TY  - JOUR
AU  - Jegdić, Bore
AU  - Bajat, Jelena
AU  - Popić, Jovan P.
AU  - Mišković-Stanković, Vesna
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/902
AB  - The influence of steel surface pretreatment with different types of iron-phosphate coatings on the corrosion stability and adhesion characteristics of polyester coatings on steel was investigated. The phosphate coating was chemically deposited either from the simple novel plating bath, or with the addition of NaNO(2), as an accelerator in the plating bath. The morphology of phosphate coatings was investigated using atomic force microscopy (AFM). The corrosion stability of polyester coatings on steel pretreated by iron-phosphate coatings was investigated by electrochemical impedance spectroscopy (EIS) in 3% NaCl solution, while "dry" and "wet" adhesion were measured by a direct pull-off standardized procedure. It was shown that greater values of pore resistance. R(p), and smaller values of coating capacitance of polyester coating, C(c), on steel pretreated with iron-phosphate coating were obtained, as compared to polyester coating on steel phosphated with accelerator, and on the bare steel. The surface roughness of phosphate coating deposited on steel from the bath without accelerator is favorable in forming stronger bonds with polyester coating. Namely, the dry and wet adhesion measurements are in accordance with EIS measurements in 3% NaCl solution, i.e. lower adhesion values were obtained for polyester coating on steel phosphated with accelerator and on the bare steel, while the iron-phosphate pretreatment from the novel bath enhanced the adhesion of polyester coating on steel.
PB  - Elsevier Science Sa, Lausanne
T2  - Progress in Organic Coatings
T1  - Corrosion stability of polyester coatings on steel pretreated with different iron-phosphate coatings
VL  - 70
IS  - 2-3
SP  - 127
EP  - 133
DO  - 10.1016/j.porgcoat.2010.11.004
ER  - 

@article{
author = "Jegdić, Bore and Bajat, Jelena and Popić, Jovan P. and Mišković-Stanković, Vesna",
year = "2011",
abstract = "The influence of steel surface pretreatment with different types of iron-phosphate coatings on the corrosion stability and adhesion characteristics of polyester coatings on steel was investigated. The phosphate coating was chemically deposited either from the simple novel plating bath, or with the addition of NaNO(2), as an accelerator in the plating bath. The morphology of phosphate coatings was investigated using atomic force microscopy (AFM). The corrosion stability of polyester coatings on steel pretreated by iron-phosphate coatings was investigated by electrochemical impedance spectroscopy (EIS) in 3% NaCl solution, while "dry" and "wet" adhesion were measured by a direct pull-off standardized procedure. It was shown that greater values of pore resistance. R(p), and smaller values of coating capacitance of polyester coating, C(c), on steel pretreated with iron-phosphate coating were obtained, as compared to polyester coating on steel phosphated with accelerator, and on the bare steel. The surface roughness of phosphate coating deposited on steel from the bath without accelerator is favorable in forming stronger bonds with polyester coating. Namely, the dry and wet adhesion measurements are in accordance with EIS measurements in 3% NaCl solution, i.e. lower adhesion values were obtained for polyester coating on steel phosphated with accelerator and on the bare steel, while the iron-phosphate pretreatment from the novel bath enhanced the adhesion of polyester coating on steel.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Progress in Organic Coatings",
title = "Corrosion stability of polyester coatings on steel pretreated with different iron-phosphate coatings",
volume = "70",
number = "2-3",
pages = "127-133",
doi = "10.1016/j.porgcoat.2010.11.004"
}

Jegdić, B., Bajat, J., Popić, J. P.,& Mišković-Stanković, V.. (2011). Corrosion stability of polyester coatings on steel pretreated with different iron-phosphate coatings. in Progress in Organic Coatings
Elsevier Science Sa, Lausanne., 70(2-3), 127-133.
https://doi.org/10.1016/j.porgcoat.2010.11.004

Jegdić B, Bajat J, Popić JP, Mišković-Stanković V. Corrosion stability of polyester coatings on steel pretreated with different iron-phosphate coatings. in Progress in Organic Coatings. 2011;70(2-3):127-133.
doi:10.1016/j.porgcoat.2010.11.004 .

Jegdić, Bore, Bajat, Jelena, Popić, Jovan P., Mišković-Stanković, Vesna, "Corrosion stability of polyester coatings on steel pretreated with different iron-phosphate coatings" in Progress in Organic Coatings, 70, no. 2-3 (2011):127-133,
https://doi.org/10.1016/j.porgcoat.2010.11.004 . .

TY  - JOUR
AU  - Bajat, Jelena
AU  - Popić, Jovan P.
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3171
AB  - One of the most important factors in corrosion prevention by protective coatings is the coating adhesion loss under environmental influence. Thus, adhesion strength is often used when characterizing protective properties of organic coatings on a metal substrate. In order to improve the adhesion of organic coating the metal substrate is often pretreated in some way. In this work, the adhesion of polyester coatings on differently pretreated aluminium surface (by anodizing, with and without sealing, by phosphating and by silane film deposition) was examined. The dry and wet adhesion of polyester coatings were measured by a direct pull-off standardized procedure, as well as indirectly by NMP test. It was shown that under dry test conditions all polyester coatings showed very good adhesion, but that aluminium surface pretreated by silane film showed superior adhesion. The overall increase of wet adhesion for polyester coating on aluminium pretreated by silane film was maintained throughout the whole investigated time period. The different trends in the change of adhesion of polyester coatings were observed for different aluminium pretreatments during exposure to the corrosive agent (3% NaCl solution). The highest adhesion reduction was obtained for polyester coating on aluminium pretreated with phosphate coating. The corrosion stability of polyester coated aluminium was investigated by electrochemical impedance spectroscopy in 3% NaCl solution. The results confirmed good protective properties of polyester coating on aluminium pretreated with silane film, i.e. greater values of pore resistance and smaller values of coating capacitance were obtained in respect to other protective systems, whereas charge-transfer resistance and double-layer capacitance were not measurable during 2 months of exposure to a corrosive agent.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - The influence of aluminium surface pretreatment on the corrosion stability and adhesion of powder polyester coating
VL  - 69
IS  - 4
SP  - 316
EP  - 321
DO  - 10.1016/j.porgcoat.2010.07.004
ER  - 

@article{
author = "Bajat, Jelena and Popić, Jovan P. and Mišković-Stanković, Vesna",
year = "2010",
abstract = "One of the most important factors in corrosion prevention by protective coatings is the coating adhesion loss under environmental influence. Thus, adhesion strength is often used when characterizing protective properties of organic coatings on a metal substrate. In order to improve the adhesion of organic coating the metal substrate is often pretreated in some way. In this work, the adhesion of polyester coatings on differently pretreated aluminium surface (by anodizing, with and without sealing, by phosphating and by silane film deposition) was examined. The dry and wet adhesion of polyester coatings were measured by a direct pull-off standardized procedure, as well as indirectly by NMP test. It was shown that under dry test conditions all polyester coatings showed very good adhesion, but that aluminium surface pretreated by silane film showed superior adhesion. The overall increase of wet adhesion for polyester coating on aluminium pretreated by silane film was maintained throughout the whole investigated time period. The different trends in the change of adhesion of polyester coatings were observed for different aluminium pretreatments during exposure to the corrosive agent (3% NaCl solution). The highest adhesion reduction was obtained for polyester coating on aluminium pretreated with phosphate coating. The corrosion stability of polyester coated aluminium was investigated by electrochemical impedance spectroscopy in 3% NaCl solution. The results confirmed good protective properties of polyester coating on aluminium pretreated with silane film, i.e. greater values of pore resistance and smaller values of coating capacitance were obtained in respect to other protective systems, whereas charge-transfer resistance and double-layer capacitance were not measurable during 2 months of exposure to a corrosive agent.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "The influence of aluminium surface pretreatment on the corrosion stability and adhesion of powder polyester coating",
volume = "69",
number = "4",
pages = "316-321",
doi = "10.1016/j.porgcoat.2010.07.004"
}

Bajat, J., Popić, J. P.,& Mišković-Stanković, V.. (2010). The influence of aluminium surface pretreatment on the corrosion stability and adhesion of powder polyester coating. in Progress in Organic Coatings
Elsevier., 69(4), 316-321.
https://doi.org/10.1016/j.porgcoat.2010.07.004

Bajat J, Popić JP, Mišković-Stanković V. The influence of aluminium surface pretreatment on the corrosion stability and adhesion of powder polyester coating. in Progress in Organic Coatings. 2010;69(4):316-321.
doi:10.1016/j.porgcoat.2010.07.004 .

Bajat, Jelena, Popić, Jovan P., Mišković-Stanković, Vesna, "The influence of aluminium surface pretreatment on the corrosion stability and adhesion of powder polyester coating" in Progress in Organic Coatings, 69, no. 4 (2010):316-321,
https://doi.org/10.1016/j.porgcoat.2010.07.004 . .

