Mira
AU - Mihailović, Milan M.
AU - Mihailović, Mihailo Lj.
PY - 1985
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4185
AB - Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.
PB - Wiley
T2 - Helvetica Chimica Acta
T1 - The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride
VL - 68
IS - 7
SP - 2030
EP - 2032
DO - 10.1002/hlca.19850680727
ER -
@article{
author = "Andrejević Vladimir and Bjelaković, Mira and Mihailović, Milan M. and Mihailović, Mihailo Lj.",
year = "1985",
abstract = "Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.",
publisher = "Wiley",
journal = "Helvetica Chimica Acta",
title = "The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride",
volume = "68",
number = "7",
pages = "2030-2032",
doi = "10.1002/hlca.19850680727"
}
Andrejević Vladimir, Bjelaković, M., Mihailović, M. M.,& Mihailović, M. Lj.. (1985). The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride. in Helvetica Chimica Acta
Wiley., 68(7), 2030-2032.
https://doi.org/10.1002/hlca.19850680727
Andrejević Vladimir, Bjelaković M, Mihailović MM, Mihailović ML. The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride. in Helvetica Chimica Acta. 1985;68(7):2030-2032.
doi:10.1002/hlca.19850680727 .
Andrejević Vladimir, Bjelaković, Mira, Mihailović, Milan M., Mihailović, Mihailo Lj., "The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride" in Helvetica Chimica Acta, 68, no. 7 (1985):2030-2032,
https://doi.org/10.1002/hlca.19850680727 . .
