Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200023 (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina - ITNMS, Beograd) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200023 (Институт за технологију нуклеарних и других минералних сировина - ИТНМС, Београд) (sr)
Authors

Publications

Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom

Avdalović, Jelena; Matić, J.; Miletić, Srđan; Spasić, Snežana; Lugonja, Nikoleta; Beškoski, Vladimir; Lopičić, Zorica

(Srpsko hemijsko društvo, 2023)

TY  - CONF
AU  - Avdalović, Jelena
AU  - Matić, J.
AU  - Miletić, Srđan
AU  - Spasić, Snežana
AU  - Lugonja, Nikoleta
AU  - Beškoski, Vladimir
AU  - Lopičić, Zorica
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6233
AB  - U ovom radu je ispitivano kombinovanje adsorpcije i bioremedijacije u postupku prečišćavanja voda kontaminiranih dizelom. Prva faza je ispitivanje adsorpcije dizela na biouglju, dobijenom pirolizom koštica šljive. Druga faza je biorazgradnja dizela zaostalog u rastvoru nakon adsorpcije. Oba procesa podržavaju koncept održivog razvoja, kome je imperativ obnovljivost, efikasnost i ekološka prihvatljivost.
PB  - Srpsko hemijsko društvo
C3  - Knjiga izvoda - 9. Simpozijum Hemija i Zaštita Životne Sredine - EnviroChem2023, 4-7. jun 2023, Kladovo / Book of abstracts - 9 th Symposium Chemistry and Environmental Protection - EnviroChem2023, 4-7 th June 2023, Kladovo, Serbia
T1  - Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom
T1  - Investigation of adsorption and bioremediation in a combined procedure for purification of water contaminated with disel
SP  - 121
EP  - 122
UR  - https://hdl.handle.net/21.15107/rcub_cer_6233
ER  - 
@conference{
author = "Avdalović, Jelena and Matić, J. and Miletić, Srđan and Spasić, Snežana and Lugonja, Nikoleta and Beškoski, Vladimir and Lopičić, Zorica",
year = "2023",
abstract = "U ovom radu je ispitivano kombinovanje adsorpcije i bioremedijacije u postupku prečišćavanja voda kontaminiranih dizelom. Prva faza je ispitivanje adsorpcije dizela na biouglju, dobijenom pirolizom koštica šljive. Druga faza je biorazgradnja dizela zaostalog u rastvoru nakon adsorpcije. Oba procesa podržavaju koncept održivog razvoja, kome je imperativ obnovljivost, efikasnost i ekološka prihvatljivost.",
publisher = "Srpsko hemijsko društvo",
journal = "Knjiga izvoda - 9. Simpozijum Hemija i Zaštita Životne Sredine - EnviroChem2023, 4-7. jun 2023, Kladovo / Book of abstracts - 9 th Symposium Chemistry and Environmental Protection - EnviroChem2023, 4-7 th June 2023, Kladovo, Serbia",
title = "Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom, Investigation of adsorption and bioremediation in a combined procedure for purification of water contaminated with disel",
pages = "121-122",
url = "https://hdl.handle.net/21.15107/rcub_cer_6233"
}
Avdalović, J., Matić, J., Miletić, S., Spasić, S., Lugonja, N., Beškoski, V.,& Lopičić, Z.. (2023). Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom. in Knjiga izvoda - 9. Simpozijum Hemija i Zaštita Životne Sredine - EnviroChem2023, 4-7. jun 2023, Kladovo / Book of abstracts - 9 th Symposium Chemistry and Environmental Protection - EnviroChem2023, 4-7 th June 2023, Kladovo, Serbia
Srpsko hemijsko društvo., 121-122.
https://hdl.handle.net/21.15107/rcub_cer_6233
Avdalović J, Matić J, Miletić S, Spasić S, Lugonja N, Beškoski V, Lopičić Z. Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom. in Knjiga izvoda - 9. Simpozijum Hemija i Zaštita Životne Sredine - EnviroChem2023, 4-7. jun 2023, Kladovo / Book of abstracts - 9 th Symposium Chemistry and Environmental Protection - EnviroChem2023, 4-7 th June 2023, Kladovo, Serbia. 2023;:121-122.
https://hdl.handle.net/21.15107/rcub_cer_6233 .
Avdalović, Jelena, Matić, J., Miletić, Srđan, Spasić, Snežana, Lugonja, Nikoleta, Beškoski, Vladimir, Lopičić, Zorica, "Ispitivanje adsorpcije i bioremedijacije u kombinovanom postupku za prečišćavanja voda zagađenih dizelom" in Knjiga izvoda - 9. Simpozijum Hemija i Zaštita Životne Sredine - EnviroChem2023, 4-7. jun 2023, Kladovo / Book of abstracts - 9 th Symposium Chemistry and Environmental Protection - EnviroChem2023, 4-7 th June 2023, Kladovo, Serbia (2023):121-122,
https://hdl.handle.net/21.15107/rcub_cer_6233 .

Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy

Šoštarić, Tatjana; Kolašinac, Stefan; Lopičić, Zorica; Atanasković, Anja; Adamović, Vladimir; Avdalović, Jelena; Bugarčić, Mladen

(Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Šoštarić, Tatjana
AU  - Kolašinac, Stefan
AU  - Lopičić, Zorica
AU  - Atanasković, Anja
AU  - Adamović, Vladimir
AU  - Avdalović, Jelena
AU  - Bugarčić, Mladen
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6249
AB  - Growing industrialization and non-renewable resource depletion have a huge impact on alternative clean up technologies  development, inducing investigation of the renewable, low-cost waste materials. Recently, lignocellulosic waste biomass,  generated at a large scale by different industries, appeared as an attractive feedstock worldwide, due to its abundance,  availability, multi-functionality and low cost. Since the fruits production has increasing trend all over the world,  generation of lignocellulosic waste such as fruit stones (that represent approximately 1/5 of the total fruit mass) became a great environmental threat. In order to minimize negative impact on the environment, avoid greenhouse gasses emissions  and help in resource depletion by its renewable nature, it is necessary to explore its performances regarding its wide  application potential. Thermo-chemical conversion of lignocellulosic biomass in oxygen limited conditions, in order to  get biochar, has received a lot of attention recently. The biochar production requires lower energy inputs and less  expensive technology compared to activated carbon (estimation is that production cost of activated carbon are six times  higher than biochar costs).  In this paper, waste peach stones biomass was effectively converted into biochar at 500 °C under inert (Ar) atmosphere.  Pyrolysis was performed in Nabertherm 1300 muffle furnace for residence time of 1.5 h, with a heating rate of 10 °C/min,  while Ar was circulated through the sample at a rate of 100 mL/min. The raw biomass (PS) and obtained biochar (PS-B)  with particle size 0.1 mm < dp < 0.5 mm, were characterized by Scanning Electron Microscopy (SEM), Fourier transform infrared spectrometry (FTIR) and Raman spectrometry to understand physicochemical changes which have been occurred  after pyrolysis. SEM analysis revealed the increased surface area due to the visible augmentation of pores and roughness.  FTIR analysis showed that many bands present in native biomass cannot be observed in biochar, due to the conversion or  removal of the most of the functional groups. Prominent bands have confirmed presences of aromatic compounds in  biochar: at 1592 cm−1 (C=C bond stretching derived from aromatic rings in the lignin), 1030 cm-1 (alcohol C-O stretching  vibration) and in the region 900 to 700 cm−1 (originating from aromatic compounds). These finding are in accordance  with results from Raman analysis, where D and G bands (at 1350 cm-1 and 1580 cm-1 respectively), indicate the presence  of poly-aromatic hydrocarbons. Thermo-chemically modified biomass like this has a great application potential: as a pollutants sorbent, biofuel, soil  amendment, biocarriers, and in construction and electronic industries.
PB  - Association of Metallurgical Engineers of Serbia (AMES)
C3  - Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
T1  - Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy
SP  - 237
EP  - 241
UR  - https://hdl.handle.net/21.15107/rcub_cer_6249
ER  - 
@conference{
author = "Šoštarić, Tatjana and Kolašinac, Stefan and Lopičić, Zorica and Atanasković, Anja and Adamović, Vladimir and Avdalović, Jelena and Bugarčić, Mladen",
year = "2023",
abstract = "Growing industrialization and non-renewable resource depletion have a huge impact on alternative clean up technologies  development, inducing investigation of the renewable, low-cost waste materials. Recently, lignocellulosic waste biomass,  generated at a large scale by different industries, appeared as an attractive feedstock worldwide, due to its abundance,  availability, multi-functionality and low cost. Since the fruits production has increasing trend all over the world,  generation of lignocellulosic waste such as fruit stones (that represent approximately 1/5 of the total fruit mass) became a great environmental threat. In order to minimize negative impact on the environment, avoid greenhouse gasses emissions  and help in resource depletion by its renewable nature, it is necessary to explore its performances regarding its wide  application potential. Thermo-chemical conversion of lignocellulosic biomass in oxygen limited conditions, in order to  get biochar, has received a lot of attention recently. The biochar production requires lower energy inputs and less  expensive technology compared to activated carbon (estimation is that production cost of activated carbon are six times  higher than biochar costs).  In this paper, waste peach stones biomass was effectively converted into biochar at 500 °C under inert (Ar) atmosphere.  Pyrolysis was performed in Nabertherm 1300 muffle furnace for residence time of 1.5 h, with a heating rate of 10 °C/min,  while Ar was circulated through the sample at a rate of 100 mL/min. The raw biomass (PS) and obtained biochar (PS-B)  with particle size 0.1 mm < dp < 0.5 mm, were characterized by Scanning Electron Microscopy (SEM), Fourier transform infrared spectrometry (FTIR) and Raman spectrometry to understand physicochemical changes which have been occurred  after pyrolysis. SEM analysis revealed the increased surface area due to the visible augmentation of pores and roughness.  FTIR analysis showed that many bands present in native biomass cannot be observed in biochar, due to the conversion or  removal of the most of the functional groups. Prominent bands have confirmed presences of aromatic compounds in  biochar: at 1592 cm−1 (C=C bond stretching derived from aromatic rings in the lignin), 1030 cm-1 (alcohol C-O stretching  vibration) and in the region 900 to 700 cm−1 (originating from aromatic compounds). These finding are in accordance  with results from Raman analysis, where D and G bands (at 1350 cm-1 and 1580 cm-1 respectively), indicate the presence  of poly-aromatic hydrocarbons. Thermo-chemically modified biomass like this has a great application potential: as a pollutants sorbent, biofuel, soil  amendment, biocarriers, and in construction and electronic industries.",
publisher = "Association of Metallurgical Engineers of Serbia (AMES)",
journal = "Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina",
title = "Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy",
pages = "237-241",
url = "https://hdl.handle.net/21.15107/rcub_cer_6249"
}
Šoštarić, T., Kolašinac, S., Lopičić, Z., Atanasković, A., Adamović, V., Avdalović, J.,& Bugarčić, M.. (2023). Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
Association of Metallurgical Engineers of Serbia (AMES)., 237-241.
https://hdl.handle.net/21.15107/rcub_cer_6249
Šoštarić T, Kolašinac S, Lopičić Z, Atanasković A, Adamović V, Avdalović J, Bugarčić M. Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina. 2023;:237-241.
https://hdl.handle.net/21.15107/rcub_cer_6249 .
Šoštarić, Tatjana, Kolašinac, Stefan, Lopičić, Zorica, Atanasković, Anja, Adamović, Vladimir, Avdalović, Jelena, Bugarčić, Mladen, "Characterization of raw peach stones and its biochar by SEM, FTIR and Raman spectroscopy" in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina (2023):237-241,
https://hdl.handle.net/21.15107/rcub_cer_6249 .

Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal

Pantović Spajić, Katarina; Pantović Pavlović, Marijana; Božić, Katarina; Gjumišev, Đorđe; Panić, Vladimir; Pavlović, Miroslav; Stojanović, Ksenija

(Zvornik : Faculty of Technology, 2023)