TY  - JOUR
AU  - Bučko, M.M.
AU  - Tomić, Milorad V.
AU  - Stojanović, M.V.
AU  - Pavlović, Miomir
AU  - Bajat, Jelena
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/741
AB  - The influence of the type of the deposition solution on the current efficiency during electrodeposition of Zn-Mn alloys was examined. The Zn-Mn alloys were deposited on steel from chloride, sulphate and pyrophosphate plating baths at different current densities. The influence of deposition current density on the appearance of alloy coatings, as well as their corrosion stability, was examined. It was shown that Zn-Mn alloys with the best corrosion properties, among all investigated in this work, were obtained from chloride plating bath at 2 A dm-2. .
AB  - Izučavan je uticaj vrste rastvora za taloženje na iskorišćenje struje prilikom elektrohemijskog taloženja Zn-Mn legura. Legure su taložene na čeliku iz hloridnog, sulfatnog i pirofosfatnog rastvora različitim gustinama struje. Ispitivan je uticaj gustine struje taloženja na izgled prevlaka legura, kao i njihovu korozionu stabilnost. Pokazano je da najveću korozionu stabilnost imaju legure dobijene taloženjem iz hloridnog rastvora gustinom struje od 2 A dm-2.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - The electrochemical deposition and corrosion stability of Zn-Mn alloy coatings
T1  - Elektrohemijsko taloženje i koroziona stabilnost prevlaka Zn-Mn legura
VL  - 51
IS  - 2
SP  - 105
EP  - 110
UR  - https://hdl.handle.net/21.15107/rcub_cer_741
ER  - 

@article{
author = "Bučko, M.M. and Tomić, Milorad V. and Stojanović, M.V. and Pavlović, Miomir and Bajat, Jelena",
year = "2010",
abstract = "The influence of the type of the deposition solution on the current efficiency during electrodeposition of Zn-Mn alloys was examined. The Zn-Mn alloys were deposited on steel from chloride, sulphate and pyrophosphate plating baths at different current densities. The influence of deposition current density on the appearance of alloy coatings, as well as their corrosion stability, was examined. It was shown that Zn-Mn alloys with the best corrosion properties, among all investigated in this work, were obtained from chloride plating bath at 2 A dm-2. ., Izučavan je uticaj vrste rastvora za taloženje na iskorišćenje struje prilikom elektrohemijskog taloženja Zn-Mn legura. Legure su taložene na čeliku iz hloridnog, sulfatnog i pirofosfatnog rastvora različitim gustinama struje. Ispitivan je uticaj gustine struje taloženja na izgled prevlaka legura, kao i njihovu korozionu stabilnost. Pokazano je da najveću korozionu stabilnost imaju legure dobijene taloženjem iz hloridnog rastvora gustinom struje od 2 A dm-2.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "The electrochemical deposition and corrosion stability of Zn-Mn alloy coatings, Elektrohemijsko taloženje i koroziona stabilnost prevlaka Zn-Mn legura",
volume = "51",
number = "2",
pages = "105-110",
url = "https://hdl.handle.net/21.15107/rcub_cer_741"
}

Bučko, M.M., Tomić, M. V., Stojanović, M.V., Pavlović, M.,& Bajat, J.. (2010). The electrochemical deposition and corrosion stability of Zn-Mn alloy coatings. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 51(2), 105-110.
https://hdl.handle.net/21.15107/rcub_cer_741

Bučko M, Tomić MV, Stojanović M, Pavlović M, Bajat J. The electrochemical deposition and corrosion stability of Zn-Mn alloy coatings. in Zaštita materijala. 2010;51(2):105-110.
https://hdl.handle.net/21.15107/rcub_cer_741 .

Bučko, M.M., Tomić, Milorad V., Stojanović, M.V., Pavlović, Miomir, Bajat, Jelena, "The electrochemical deposition and corrosion stability of Zn-Mn alloy coatings" in Zaštita materijala, 51, no. 2 (2010):105-110,
https://hdl.handle.net/21.15107/rcub_cer_741 .

TY  - JOUR
AU  - Bajat, Jelena
AU  - Stankovic, S.
AU  - Jokić, Bojan
AU  - Stevanović, Sanja
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/657
AB  - Electrochemically deposited Zn-Co alloys under various deposition conditions were investigated using atomic absorption spectroscopy (AAS) for determination of chemical composition, anodic linear sweep voltammetry (ALSV) and X-ray diffraction (XRD) for phase structure determination, SEM and AFM for surface morphology analysis, and polarization measurements for determination of corrosion properties. The influence of deposition current density and composition of deposition solution on the phase structure, morphology and corrosion properties of Zn-Co alloys were studied. The plating baths used were with low metal concentration, free of additives and deposition was carried out at room temperature, since the aim of the work was to investigate only the influence of different deposition current densities using economically favorable deposition parameters. It was shown that the ratio of cobalt to zinc ions in the plating bath strongly affects the chemical content and phase structure, as well as the morphology and corrosion stability, of Zn-Co alloys. The single-phased Zn-Co alloys showed the best corrosion stability. The alloys deposited at the highest current density from plating bath with the lower ratio of cobalt to zinc ions, as well as the one deposited at the intermediate current density from bath with higher ratio of cobalt to zinc ions, exhibited the lowest corrosion rates. It was also shown that the deposit having smaller crystallite grains (obtained at higher current density), among two alloy deposits having the same chemical content and phase structure, yielded lower corrosion rate.
PB  - Elsevier
T2  - Surface and Coatings Technology
T1  - Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density
VL  - 204
IS  - 16-17
SP  - 2745
EP  - 2753
DO  - 10.1016/j.surfcoat.2010.02.032
ER  - 

@article{
author = "Bajat, Jelena and Stankovic, S. and Jokić, Bojan and Stevanović, Sanja",
year = "2010",
abstract = "Electrochemically deposited Zn-Co alloys under various deposition conditions were investigated using atomic absorption spectroscopy (AAS) for determination of chemical composition, anodic linear sweep voltammetry (ALSV) and X-ray diffraction (XRD) for phase structure determination, SEM and AFM for surface morphology analysis, and polarization measurements for determination of corrosion properties. The influence of deposition current density and composition of deposition solution on the phase structure, morphology and corrosion properties of Zn-Co alloys were studied. The plating baths used were with low metal concentration, free of additives and deposition was carried out at room temperature, since the aim of the work was to investigate only the influence of different deposition current densities using economically favorable deposition parameters. It was shown that the ratio of cobalt to zinc ions in the plating bath strongly affects the chemical content and phase structure, as well as the morphology and corrosion stability, of Zn-Co alloys. The single-phased Zn-Co alloys showed the best corrosion stability. The alloys deposited at the highest current density from plating bath with the lower ratio of cobalt to zinc ions, as well as the one deposited at the intermediate current density from bath with higher ratio of cobalt to zinc ions, exhibited the lowest corrosion rates. It was also shown that the deposit having smaller crystallite grains (obtained at higher current density), among two alloy deposits having the same chemical content and phase structure, yielded lower corrosion rate.",
publisher = "Elsevier",
journal = "Surface and Coatings Technology",
title = "Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density",
volume = "204",
number = "16-17",
pages = "2745-2753",
doi = "10.1016/j.surfcoat.2010.02.032"
}

Bajat, J., Stankovic, S., Jokić, B.,& Stevanović, S.. (2010). Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density. in Surface and Coatings Technology
Elsevier., 204(16-17), 2745-2753.
https://doi.org/10.1016/j.surfcoat.2010.02.032

Bajat J, Stankovic S, Jokić B, Stevanović S. Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density. in Surface and Coatings Technology. 2010;204(16-17):2745-2753.
doi:10.1016/j.surfcoat.2010.02.032 .

Bajat, Jelena, Stankovic, S., Jokić, Bojan, Stevanović, Sanja, "Corrosion stability of Zn-Co alloys deposited from baths with high and low Co content - The influence of deposition current density" in Surface and Coatings Technology, 204, no. 16-17 (2010):2745-2753,
https://doi.org/10.1016/j.surfcoat.2010.02.032 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mitrić, Miodrag
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolic, Branislav Z.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/638
AB  - Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.
PB  - Royal Soc Chemistry, Cambridge
T2  - Physical Chemistry Chemical Physics
T1  - The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties
VL  - 12
IS  - 27
SP  - 7521
EP  - 7528
DO  - 10.1039/b921582d
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mitrić, Miodrag and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolic, Branislav Z.",
year = "2010",
abstract = "Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Physical Chemistry Chemical Physics",
title = "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties",
volume = "12",
number = "27",
pages = "7521-7528",
doi = "10.1039/b921582d"
}

Panić, V., Dekanski, A., Mitrić, M., Milonjić, S. K., Mišković-Stanković, V.,& Nikolic, B. Z.. (2010). The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics
Royal Soc Chemistry, Cambridge., 12(27), 7521-7528.
https://doi.org/10.1039/b921582d

Panić V, Dekanski A, Mitrić M, Milonjić SK, Mišković-Stanković V, Nikolic BZ. The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics. 2010;12(27):7521-7528.
doi:10.1039/b921582d .

Panić, Vladimir, Dekanski, Aleksandar, Mitrić, Miodrag, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolic, Branislav Z., "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties" in Physical Chemistry Chemical Physics, 12, no. 27 (2010):7521-7528,
https://doi.org/10.1039/b921582d . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Nikolic, B. Z.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/545
AB  - The changes in capacitive behavior of C/H(x)RuO(y) composite material prepared by impregnating the Vulcan (R) XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion (R)-covered composite. The techniques of cyclic voltammetry and electrochemical impedance spectroscopy are used. Results of the investigation reveal the influence of potential cycling and the exposure time to the electrolyte on registered capacitive characteristics of composite. The cycling in a wide potential range causes the decrease in energy storage ability which depends on oxide particle size. Impedance measurements, however, show that the ability initially decreases and subsequently increases during exposure to the electrolyte as the consequence of the presence of Nafion (R) top-layer. Due to wettability and resistance issues, Nafion (R) top-layer can affect the pseudo-capacitive characteristics, and the energy storage ability of the composite consequently decreases.
PB  - Croatian Society of Chemical Engineers
T2  - Chemical and Biochemical Engineering Quarterly
T1  - The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure
VL  - 23
IS  - 1
SP  - 23
EP  - 30
UR  - https://hdl.handle.net/21.15107/rcub_cer_545
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Nikolic, B. Z.",
year = "2009",
abstract = "The changes in capacitive behavior of C/H(x)RuO(y) composite material prepared by impregnating the Vulcan (R) XC 72R carbon black with oxide sols of different particle size are investigated as the electrolyte penetrates through the thin layer of the Nafion (R)-covered composite. The techniques of cyclic voltammetry and electrochemical impedance spectroscopy are used. Results of the investigation reveal the influence of potential cycling and the exposure time to the electrolyte on registered capacitive characteristics of composite. The cycling in a wide potential range causes the decrease in energy storage ability which depends on oxide particle size. Impedance measurements, however, show that the ability initially decreases and subsequently increases during exposure to the electrolyte as the consequence of the presence of Nafion (R) top-layer. Due to wettability and resistance issues, Nafion (R) top-layer can affect the pseudo-capacitive characteristics, and the energy storage ability of the composite consequently decreases.",
publisher = "Croatian Society of Chemical Engineers",
journal = "Chemical and Biochemical Engineering Quarterly",
title = "The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure",
volume = "23",
number = "1",
pages = "23-30",
url = "https://hdl.handle.net/21.15107/rcub_cer_545"
}

Panić, V., Dekanski, A., Mišković-Stanković, V.,& Nikolic, B. Z.. (2009). The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure. in Chemical and Biochemical Engineering Quarterly
Croatian Society of Chemical Engineers., 23(1), 23-30.
https://hdl.handle.net/21.15107/rcub_cer_545

Panić V, Dekanski A, Mišković-Stanković V, Nikolic BZ. The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure. in Chemical and Biochemical Engineering Quarterly. 2009;23(1):23-30.
https://hdl.handle.net/21.15107/rcub_cer_545 .

Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Nikolic, B. Z., "The Study of Capacitance Change during Electrolyte Penetration through Carbon-Supported Hydrous Ruthenium Oxide Prepared by the Sol-Gel Procedure" in Chemical and Biochemical Engineering Quarterly, 23, no. 1 (2009):23-30,
https://hdl.handle.net/21.15107/rcub_cer_545 .

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Popić, Jovan
AU  - Dražić, Dragutin M.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4117
AB  - The influence of hot-dip galvanized steel (HDG) surface pretreatment with phosphate coatings on the corrosion stability and adhesion characteristics of epoxy coatings electrodeposited on HDG steel was investigated. Phosphate coatings were deposited on hot-dip galvanized steel from baths with different concentrations of NaF (0.1, 0.5 and 1.0 g dm-3) and at different temperatures (50, 65 and 80 °C). The influence of fluoride ion concentration in the phosphating bath, as well as the deposition temperature of the bath, on the adhesion characteristics and corrosion stability of epoxy coatings on phosphated HDG steel was investigated. The dry and wet adhesions were measured by a direct pull-off standardized procedure, as well as indirectly by NMP test, while corrosion stability was investigated by electrochemical impedance spectroscopy (EIS). It was shown that under dry testing conditions all the samples exhibited very good adhesion. However, the different trends of adhesion loss of different protective systems during exposure to corrosive agent (3% NaCl solution) were observed. The lowest adhesion values were obtained for epoxy coating on hot-dip galvanized steel, while the phosphate pretreatments significantly increase the adhesion of epoxy coatings. The highest values of adhesion strength were obtained for epoxy coating on HDG steel modified by phosphate coating deposited at 65 °C with 0.5 g dm-3 NaF in the phosphating bath. EIS measurements in 3% NaCl solution are in accordance with adhesion measurements, i.e. greater values of charge-transfer resistance and smaller values of double-layer capacitance were obtained, as compared to other protective systems.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel
VL  - 63
IS  - 2
SP  - 201
EP  - 208
DO  - 10.1016/j.porgcoat.2008.06.002
ER  - 

@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Popić, Jovan and Dražić, Dragutin M.",
year = "2008",
abstract = "The influence of hot-dip galvanized steel (HDG) surface pretreatment with phosphate coatings on the corrosion stability and adhesion characteristics of epoxy coatings electrodeposited on HDG steel was investigated. Phosphate coatings were deposited on hot-dip galvanized steel from baths with different concentrations of NaF (0.1, 0.5 and 1.0 g dm-3) and at different temperatures (50, 65 and 80 °C). The influence of fluoride ion concentration in the phosphating bath, as well as the deposition temperature of the bath, on the adhesion characteristics and corrosion stability of epoxy coatings on phosphated HDG steel was investigated. The dry and wet adhesions were measured by a direct pull-off standardized procedure, as well as indirectly by NMP test, while corrosion stability was investigated by electrochemical impedance spectroscopy (EIS). It was shown that under dry testing conditions all the samples exhibited very good adhesion. However, the different trends of adhesion loss of different protective systems during exposure to corrosive agent (3% NaCl solution) were observed. The lowest adhesion values were obtained for epoxy coating on hot-dip galvanized steel, while the phosphate pretreatments significantly increase the adhesion of epoxy coatings. The highest values of adhesion strength were obtained for epoxy coating on HDG steel modified by phosphate coating deposited at 65 °C with 0.5 g dm-3 NaF in the phosphating bath. EIS measurements in 3% NaCl solution are in accordance with adhesion measurements, i.e. greater values of charge-transfer resistance and smaller values of double-layer capacitance were obtained, as compared to other protective systems.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel",
volume = "63",
number = "2",
pages = "201-208",
doi = "10.1016/j.porgcoat.2008.06.002"
}

Bajat, J., Mišković-Stanković, V., Popić, J.,& Dražić, D. M.. (2008). Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel. in Progress in Organic Coatings
Elsevier., 63(2), 201-208.
https://doi.org/10.1016/j.porgcoat.2008.06.002

Bajat J, Mišković-Stanković V, Popić J, Dražić DM. Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel. in Progress in Organic Coatings. 2008;63(2):201-208.
doi:10.1016/j.porgcoat.2008.06.002 .

Bajat, Jelena, Mišković-Stanković, Vesna, Popić, Jovan, Dražić, Dragutin M., "Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel" in Progress in Organic Coatings, 63, no. 2 (2008):201-208,
https://doi.org/10.1016/j.porgcoat.2008.06.002 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Stevanović, Sanja
AU  - Mišković-Stanković, Vesna
AU  - Jovanović, Bratislav Ž.
AU  - Nikolic, Branislav Z.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/438
AB  - The photoelectrochemical properties of a sol-gel prepared titanium oxide coating applied onto a Ti substrate were investigated. The oxide coating was formed from an inorganic sol thermally treated in air at 350°C. The coating consisted of agglomerates of narrow size distribution around 100 nm. The photoelectrochemical characteristics were evaluated by investigating the changes in the open circuit potential, current transients and impedance characteristics of a Ti/TiO2 electrode upon illumination by UV light in H2SO4 solution and in the oxidation of benzyl alcohol. The electrode was found to be active for photoelectrochemical reactions in the investigated solutions.
AB  - Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel portupkom ispitivana su na oksidnoj prevlaci nanetoj na titansku podlogu. Prevlaka je termički tretirana u vazduhu na temperaturi od 350°C. Prevlaka se sastoji od zrna ujednačene raspodele po veličini od oko 100 nm. Fotoelektrohemijske karakteristike ustanovljene su ispitivanjem promena potencijala otvorenog kola, vremenske zavisnosti struje i impedansnih karakteristika Ti/TiO2 elektrode pri osvetljenosti UV svetlošću u rastvoru H2SO4 i pri oksidaciji benzil-alkohola. Ustanovljena je fotoaktivnost elektrode u ispitivanim sistemima.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Photoelectrochemical properties of sol-gel obtained titanium oxide
T1  - Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel postupkom
VL  - 73
IS  - 12
SP  - 1211
EP  - 1221
DO  - 10.2298/JSC0812211P
ER  - 