TY  - CONF
AU  - Pantović Spajić, Katarina
AU  - Pantović Pavlović, Marijana
AU  - Božić, Katarina
AU  - Gjumišev, Đorđe
AU  - Panić, Vladimir
AU  - Pavlović, Miroslav
AU  - Stojanović, Ksenija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6555
AB  - The removal of organic and inorganic sulfur from the Bogovina Basin subbituminous coal by electrochemical redox reactions was performed. The effect of presence of active bromine species on the desulfurization process was monitored. The desulfurization was performed in inorganic acidic solutions that contained different bromide concentrations and in pure acid solution. To 
determine the optimal conditions for the desulfurization process, polarization curves were 
recorded in three different electrolytes: 0.1 M H2SO4, 0.1 M H2SO4 + 0.01 M KBr, and 0.1 M 
H2SO4 + 0.1 M KBr using graphite and dimensionally stable anode (DSA) electrodes as the 
anode, while in all cases stainless steel S31603 electrode was used as cathode. By analyzing the 
results obtained from the polarization curves, 0.1 M H2SO4 and 0.1 M H2SO4 + 0.1 M KBr were 
chosen as the most suitable electrolytes. Also, it was found that the DSA anode showed better 
results in terms of energy efficiency of the process compared to the graphite anode and therefore
it was selected for the coal desulfurization process. It is considered that finely suspended coal 
particles in an electrolyte can behave according to bipolar electrochemistry. Coal was treated 
for 4 hours in two selected electrolytes. The suspension was sampled at different times up to 240 
min from the beginning of the process. Sulfur content in coal was determined by elemental 
analysis. The results showed that the sulfur content decreases faster in the case of the electrolyte 
containing KBr, i.e. that the desulfurization effect is significantly better than in the case of the 
system containing only H2SO4. It can be concluded that active bromine species accelerate the 
desulfurization process and thus improve energy efficiency.
PB  - Zvornik : Faculty of Technology
C3  - Book of Abstracts - VIII International Congress Engineering, Environment and Materials in Process Industry, March 20-23, 2023, Jahorina - Republic of Srpska, Bosnia and Herzegovina
T1  - Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal
SP  - 64
EP  - 64
UR  - https://hdl.handle.net/21.15107/rcub_cer_6555
ER  - 
@conference{
author = "Pantović Spajić, Katarina and Pantović Pavlović, Marijana and Božić, Katarina and Gjumišev, Đorđe and Panić, Vladimir and Pavlović, Miroslav and Stojanović, Ksenija",
year = "2023",
abstract = "The removal of organic and inorganic sulfur from the Bogovina Basin subbituminous coal by electrochemical redox reactions was performed. The effect of presence of active bromine species on the desulfurization process was monitored. The desulfurization was performed in inorganic acidic solutions that contained different bromide concentrations and in pure acid solution. To 
determine the optimal conditions for the desulfurization process, polarization curves were 
recorded in three different electrolytes: 0.1 M H2SO4, 0.1 M H2SO4 + 0.01 M KBr, and 0.1 M 
H2SO4 + 0.1 M KBr using graphite and dimensionally stable anode (DSA) electrodes as the 
anode, while in all cases stainless steel S31603 electrode was used as cathode. By analyzing the 
results obtained from the polarization curves, 0.1 M H2SO4 and 0.1 M H2SO4 + 0.1 M KBr were 
chosen as the most suitable electrolytes. Also, it was found that the DSA anode showed better 
results in terms of energy efficiency of the process compared to the graphite anode and therefore
it was selected for the coal desulfurization process. It is considered that finely suspended coal 
particles in an electrolyte can behave according to bipolar electrochemistry. Coal was treated 
for 4 hours in two selected electrolytes. The suspension was sampled at different times up to 240 
min from the beginning of the process. Sulfur content in coal was determined by elemental 
analysis. The results showed that the sulfur content decreases faster in the case of the electrolyte 
containing KBr, i.e. that the desulfurization effect is significantly better than in the case of the 
system containing only H2SO4. It can be concluded that active bromine species accelerate the 
desulfurization process and thus improve energy efficiency.",
publisher = "Zvornik : Faculty of Technology",
journal = "Book of Abstracts - VIII International Congress Engineering, Environment and Materials in Process Industry, March 20-23, 2023, Jahorina - Republic of Srpska, Bosnia and Herzegovina",
title = "Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal",
pages = "64-64",
url = "https://hdl.handle.net/21.15107/rcub_cer_6555"
}
Pantović Spajić, K., Pantović Pavlović, M., Božić, K., Gjumišev, Đ., Panić, V., Pavlović, M.,& Stojanović, K.. (2023). Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal. in Book of Abstracts - VIII International Congress Engineering, Environment and Materials in Process Industry, March 20-23, 2023, Jahorina - Republic of Srpska, Bosnia and Herzegovina
Zvornik : Faculty of Technology., 64-64.
https://hdl.handle.net/21.15107/rcub_cer_6555
Pantović Spajić K, Pantović Pavlović M, Božić K, Gjumišev Đ, Panić V, Pavlović M, Stojanović K. Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal. in Book of Abstracts - VIII International Congress Engineering, Environment and Materials in Process Industry, March 20-23, 2023, Jahorina - Republic of Srpska, Bosnia and Herzegovina. 2023;:64-64.
https://hdl.handle.net/21.15107/rcub_cer_6555 .
Pantović Spajić, Katarina, Pantović Pavlović, Marijana, Božić, Katarina, Gjumišev, Đorđe, Panić, Vladimir, Pavlović, Miroslav, Stojanović, Ksenija, "Study of the effects of active bromine species presence in electrolytic desulfurization of subbituminous coal" in Book of Abstracts - VIII International Congress Engineering, Environment and Materials in Process Industry, March 20-23, 2023, Jahorina - Republic of Srpska, Bosnia and Herzegovina (2023):64-64,
https://hdl.handle.net/21.15107/rcub_cer_6555 .

Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for potential biomedical application

Milojkov, Dušan; Marković, Gordana; Sokić, Miroslav; Manojlović, Vaso; Mutavdžić, Dragosav; Janjić, Goran

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Milojkov, Dušan
AU  - Marković, Gordana
AU  - Sokić, Miroslav
AU  - Manojlović, Vaso
AU  - Mutavdžić, Dragosav
AU  - Janjić, Goran
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7341
AB  - Fluorapatite (FAP) crystals have drawn significant interest over the last few decades as important hosts matrix for optically active trivalent rare earth ions, due to the strong crystal field splitting and large transition cross-sections. Nano-sized FAP particles doped with rare earth ions have been extensively studied as luminescent materials for biomedical applications for cell labeling and bioimaging, as well as antimicrobial agents for therapeutics.Fluorapatite nanoparticles doped with praseodymium ions (Pr3+) were prepared by the co precipitation method and characterized. The different number of Pr3+ (4f2) transitions in the ultraviolet and visible parts of the spectrum was investigated by photoluminescence spectroscopy. Multivariate Curve Resolution–Alternating Least Squares (MCR-ALS) analyses of fluorescence spectra and ab initio calculation indicated that Pr3+ ions are preferentially substituted Ca2 (6h) sites in FAP lattice. In addition to the substitution of cations, there is also the substitution of anionic species such as OH-, CO32-, and NO3-, which are confirmed by the CHNS method. The obtained samples were tested as bioimaging and antibacterial agents and can potentially be used for further biomedical research.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of Abstracts, The Eleventh Serbian Ceramic Society Conference Advanced Ceramics and Application, September 18-20, 2023
T1  - Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for  potential biomedical application
SP  - 38
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_cer_7341
ER  - 
@conference{
author = "Milojkov, Dušan and Marković, Gordana and Sokić, Miroslav and Manojlović, Vaso and Mutavdžić, Dragosav and Janjić, Goran",
year = "2023",
abstract = "Fluorapatite (FAP) crystals have drawn significant interest over the last few decades as important hosts matrix for optically active trivalent rare earth ions, due to the strong crystal field splitting and large transition cross-sections. Nano-sized FAP particles doped with rare earth ions have been extensively studied as luminescent materials for biomedical applications for cell labeling and bioimaging, as well as antimicrobial agents for therapeutics.Fluorapatite nanoparticles doped with praseodymium ions (Pr3+) were prepared by the co precipitation method and characterized. The different number of Pr3+ (4f2) transitions in the ultraviolet and visible parts of the spectrum was investigated by photoluminescence spectroscopy. Multivariate Curve Resolution–Alternating Least Squares (MCR-ALS) analyses of fluorescence spectra and ab initio calculation indicated that Pr3+ ions are preferentially substituted Ca2 (6h) sites in FAP lattice. In addition to the substitution of cations, there is also the substitution of anionic species such as OH-, CO32-, and NO3-, which are confirmed by the CHNS method. The obtained samples were tested as bioimaging and antibacterial agents and can potentially be used for further biomedical research.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of Abstracts, The Eleventh Serbian Ceramic Society Conference Advanced Ceramics and Application, September 18-20, 2023",
title = "Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for  potential biomedical application",
pages = "38-39",
url = "https://hdl.handle.net/21.15107/rcub_cer_7341"
}
Milojkov, D., Marković, G., Sokić, M., Manojlović, V., Mutavdžić, D.,& Janjić, G.. (2023). Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for  potential biomedical application. in Program and the Book of Abstracts, The Eleventh Serbian Ceramic Society Conference Advanced Ceramics and Application, September 18-20, 2023
Belgrade : Serbian Ceramic Society., 38-39.
https://hdl.handle.net/21.15107/rcub_cer_7341
Milojkov D, Marković G, Sokić M, Manojlović V, Mutavdžić D, Janjić G. Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for  potential biomedical application. in Program and the Book of Abstracts, The Eleventh Serbian Ceramic Society Conference Advanced Ceramics and Application, September 18-20, 2023. 2023;:38-39.
https://hdl.handle.net/21.15107/rcub_cer_7341 .
Milojkov, Dušan, Marković, Gordana, Sokić, Miroslav, Manojlović, Vaso, Mutavdžić, Dragosav, Janjić, Goran, "Luminescence transitions of Pr3+ (4f2) in fluorapatite nanocrystals for  potential biomedical application" in Program and the Book of Abstracts, The Eleventh Serbian Ceramic Society Conference Advanced Ceramics and Application, September 18-20, 2023 (2023):38-39,
https://hdl.handle.net/21.15107/rcub_cer_7341 .

Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater

Jovanović, Aleksandar; Bugarčić, Mladen; Milošević, Milena; Vuksanovic, Marija; Abdualatif Abduarahman, Muna; Sokić, Miroslav; Marinković, Aleksandar

(Bor : University of Belgrade, Technical Faculty in Bor, 2023)

TY  - CONF
AU  - Jovanović, Aleksandar
AU  - Bugarčić, Mladen
AU  - Milošević, Milena
AU  - Vuksanovic, Marija
AU  - Abdualatif Abduarahman, Muna
AU  - Sokić, Miroslav
AU  - Marinković, Aleksandar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7334
AB  - Nickel pollution of water induces several problems for the environment. The purpose of this paper was toinvestigate the adsorption of Ni2+ ions on fabricated biomembranes. The proposed adsorbent was preparedfrom epoxy and amino-functionalized waste cellulose fibers, able to participate in cross-linking with aminoacid lysine - wCell/Mn-Fe_LDH. The prepared material underwent preliminary structural characterizationby Fourier-transform infrared spectroscopy. In a batch system, the influence of pH, contact time,temperature, and initial concentration on adsorption efficiency was investigated. The effectiveness of themembrane was demonstrated by acceptable adsorption capacities of 40.49 mg g-1 obtained for Ni2+ at 45°C.The kinetic study, using the Weber-Morris model, indicates intraparticle diffusion as the rate limiting step.Adsorption mechanism physisorption was proposed based on thermodynamic behaviors. The outcomesdemonstrated that environmentally friendly sustainable technology has been successfully developed.
PB  - Bor : University of Belgrade, Technical Faculty in Bor
C3  - 54th International October Conference on Mining and Metallurgy
T1  - Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater
SP  - 514
EP  - 517
UR  - https://hdl.handle.net/21.15107/rcub_cer_7334
ER  - 
@conference{
author = "Jovanović, Aleksandar and Bugarčić, Mladen and Milošević, Milena and Vuksanovic, Marija and Abdualatif Abduarahman, Muna and Sokić, Miroslav and Marinković, Aleksandar",
year = "2023",
abstract = "Nickel pollution of water induces several problems for the environment. The purpose of this paper was toinvestigate the adsorption of Ni2+ ions on fabricated biomembranes. The proposed adsorbent was preparedfrom epoxy and amino-functionalized waste cellulose fibers, able to participate in cross-linking with aminoacid lysine - wCell/Mn-Fe_LDH. The prepared material underwent preliminary structural characterizationby Fourier-transform infrared spectroscopy. In a batch system, the influence of pH, contact time,temperature, and initial concentration on adsorption efficiency was investigated. The effectiveness of themembrane was demonstrated by acceptable adsorption capacities of 40.49 mg g-1 obtained for Ni2+ at 45°C.The kinetic study, using the Weber-Morris model, indicates intraparticle diffusion as the rate limiting step.Adsorption mechanism physisorption was proposed based on thermodynamic behaviors. The outcomesdemonstrated that environmentally friendly sustainable technology has been successfully developed.",
publisher = "Bor : University of Belgrade, Technical Faculty in Bor",
journal = "54th International October Conference on Mining and Metallurgy",
title = "Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater",
pages = "514-517",
url = "https://hdl.handle.net/21.15107/rcub_cer_7334"
}
Jovanović, A., Bugarčić, M., Milošević, M., Vuksanovic, M., Abdualatif Abduarahman, M., Sokić, M.,& Marinković, A.. (2023). Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater. in 54th International October Conference on Mining and Metallurgy
Bor : University of Belgrade, Technical Faculty in Bor., 514-517.
https://hdl.handle.net/21.15107/rcub_cer_7334
Jovanović A, Bugarčić M, Milošević M, Vuksanovic M, Abdualatif Abduarahman M, Sokić M, Marinković A. Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater. in 54th International October Conference on Mining and Metallurgy. 2023;:514-517.
https://hdl.handle.net/21.15107/rcub_cer_7334 .
Jovanović, Aleksandar, Bugarčić, Mladen, Milošević, Milena, Vuksanovic, Marija, Abdualatif Abduarahman, Muna, Sokić, Miroslav, Marinković, Aleksandar, "Modified hybrid cellulose membrane for Nickel(ii) ions removal from industrial wastewater" in 54th International October Conference on Mining and Metallurgy (2023):514-517,
https://hdl.handle.net/21.15107/rcub_cer_7334 .

Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning

Marković, Gordana; Manojlović, Vaso; Sokić, Miroslav; Ruzic, Jovana; Milojkov, Dušan; Patarić, Aleksandra

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - CONF
AU  - Marković, Gordana
AU  - Manojlović, Vaso
AU  - Sokić, Miroslav
AU  - Ruzic, Jovana
AU  - Milojkov, Dušan
AU  - Patarić, Aleksandra
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7362
AB  - Titanium alloys are widely employed in various fields, particularly in biomedical engineering, due to their mechanical  and corrosion resistance properties combined with good biocompatibility. The modulus of elasticity is a distinguishing  feature of this group of materials compared to others used for similar purposes. A database of approximately 238 titanium alloys free of toxic elements was compiled for this study. The influence of different factors (such as alloy element  proportions, density, and specific heat) on the modulus of elasticity was predicted using four methods: support vector machine, XGBoost, Neural Network, and Random Forest. The Random Forest mean absolute error (MAE) of 7.33 GPa, falls within the range of experimentally obtained absolute errors in the literature (up to about 11 GPa). A strong correlation (R2 = 0.72) was observed between experimental and predicted data. Lastly, specific alloying element regions were identified for the modulus of elasticity, which can be used to design new biocompatible titanium alloys in the future.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe
T1  - Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning
SP  - 154
EP  - 158
UR  - https://hdl.handle.net/21.15107/rcub_cer_7362
ER  - 
@conference{
author = "Marković, Gordana and Manojlović, Vaso and Sokić, Miroslav and Ruzic, Jovana and Milojkov, Dušan and Patarić, Aleksandra",
year = "2023",
abstract = "Titanium alloys are widely employed in various fields, particularly in biomedical engineering, due to their mechanical  and corrosion resistance properties combined with good biocompatibility. The modulus of elasticity is a distinguishing  feature of this group of materials compared to others used for similar purposes. A database of approximately 238 titanium alloys free of toxic elements was compiled for this study. The influence of different factors (such as alloy element  proportions, density, and specific heat) on the modulus of elasticity was predicted using four methods: support vector machine, XGBoost, Neural Network, and Random Forest. The Random Forest mean absolute error (MAE) of 7.33 GPa, falls within the range of experimentally obtained absolute errors in the literature (up to about 11 GPa). A strong correlation (R2 = 0.72) was observed between experimental and predicted data. Lastly, specific alloying element regions were identified for the modulus of elasticity, which can be used to design new biocompatible titanium alloys in the future.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe",
title = "Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning",
pages = "154-158",
url = "https://hdl.handle.net/21.15107/rcub_cer_7362"
}
Marković, G., Manojlović, V., Sokić, M., Ruzic, J., Milojkov, D.,& Patarić, A.. (2023). Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning. in 5th Metallurgical & Materials Engineering Congress of South-East Europe
Belgrade : Association of Metallurgical Engineers of Serbia., 154-158.
https://hdl.handle.net/21.15107/rcub_cer_7362
Marković G, Manojlović V, Sokić M, Ruzic J, Milojkov D, Patarić A. Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning. in 5th Metallurgical & Materials Engineering Congress of South-East Europe. 2023;:154-158.
https://hdl.handle.net/21.15107/rcub_cer_7362 .
Marković, Gordana, Manojlović, Vaso, Sokić, Miroslav, Ruzic, Jovana, Milojkov, Dušan, Patarić, Aleksandra, "Predicting the modulus of elasticity of biocompatible titanium alloys using machine learning" in 5th Metallurgical & Materials Engineering Congress of South-East Europe (2023):154-158,
https://hdl.handle.net/21.15107/rcub_cer_7362 .

Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions

Jovanović, Aleksandar; Vuksanović, Marija; Knežević, Nataša; Bošnjaković, Jovana; Bugarčić, Mladen; Milošević, Milena; Marinković, Aleksandar

(Novi Sad : University of Novi Sad, Faculty of Sciences, 2023)

TY  - CONF
AU  - Jovanović, Aleksandar
AU  - Vuksanović, Marija
AU  - Knežević, Nataša
AU  - Bošnjaković, Jovana
AU  - Bugarčić, Mladen
AU  - Milošević, Milena
AU  - Marinković, Aleksandar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7335
AB  - Worldwide pollution induces a negative impact on the complete environment. Modern societies are becomingmore involved in developing and implementing climate change adaptation policies as a result ofthe enormous hazards that climate change poses to human safety worldwide. One of the biggest problemsthat highly affects climate change is plastic pollution. Also, the utilization of a linear economy prevents theopportunity of solving mentioned problem. Hence, a major component of the strategy for tackling plasticpollution and trying to decrease global weather changes is an implementation of a circular economy. Plastichas to be reduced, reused, and recycled since its widespread consumption has put environmental protectionat risk. PET, also known as polyethylene terephthalate, is a prominent polymer material used forthe production of packaging, particularly plastic bottles. The majority of PET-based products are madeusing raw materials supplied from fossil fuels. However, methods based on biobased materials and recycling-modified products for obtaining novel products from waste PET have fewer greenhouse gas (GHG)emissions than the traditional method. Therefore, the subject of this paper is the innovative technology forthe fabrication of materials by PET recycling. Obtained monomer units - glycolysates were acquired by PETdepolymerization by inducing greener solutions. The resulting glycolysate was structurally modified withmaleic anhydride and finally with 2-octanol to obtain a novel plasticizer. The physicochemical characterizationof the obtained plasticizer, performed by infrared spectroscopy with Fourier transform (FTIR) andNMR spectroscopy, confirmed structural modifications. The mechanical characteristics of the final productwere tested after the plasticizers had been combined with bitumen at a range from 1 to 10 wt.% concentration.In addition, other PET recycling techniques will be presented and discussed. By comparing them,it will be determined which technique is most suitable for recycling with the smallest carbon footprint. Thesecond purpose of the research is to evaluate and contrast the financial and ecological implications of recyclingPET in comparison to other types of waste and renewable energy sources.
PB  - Novi Sad : University of Novi Sad, Faculty of Sciences
C3  - International conference on Hydro-Climate Extremes and Society
T1  - Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions
SP  - 35
EP  - 35
UR  - https://hdl.handle.net/21.15107/rcub_cer_7335
ER  - 
@conference{
author = "Jovanović, Aleksandar and Vuksanović, Marija and Knežević, Nataša and Bošnjaković, Jovana and Bugarčić, Mladen and Milošević, Milena and Marinković, Aleksandar",
year = "2023",
abstract = "Worldwide pollution induces a negative impact on the complete environment. Modern societies are becomingmore involved in developing and implementing climate change adaptation policies as a result ofthe enormous hazards that climate change poses to human safety worldwide. One of the biggest problemsthat highly affects climate change is plastic pollution. Also, the utilization of a linear economy prevents theopportunity of solving mentioned problem. Hence, a major component of the strategy for tackling plasticpollution and trying to decrease global weather changes is an implementation of a circular economy. Plastichas to be reduced, reused, and recycled since its widespread consumption has put environmental protectionat risk. PET, also known as polyethylene terephthalate, is a prominent polymer material used forthe production of packaging, particularly plastic bottles. The majority of PET-based products are madeusing raw materials supplied from fossil fuels. However, methods based on biobased materials and recycling-modified products for obtaining novel products from waste PET have fewer greenhouse gas (GHG)emissions than the traditional method. Therefore, the subject of this paper is the innovative technology forthe fabrication of materials by PET recycling. Obtained monomer units - glycolysates were acquired by PETdepolymerization by inducing greener solutions. The resulting glycolysate was structurally modified withmaleic anhydride and finally with 2-octanol to obtain a novel plasticizer. The physicochemical characterizationof the obtained plasticizer, performed by infrared spectroscopy with Fourier transform (FTIR) andNMR spectroscopy, confirmed structural modifications. The mechanical characteristics of the final productwere tested after the plasticizers had been combined with bitumen at a range from 1 to 10 wt.% concentration.In addition, other PET recycling techniques will be presented and discussed. By comparing them,it will be determined which technique is most suitable for recycling with the smallest carbon footprint. Thesecond purpose of the research is to evaluate and contrast the financial and ecological implications of recyclingPET in comparison to other types of waste and renewable energy sources.",
publisher = "Novi Sad : University of Novi Sad, Faculty of Sciences",
journal = "International conference on Hydro-Climate Extremes and Society",
title = "Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions",
pages = "35-35",
url = "https://hdl.handle.net/21.15107/rcub_cer_7335"
}
Jovanović, A., Vuksanović, M., Knežević, N., Bošnjaković, J., Bugarčić, M., Milošević, M.,& Marinković, A.. (2023). Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions. in International conference on Hydro-Climate Extremes and Society
Novi Sad : University of Novi Sad, Faculty of Sciences., 35-35.
https://hdl.handle.net/21.15107/rcub_cer_7335
Jovanović A, Vuksanović M, Knežević N, Bošnjaković J, Bugarčić M, Milošević M, Marinković A. Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions. in International conference on Hydro-Climate Extremes and Society. 2023;:35-35.
https://hdl.handle.net/21.15107/rcub_cer_7335 .
Jovanović, Aleksandar, Vuksanović, Marija, Knežević, Nataša, Bošnjaković, Jovana, Bugarčić, Mladen, Milošević, Milena, Marinković, Aleksandar, "Innovative Technology for Recycling Polyethylene Terephthalate: Climate Changes, Approaches, Solutions" in International conference on Hydro-Climate Extremes and Society (2023):35-35,
https://hdl.handle.net/21.15107/rcub_cer_7335 .

Microstructure assessment of Co alloy intended for dentistry

Patarić, Aleksandra; Marković, Gordana; Đorđević, Nataša G.; Mihajlović, Slavica; Mihailović, Marija

(Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Patarić, Aleksandra
AU  - Marković, Gordana
AU  - Đorđević, Nataša G.
AU  - Mihajlović, Slavica
AU  - Mihailović, Marija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6248
AB  - Cobalt–chromium–molybdenum (CoCrMo) alloys are known for medical use due to their biocompatibility, corrosion and  wear resistance. The chemical and phase composition, as well as microstructure of the alloy directly affect the mechanical  properties. In this investigation, CoCrMo alloy samples were obtained by vacuum precise casting. The procedure of  melting and casting process as well as their parameters are given. Molds fabricated of copper, gray iron, steel, ceramics  and graphite were used during the casting process. In this way, the cooling rate influence on the obtained microstructure  was examined. Besides, different casting temperatures (1400°C, 1450°C and 1500°C) were applied for each kind of mold.  After metallographic preparation, the microstructure was examined on the cross section of samples by optical microscopy.  The obtained results show that by increasing the cooling rate, the microstructure of samples become finer and more  homogeneous.
PB  - Association of Metallurgical Engineers of Serbia (AMES)
C3  - Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
T1  - Microstructure assessment of Co alloy intended for dentistry
SP  - 221
EP  - 225
UR  - https://hdl.handle.net/21.15107/rcub_cer_6248
ER  - 
@conference{
author = "Patarić, Aleksandra and Marković, Gordana and Đorđević, Nataša G. and Mihajlović, Slavica and Mihailović, Marija",
year = "2023",
abstract = "Cobalt–chromium–molybdenum (CoCrMo) alloys are known for medical use due to their biocompatibility, corrosion and  wear resistance. The chemical and phase composition, as well as microstructure of the alloy directly affect the mechanical  properties. In this investigation, CoCrMo alloy samples were obtained by vacuum precise casting. The procedure of  melting and casting process as well as their parameters are given. Molds fabricated of copper, gray iron, steel, ceramics  and graphite were used during the casting process. In this way, the cooling rate influence on the obtained microstructure  was examined. Besides, different casting temperatures (1400°C, 1450°C and 1500°C) were applied for each kind of mold.  After metallographic preparation, the microstructure was examined on the cross section of samples by optical microscopy.  The obtained results show that by increasing the cooling rate, the microstructure of samples become finer and more  homogeneous.",
publisher = "Association of Metallurgical Engineers of Serbia (AMES)",
journal = "Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina",
title = "Microstructure assessment of Co alloy intended for dentistry",
pages = "221-225",
url = "https://hdl.handle.net/21.15107/rcub_cer_6248"
}
Patarić, A., Marković, G., Đorđević, N. G., Mihajlović, S.,& Mihailović, M.. (2023). Microstructure assessment of Co alloy intended for dentistry. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
Association of Metallurgical Engineers of Serbia (AMES)., 221-225.
https://hdl.handle.net/21.15107/rcub_cer_6248
Patarić A, Marković G, Đorđević NG, Mihajlović S, Mihailović M. Microstructure assessment of Co alloy intended for dentistry. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina. 2023;:221-225.
https://hdl.handle.net/21.15107/rcub_cer_6248 .
Patarić, Aleksandra, Marković, Gordana, Đorđević, Nataša G., Mihajlović, Slavica, Mihailović, Marija, "Microstructure assessment of Co alloy intended for dentistry" in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina (2023):221-225,
https://hdl.handle.net/21.15107/rcub_cer_6248 .