@article{
author = "Panić, Vladimir and Stevanović, Sanja and Mišković-Stanković, Vesna and Jovanović, Bratislav Ž. and Nikolic, Branislav Z.",
year = "2008",
abstract = "The photoelectrochemical properties of a sol-gel prepared titanium oxide coating applied onto a Ti substrate were investigated. The oxide coating was formed from an inorganic sol thermally treated in air at 350°C. The coating consisted of agglomerates of narrow size distribution around 100 nm. The photoelectrochemical characteristics were evaluated by investigating the changes in the open circuit potential, current transients and impedance characteristics of a Ti/TiO2 electrode upon illumination by UV light in H2SO4 solution and in the oxidation of benzyl alcohol. The electrode was found to be active for photoelectrochemical reactions in the investigated solutions., Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel portupkom ispitivana su na oksidnoj prevlaci nanetoj na titansku podlogu. Prevlaka je termički tretirana u vazduhu na temperaturi od 350°C. Prevlaka se sastoji od zrna ujednačene raspodele po veličini od oko 100 nm. Fotoelektrohemijske karakteristike ustanovljene su ispitivanjem promena potencijala otvorenog kola, vremenske zavisnosti struje i impedansnih karakteristika Ti/TiO2 elektrode pri osvetljenosti UV svetlošću u rastvoru H2SO4 i pri oksidaciji benzil-alkohola. Ustanovljena je fotoaktivnost elektrode u ispitivanim sistemima.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Photoelectrochemical properties of sol-gel obtained titanium oxide, Fotoelektrohemijska svojstva titan-oksida dobijenog sol-gel postupkom",
volume = "73",
number = "12",
pages = "1211-1221",
doi = "10.2298/JSC0812211P"
}

Panić, V., Stevanović, S., Mišković-Stanković, V., Jovanović, B. Ž.,& Nikolic, B. Z.. (2008). Photoelectrochemical properties of sol-gel obtained titanium oxide. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 73(12), 1211-1221.
https://doi.org/10.2298/JSC0812211P

Panić V, Stevanović S, Mišković-Stanković V, Jovanović BŽ, Nikolic BZ. Photoelectrochemical properties of sol-gel obtained titanium oxide. in Journal of the Serbian Chemical Society. 2008;73(12):1211-1221.
doi:10.2298/JSC0812211P .

Panić, Vladimir, Stevanović, Sanja, Mišković-Stanković, Vesna, Jovanović, Bratislav Ž., Nikolic, Branislav Z., "Photoelectrochemical properties of sol-gel obtained titanium oxide" in Journal of the Serbian Chemical Society, 73, no. 12 (2008):1211-1221,
https://doi.org/10.2298/JSC0812211P . .

TY  - JOUR
AU  - Panić, Vladimir
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/439
AB  - The results of an investigation of the capacitive characteristics of sol-gel-processed titanium- and carbon-supported electrochemically active noble metal oxides, as representatives of porous electrode materials, are presented in the lecture. The capacitive properties of these materials were correlated to their composition, the preparation conditions of the oxides and coatings, the properties of the carbon support and to the composition of the electrolyte. The results of the electrochemical test methods, cyclic voltammetry and electrochemical impedance spectroscopy, were employed to resolve the possible physical structures of the mentioned porous materials, which are governed by the controlled conditions of the preparation of the oxide by the sol-gel process.
AB  - U okviru predavanja su prikazani rezultati ispitivanja kapacitivnih karakteristika elektrohemijski aktivnih prevlaka oksida plemenitih metala formiranih na titanskom nosaču i kompozitnih ugljenično-oksidnih materijala kao najčešćih tipova planarnih poroznih elektroda. Kapacitivna svojstva ovih elektroda ispitivana su u funkciji njihovog sastava, uslova pod kojima su dobijeni oksidi i prevlake, karakteristika ugljeničnog nosača i sastava elektrolita, metodama ciklične voltametrije i spektroskopije elektrohemijske impedancije. Rezultati elektrohemijskih metoda korelisani su sa mogućom strukturom ovih materijala koju definiše kontrolisani proces dobijanja oksida sol-gel postupkom.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Supercapacitive characteristics of electrochemically active porous materials
T1  - Superkondenzatorske karakteristike elektrohemijski aktivnih poroznih materijala
VL  - 73
IS  - 6
SP  - 661
EP  - 664
DO  - 10.2298/JSC0806661P
ER  - 

@article{
author = "Panić, Vladimir",
year = "2008",
abstract = "The results of an investigation of the capacitive characteristics of sol-gel-processed titanium- and carbon-supported electrochemically active noble metal oxides, as representatives of porous electrode materials, are presented in the lecture. The capacitive properties of these materials were correlated to their composition, the preparation conditions of the oxides and coatings, the properties of the carbon support and to the composition of the electrolyte. The results of the electrochemical test methods, cyclic voltammetry and electrochemical impedance spectroscopy, were employed to resolve the possible physical structures of the mentioned porous materials, which are governed by the controlled conditions of the preparation of the oxide by the sol-gel process., U okviru predavanja su prikazani rezultati ispitivanja kapacitivnih karakteristika elektrohemijski aktivnih prevlaka oksida plemenitih metala formiranih na titanskom nosaču i kompozitnih ugljenično-oksidnih materijala kao najčešćih tipova planarnih poroznih elektroda. Kapacitivna svojstva ovih elektroda ispitivana su u funkciji njihovog sastava, uslova pod kojima su dobijeni oksidi i prevlake, karakteristika ugljeničnog nosača i sastava elektrolita, metodama ciklične voltametrije i spektroskopije elektrohemijske impedancije. Rezultati elektrohemijskih metoda korelisani su sa mogućom strukturom ovih materijala koju definiše kontrolisani proces dobijanja oksida sol-gel postupkom.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Supercapacitive characteristics of electrochemically active porous materials, Superkondenzatorske karakteristike elektrohemijski aktivnih poroznih materijala",
volume = "73",
number = "6",
pages = "661-664",
doi = "10.2298/JSC0806661P"
}

Panić, V.. (2008). Supercapacitive characteristics of electrochemically active porous materials. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 73(6), 661-664.
https://doi.org/10.2298/JSC0806661P

Panić V. Supercapacitive characteristics of electrochemically active porous materials. in Journal of the Serbian Chemical Society. 2008;73(6):661-664.
doi:10.2298/JSC0806661P .

Panić, Vladimir, "Supercapacitive characteristics of electrochemically active porous materials" in Journal of the Serbian Chemical Society, 73, no. 6 (2008):661-664,
https://doi.org/10.2298/JSC0806661P . .

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Dražić, Dragutin M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4303
AB  - One of the most important factors in corrosion prevention by protective coatings is the loss of coating adhesion under environmental influence. In this work, the adhesion of epoxy cataphoretic coatings was examined on steel and steel modified by Zn-Fe and Zn-Co alloys. The dry and wet adhesions of epoxy primers were measured by the direct pull-off standardized procedure, as well as indirectly by the NMP test. The corrosion stability of the coated samples was investigated by electrochemical impedance spectroscopy. It was shown that under dry testing conditions all the samples exhibited very good adhesion. However, different trends of adhesion loss of different protective systems during exposure to a corrosive agent (3 % NaCl solution) were observed. The lowest adhesion values were obtained for epoxy coating on the steel substrate. The change in adhesion of the epoxy coating on steel modified by Zn-Co alloy during immersion in 3 % NaCl solution for 24 days was the smallest of all the investigated samples. Electrochemical impedance measurements in 3 % NaCl solution confirmed the good protective properties of this protective system, i.e., greater values of pore resistance were obtained.
AB  - Један од најважнијих фактора у заштити од корозије органским превлакама је губитак
адхезије органских превлака под утицајем корозионе средине. У овом раду проучавана је ад-
хезија епоксидних катафоретских превлака на челику и челику модификованом легурама
Zn–Fe и Zn–Co. Испитиване су тзв. сува и мокра адхезија стандардним pull-off поступком,
као и NMP тестом. Корозиона стабилност свих узорака је испитивана спектроскопијом елек-
трохемијске импеданције. Сви узорци су имали добру почетну адхезију, међутим током де-
ловања корозионог агенса (3 % NaCl) промена адхезије се значајно разликовала код различи-
тих заштитних система. Најмање вредности адхезије су добијене у случају епоксидне пре-
влаке на челику. Укупно смањење адхезије током 24 дана испитивања је најмање за епок-
сидну превлаку на челику модификованом Zn–Co легуром. Највеће вредности отпорности у
порама епоксидне превлаке током целокупног испитиваног периода деловања корозионог аг-
енса код превлаке на челику модификованом Zn–Co легуром такође указују на велику ста-
билност овог заштитног система.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Adhesion of epoxy cataphoretic coatings on Zn alloys
T1  - Адхезија епоксидних катафоретских превлака на легурама цинка
VL  - 72
VL  - 1392
IS  - 12
SP  - 1383
DO  - 10.2298/JSC0712383B
ER  - 

@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Dražić, Dragutin M.",
year = "2007",
abstract = "One of the most important factors in corrosion prevention by protective coatings is the loss of coating adhesion under environmental influence. In this work, the adhesion of epoxy cataphoretic coatings was examined on steel and steel modified by Zn-Fe and Zn-Co alloys. The dry and wet adhesions of epoxy primers were measured by the direct pull-off standardized procedure, as well as indirectly by the NMP test. The corrosion stability of the coated samples was investigated by electrochemical impedance spectroscopy. It was shown that under dry testing conditions all the samples exhibited very good adhesion. However, different trends of adhesion loss of different protective systems during exposure to a corrosive agent (3 % NaCl solution) were observed. The lowest adhesion values were obtained for epoxy coating on the steel substrate. The change in adhesion of the epoxy coating on steel modified by Zn-Co alloy during immersion in 3 % NaCl solution for 24 days was the smallest of all the investigated samples. Electrochemical impedance measurements in 3 % NaCl solution confirmed the good protective properties of this protective system, i.e., greater values of pore resistance were obtained., Један од најважнијих фактора у заштити од корозије органским превлакама је губитак
адхезије органских превлака под утицајем корозионе средине. У овом раду проучавана је ад-
хезија епоксидних катафоретских превлака на челику и челику модификованом легурама
Zn–Fe и Zn–Co. Испитиване су тзв. сува и мокра адхезија стандардним pull-off поступком,
као и NMP тестом. Корозиона стабилност свих узорака је испитивана спектроскопијом елек-
трохемијске импеданције. Сви узорци су имали добру почетну адхезију, међутим током де-
ловања корозионог агенса (3 % NaCl) промена адхезије се значајно разликовала код различи-
тих заштитних система. Најмање вредности адхезије су добијене у случају епоксидне пре-
влаке на челику. Укупно смањење адхезије током 24 дана испитивања је најмање за епок-
сидну превлаку на челику модификованом Zn–Co легуром. Највеће вредности отпорности у
порама епоксидне превлаке током целокупног испитиваног периода деловања корозионог аг-
енса код превлаке на челику модификованом Zn–Co легуром такође указују на велику ста-
билност овог заштитног система.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Adhesion of epoxy cataphoretic coatings on Zn alloys, Адхезија епоксидних катафоретских превлака на легурама цинка",
volume = "72, 1392",
number = "12",
pages = "1383",
doi = "10.2298/JSC0712383B"
}

Bajat, J., Mišković-Stanković, V.,& Dražić, D. M.. (2007). Adhesion of epoxy cataphoretic coatings on Zn alloys. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 72(12), 1383.
https://doi.org/10.2298/JSC0712383B

Bajat J, Mišković-Stanković V, Dražić DM. Adhesion of epoxy cataphoretic coatings on Zn alloys. in Journal of the Serbian Chemical Society. 2007;72(12):1383.
doi:10.2298/JSC0712383B .

Bajat, Jelena, Mišković-Stanković, Vesna, Dražić, Dragutin M., "Adhesion of epoxy cataphoretic coatings on Zn alloys" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1383,
https://doi.org/10.2298/JSC0712383B . .

TY  - JOUR
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Bibić, Nataša M.
AU  - Dražić, Dragutin M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4331
AB  - The adhesion and electrochemical properties of epoxy coatings electrodeposited on hot-dip galvanized steel with and without passive films were investigated during exposure to 3% NaCl. The passive films were formed in hot air, in boiling water and by chromating. Adhesion was measured both by a standardized pull-off method and by swelling in N-methyl pyrrolidone. Pretreatment of hot-dip galvanized steel with passive film formed in hot air increases both dry and wet adhesion strength of the epoxy coating compared to pretreatment with passive film formed in boiling water and chromate coating. The overall increase of wet adhesion for this sample was maintained throughout the whole investigated time period. It was shown that the change in adhesion of epoxy coating on a chromate coating is smallest of all investigated samples, although the initial value of adhesion on this surface had the lowest value. The corrosion stability of coated Zn samples pretreated by different methods, was investigated by electrochemical impedance spectroscopy and in the initial time of exposure to NaCl the highest values of pore resistance were also obtained for the epoxy coating on Zn pretreated in hot air, whereas the epoxy coating on a HDG steel with a chromate coating showed the smallest change in electrochemical properties (pore resistance, coating capacitance, charge-transfer resistance) during prolonged exposure time.
PB  - Elsevier
T2  - Progress in Organic Coatings
T1  - The influence of zinc surface pretreatment on the adhesion of epoxy coating electrodeposited on hot-dip galvanized steel
VL  - 58
IS  - 4
SP  - 323
EP  - 330
DO  - 10.1016/j.porgcoat.2007.01.011
ER  - 

@article{
author = "Bajat, Jelena and Mišković-Stanković, Vesna and Bibić, Nataša M. and Dražić, Dragutin M.",
year = "2007",
abstract = "The adhesion and electrochemical properties of epoxy coatings electrodeposited on hot-dip galvanized steel with and without passive films were investigated during exposure to 3% NaCl. The passive films were formed in hot air, in boiling water and by chromating. Adhesion was measured both by a standardized pull-off method and by swelling in N-methyl pyrrolidone. Pretreatment of hot-dip galvanized steel with passive film formed in hot air increases both dry and wet adhesion strength of the epoxy coating compared to pretreatment with passive film formed in boiling water and chromate coating. The overall increase of wet adhesion for this sample was maintained throughout the whole investigated time period. It was shown that the change in adhesion of epoxy coating on a chromate coating is smallest of all investigated samples, although the initial value of adhesion on this surface had the lowest value. The corrosion stability of coated Zn samples pretreated by different methods, was investigated by electrochemical impedance spectroscopy and in the initial time of exposure to NaCl the highest values of pore resistance were also obtained for the epoxy coating on Zn pretreated in hot air, whereas the epoxy coating on a HDG steel with a chromate coating showed the smallest change in electrochemical properties (pore resistance, coating capacitance, charge-transfer resistance) during prolonged exposure time.",
publisher = "Elsevier",
journal = "Progress in Organic Coatings",
title = "The influence of zinc surface pretreatment on the adhesion of epoxy coating electrodeposited on hot-dip galvanized steel",
volume = "58",
number = "4",
pages = "323-330",
doi = "10.1016/j.porgcoat.2007.01.011"
}

Bajat, J., Mišković-Stanković, V., Bibić, N. M.,& Dražić, D. M.. (2007). The influence of zinc surface pretreatment on the adhesion of epoxy coating electrodeposited on hot-dip galvanized steel. in Progress in Organic Coatings
Elsevier., 58(4), 323-330.
https://doi.org/10.1016/j.porgcoat.2007.01.011

Bajat J, Mišković-Stanković V, Bibić NM, Dražić DM. The influence of zinc surface pretreatment on the adhesion of epoxy coating electrodeposited on hot-dip galvanized steel. in Progress in Organic Coatings. 2007;58(4):323-330.
doi:10.1016/j.porgcoat.2007.01.011 .

Bajat, Jelena, Mišković-Stanković, Vesna, Bibić, Nataša M., Dražić, Dragutin M., "The influence of zinc surface pretreatment on the adhesion of epoxy coating electrodeposited on hot-dip galvanized steel" in Progress in Organic Coatings, 58, no. 4 (2007):323-330,
https://doi.org/10.1016/j.porgcoat.2007.01.011 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković, Tanja R.
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B.Z.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/369
AB  - The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different masses of coating (thin and thick coating) were prepared from an ink suspension of the oxide synthesized by hydrolysis of ruthenium-ethoxide in ethanolic solution. The capacitive characteristics were found to be dependent on the coating mass and the electrolyte composition. It was shown that the impedance data of the prepared electrodes, registered at the open circuit potential, can be interpreted by a transmission line model of the equivalent electrical circuit. In this interpretation, the number of parallel branches containing resistor and capacitor in series is different for thin and thick coatings and in different electrolytes. More branches were required to describe the impedance behavior of the thick coating and to simulate the impedance data in NaCl solution. Simulation of the impedance data with the transmission line model of the equivalent circuit was also used to analyze the distribution of capacitance throughout the porous coating. The simulation indicated a more pronounced contribution of the capacitance of the outer coating layer to the total coating capacitance in the case of the proton-rich electrolyte. On the other hand, the presence of chloride ions in the electrolyte promoted a charging process at the inner coating surface, which is hardly accessible to the electrolyte.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure
VL  - 609
IS  - 2
SP  - 120
EP  - 128
DO  - 10.1016/j.jelechem.2007.06.011
ER  - 

@article{
author = "Panić, Vladimir and Vidaković, Tanja R. and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Nikolić, B.Z.",
year = "2007",
abstract = "The capacitive properties of titanium electrodes with an active porous RuO2 coating were investigated in H2SO4 and NaCl solution by cyclic voltammetry and electrochemical impedance spectroscopy. Electrodes with two different masses of coating (thin and thick coating) were prepared from an ink suspension of the oxide synthesized by hydrolysis of ruthenium-ethoxide in ethanolic solution. The capacitive characteristics were found to be dependent on the coating mass and the electrolyte composition. It was shown that the impedance data of the prepared electrodes, registered at the open circuit potential, can be interpreted by a transmission line model of the equivalent electrical circuit. In this interpretation, the number of parallel branches containing resistor and capacitor in series is different for thin and thick coatings and in different electrolytes. More branches were required to describe the impedance behavior of the thick coating and to simulate the impedance data in NaCl solution. Simulation of the impedance data with the transmission line model of the equivalent circuit was also used to analyze the distribution of capacitance throughout the porous coating. The simulation indicated a more pronounced contribution of the capacitance of the outer coating layer to the total coating capacitance in the case of the proton-rich electrolyte. On the other hand, the presence of chloride ions in the electrolyte promoted a charging process at the inner coating surface, which is hardly accessible to the electrolyte.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure",
volume = "609",
number = "2",
pages = "120-128",
doi = "10.1016/j.jelechem.2007.06.011"
}

Panić, V., Vidaković, T. R., Dekanski, A., Mišković-Stanković, V.,& Nikolić, B.Z.. (2007). Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure. in Journal of Electroanalytical Chemistry
Elsevier., 609(2), 120-128.
https://doi.org/10.1016/j.jelechem.2007.06.011

Panić V, Vidaković TR, Dekanski A, Mišković-Stanković V, Nikolić B. Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure. in Journal of Electroanalytical Chemistry. 2007;609(2):120-128.
doi:10.1016/j.jelechem.2007.06.011 .