Microstructure development during heat treatment of high chromium white cast iron

Mihailović, Marija; Patarić, Aleksandra; Aksentijević, Snežana; Jordović, Branka

(Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Mihailović, Marija
AU  - Patarić, Aleksandra
AU  - Aksentijević, Snežana
AU  - Jordović, Branka
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6247
AB  - Even though it has been in use for a very long time, the high chromium white cast iron (HCWCI) still triggers scientists  due to its outstanding wear resistance. Besides its well-known as-cast usage, it can be used as a coating material, as well.  HCWCI owes this feature due to the presence of carbides in microstructure, which depends on the composition and heat  treatment regime. This investigation was conducted on two HCWCI alloys, where in addition to chromium, the second  important alloying element is molybdenum (Mo). Apart from other alloying elements, HCWCI_1 is alloyed with 24.48%  Cr and 1.32% Mo, while HCWCI_2 contains 14.11% Cr and 2.47% Mo. The comprehensive microstructural  characterization was carried out on as-cast samples and samples obtained after quenching (at -196oC) and/or quenching  followed by tempering (at 250oC). Important microstructure indicators are: the stability of austenite, the ratio of microconstituents (especially different types of carbides), as well as their arrangement and morphology, so they are revealed  and discussed in relation to the influencing mechanical properties.
PB  - Association of Metallurgical Engineers of Serbia (AMES)
C3  - Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
T1  - Microstructure development during heat treatment of high chromium white cast iron
SP  - 216
EP  - 220
UR  - https://hdl.handle.net/21.15107/rcub_cer_6247
ER  - 
@conference{
author = "Mihailović, Marija and Patarić, Aleksandra and Aksentijević, Snežana and Jordović, Branka",
year = "2023",
abstract = "Even though it has been in use for a very long time, the high chromium white cast iron (HCWCI) still triggers scientists  due to its outstanding wear resistance. Besides its well-known as-cast usage, it can be used as a coating material, as well.  HCWCI owes this feature due to the presence of carbides in microstructure, which depends on the composition and heat  treatment regime. This investigation was conducted on two HCWCI alloys, where in addition to chromium, the second  important alloying element is molybdenum (Mo). Apart from other alloying elements, HCWCI_1 is alloyed with 24.48%  Cr and 1.32% Mo, while HCWCI_2 contains 14.11% Cr and 2.47% Mo. The comprehensive microstructural  characterization was carried out on as-cast samples and samples obtained after quenching (at -196oC) and/or quenching  followed by tempering (at 250oC). Important microstructure indicators are: the stability of austenite, the ratio of microconstituents (especially different types of carbides), as well as their arrangement and morphology, so they are revealed  and discussed in relation to the influencing mechanical properties.",
publisher = "Association of Metallurgical Engineers of Serbia (AMES)",
journal = "Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina",
title = "Microstructure development during heat treatment of high chromium white cast iron",
pages = "216-220",
url = "https://hdl.handle.net/21.15107/rcub_cer_6247"
}
Mihailović, M., Patarić, A., Aksentijević, S.,& Jordović, B.. (2023). Microstructure development during heat treatment of high chromium white cast iron. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina
Association of Metallurgical Engineers of Serbia (AMES)., 216-220.
https://hdl.handle.net/21.15107/rcub_cer_6247
Mihailović M, Patarić A, Aksentijević S, Jordović B. Microstructure development during heat treatment of high chromium white cast iron. in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina. 2023;:216-220.
https://hdl.handle.net/21.15107/rcub_cer_6247 .
Mihailović, Marija, Patarić, Aleksandra, Aksentijević, Snežana, Jordović, Branka, "Microstructure development during heat treatment of high chromium white cast iron" in Proceedings of the 5th Metallurgical and Materials Engineering Congress of South-East Europe, 7-10.06.2023, Trebinje, Bosnia and Herzegovina (2023):216-220,
https://hdl.handle.net/21.15107/rcub_cer_6247 .

Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid

Knežević, Nataša; Jovanović, Aleksandar; Bugarčić, Mladen; Vuksanović, Marija; Milošević, Milena; Pešić, Ivan; Marinković, Aleksandar

(Belgrade : University of Belgrade, Faculty of Technology and Metallurgy, 2023)

TY  - CONF
AU  - Knežević, Nataša
AU  - Jovanović, Aleksandar
AU  - Bugarčić, Mladen
AU  - Vuksanović, Marija
AU  - Milošević, Milena
AU  - Pešić, Ivan
AU  - Marinković, Aleksandar
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7401
AB  - Cotton-based membranes, due to their exceptional biocompatibility and sustainability,have attracted considerable attention in various applications, especially in the field of bio andgreen technologies. This study investigates the biodegradation potential of cotton membranesmodified with TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical and citric acid (CA),with the aim of improving their properties and facilitating environmentally friendly disposal.TEMPO radicals, in conjunction with the crosslinker citric acid, are incorporated into thecellulose structure through a novel modification process. The citric acid component acted as aplasticizer, increasing the amorphous parts of the cellulose and promoting enzymatic attack.The TEMPO radical, with its nitroxyl group, contributed to the oxidation of cellulose, furtherfacilitating biodegradation.The biodegradation aspect of these modified membranes was investigated incontrolled environmental conditions (Soil Burial test), simulating natural scenarios (humidity,influence of enzymes, and bacteria). Biodegradation parameters such as weight loss,structural changes, and degradation kinetics were examined during 90 days. Characterizationof the structure was performed using FTIR and SEM methods.Our findings suggest that cellulosic membranes possess complete (100%)biodegradability after 70 days compared to unmodified membranes. Obtained result shedlight on the potential of membranes modified in this way as sustainable and biodegradablealternatives in various applications. The results emphasize their ecological nature and abilityto reduce environmental stress. Such cellulose-based materials promise a much greener futurein biotechnology, healthcare, and environmental protection.
PB  - Belgrade : University of Belgrade, Faculty of Technology and Metallurgy
C3  - International Conference: Biochemical Engineering and Biotechnology for Young Scientists, Book of abstracts
T1  - Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid
SP  - 42
EP  - 42
UR  - https://hdl.handle.net/21.15107/rcub_cer_7401
ER  - 
@conference{
author = "Knežević, Nataša and Jovanović, Aleksandar and Bugarčić, Mladen and Vuksanović, Marija and Milošević, Milena and Pešić, Ivan and Marinković, Aleksandar",
year = "2023",
abstract = "Cotton-based membranes, due to their exceptional biocompatibility and sustainability,have attracted considerable attention in various applications, especially in the field of bio andgreen technologies. This study investigates the biodegradation potential of cotton membranesmodified with TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical and citric acid (CA),with the aim of improving their properties and facilitating environmentally friendly disposal.TEMPO radicals, in conjunction with the crosslinker citric acid, are incorporated into thecellulose structure through a novel modification process. The citric acid component acted as aplasticizer, increasing the amorphous parts of the cellulose and promoting enzymatic attack.The TEMPO radical, with its nitroxyl group, contributed to the oxidation of cellulose, furtherfacilitating biodegradation.The biodegradation aspect of these modified membranes was investigated incontrolled environmental conditions (Soil Burial test), simulating natural scenarios (humidity,influence of enzymes, and bacteria). Biodegradation parameters such as weight loss,structural changes, and degradation kinetics were examined during 90 days. Characterizationof the structure was performed using FTIR and SEM methods.Our findings suggest that cellulosic membranes possess complete (100%)biodegradability after 70 days compared to unmodified membranes. Obtained result shedlight on the potential of membranes modified in this way as sustainable and biodegradablealternatives in various applications. The results emphasize their ecological nature and abilityto reduce environmental stress. Such cellulose-based materials promise a much greener futurein biotechnology, healthcare, and environmental protection.",
publisher = "Belgrade : University of Belgrade, Faculty of Technology and Metallurgy",
journal = "International Conference: Biochemical Engineering and Biotechnology for Young Scientists, Book of abstracts",
title = "Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid",
pages = "42-42",
url = "https://hdl.handle.net/21.15107/rcub_cer_7401"
}
Knežević, N., Jovanović, A., Bugarčić, M., Vuksanović, M., Milošević, M., Pešić, I.,& Marinković, A.. (2023). Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid. in International Conference: Biochemical Engineering and Biotechnology for Young Scientists, Book of abstracts
Belgrade : University of Belgrade, Faculty of Technology and Metallurgy., 42-42.
https://hdl.handle.net/21.15107/rcub_cer_7401
Knežević N, Jovanović A, Bugarčić M, Vuksanović M, Milošević M, Pešić I, Marinković A. Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid. in International Conference: Biochemical Engineering and Biotechnology for Young Scientists, Book of abstracts. 2023;:42-42.
https://hdl.handle.net/21.15107/rcub_cer_7401 .
Knežević, Nataša, Jovanović, Aleksandar, Bugarčić, Mladen, Vuksanović, Marija, Milošević, Milena, Pešić, Ivan, Marinković, Aleksandar, "Possibility of biodegradation of cotton membrane containing TEMPO radical and citric acid" in International Conference: Biochemical Engineering and Biotechnology for Young Scientists, Book of abstracts (2023):42-42,
https://hdl.handle.net/21.15107/rcub_cer_7401 .

Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis

Martinović, Sanja; Alil, Ana; Milićević, Sonja; Živojinović, Dragana; Volkov Husović, Tatjana

(Elsevier, 2023)

TY  - JOUR
AU  - Martinović, Sanja
AU  - Alil, Ana
AU  - Milićević, Sonja
AU  - Živojinović, Dragana
AU  - Volkov Husović, Tatjana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6031
AB  - The pattern recognition approach, explored by this study, applies the principal component
analysis (PCA) as the most widely used statistical method with the aim of assessing the initiation
and propagation of the cracks and defects that appear on the surface of material exposed to the
cavitation. The experiment was performed in four stages: (a) synthesis of two ceramic materials
(cordierite and zircon); (b) subjecting the samples to the cavitation; (c) using image analysis
software for collecting the data about morphological characteristics that describe defects; (d)
principal component analysis as a pattern recognition tool in order to characterize the defects at
the material surface. Besides that, according to standard, cavitation erosion was monitored by
determining material mass loss during the cavitation. Large experimental datasets collected from
morphological descriptors by image analysis are multivariate and difficult to interpret, thus are
processed by principal component analysis as the most informative technique for extracting
possible differences. The performed approach proved that this method has a great potential for
better assessment of induced defects by proper distinguishing among them at different levels and
that can be considered a very efficient and cost-effective one.
PB  - Elsevier
T2  - Engineering Failure Analysis
T1  - Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis
VL  - 148
IS  - June 2023
SP  - 107224
DO  - 10.1016/j.engfailanal.2023.107224
ER  - 
@article{
author = "Martinović, Sanja and Alil, Ana and Milićević, Sonja and Živojinović, Dragana and Volkov Husović, Tatjana",
year = "2023",
abstract = "The pattern recognition approach, explored by this study, applies the principal component
analysis (PCA) as the most widely used statistical method with the aim of assessing the initiation
and propagation of the cracks and defects that appear on the surface of material exposed to the
cavitation. The experiment was performed in four stages: (a) synthesis of two ceramic materials
(cordierite and zircon); (b) subjecting the samples to the cavitation; (c) using image analysis
software for collecting the data about morphological characteristics that describe defects; (d)
principal component analysis as a pattern recognition tool in order to characterize the defects at
the material surface. Besides that, according to standard, cavitation erosion was monitored by
determining material mass loss during the cavitation. Large experimental datasets collected from
morphological descriptors by image analysis are multivariate and difficult to interpret, thus are
processed by principal component analysis as the most informative technique for extracting
possible differences. The performed approach proved that this method has a great potential for
better assessment of induced defects by proper distinguishing among them at different levels and
that can be considered a very efficient and cost-effective one.",
publisher = "Elsevier",
journal = "Engineering Failure Analysis",
title = "Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis",
volume = "148",
number = "June 2023",
pages = "107224",
doi = "10.1016/j.engfailanal.2023.107224"
}
Martinović, S., Alil, A., Milićević, S., Živojinović, D.,& Volkov Husović, T.. (2023). Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis. in Engineering Failure Analysis
Elsevier., 148(June 2023), 107224.
https://doi.org/10.1016/j.engfailanal.2023.107224
Martinović S, Alil A, Milićević S, Živojinović D, Volkov Husović T. Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis. in Engineering Failure Analysis. 2023;148(June 2023):107224.
doi:10.1016/j.engfailanal.2023.107224 .
Martinović, Sanja, Alil, Ana, Milićević, Sonja, Živojinović, Dragana, Volkov Husović, Tatjana, "Morphological assessment of cavitation caused damage of cordierite and zircon based materials using principal component analysis" in Engineering Failure Analysis, 148, no. June 2023 (2023):107224,
https://doi.org/10.1016/j.engfailanal.2023.107224 . .
4
4

Influence of type and quantity of filler on change of density of sulfur concrete

Đorđević, Nataša; Vlahović, Milica; Martinović, Sanja; Mihajlović, Slavica; Kašić, Vladan; Grubišić, Mirko

(Belgrade : University of Belgrade, Faculty of Mining and Geology, 2023)

TY  - JOUR
AU  - Đorđević, Nataša
AU  - Vlahović, Milica
AU  - Martinović, Sanja
AU  - Mihajlović, Slavica
AU  - Kašić, Vladan
AU  - Grubišić, Mirko
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7201
AB  - Concrete  is  a  material  that  has  been  used  for  centuries  and  is  often modified using polymers. In the last fifty years, synthetic polymers have been used for the modification of concrete, but also for the production of concrete. In recent decades, sulfur concrete has been an interesting product that can be used mainly in low-rise construction due to its characteristics. In this work, we used the starting mixture  for  the  preparation  of  sulfur  concrete  (sand,  elemental  sulfur  with  the addition of modified sulfur and fillers) heated to a temperature of 120 ºC to 170 ºC and  homogenized.  The  results  of  previous  research  on  the  production  of  sulfur concrete showed that the density of the obtained product changes depending on the type  as  well  as  the  amount  of  filler  added  to  the  basic  mixture  based  on  raw materials. Talc, microsilicon, plate alumina and fly ash were used as fillers. The amounts of fillers were 0%, 1%, 3%, 5%, 7% and 10%.
PB  - Belgrade : University of Belgrade, Faculty of Mining and Geology
T2  - Undeground mining engineering
T1  - Influence of type and quantity of filler on change of density of sulfur concrete
IS  - 42
SP  - 19
EP  - 25
DO  - 10.5937/podrad2342019Q
ER  - 
@article{
author = "Đorđević, Nataša and Vlahović, Milica and Martinović, Sanja and Mihajlović, Slavica and Kašić, Vladan and Grubišić, Mirko",
year = "2023",
abstract = "Concrete  is  a  material  that  has  been  used  for  centuries  and  is  often modified using polymers. In the last fifty years, synthetic polymers have been used for the modification of concrete, but also for the production of concrete. In recent decades, sulfur concrete has been an interesting product that can be used mainly in low-rise construction due to its characteristics. In this work, we used the starting mixture  for  the  preparation  of  sulfur  concrete  (sand,  elemental  sulfur  with  the addition of modified sulfur and fillers) heated to a temperature of 120 ºC to 170 ºC and  homogenized.  The  results  of  previous  research  on  the  production  of  sulfur concrete showed that the density of the obtained product changes depending on the type  as  well  as  the  amount  of  filler  added  to  the  basic  mixture  based  on  raw materials. Talc, microsilicon, plate alumina and fly ash were used as fillers. The amounts of fillers were 0%, 1%, 3%, 5%, 7% and 10%.",
publisher = "Belgrade : University of Belgrade, Faculty of Mining and Geology",
journal = "Undeground mining engineering",
title = "Influence of type and quantity of filler on change of density of sulfur concrete",
number = "42",
pages = "19-25",
doi = "10.5937/podrad2342019Q"
}
Đorđević, N., Vlahović, M., Martinović, S., Mihajlović, S., Kašić, V.,& Grubišić, M.. (2023). Influence of type and quantity of filler on change of density of sulfur concrete. in Undeground mining engineering
Belgrade : University of Belgrade, Faculty of Mining and Geology.(42), 19-25.
https://doi.org/10.5937/podrad2342019Q
Đorđević N, Vlahović M, Martinović S, Mihajlović S, Kašić V, Grubišić M. Influence of type and quantity of filler on change of density of sulfur concrete. in Undeground mining engineering. 2023;(42):19-25.
doi:10.5937/podrad2342019Q .
Đorđević, Nataša, Vlahović, Milica, Martinović, Sanja, Mihajlović, Slavica, Kašić, Vladan, Grubišić, Mirko, "Influence of type and quantity of filler on change of density of sulfur concrete" in Undeground mining engineering, no. 42 (2023):19-25,
https://doi.org/10.5937/podrad2342019Q . .

Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling

Mališić, Vanja; Pezo, Milada L.; Jelić, Aleksandra; Patarić, Aleksandra; Putić, Slaviša

(Association of Chemical Engineers of Serbia, 2023)

TY  - JOUR
AU  - Mališić, Vanja
AU  - Pezo, Milada L.
AU  - Jelić, Aleksandra
AU  - Patarić, Aleksandra
AU  - Putić, Slaviša
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7214
AB  - Poly(methyl methacrylate) (PMMA) has a broad spectrum of uses, especially in medical applications. The role of fine-grained alumina particles of PMMA composites was investigated in this study. The composites were based on PMMA modified with dimethyl itaconate (DMI) as a matrix and alumina particles (Al2O3) and alumina doped with iron (Al2O3-Fe) modified with
3-aminopropyl-trimethoxysilane (AM) and flax oil fatty acid methyl esters (biodiesel) as reinforcements. Three particle sizes were measured (~0.4, ~0.6 and ~1.2 μm). The highest thermal conductivity values were measured for the composite 5 wt.% Al2O3-Fe-AM. With the addition of 3 wt.% Al2O3-AM to the PMMA/DMI matrix, mechanical properties were improved (tensile strength, strain, and modulus of elasticity). An artificial neural network model based on the Broyden-Fletcher-Goldfarb-Shanno iterative algorithm was investigated for prediction of thermal conductivity and mechanical properties of the composites showing satisfactory results. This is relevant for applications for optimization of dental materials to produce dentures, which were exposed to variations in temperature during the application.
AB  - Poli (metil metakrilata) (PMMA) ima široku upotrebu, posebno u stomatologiji i medicini. Kompoziti su napravljeni od PMMA modifikovanog dimetil itakonatom (DMI) kao matrice. Kao pojačanje korišćene su čestice glinice (Al2O3) i glinice dopirane oksidom gvožđa (Al2O3-Fe) modifikovanim sa 3-aminopropiltrimetoksilanom (AM) i metil estrima masnih kiselina lanenog ulja (biodizel – BD). Prema merenjima toplotne provodljivosti, najveće vrednosti toplotne provodljivosti imao je kompozit sa česticama glinice 5 wt.% Al2O3-Fe-AM. Dodatkom modifikovanih čestica glinice u PMMA/DMI matricu, poboljšane su mehaničke osobine (zatezna čvrstoća, deformacija i modul elastičnosti). Razvijen je model veštačke neuronske mreže zasnovan na iterativnom algoritmu predloženom u literaturi (Broiden-Fletcher-Goldfarb-Shanno), za predviđanje toplotne provodljivosti i mehaničkih svojstava kompozita na bazi akrilata u kombinaciji sa česticama na bazi glinice, u zavisnosti od masenog udela čestica, i dodatka oksida gvožđa i modifikatora. Pokazano je da ovi matematički modeli mogu predvideti mehanička i termička svojstva kompozitnih materijala. Ovo je posebno relevantno za predviđanje toplotne provodljivosti materijala koji se koriste u stomatologiji za izradu proteza i koji su izloženi temperaturnim promenama tokom primene.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling
T1  - Predviđanje termičkih i mehaničkih svojstava kompozita na bazi akrilata  korišćenjem modela veštačke neuronske mreže
VL  - 77
IS  - 4
SP  - 293
EP  - 302
DO  - 10.2298/HEMIND230119029M
ER  - 
@article{
author = "Mališić, Vanja and Pezo, Milada L. and Jelić, Aleksandra and Patarić, Aleksandra and Putić, Slaviša",
year = "2023",
abstract = "Poly(methyl methacrylate) (PMMA) has a broad spectrum of uses, especially in medical applications. The role of fine-grained alumina particles of PMMA composites was investigated in this study. The composites were based on PMMA modified with dimethyl itaconate (DMI) as a matrix and alumina particles (Al2O3) and alumina doped with iron (Al2O3-Fe) modified with
3-aminopropyl-trimethoxysilane (AM) and flax oil fatty acid methyl esters (biodiesel) as reinforcements. Three particle sizes were measured (~0.4, ~0.6 and ~1.2 μm). The highest thermal conductivity values were measured for the composite 5 wt.% Al2O3-Fe-AM. With the addition of 3 wt.% Al2O3-AM to the PMMA/DMI matrix, mechanical properties were improved (tensile strength, strain, and modulus of elasticity). An artificial neural network model based on the Broyden-Fletcher-Goldfarb-Shanno iterative algorithm was investigated for prediction of thermal conductivity and mechanical properties of the composites showing satisfactory results. This is relevant for applications for optimization of dental materials to produce dentures, which were exposed to variations in temperature during the application., Poli (metil metakrilata) (PMMA) ima široku upotrebu, posebno u stomatologiji i medicini. Kompoziti su napravljeni od PMMA modifikovanog dimetil itakonatom (DMI) kao matrice. Kao pojačanje korišćene su čestice glinice (Al2O3) i glinice dopirane oksidom gvožđa (Al2O3-Fe) modifikovanim sa 3-aminopropiltrimetoksilanom (AM) i metil estrima masnih kiselina lanenog ulja (biodizel – BD). Prema merenjima toplotne provodljivosti, najveće vrednosti toplotne provodljivosti imao je kompozit sa česticama glinice 5 wt.% Al2O3-Fe-AM. Dodatkom modifikovanih čestica glinice u PMMA/DMI matricu, poboljšane su mehaničke osobine (zatezna čvrstoća, deformacija i modul elastičnosti). Razvijen je model veštačke neuronske mreže zasnovan na iterativnom algoritmu predloženom u literaturi (Broiden-Fletcher-Goldfarb-Shanno), za predviđanje toplotne provodljivosti i mehaničkih svojstava kompozita na bazi akrilata u kombinaciji sa česticama na bazi glinice, u zavisnosti od masenog udela čestica, i dodatka oksida gvožđa i modifikatora. Pokazano je da ovi matematički modeli mogu predvideti mehanička i termička svojstva kompozitnih materijala. Ovo je posebno relevantno za predviđanje toplotne provodljivosti materijala koji se koriste u stomatologiji za izradu proteza i koji su izloženi temperaturnim promenama tokom primene.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling, Predviđanje termičkih i mehaničkih svojstava kompozita na bazi akrilata  korišćenjem modela veštačke neuronske mreže",
volume = "77",
number = "4",
pages = "293-302",
doi = "10.2298/HEMIND230119029M"
}
Mališić, V., Pezo, M. L., Jelić, A., Patarić, A.,& Putić, S.. (2023). Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling. in Hemijska industrija
Association of Chemical Engineers of Serbia., 77(4), 293-302.
https://doi.org/10.2298/HEMIND230119029M
Mališić V, Pezo ML, Jelić A, Patarić A, Putić S. Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling. in Hemijska industrija. 2023;77(4):293-302.
doi:10.2298/HEMIND230119029M .
Mališić, Vanja, Pezo, Milada L., Jelić, Aleksandra, Patarić, Aleksandra, Putić, Slaviša, "Prediction of thermal and mechanical properties of acrylate-based composites using artificial neural network modeling" in Hemijska industrija, 77, no. 4 (2023):293-302,
https://doi.org/10.2298/HEMIND230119029M . .

X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation

Đorđević, Nataša; Vlahović, Milica; Mihajlović, Slavica

(Belgrade : University of Belgrade, Faculty of Mining and Geology, 2023)

TY  - JOUR
AU  - Đorđević, Nataša
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7197
AB  - The aim of this research was to obtain an initial characterization of  the  BaO  and  TiO2components,  as  well  as  to  conduct  preliminary research into the possibility of activating the initial components in order toobtain barium titanate. Chemical and X-ray structural analysis of the initial components  was  performed.  In  order  to  determine  the  possibility  of applying a mechanochemical activator and the activation time in which the first intermediate compounds were formed by the activation of the starting substances, the system was activated for 30 minutes. After this, an X-ray structural analysis was performed and certain changes in the crystal lattice of  the  starting components  were  made. X-ray  structural analysis  showed that  during  grinding,  amorphization  of  the  initial  components  occurred, which is the first stage in the process of obtaining titanate, as well as the presence  of  a  small  amount  of  barium  titanate,  which  is  indicating  the presence of an intermediate compound in the process of finally obtaining barium titanate.
PB  - Belgrade : University of Belgrade, Faculty of Mining and Geology
T2  - Undeground mining engineering
T1  - X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation
IS  - 42
SP  - 37
EP  - 46
DO  - 10.5937/podrad2342037Q
ER  - 
@article{
author = "Đorđević, Nataša and Vlahović, Milica and Mihajlović, Slavica",
year = "2023",
abstract = "The aim of this research was to obtain an initial characterization of  the  BaO  and  TiO2components,  as  well  as  to  conduct  preliminary research into the possibility of activating the initial components in order toobtain barium titanate. Chemical and X-ray structural analysis of the initial components  was  performed.  In  order  to  determine  the  possibility  of applying a mechanochemical activator and the activation time in which the first intermediate compounds were formed by the activation of the starting substances, the system was activated for 30 minutes. After this, an X-ray structural analysis was performed and certain changes in the crystal lattice of  the  starting components  were  made. X-ray  structural analysis  showed that  during  grinding,  amorphization  of  the  initial  components  occurred, which is the first stage in the process of obtaining titanate, as well as the presence  of  a  small  amount  of  barium  titanate,  which  is  indicating  the presence of an intermediate compound in the process of finally obtaining barium titanate.",
publisher = "Belgrade : University of Belgrade, Faculty of Mining and Geology",
journal = "Undeground mining engineering",
title = "X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation",
number = "42",
pages = "37-46",
doi = "10.5937/podrad2342037Q"
}
Đorđević, N., Vlahović, M.,& Mihajlović, S.. (2023). X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation. in Undeground mining engineering
Belgrade : University of Belgrade, Faculty of Mining and Geology.(42), 37-46.
https://doi.org/10.5937/podrad2342037Q
Đorđević N, Vlahović M, Mihajlović S. X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation. in Undeground mining engineering. 2023;(42):37-46.
doi:10.5937/podrad2342037Q .
Đorđević, Nataša, Vlahović, Milica, Mihajlović, Slavica, "X-ray structural analysis of the BaO and TiO2 starting compounds and initial mechanochemical activation" in Undeground mining engineering, no. 42 (2023):37-46,
https://doi.org/10.5937/podrad2342037Q . .

Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions

Milojkov, Dušan V.; Sokić, Miroslav D.; Živković-Radovanović, Vukosava; Manojlović, Vaso D.; Mutavdžić, Dragosav R.; Janjić, Goran; Radotić, Ksenija

(Springer, 2023)

TY  - JOUR
AU  - Milojkov, Dušan V.
AU  - Sokić, Miroslav D.
AU  - Živković-Radovanović, Vukosava
AU  - Manojlović, Vaso D.
AU  - Mutavdžić, Dragosav R.
AU  - Janjić, Goran
AU  - Radotić, Ksenija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5804
AB  - In this study, luminescence and antibacterial behavior of pure fluorapatite (FAp) and praseodymium-nitrate-carbonate co-doped fluorapatite (PrNCFAp) nanopowders were investigated. Uniform nanopowders were synthesized by precipitation reaction followed by centrifugation and systematically characterized by XRD, FTIR, SEM–EDS, TG and PL methods. XRD analysis revealed the formation of hexagonal FAp crystals, and FTIR spectra indicate the presence of nitrate (NO3−) and carbonate (CO32−) species. SEM analyzes confirm agglomerates composed of irregular nanometer-sized spheres. Emission of FAp nanopowder occurred in the violet-blue region of the visible part of the spectrum, with redshift to the blue-green color region when Pr3+, NO3− and CO32− co-doped in the lattice. Analysis of luminescence spectra by MCR-ALS method extract three fluorophores from the PrNCFAp sample and showed simultaneous existents of emission-reabsorption-emission between dopants in FAp lattice. Antibacterial activity against pathogen Staphylococcus aureus was investigated before and after treatment of nanopowders by UVA radiation of 365 nm. Nanopowders irradiated with UVA compared to non-irradiated reduced Staphylococcus aureus by 84.9% for PrNCFAp and 33.3% for FAp in the first 0.5 h of contact, and 76.1% and 42.9% after 24 h of contact. In addition, the obtained luminescent nanomaterials showed a low degree of hemolytic activity and could potentially be candidates for further research in dentistry.
PB  - Springer
T2  - Optical and Quantum Electronics
T1  - Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions
VL  - 55
IS  - 1
SP  - 84
DO  - 10.1007/s11082-022-04347-7
ER  - 
@article{
author = "Milojkov, Dušan V. and Sokić, Miroslav D. and Živković-Radovanović, Vukosava and Manojlović, Vaso D. and Mutavdžić, Dragosav R. and Janjić, Goran and Radotić, Ksenija",
year = "2023",
abstract = "In this study, luminescence and antibacterial behavior of pure fluorapatite (FAp) and praseodymium-nitrate-carbonate co-doped fluorapatite (PrNCFAp) nanopowders were investigated. Uniform nanopowders were synthesized by precipitation reaction followed by centrifugation and systematically characterized by XRD, FTIR, SEM–EDS, TG and PL methods. XRD analysis revealed the formation of hexagonal FAp crystals, and FTIR spectra indicate the presence of nitrate (NO3−) and carbonate (CO32−) species. SEM analyzes confirm agglomerates composed of irregular nanometer-sized spheres. Emission of FAp nanopowder occurred in the violet-blue region of the visible part of the spectrum, with redshift to the blue-green color region when Pr3+, NO3− and CO32− co-doped in the lattice. Analysis of luminescence spectra by MCR-ALS method extract three fluorophores from the PrNCFAp sample and showed simultaneous existents of emission-reabsorption-emission between dopants in FAp lattice. Antibacterial activity against pathogen Staphylococcus aureus was investigated before and after treatment of nanopowders by UVA radiation of 365 nm. Nanopowders irradiated with UVA compared to non-irradiated reduced Staphylococcus aureus by 84.9% for PrNCFAp and 33.3% for FAp in the first 0.5 h of contact, and 76.1% and 42.9% after 24 h of contact. In addition, the obtained luminescent nanomaterials showed a low degree of hemolytic activity and could potentially be candidates for further research in dentistry.",
publisher = "Springer",
journal = "Optical and Quantum Electronics",
title = "Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions",
volume = "55",
number = "1",
pages = "84",
doi = "10.1007/s11082-022-04347-7"
}
Milojkov, D. V., Sokić, M. D., Živković-Radovanović, V., Manojlović, V. D., Mutavdžić, D. R., Janjić, G.,& Radotić, K.. (2023). Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions. in Optical and Quantum Electronics
Springer., 55(1), 84.
https://doi.org/10.1007/s11082-022-04347-7
Milojkov DV, Sokić MD, Živković-Radovanović V, Manojlović VD, Mutavdžić DR, Janjić G, Radotić K. Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions. in Optical and Quantum Electronics. 2023;55(1):84.
doi:10.1007/s11082-022-04347-7 .
Milojkov, Dušan V., Sokić, Miroslav D., Živković-Radovanović, Vukosava, Manojlović, Vaso D., Mutavdžić, Dragosav R., Janjić, Goran, Radotić, Ksenija, "Cascade luminescence and antibacterial behavior of fluorapatite nanopowder co-doped with Pr3+, NO3− and CO32− ions" in Optical and Quantum Electronics, 55, no. 1 (2023):84,
https://doi.org/10.1007/s11082-022-04347-7 . .
1

Recovery of Copper from ore dump using bioleaching approach

Avdalović, Jelena; Lugonja, Nikoleta; Šoštarić, Tatjana; Lukić, Marija; Milić, Jelena; Milojković, Jelena; Conić, Vesna

(Society of Physical Chemists of Serbia, 2022-09)

TY  - CONF
AU  - Avdalović, Jelena
AU  - Lugonja, Nikoleta
AU  - Šoštarić, Tatjana
AU  - Lukić, Marija
AU  - Milić, Jelena
AU  - Milojković, Jelena
AU  - Conić, Vesna
PY  - 2022-09
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7475
AB  - Bioleaching is an environmentally-friendly approach for the extraction of useful metals from low-grade ores and secondary mineral materials.
The object of this paper was to examine the possibility of microbiological solubilisation of copper
from ore dump by Acidithiobacillus sp. B2.
Leaching experiments were performed by the shake flask testing technique at 28 oC, during two-week period. The percentage of the copper leached at the end of this experiment was 31%.
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia
T1  - Recovery of Copper from ore dump using bioleaching approach
VL  - 1
SP  - 453
EP  - 456
UR  - https://hdl.handle.net/21.15107/rcub_cer_7475
ER  - 
@conference{
author = "Avdalović, Jelena and Lugonja, Nikoleta and Šoštarić, Tatjana and Lukić, Marija and Milić, Jelena and Milojković, Jelena and Conić, Vesna",
year = "2022-09",
abstract = "Bioleaching is an environmentally-friendly approach for the extraction of useful metals from low-grade ores and secondary mineral materials.
The object of this paper was to examine the possibility of microbiological solubilisation of copper
from ore dump by Acidithiobacillus sp. B2.
Leaching experiments were performed by the shake flask testing technique at 28 oC, during two-week period. The percentage of the copper leached at the end of this experiment was 31%.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia",
title = "Recovery of Copper from ore dump using bioleaching approach",
volume = "1",
pages = "453-456",
url = "https://hdl.handle.net/21.15107/rcub_cer_7475"
}
Avdalović, J., Lugonja, N., Šoštarić, T., Lukić, M., Milić, J., Milojković, J.,& Conić, V.. (2022-09). Recovery of Copper from ore dump using bioleaching approach. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia
Society of Physical Chemists of Serbia., 1, 453-456.
https://hdl.handle.net/21.15107/rcub_cer_7475
Avdalović J, Lugonja N, Šoštarić T, Lukić M, Milić J, Milojković J, Conić V. Recovery of Copper from ore dump using bioleaching approach. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia. 2022;1:453-456.
https://hdl.handle.net/21.15107/rcub_cer_7475 .
Avdalović, Jelena, Lugonja, Nikoleta, Šoštarić, Tatjana, Lukić, Marija, Milić, Jelena, Milojković, Jelena, Conić, Vesna, "Recovery of Copper from ore dump using bioleaching approach" in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia, 1 (2022-09):453-456,
https://hdl.handle.net/21.15107/rcub_cer_7475 .

Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation

Darmanović, Darinka; Radanović, Dušanka; Jevtović, Mima; Turel, Iztok; Pevec, Andrej; Milčić, Miloš; Gruden, Maja; Zlatar, Matija; Đorđević, Nataša G.; Anđelković, Katarina; Čobeljić, Božidar

(Elsevier, 2022)

TY  - JOUR
AU  - Darmanović, Darinka
AU  - Radanović, Dušanka
AU  - Jevtović, Mima
AU  - Turel, Iztok
AU  - Pevec, Andrej
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Đorđević, Nataša G.
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5109
AB  - Two Co(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) and the condensation product of 2-acetylpyridine and Girard's P reagent (HL2Cl ligand, (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride) have been synthesized and characterized based on the results of single-crystal X-ray diffraction, NMR and IR spectroscopy and elemental analysis. Cobalt(III) complex with HL1 ligand, [Co(L1)2]BF4⋅H2O (1), is bis octahedral complex in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms. In cobalt(III) complex with HL2Cl, [Co(L2)(N3)3] (2), the ligand is coordinated in deprotonated, formally neutral, form to Co(III) ion in tridentate fashion through NNO set of donor atoms, and the other three coordination sites of a monokis octahedron are occupied by meridionally coordinated azide anions. DFT calculations were performed to elucidate coordination preferences of these ligands toward Co(III) ion.
PB  - Elsevier
T2  - Journal of Molecular Structure
T1  - Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation
VL  - 1266
SP  - 133509
DO  - 10.1016/j.molstruc.2022.133509
ER  - 
@article{
author = "Darmanović, Darinka and Radanović, Dušanka and Jevtović, Mima and Turel, Iztok and Pevec, Andrej and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Đorđević, Nataša G. and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "Two Co(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) and the condensation product of 2-acetylpyridine and Girard's P reagent (HL2Cl ligand, (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride) have been synthesized and characterized based on the results of single-crystal X-ray diffraction, NMR and IR spectroscopy and elemental analysis. Cobalt(III) complex with HL1 ligand, [Co(L1)2]BF4⋅H2O (1), is bis octahedral complex in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms. In cobalt(III) complex with HL2Cl, [Co(L2)(N3)3] (2), the ligand is coordinated in deprotonated, formally neutral, form to Co(III) ion in tridentate fashion through NNO set of donor atoms, and the other three coordination sites of a monokis octahedron are occupied by meridionally coordinated azide anions. DFT calculations were performed to elucidate coordination preferences of these ligands toward Co(III) ion.",
publisher = "Elsevier",
journal = "Journal of Molecular Structure",
title = "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation",
volume = "1266",
pages = "133509",
doi = "10.1016/j.molstruc.2022.133509"
}
Darmanović, D., Radanović, D., Jevtović, M., Turel, I., Pevec, A., Milčić, M., Gruden, M., Zlatar, M., Đorđević, N. G., Anđelković, K.,& Čobeljić, B.. (2022). Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation. in Journal of Molecular Structure
Elsevier., 1266, 133509.
https://doi.org/10.1016/j.molstruc.2022.133509
Darmanović D, Radanović D, Jevtović M, Turel I, Pevec A, Milčić M, Gruden M, Zlatar M, Đorđević NG, Anđelković K, Čobeljić B. Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation. in Journal of Molecular Structure. 2022;1266:133509.
doi:10.1016/j.molstruc.2022.133509 .
Darmanović, Darinka, Radanović, Dušanka, Jevtović, Mima, Turel, Iztok, Pevec, Andrej, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Đorđević, Nataša G., Anđelković, Katarina, Čobeljić, Božidar, "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation" in Journal of Molecular Structure, 1266 (2022):133509,
https://doi.org/10.1016/j.molstruc.2022.133509 . .
1
3

CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"

Darmanović, Darinka; Radanović, Dušanka; Jevtović, Mima; Turel, Iztok; Pevec, Andrej; Milčić, Miloš; Gruden, Maja; Zlatar, Matija; Đorđević, Nataša G.; Anđelković, Katarina; Čobeljić, Božidar

(The Cambridge Crystallographic Data Centre (CCDC), 2022)

TY  - DATA
AU  - Darmanović, Darinka
AU  - Radanović, Dušanka
AU  - Jevtović, Mima
AU  - Turel, Iztok
AU  - Pevec, Andrej
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Đorđević, Nataša G.
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5110
AB  - YEJPEM: Space Group: P b c a (61), Cell: a 17.8984(5)Å b 12.1563(3)Å c 18.9956(5)Å, α 90° β 90° γ 90°
PB  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"
DO  - 10.5517/ccdc.csd.cc2bsrd9
ER  - 
@misc{
author = "Darmanović, Darinka and Radanović, Dušanka and Jevtović, Mima and Turel, Iztok and Pevec, Andrej and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Đorđević, Nataša G. and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "YEJPEM: Space Group: P b c a (61), Cell: a 17.8984(5)Å b 12.1563(3)Å c 18.9956(5)Å, α 90° β 90° γ 90°",
publisher = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"",
doi = "10.5517/ccdc.csd.cc2bsrd9"
}
Darmanović, D., Radanović, D., Jevtović, M., Turel, I., Pevec, A., Milčić, M., Gruden, M., Zlatar, M., Đorđević, N. G., Anđelković, K.,& Čobeljić, B.. (2022). CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". 
The Cambridge Crystallographic Data Centre (CCDC)..
https://doi.org/10.5517/ccdc.csd.cc2bsrd9
Darmanović D, Radanović D, Jevtović M, Turel I, Pevec A, Milčić M, Gruden M, Zlatar M, Đorđević NG, Anđelković K, Čobeljić B. CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". 2022;.
doi:10.5517/ccdc.csd.cc2bsrd9 .
Darmanović, Darinka, Radanović, Dušanka, Jevtović, Mima, Turel, Iztok, Pevec, Andrej, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Đorđević, Nataša G., Anđelković, Katarina, Čobeljić, Božidar, "CCDC 2168741: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"" (2022),
https://doi.org/10.5517/ccdc.csd.cc2bsrd9 . .

CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"

Darmanović, Darinka; Radanović, Dušanka; Jevtović, Mima; Turel, Iztok; Pevec, Andrej; Milčić, Miloš; Gruden, Maja; Zlatar, Matija; Đorđević, Nataša G.; Anđelković, Katarina; Čobeljić, Božidar

(The Cambridge Crystallographic Data Centre (CCDC), 2022)

TY  - DATA
AU  - Darmanović, Darinka
AU  - Radanović, Dušanka
AU  - Jevtović, Mima
AU  - Turel, Iztok
AU  - Pevec, Andrej
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Đorđević, Nataša G.
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5111
AB  - YEJPIQ: Space Group: P 1 (2), Cell: a 7.7052(3)Å b 8.6197(6)Å c 14.6157(8)Å, α 78.908(5)° β 84.048(4)° γ 69.181(5)°
PB  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"
DO  - 10.5517/ccdc.csd.cc2bsrfb
ER  - 
@misc{
author = "Darmanović, Darinka and Radanović, Dušanka and Jevtović, Mima and Turel, Iztok and Pevec, Andrej and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Đorđević, Nataša G. and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "YEJPIQ: Space Group: P 1 (2), Cell: a 7.7052(3)Å b 8.6197(6)Å c 14.6157(8)Å, α 78.908(5)° β 84.048(4)° γ 69.181(5)°",
publisher = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"",
doi = "10.5517/ccdc.csd.cc2bsrfb"
}
Darmanović, D., Radanović, D., Jevtović, M., Turel, I., Pevec, A., Milčić, M., Gruden, M., Zlatar, M., Đorđević, N. G., Anđelković, K.,& Čobeljić, B.. (2022). CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". 
The Cambridge Crystallographic Data Centre (CCDC)..
https://doi.org/10.5517/ccdc.csd.cc2bsrfb
Darmanović D, Radanović D, Jevtović M, Turel I, Pevec A, Milčić M, Gruden M, Zlatar M, Đorđević NG, Anđelković K, Čobeljić B. CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". 2022;.
doi:10.5517/ccdc.csd.cc2bsrfb .
Darmanović, Darinka, Radanović, Dušanka, Jevtović, Mima, Turel, Iztok, Pevec, Andrej, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Đorđević, Nataša G., Anđelković, Katarina, Čobeljić, Božidar, "CCDC 2168742: Experimental Crystal Structure Determination. Crystallographic data for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"" (2022),
https://doi.org/10.5517/ccdc.csd.cc2bsrfb . .

Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"

Darmanović, Darinka; Radanović, Dušanka; Jevtović, Mima; Turel, Iztok; Pevec, Andrej; Milčić, Miloš; Gruden, Maja; Zlatar, Matija; Đorđević, Nataša G.; Anđelković, Katarina; Čobeljić, Božidar

(Elsevier, 2022)

TY  - DATA
AU  - Darmanović, Darinka
AU  - Radanović, Dušanka
AU  - Jevtović, Mima
AU  - Turel, Iztok
AU  - Pevec, Andrej
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Đorđević, Nataša G.
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5112
AB  - Selected bond lengths (Å) and angles (°) of complexes 1 and 2. Comparison of Co-Nthiazole, Co-Nimine and Co-Sthiolate bond lengths (Å) in octahedral Co(III)-N4S2 complexes with thiosemicarbazone based ligands. Comparison of Co-Npy, Co-Nimine, Co-Nazide and Co-Oenolate bond lengths (Å) in octahedral Co(III)N4O2–Co(III)N2O(N3)3 complexes with hydrazone and azide ligands.Hydrogen-bond parameters for complex 1.Intermolecular p×××p interaction parameters for complex 2. Hydrogen-bond parameters for complex 2.Crystal packing of 1 showing self-assembled complex cations within a layer parallel with the (001) lattice plane by means of intermolecular N–H×××N and N–H×××S hydrogen bonds and (b) Intermolecular p×××p interactions between thiazole rings.Crystal packing of 2 showing 2D assembly parallel with the (10-1) lattice plane generated by intermolecular p×××p interactions and C–H×××N hydrogen bonds.Cartesian coordinates of all DFT optimized structures
PB  - Elsevier
T2  - Journal of Molecular Structure
T1  - Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"
UR  - https://hdl.handle.net/21.15107/rcub_cer_5112
ER  - 
@misc{
author = "Darmanović, Darinka and Radanović, Dušanka and Jevtović, Mima and Turel, Iztok and Pevec, Andrej and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Đorđević, Nataša G. and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "Selected bond lengths (Å) and angles (°) of complexes 1 and 2. Comparison of Co-Nthiazole, Co-Nimine and Co-Sthiolate bond lengths (Å) in octahedral Co(III)-N4S2 complexes with thiosemicarbazone based ligands. Comparison of Co-Npy, Co-Nimine, Co-Nazide and Co-Oenolate bond lengths (Å) in octahedral Co(III)N4O2–Co(III)N2O(N3)3 complexes with hydrazone and azide ligands.Hydrogen-bond parameters for complex 1.Intermolecular p×××p interaction parameters for complex 2. Hydrogen-bond parameters for complex 2.Crystal packing of 1 showing self-assembled complex cations within a layer parallel with the (001) lattice plane by means of intermolecular N–H×××N and N–H×××S hydrogen bonds and (b) Intermolecular p×××p interactions between thiazole rings.Crystal packing of 2 showing 2D assembly parallel with the (10-1) lattice plane generated by intermolecular p×××p interactions and C–H×××N hydrogen bonds.Cartesian coordinates of all DFT optimized structures",
publisher = "Elsevier",
journal = "Journal of Molecular Structure",
title = "Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"",
url = "https://hdl.handle.net/21.15107/rcub_cer_5112"
}
Darmanović, D., Radanović, D., Jevtović, M., Turel, I., Pevec, A., Milčić, M., Gruden, M., Zlatar, M., Đorđević, N. G., Anđelković, K.,& Čobeljić, B.. (2022). Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". in Journal of Molecular Structure
Elsevier..
https://hdl.handle.net/21.15107/rcub_cer_5112
Darmanović D, Radanović D, Jevtović M, Turel I, Pevec A, Milčić M, Gruden M, Zlatar M, Đorđević NG, Anđelković K, Čobeljić B. Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation". in Journal of Molecular Structure. 2022;.
https://hdl.handle.net/21.15107/rcub_cer_5112 .
Darmanović, Darinka, Radanović, Dušanka, Jevtović, Mima, Turel, Iztok, Pevec, Andrej, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Đorđević, Nataša G., Anđelković, Katarina, Čobeljić, Božidar, "Supplementary material for: "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation"" in Journal of Molecular Structure (2022),
https://hdl.handle.net/21.15107/rcub_cer_5112 .

Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation

Darmanović, Darinka; Radanović, Dušanka; Jevtović, Mima; Turel, Iztok; Pevec, Andrej; Milčić, Miloš; Gruden, Maja; Zlatar, Matija; Đorđević, Nataša G.; Anđelković, Katarina; Čobeljić, Božidar

(Elsevier, 2022)

TY  - JOUR
AU  - Darmanović, Darinka
AU  - Radanović, Dušanka
AU  - Jevtović, Mima
AU  - Turel, Iztok
AU  - Pevec, Andrej
AU  - Milčić, Miloš
AU  - Gruden, Maja
AU  - Zlatar, Matija
AU  - Đorđević, Nataša G.
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5113
AB  - Two Co(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) and the condensation product of 2-acetylpyridine and Girard's P reagent (HL2Cl ligand, (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride) have been synthesized and characterized based on the results of single-crystal X-ray diffraction, NMR and IR spectroscopy and elemental analysis. Cobalt(III) complex with HL1 ligand, [Co(L1)2]BF4⋅H2O (1), is bis octahedral complex in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms. In cobalt(III) complex with HL2Cl, [Co(L2)(N3)3] (2), the ligand is coordinated in deprotonated, formally neutral, form to Co(III) ion in tridentate fashion through NNO set of donor atoms, and the other three coordination sites of a monokis octahedron are occupied by meridionally coordinated azide anions. DFT calculations were performed to elucidate coordination preferences of these ligands toward Co(III) ion.
PB  - Elsevier
T2  - Journal of Molecular Structure
T1  - Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation
VL  - 1266
SP  - 133509
DO  - 10.1016/j.molstruc.2022.133509
ER  - 
@article{
author = "Darmanović, Darinka and Radanović, Dušanka and Jevtović, Mima and Turel, Iztok and Pevec, Andrej and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Đorđević, Nataša G. and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "Two Co(III) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide) and the condensation product of 2-acetylpyridine and Girard's P reagent (HL2Cl ligand, (E)-1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride) have been synthesized and characterized based on the results of single-crystal X-ray diffraction, NMR and IR spectroscopy and elemental analysis. Cobalt(III) complex with HL1 ligand, [Co(L1)2]BF4⋅H2O (1), is bis octahedral complex in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms. In cobalt(III) complex with HL2Cl, [Co(L2)(N3)3] (2), the ligand is coordinated in deprotonated, formally neutral, form to Co(III) ion in tridentate fashion through NNO set of donor atoms, and the other three coordination sites of a monokis octahedron are occupied by meridionally coordinated azide anions. DFT calculations were performed to elucidate coordination preferences of these ligands toward Co(III) ion.",
publisher = "Elsevier",
journal = "Journal of Molecular Structure",
title = "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation",
volume = "1266",
pages = "133509",
doi = "10.1016/j.molstruc.2022.133509"
}
Darmanović, D., Radanović, D., Jevtović, M., Turel, I., Pevec, A., Milčić, M., Gruden, M., Zlatar, M., Đorđević, N. G., Anđelković, K.,& Čobeljić, B.. (2022). Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation. in Journal of Molecular Structure
Elsevier., 1266, 133509.
https://doi.org/10.1016/j.molstruc.2022.133509
Darmanović D, Radanović D, Jevtović M, Turel I, Pevec A, Milčić M, Gruden M, Zlatar M, Đorđević NG, Anđelković K, Čobeljić B. Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation. in Journal of Molecular Structure. 2022;1266:133509.
doi:10.1016/j.molstruc.2022.133509 .
Darmanović, Darinka, Radanović, Dušanka, Jevtović, Mima, Turel, Iztok, Pevec, Andrej, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Đorđević, Nataša G., Anđelković, Katarina, Čobeljić, Božidar, "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes: Synthesis, characterization and DFT calculation" in Journal of Molecular Structure, 1266 (2022):133509,
https://doi.org/10.1016/j.molstruc.2022.133509 . .
1
3

Contemporary methods of testing human milk quality

Lugonja, Nikoleta; Avdalović, Jelena; Ilić, Mila; Lopičić, Zorica; Šoštarić, Tatjana; Stanković, Dalibor; Spasić, Snežana

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Lugonja, Nikoleta
AU  - Avdalović, Jelena
AU  - Ilić, Mila
AU  - Lopičić, Zorica
AU  - Šoštarić, Tatjana
AU  - Stanković, Dalibor
AU  - Spasić, Snežana
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7467
AB  - Infant nutrition is essential for their growth and development. This research aims to determine the total antioxidant capacity of the infant food for preterm infants and indicate adequate methods for testing the quality and biological value of milk and infant food. The total antioxidant capacity (TAC) was determined in human milk and an infant formula for premature infants. The determination of the total antioxidant capacity was made using cyclic and differential pulse voltammetry, potentiometry and electron paramagnetic resonance spectroscopy. The results of three comparative electrochemical methods indicate that human milk has a higher antioxidant potential compared to infant formula, which contributes to better physiological development of the child. Fenton-based electron paramagnetic resonance spectroscopy method provides additional insight into TAC analysis, whereby a carbon-centered radical and an ascorbyl radical are formed in infant food. All methods can be used to determine TAC, since the results obtained individually with each method follow the same trend.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia
T1  - Contemporary methods of testing human milk quality
VL  - I
SP  - 537
EP  - 540
UR  - https://hdl.handle.net/21.15107/rcub_cer_7467
ER  - 
@conference{
author = "Lugonja, Nikoleta and Avdalović, Jelena and Ilić, Mila and Lopičić, Zorica and Šoštarić, Tatjana and Stanković, Dalibor and Spasić, Snežana",
year = "2022",
abstract = "Infant nutrition is essential for their growth and development. This research aims to determine the total antioxidant capacity of the infant food for preterm infants and indicate adequate methods for testing the quality and biological value of milk and infant food. The total antioxidant capacity (TAC) was determined in human milk and an infant formula for premature infants. The determination of the total antioxidant capacity was made using cyclic and differential pulse voltammetry, potentiometry and electron paramagnetic resonance spectroscopy. The results of three comparative electrochemical methods indicate that human milk has a higher antioxidant potential compared to infant formula, which contributes to better physiological development of the child. Fenton-based electron paramagnetic resonance spectroscopy method provides additional insight into TAC analysis, whereby a carbon-centered radical and an ascorbyl radical are formed in infant food. All methods can be used to determine TAC, since the results obtained individually with each method follow the same trend.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia",
title = "Contemporary methods of testing human milk quality",
volume = "I",
pages = "537-540",
url = "https://hdl.handle.net/21.15107/rcub_cer_7467"
}
Lugonja, N., Avdalović, J., Ilić, M., Lopičić, Z., Šoštarić, T., Stanković, D.,& Spasić, S.. (2022). Contemporary methods of testing human milk quality. in 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia
Belgrade : Society of Physical Chemists of Serbia., I, 537-540.
https://hdl.handle.net/21.15107/rcub_cer_7467
Lugonja N, Avdalović J, Ilić M, Lopičić Z, Šoštarić T, Stanković D, Spasić S. Contemporary methods of testing human milk quality. in 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia. 2022;I:537-540.
https://hdl.handle.net/21.15107/rcub_cer_7467 .
Lugonja, Nikoleta, Avdalović, Jelena, Ilić, Mila, Lopičić, Zorica, Šoštarić, Tatjana, Stanković, Dalibor, Spasić, Snežana, "Contemporary methods of testing human milk quality" in 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September 26-30, 2018, Belgrade, Serbia, I (2022):537-540,
https://hdl.handle.net/21.15107/rcub_cer_7467 .

Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent

Šoštarić, Tatjana; Milojković, Jelena; Avdalović, Jelena; Lugonja, Nikoleta; Adamović, Vladimir; Antanasković, Anja; Lopičić, Zorica

(Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Šoštarić, Tatjana
AU  - Milojković, Jelena
AU  - Avdalović, Jelena
AU  - Lugonja, Nikoleta
AU  - Adamović, Vladimir
AU  - Antanasković, Anja
AU  - Lopičić, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7479
AB  - The mutual interaction of metal ions (lead, zinc and copper) on removal efficiency in binary and
ternary systems, by biosorbent based on alkali treated apricot shells (Prunus armeniaca L.) was
examined. The evaluation was done in batch system at two metals concentrations: 0.2 and 0.5mmol/
dm3. Tested biosorbent exhibited preferential uptake of lead in a multimetal systems. It is evident that mutual inhibition exists in all multimetal systems, but systems containing lead ex-hibited extreme inhibition toward copper and zinc ions. Process of sorption depends not only on specific chemistry of each metal, their affinity toward binding sites and the type of metal binding onto biosorbent, but also on sorbent chemical and morphological characteristics. In multimetal systems, tested sorbent showed preferential sorption orders: Pb (II)>Cu (II)>Zn (II).
PB  - Society of Physical Chemists of Serbia
C3  - Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September, 26-30, 2022, Belgrade, Serbia
T1  - Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent
SP  - 457
EP  - 460
UR  - https://hdl.handle.net/21.15107/rcub_cer_7479
ER  - 
@conference{
author = "Šoštarić, Tatjana and Milojković, Jelena and Avdalović, Jelena and Lugonja, Nikoleta and Adamović, Vladimir and Antanasković, Anja and Lopičić, Zorica",
year = "2022",
abstract = "The mutual interaction of metal ions (lead, zinc and copper) on removal efficiency in binary and
ternary systems, by biosorbent based on alkali treated apricot shells (Prunus armeniaca L.) was
examined. The evaluation was done in batch system at two metals concentrations: 0.2 and 0.5mmol/
dm3. Tested biosorbent exhibited preferential uptake of lead in a multimetal systems. It is evident that mutual inhibition exists in all multimetal systems, but systems containing lead ex-hibited extreme inhibition toward copper and zinc ions. Process of sorption depends not only on specific chemistry of each metal, their affinity toward binding sites and the type of metal binding onto biosorbent, but also on sorbent chemical and morphological characteristics. In multimetal systems, tested sorbent showed preferential sorption orders: Pb (II)>Cu (II)>Zn (II).",
publisher = "Society of Physical Chemists of Serbia",
journal = "Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September, 26-30, 2022, Belgrade, Serbia",
title = "Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent",
pages = "457-460",
url = "https://hdl.handle.net/21.15107/rcub_cer_7479"
}
Šoštarić, T., Milojković, J., Avdalović, J., Lugonja, N., Adamović, V., Antanasković, A.,& Lopičić, Z.. (2022). Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September, 26-30, 2022, Belgrade, Serbia
Society of Physical Chemists of Serbia., 457-460.
https://hdl.handle.net/21.15107/rcub_cer_7479
Šoštarić T, Milojković J, Avdalović J, Lugonja N, Adamović V, Antanasković A, Lopičić Z. Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent. in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September, 26-30, 2022, Belgrade, Serbia. 2022;:457-460.
https://hdl.handle.net/21.15107/rcub_cer_7479 .
Šoštarić, Tatjana, Milojković, Jelena, Avdalović, Jelena, Lugonja, Nikoleta, Adamović, Vladimir, Antanasković, Anja, Lopičić, Zorica, "Removal efficiency of pb(II), Zn(II) and Cu(II) in mono- and multimetal systems by alkali treated apricot shells biosorbent" in Proceedings - 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2022, September, 26-30, 2022, Belgrade, Serbia (2022):457-460,
https://hdl.handle.net/21.15107/rcub_cer_7479 .

Spatial distribution and source identification of heavy metals in European mountain beech forests soils

Štrbac, Snežana; Ranđelović, Dragana; Gajica, Gordana; Hukić, Emira; Stojadinović, Sanja; Veselinović, Gorica; Orlić, Jovana; Tognetti, Roberto; Kašanin-Grubin, Milica

(Elsevier BV, 2022)

TY  - JOUR
AU  - Štrbac, Snežana
AU  - Ranđelović, Dragana
AU  - Gajica, Gordana
AU  - Hukić, Emira
AU  - Stojadinović, Sanja
AU  - Veselinović, Gorica
AU  - Orlić, Jovana
AU  - Tognetti, Roberto
AU  - Kašanin-Grubin, Milica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5577
AB  - The main objectives of this research were to (i) investigate the concentration; (ii) characterize the distribution; (iii) determine the sources apportionment; (iv) estimate environmental and health risks of heavy metals in soil from mountain beech forest. A total of 76 soil samples from 20 pure beech forest stands from Bosnia and Herzegovina (BA), Bulgaria (BG), Check Republic (CZ), Germany (DE), Italy (IT), Poland (PL), Romania (RO), Serbia (RS), Slovakia (SK), Slovenia (SL), and Spain (ES) were collected. The content of major elements was measured by X-ray fluorescence spectroscopy (XRF). The content of heavy metals was measured by inductively coupled plasma–optical emission spectrometry (ICP/OES). Heavy metals had a specific concentration range, which followed in soil samples from depth 0–40 cm the common order (low to high): Hg < Cd < As < Co < Pb < Ni < Cu < Cr < Zn, and from depth 40–80 cm: Hg < Cd < As < Pb < Co < Ni < Cu < Cr < Zn. The grouping of the examined parameters according to rock types, soil types, and localities indicated the separation of carbonate rocks from other substrates, luvisol, and rendzina from other soil types, and samples from BA, SL, and IT from other localities. According to sources apportionment As, Pb and Zn are of anthropogenic origin, Cd, Co, Cr, and Ni are of geogenic origin, while the middle position of Cu and Hg indicates a combined contribution of both sources. Elements Cd and Hg indicated severe to extremely severe enrichment with a mean value of 24.3 and 70.6, respectively. Based on the determined values Ni, Cr, As and Cd do not pose a health risk.
PB  - Elsevier BV
T2  - Chemosphere
T1  - Spatial distribution and source identification of heavy metals in European mountain beech forests soils
VL  - 309
SP  - 136662
DO  - 10.1016/j.chemosphere.2022.136662
ER  - 
@article{
author = "Štrbac, Snežana and Ranđelović, Dragana and Gajica, Gordana and Hukić, Emira and Stojadinović, Sanja and Veselinović, Gorica and Orlić, Jovana and Tognetti, Roberto and Kašanin-Grubin, Milica",
year = "2022",
abstract = "The main objectives of this research were to (i) investigate the concentration; (ii) characterize the distribution; (iii) determine the sources apportionment; (iv) estimate environmental and health risks of heavy metals in soil from mountain beech forest. A total of 76 soil samples from 20 pure beech forest stands from Bosnia and Herzegovina (BA), Bulgaria (BG), Check Republic (CZ), Germany (DE), Italy (IT), Poland (PL), Romania (RO), Serbia (RS), Slovakia (SK), Slovenia (SL), and Spain (ES) were collected. The content of major elements was measured by X-ray fluorescence spectroscopy (XRF). The content of heavy metals was measured by inductively coupled plasma–optical emission spectrometry (ICP/OES). Heavy metals had a specific concentration range, which followed in soil samples from depth 0–40 cm the common order (low to high): Hg < Cd < As < Co < Pb < Ni < Cu < Cr < Zn, and from depth 40–80 cm: Hg < Cd < As < Pb < Co < Ni < Cu < Cr < Zn. The grouping of the examined parameters according to rock types, soil types, and localities indicated the separation of carbonate rocks from other substrates, luvisol, and rendzina from other soil types, and samples from BA, SL, and IT from other localities. According to sources apportionment As, Pb and Zn are of anthropogenic origin, Cd, Co, Cr, and Ni are of geogenic origin, while the middle position of Cu and Hg indicates a combined contribution of both sources. Elements Cd and Hg indicated severe to extremely severe enrichment with a mean value of 24.3 and 70.6, respectively. Based on the determined values Ni, Cr, As and Cd do not pose a health risk.",
publisher = "Elsevier BV",
journal = "Chemosphere",
title = "Spatial distribution and source identification of heavy metals in European mountain beech forests soils",
volume = "309",
pages = "136662",
doi = "10.1016/j.chemosphere.2022.136662"
}
Štrbac, S., Ranđelović, D., Gajica, G., Hukić, E., Stojadinović, S., Veselinović, G., Orlić, J., Tognetti, R.,& Kašanin-Grubin, M.. (2022). Spatial distribution and source identification of heavy metals in European mountain beech forests soils. in Chemosphere
Elsevier BV., 309, 136662.
https://doi.org/10.1016/j.chemosphere.2022.136662
Štrbac S, Ranđelović D, Gajica G, Hukić E, Stojadinović S, Veselinović G, Orlić J, Tognetti R, Kašanin-Grubin M. Spatial distribution and source identification of heavy metals in European mountain beech forests soils. in Chemosphere. 2022;309:136662.
doi:10.1016/j.chemosphere.2022.136662 .
Štrbac, Snežana, Ranđelović, Dragana, Gajica, Gordana, Hukić, Emira, Stojadinović, Sanja, Veselinović, Gorica, Orlić, Jovana, Tognetti, Roberto, Kašanin-Grubin, Milica, "Spatial distribution and source identification of heavy metals in European mountain beech forests soils" in Chemosphere, 309 (2022):136662,
https://doi.org/10.1016/j.chemosphere.2022.136662 . .
6
7

Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies

Obradović, Milena; Daković, Aleksandra; Smiljanić, Danijela; Ožegović, Milica; Marković, Marija A.; Rottinghaus, George E.; Krstić, Jugoslav

(Elsevier, 2022)

TY  - JOUR
AU  - Obradović, Milena
AU  - Daković, Aleksandra
AU  - Smiljanić, Danijela
AU  - Ožegović, Milica
AU  - Marković, Marija A.
AU  - Rottinghaus, George E.
AU  - Krstić, Jugoslav
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5349
AB  - Cationic surfactant - octadecyldimethylbenzyl ammonium chloride (ODMBA) was used for modification of the three natural raw materials - bentonite, kaolin and zeolite. Adsorption of ODMBA by minerals occurred via ion exchange of inorganic cations on minerals with surfactant. Organomodified minerals - organobentonite (OB), organokaolin (OK) and organozeolite (OZ) were studied as adsorbents for removal of two non-steroidal anti-inflammatory drugs - ibuprofen (IBU) and diclofenac sodium (DS) at pH 7. For all systems, the pseudo-second order model showed the best correlation to kinetic experimental data. In all cases, the positive values of Delta H degrees indicated that the adsorption of both IBU and DS by organomodified minerals was endothermic in nature. Equilibrium data were better described by the Freundlich isotherm model, pointing to adsorbent heterogeneous active sites for adsorption. Under applied experimental conditions, the highest adsorption of both drugs was achieved by OB, while much lower capacities were observed for OK and OZ. Nonlinear isotherms and physicochemical characterization of organomodified minerals after drugs adsorption suggested complex mechanism consisting of hydrophobic interactions between hydrophobic part of the drugs and surfactants alkyl chains, electrostatic interactions of anionic forms of IBU and DS with the cationic "head" of ODMBA, as well as anion exchange of counterion ions from ODMBA micelle and anionic forms of both drugs. Adsorption of both IBU and DS was strongly dependent on the amount of ODMBA ions in the minerals.
PB  - Elsevier
T2  - Microporous and Mesoporous Materials
T1  - Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies
VL  - 335
SP  - 111795
DO  - 10.1016/j.micromeso.2022.111795
ER  - 
@article{
author = "Obradović, Milena and Daković, Aleksandra and Smiljanić, Danijela and Ožegović, Milica and Marković, Marija A. and Rottinghaus, George E. and Krstić, Jugoslav",
year = "2022",
abstract = "Cationic surfactant - octadecyldimethylbenzyl ammonium chloride (ODMBA) was used for modification of the three natural raw materials - bentonite, kaolin and zeolite. Adsorption of ODMBA by minerals occurred via ion exchange of inorganic cations on minerals with surfactant. Organomodified minerals - organobentonite (OB), organokaolin (OK) and organozeolite (OZ) were studied as adsorbents for removal of two non-steroidal anti-inflammatory drugs - ibuprofen (IBU) and diclofenac sodium (DS) at pH 7. For all systems, the pseudo-second order model showed the best correlation to kinetic experimental data. In all cases, the positive values of Delta H degrees indicated that the adsorption of both IBU and DS by organomodified minerals was endothermic in nature. Equilibrium data were better described by the Freundlich isotherm model, pointing to adsorbent heterogeneous active sites for adsorption. Under applied experimental conditions, the highest adsorption of both drugs was achieved by OB, while much lower capacities were observed for OK and OZ. Nonlinear isotherms and physicochemical characterization of organomodified minerals after drugs adsorption suggested complex mechanism consisting of hydrophobic interactions between hydrophobic part of the drugs and surfactants alkyl chains, electrostatic interactions of anionic forms of IBU and DS with the cationic "head" of ODMBA, as well as anion exchange of counterion ions from ODMBA micelle and anionic forms of both drugs. Adsorption of both IBU and DS was strongly dependent on the amount of ODMBA ions in the minerals.",
publisher = "Elsevier",
journal = "Microporous and Mesoporous Materials",
title = "Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies",
volume = "335",
pages = "111795",
doi = "10.1016/j.micromeso.2022.111795"
}
Obradović, M., Daković, A., Smiljanić, D., Ožegović, M., Marković, M. A., Rottinghaus, G. E.,& Krstić, J.. (2022). Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies. in Microporous and Mesoporous Materials
Elsevier., 335, 111795.
https://doi.org/10.1016/j.micromeso.2022.111795
Obradović M, Daković A, Smiljanić D, Ožegović M, Marković MA, Rottinghaus GE, Krstić J. Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies. in Microporous and Mesoporous Materials. 2022;335:111795.
doi:10.1016/j.micromeso.2022.111795 .
Obradović, Milena, Daković, Aleksandra, Smiljanić, Danijela, Ožegović, Milica, Marković, Marija A., Rottinghaus, George E., Krstić, Jugoslav, "Ibuprofen and diclofenac sodium adsorption onto functionalized minerals: Equilibrium, kinetic and thermodynamic studies" in Microporous and Mesoporous Materials, 335 (2022):111795,
https://doi.org/10.1016/j.micromeso.2022.111795 . .
18
13