Panić, Vladimir, Vidaković, Tanja R., Dekanski, Aleksandar, Mišković-Stanković, Vesna, Nikolić, B.Z., "Capacitive properties of RuO2-coated titanium electrodes prepared by the alkoxide ink procedure" in Journal of Electroanalytical Chemistry, 609, no. 2 (2007):120-128,
https://doi.org/10.1016/j.jelechem.2007.06.011 . .

TY  - JOUR
AU  - Jegdić, Bore
AU  - Dražić, Dragutin M.
AU  - Popić, Jovan P.
AU  - Radmilović, Velimir R.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/311
AB  - Chromium dissolution in aqueous sulfuric acid solution of pH 1 was studied electrochemically on chromium electrodes with different crystallographic structures. A slow potentiodynamic method was used for the electrochemical measurements in deaerated solutions (purged with nitrogen),while the Cr(III) ions in the solution after the corrosion were determined by atomic absorption spectrometry. Three electrode materials with a very dominant crystallite orientation resembling single crystal structures (i.e., 111 and 110) confirmed by the electron backscattering diffraction (EBSD), were used in the experiments. The (111) structures were somewhat more active electrochemically (both anodic and cathodic) than the (110) structure. However, Cr electrochemically deposited in standard plating bath, assumed from literature data to has also the (111) structure, was more than 4 times active for anodic dissolution and, by the same number, less active for cathodic hydrogen evolution. The concentrations of Cr(III) ions determined in the solution after definite times of corrosion of all the materials showed almost two times larger dissolution rates than observed electrochemically by three different electrochemical methods (Wagner-Traud, Stern-Geary, electrochemical impedance spectroscopy). This is explained by the simultaneous occurrence of potential independent chemical dissolution of Cr, by a direct reaction of metallic Cr with H2O molecules, proposed a long time ago by Kolotyrkin and coworkers. .
AB  - Proučavano je elektrohemijsko rastvaranje hroma u vodenim rastvorima sumporne kiseline (pH 1) sa elektrodama od hroma različite kristalografske strukture. Primenjena je spora potenciodinamička metoda u deaeriranim rastvorima (uz provođenje azota) na 25°C, a joni Cr(III) u rastvoru posle određenog vremena korozije određivani su atomskom apsorpcionom spektroskopijom. U eksperimentima su upotrebljena tri elektrodna materijala sa dominantnim kristalnim strukturama koje podsećaju na mono kristalne (tj. 111 i 110), a što je potvrđeno EBSD metodom. Nađeno je da je struktura (111) elektrohemijski aktivnija (i anodno i katodno) od strukture (110). Međutim, elektrolitički istaložen Cr iz standardnog kupatila za hromiranje, a koji na osnovu literaturnih podataka ima strukturu (111) bio je oko 4 puta aktivniji u anodnoj reakciji i isto toliko manje aktivan za katodnu reakciju izdvajanja vodonika. Analitički određivane koncentracije Cr(III) jona u rastvoru posle određenog vremena spontane korozije pokazivale su dva puta veće koncentracije nego što bi se očekivalo na osnovu brzine elektrohemijske korozije, određivanih metodama Wagner-Traud, Stern-Geary i elektrohemijskom impedansnom spektroskopijom. Ovo je objašnjeno jednovremenim odigravanjem i elektrohemijske reakcije i hemijske reakcije direktnog reagovanja metalnog Cr sa molekulima vode, po mehanizmu predloženom od Kolotirkina i saradnika. .
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Structural effects of metallic chromium on its electrochemical behavior
T1  - Uticaj strukture metalnog hroma na njegovo elektrohemijsko ponašanje
VL  - 72
IS  - 6
SP  - 563
EP  - 578
DO  - 10.2298/JSC0706563J
ER  - 

@article{
author = "Jegdić, Bore and Dražić, Dragutin M. and Popić, Jovan P. and Radmilović, Velimir R.",
year = "2007",
abstract = "Chromium dissolution in aqueous sulfuric acid solution of pH 1 was studied electrochemically on chromium electrodes with different crystallographic structures. A slow potentiodynamic method was used for the electrochemical measurements in deaerated solutions (purged with nitrogen),while the Cr(III) ions in the solution after the corrosion were determined by atomic absorption spectrometry. Three electrode materials with a very dominant crystallite orientation resembling single crystal structures (i.e., 111 and 110) confirmed by the electron backscattering diffraction (EBSD), were used in the experiments. The (111) structures were somewhat more active electrochemically (both anodic and cathodic) than the (110) structure. However, Cr electrochemically deposited in standard plating bath, assumed from literature data to has also the (111) structure, was more than 4 times active for anodic dissolution and, by the same number, less active for cathodic hydrogen evolution. The concentrations of Cr(III) ions determined in the solution after definite times of corrosion of all the materials showed almost two times larger dissolution rates than observed electrochemically by three different electrochemical methods (Wagner-Traud, Stern-Geary, electrochemical impedance spectroscopy). This is explained by the simultaneous occurrence of potential independent chemical dissolution of Cr, by a direct reaction of metallic Cr with H2O molecules, proposed a long time ago by Kolotyrkin and coworkers. ., Proučavano je elektrohemijsko rastvaranje hroma u vodenim rastvorima sumporne kiseline (pH 1) sa elektrodama od hroma različite kristalografske strukture. Primenjena je spora potenciodinamička metoda u deaeriranim rastvorima (uz provođenje azota) na 25°C, a joni Cr(III) u rastvoru posle određenog vremena korozije određivani su atomskom apsorpcionom spektroskopijom. U eksperimentima su upotrebljena tri elektrodna materijala sa dominantnim kristalnim strukturama koje podsećaju na mono kristalne (tj. 111 i 110), a što je potvrđeno EBSD metodom. Nađeno je da je struktura (111) elektrohemijski aktivnija (i anodno i katodno) od strukture (110). Međutim, elektrolitički istaložen Cr iz standardnog kupatila za hromiranje, a koji na osnovu literaturnih podataka ima strukturu (111) bio je oko 4 puta aktivniji u anodnoj reakciji i isto toliko manje aktivan za katodnu reakciju izdvajanja vodonika. Analitički određivane koncentracije Cr(III) jona u rastvoru posle određenog vremena spontane korozije pokazivale su dva puta veće koncentracije nego što bi se očekivalo na osnovu brzine elektrohemijske korozije, određivanih metodama Wagner-Traud, Stern-Geary i elektrohemijskom impedansnom spektroskopijom. Ovo je objašnjeno jednovremenim odigravanjem i elektrohemijske reakcije i hemijske reakcije direktnog reagovanja metalnog Cr sa molekulima vode, po mehanizmu predloženom od Kolotirkina i saradnika. .",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Structural effects of metallic chromium on its electrochemical behavior, Uticaj strukture metalnog hroma na njegovo elektrohemijsko ponašanje",
volume = "72",
number = "6",
pages = "563-578",
doi = "10.2298/JSC0706563J"
}

Jegdić, B., Dražić, D. M., Popić, J. P.,& Radmilović, V. R.. (2007). Structural effects of metallic chromium on its electrochemical behavior. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 72(6), 563-578.
https://doi.org/10.2298/JSC0706563J

Jegdić B, Dražić DM, Popić JP, Radmilović VR. Structural effects of metallic chromium on its electrochemical behavior. in Journal of the Serbian Chemical Society. 2007;72(6):563-578.
doi:10.2298/JSC0706563J .

Jegdić, Bore, Dražić, Dragutin M., Popić, Jovan P., Radmilović, Velimir R., "Structural effects of metallic chromium on its electrochemical behavior" in Journal of the Serbian Chemical Society, 72, no. 6 (2007):563-578,
https://doi.org/10.2298/JSC0706563J . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Nikolic, Branislav Z.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/332
AB  - The characteristics of a ternary oxide coating, on titanium, which consisted of TiO2, RuO2 and IrO2 in the molar ratio 0.6:0.3:0.1, calculated on the metal atom, were investigated for potential application for cathodic protection in a seawater environment. The oxide coatings on titanium were prepared by the sol-gel procedure from a mixture of inorganic oxide sols, which were obtained by forced hydrolysis of metal chlorides. The morphology of the coating was examined by scanning electron microscopy. The electrochemical properties of activated titanium anodes were investigated by cyclic voltammetry and polarization measurements in a H2SO4- and NaCl-containing electrolyte, as well as in seawater sampled on the Adriatic coast in Tivat, Montenegro. The anode stability during operation in seawater was investigated by the galvanostatic accelerated corrosion stability test. The morphology and electrochemical characteristics of the ternary coating are compared to that of a sol-gel-prepared binary Ti0.6Ru0.4O2 coating. The activity of the ternary coating was similar to that of the binary Ti0.6Ru0.4O2 coating in the investigated solutions. However, the stability in seawater is found to be considerably greater for the ternary coating.
AB  - Karakteristike trojne oksidne prevlake na titanu, koja se sastoji od TiO2, RuO2 i IrO2 u molskom odnosu 0.6:0.3:0.1 računato na atom metala, ispitivane su sa ciljem potencijalne primene za katodnu zaštitu u morskoj vodi. Oksidna prevlaka na titanu formirana je sol-gel postupkom iz smeše neorganskih oksidnih solova, koji su dobijeni forsiranom hidrolizom hlorida metala. Morfologija prevlake je ispitivana skenirajućom elektronskom mikroskopijom, dok su elektrohemijska svojstva aktiviranih titankih anoda ispitivana metodom ciklične voltametrije i polarizacionim merenjima u rastvorima H2SO4, NaCl i u realnim uslovima, u morskoj vodi uzorkovanoj iz Jadranskog mora (Tivat, Crna Gora). Stabilnost anode tokom rada u morskoj vodi ispitivana je galvanostatski, ubrzanim testom stabilnosti. Dobijene prevlake upoređene su sa dvojnom Ti0,6Ru0,4O2 prevlakom, u pogledu morfologije i elektrohemiskih karakteristika. Pokazano je da su trojna i dvojna prevlaka slične aktivnosti u ispitivanim rastvorima. Međutim, u morskoj vodi stabilnost trojne prevlake je znatno veća.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Sol-gel prepared active ternary oxide coating on titanium in cathodic protection
T1  - Aktivna oksidna prevlaka na titanu dobijena sol-gel postupkom kao anoda za katodnu zaštitu u morskoj vodi
VL  - 72
IS  - 12
SP  - 1393
EP  - 1402
DO  - 10.2298/JSC0712393P
ER  - 

@article{
author = "Panić, Vladimir and Nikolic, Branislav Z.",
year = "2007",
abstract = "The characteristics of a ternary oxide coating, on titanium, which consisted of TiO2, RuO2 and IrO2 in the molar ratio 0.6:0.3:0.1, calculated on the metal atom, were investigated for potential application for cathodic protection in a seawater environment. The oxide coatings on titanium were prepared by the sol-gel procedure from a mixture of inorganic oxide sols, which were obtained by forced hydrolysis of metal chlorides. The morphology of the coating was examined by scanning electron microscopy. The electrochemical properties of activated titanium anodes were investigated by cyclic voltammetry and polarization measurements in a H2SO4- and NaCl-containing electrolyte, as well as in seawater sampled on the Adriatic coast in Tivat, Montenegro. The anode stability during operation in seawater was investigated by the galvanostatic accelerated corrosion stability test. The morphology and electrochemical characteristics of the ternary coating are compared to that of a sol-gel-prepared binary Ti0.6Ru0.4O2 coating. The activity of the ternary coating was similar to that of the binary Ti0.6Ru0.4O2 coating in the investigated solutions. However, the stability in seawater is found to be considerably greater for the ternary coating., Karakteristike trojne oksidne prevlake na titanu, koja se sastoji od TiO2, RuO2 i IrO2 u molskom odnosu 0.6:0.3:0.1 računato na atom metala, ispitivane su sa ciljem potencijalne primene za katodnu zaštitu u morskoj vodi. Oksidna prevlaka na titanu formirana je sol-gel postupkom iz smeše neorganskih oksidnih solova, koji su dobijeni forsiranom hidrolizom hlorida metala. Morfologija prevlake je ispitivana skenirajućom elektronskom mikroskopijom, dok su elektrohemijska svojstva aktiviranih titankih anoda ispitivana metodom ciklične voltametrije i polarizacionim merenjima u rastvorima H2SO4, NaCl i u realnim uslovima, u morskoj vodi uzorkovanoj iz Jadranskog mora (Tivat, Crna Gora). Stabilnost anode tokom rada u morskoj vodi ispitivana je galvanostatski, ubrzanim testom stabilnosti. Dobijene prevlake upoređene su sa dvojnom Ti0,6Ru0,4O2 prevlakom, u pogledu morfologije i elektrohemiskih karakteristika. Pokazano je da su trojna i dvojna prevlaka slične aktivnosti u ispitivanim rastvorima. Međutim, u morskoj vodi stabilnost trojne prevlake je znatno veća.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Sol-gel prepared active ternary oxide coating on titanium in cathodic protection, Aktivna oksidna prevlaka na titanu dobijena sol-gel postupkom kao anoda za katodnu zaštitu u morskoj vodi",
volume = "72",
number = "12",
pages = "1393-1402",
doi = "10.2298/JSC0712393P"
}

Panić, V.,& Nikolic, B. Z.. (2007). Sol-gel prepared active ternary oxide coating on titanium in cathodic protection. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 72(12), 1393-1402.
https://doi.org/10.2298/JSC0712393P

Panić V, Nikolic BZ. Sol-gel prepared active ternary oxide coating on titanium in cathodic protection. in Journal of the Serbian Chemical Society. 2007;72(12):1393-1402.
doi:10.2298/JSC0712393P .

Panić, Vladimir, Nikolic, Branislav Z., "Sol-gel prepared active ternary oxide coating on titanium in cathodic protection" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1393-1402,
https://doi.org/10.2298/JSC0712393P . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B. Ž.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3413
AB  - Electrocatalytic properties of
RuO
2
/Ti
anode with different coating masses, which are prepared by
the alkoxide sol–gel procedure, are investigated in chlorine and oxygen evolution reactions by polarization
measurements and electrochemical impedance spectroscopy in
H
2
SO
4
and NaCl electrolytes. According to
polarization measurements, the activity of anodes at overpotentials below 100 mV is independent of coating
mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine
evolution reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered
in low-frequency domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V
(SCE). The observed impedance behavior is discussed with respect to the activity model for activated titanium
anodes in chlorine evolution reaction involving formation of gas channels within porous coating structure. Gas
channels enhance the mass transfer rate similarly to the forced convection, which also increases the activity of
anode. This is more pronounced for the anode of greater coating mass due to its more compact surface structure.
The more compact structure appears to be beneficial for gas channels formation.
PB  - Springer
T2  - Russian Journal of Electrochemistry
T1  - Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions
VL  - 42
IS  - 10
SP  - 1055
EP  - 1060
DO  - 10.1134/S1023193506100107
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, B. Ž.",
year = "2006",
abstract = "Electrocatalytic properties of
RuO
2
/Ti
anode with different coating masses, which are prepared by
the alkoxide sol–gel procedure, are investigated in chlorine and oxygen evolution reactions by polarization
measurements and electrochemical impedance spectroscopy in
H
2
SO
4
and NaCl electrolytes. According to
polarization measurements, the activity of anodes at overpotentials below 100 mV is independent of coating
mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine
evolution reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered
in low-frequency domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V
(SCE). The observed impedance behavior is discussed with respect to the activity model for activated titanium
anodes in chlorine evolution reaction involving formation of gas channels within porous coating structure. Gas
channels enhance the mass transfer rate similarly to the forced convection, which also increases the activity of
anode. This is more pronounced for the anode of greater coating mass due to its more compact surface structure.
The more compact structure appears to be beneficial for gas channels formation.",
publisher = "Springer",
journal = "Russian Journal of Electrochemistry",
title = "Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions",
volume = "42",
number = "10",
pages = "1055-1060",
doi = "10.1134/S1023193506100107"
}

Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B. Ž.. (2006). Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions. in Russian Journal of Electrochemistry
Springer., 42(10), 1055-1060.
https://doi.org/10.1134/S1023193506100107

Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić BŽ. Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions. in Russian Journal of Electrochemistry. 2006;42(10):1055-1060.
doi:10.1134/S1023193506100107 .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, B. Ž., "Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions" in Russian Journal of Electrochemistry, 42, no. 10 (2006):1055-1060,
https://doi.org/10.1134/S1023193506100107 . .

TY  - JOUR
AU  - Jegdić, Bore
AU  - Dražić, Dragutin M.
AU  - Popić, Jovan P.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/257
AB  - The potentiodynamic study of the electrochemical behavior of austenitic 304 stainless steel in deaerated aqueous sulfuric acid of pH 1 revealed that the steel achieved a stable corrosion potential of ca. - 0.350 V (SCE) independent of whether the electrode had previously been cathodically "activated" or anodically passivated. It was also shown that the experimentally observed anodic peak was not the usually obtained anodic passivation peak, as is the case with a number of metal, but an artifact due to the anodic oxidation of hydrogen absorbed during the previously employed cathodic polarization and hydrogen evolution, intended to activate the initially passive surface, or even hydrogen absorbed on the open circuit potential. It was shown that this potential establishes and electrochemical corrosion potential of the Wagner-Traud type due to the evolution of cathodic hydrogen on a passivated steel surface and anodic metal dissolution through the passive layer. It was impossible to activate 304 stainless steel in sulfuric acid of pH 1 by cathodic polarization, and the usually observed anodic peak obtained under these conditions should not be considered as an active metal dissolution process and a passivation anodic peak, but rather as an artifact due to the electrochemical oxidation of the in the steel absorbed hydrogen.
AB  - Potenciodinamička ispitivanja elektrohemijskog ponašanja nerđajućeg čelika 304 u deaeriranoj sumpornoj kiselini sa pH 1 pokazala su da se na čeliku uspostavlja stabilan korozioni potencijal od - 0,350 V(ZKE) nezavisno od toga da li je elektroda prethodno katodno tretirana radi "aktivacije", ili je površina bila pasivirana. Pokazano je, takođe, da eksperimentalno dobijeni anodni maksimum na potenciodinamičkoj krivi pozitivnije od korozionog potencijala nije anodni pasivacioni maksimum koji se obično dobija pri anodnoj polarizaciji većeg broja metala u sličnim uslovima, već eksperimentalni artefakt koji nastaje zbog anodne oksidacije vodonika apsorbovanog unutar čelika tokom katodnog "aktiviranja" ili čak i pri dužem držanju na korozionom potencijalu. Pokazano je da je spontano formirani potencijal otvorenog kola zapravo korozioni potencijal koji nastaje kao mešoviti potencijal Vagner-Traudovog tipa suprotnim delovawem katodne reakcije izdvajanja vodonika na pasivnom sloju i anodnog rastvaranja čelika kroz pasivni sloj. Nije bilo mogućno katodnom "aktivacijom" i dugotrajnijom katodnom polarizacijom do značajno negativnih potencijala i vrlo velikih katodnih struja da se pasivni sloj ukloni i postigne aktivno elektrohemijsko rastvaranje metala bez prisustva pasivnog sloja, tj. slobodna metalna površina. Stoga, često eksperimentalno konstatovan anodni maksimum na ovakvim čelicima ne treba da se interpretira kao anodno rastvaranje sa pasivacionim maksimumom, već kao posledica anodne oksidacije apsorbovanog vodonika u pasivnom čeliku, a koji se pod ovim uslovima ne može elektrohemijski aktivirati, odn. depasivirati.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Corrosion potential of 304 stainless steel in sulfuric acid
T1  - Korozioni potencijal nerđajućeg čelika 304 u sumpornoj kiselini
VL  - 71
IS  - 5
SP  - 543
EP  - 551
DO  - 10.2298/JSC0605543J
ER  - 

@article{
author = "Jegdić, Bore and Dražić, Dragutin M. and Popić, Jovan P.",
year = "2006",
abstract = "The potentiodynamic study of the electrochemical behavior of austenitic 304 stainless steel in deaerated aqueous sulfuric acid of pH 1 revealed that the steel achieved a stable corrosion potential of ca. - 0.350 V (SCE) independent of whether the electrode had previously been cathodically "activated" or anodically passivated. It was also shown that the experimentally observed anodic peak was not the usually obtained anodic passivation peak, as is the case with a number of metal, but an artifact due to the anodic oxidation of hydrogen absorbed during the previously employed cathodic polarization and hydrogen evolution, intended to activate the initially passive surface, or even hydrogen absorbed on the open circuit potential. It was shown that this potential establishes and electrochemical corrosion potential of the Wagner-Traud type due to the evolution of cathodic hydrogen on a passivated steel surface and anodic metal dissolution through the passive layer. It was impossible to activate 304 stainless steel in sulfuric acid of pH 1 by cathodic polarization, and the usually observed anodic peak obtained under these conditions should not be considered as an active metal dissolution process and a passivation anodic peak, but rather as an artifact due to the electrochemical oxidation of the in the steel absorbed hydrogen., Potenciodinamička ispitivanja elektrohemijskog ponašanja nerđajućeg čelika 304 u deaeriranoj sumpornoj kiselini sa pH 1 pokazala su da se na čeliku uspostavlja stabilan korozioni potencijal od - 0,350 V(ZKE) nezavisno od toga da li je elektroda prethodno katodno tretirana radi "aktivacije", ili je površina bila pasivirana. Pokazano je, takođe, da eksperimentalno dobijeni anodni maksimum na potenciodinamičkoj krivi pozitivnije od korozionog potencijala nije anodni pasivacioni maksimum koji se obično dobija pri anodnoj polarizaciji većeg broja metala u sličnim uslovima, već eksperimentalni artefakt koji nastaje zbog anodne oksidacije vodonika apsorbovanog unutar čelika tokom katodnog "aktiviranja" ili čak i pri dužem držanju na korozionom potencijalu. Pokazano je da je spontano formirani potencijal otvorenog kola zapravo korozioni potencijal koji nastaje kao mešoviti potencijal Vagner-Traudovog tipa suprotnim delovawem katodne reakcije izdvajanja vodonika na pasivnom sloju i anodnog rastvaranja čelika kroz pasivni sloj. Nije bilo mogućno katodnom "aktivacijom" i dugotrajnijom katodnom polarizacijom do značajno negativnih potencijala i vrlo velikih katodnih struja da se pasivni sloj ukloni i postigne aktivno elektrohemijsko rastvaranje metala bez prisustva pasivnog sloja, tj. slobodna metalna površina. Stoga, često eksperimentalno konstatovan anodni maksimum na ovakvim čelicima ne treba da se interpretira kao anodno rastvaranje sa pasivacionim maksimumom, već kao posledica anodne oksidacije apsorbovanog vodonika u pasivnom čeliku, a koji se pod ovim uslovima ne može elektrohemijski aktivirati, odn. depasivirati.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Corrosion potential of 304 stainless steel in sulfuric acid, Korozioni potencijal nerđajućeg čelika 304 u sumpornoj kiselini",
volume = "71",
number = "5",
pages = "543-551",
doi = "10.2298/JSC0605543J"
}

Jegdić, B., Dražić, D. M.,& Popić, J. P.. (2006). Corrosion potential of 304 stainless steel in sulfuric acid. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 71(5), 543-551.
https://doi.org/10.2298/JSC0605543J

Jegdić B, Dražić DM, Popić JP. Corrosion potential of 304 stainless steel in sulfuric acid. in Journal of the Serbian Chemical Society. 2006;71(5):543-551.
doi:10.2298/JSC0605543J .

Jegdić, Bore, Dražić, Dragutin M., Popić, Jovan P., "Corrosion potential of 304 stainless steel in sulfuric acid" in Journal of the Serbian Chemical Society, 71, no. 5 (2006):543-551,
https://doi.org/10.2298/JSC0605543J . .

TY  - JOUR
AU  - Jegdić, Bore
AU  - Dražić, Dragutin M.
AU  - Popić, Jovan P.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/274
AB  - Open circuit potential measurements and cyclic voltammetry of chromium in deaerated aqueous H2SO4 solution of pH 1 without and containing NaCl in the concentration range 0.5 - 4 M revealed that chromium exhibits two stable open circuit potentials having the character of a Wagner-Traud corrosion potential. One, E corr.1, was established on the passive surface formed by exposing Cr previously to air or passivated potentiostacially in a controlled manner, and the second one, E corr,2, at the bare Cr surface obtained by prolonged cathodic activation. There is a small difference in the E corr,1 values as a function of the passive layer properties. Addition of NaCl accelerates the hydrogen evolution reaction on the passive surface to some extent, while the same reaction on the bare surface was not affected by NaCl. On the other hand, presence of NaCl accelerates the anodic reaction on the bare surface, and it activates the dissolution of the passive layer so that the passive currents increase with addition of NaCl. This effect is so large that at concentration of NaCl larger than 3 M, the destruction of the passive layer was so fast that in a matter of seconds the Cr was activated, and the only one stable corrosion potential observed was E corr.2. No pitting of Cr in the presence of NaCl was observed up to the transpassive potentials.
AB  - Merenja potencijala otvorenog kola, kao i merenja primenom ciklične voltametrije u deaerisanim vodenim rastvorima H 2SO4, pH1, bez i sa dodatkom NaCl u koncentracionom opsegu 0,5-4M, otkrila su da hrom pokazuje dva stabilna potencijala otvorenog kola koji imaju osobine Wagner-Traud-ovog korozionog potencijala. Jedan korozioni potencijal, E corr.1 , se uspostavljao na pasiviranoj površini, koja se formira prethodnim izlaganjem Cr vazduhu, ili poteciostatskim pasiviranjem na kontrolisan način, a drugi, E corr.2 , se obrazovao na goloj površini Cr koja je formirana katodnom aktivacijom u dovoljno dugom periodu vremena. Postoji izvesna mala razlika u vrednostima E corr.1 kao funkcija osobina pasivnog sloja. Dodatak NaCl u određenoj meri ubrzava reakciju izdvajanja vodonika na pasiviranoj površini, dok NaCl nema uticaja na istu reakciju na goloj površini Cr. Sa druge strane prisustvo NaCl ubrzava anodnu reakciju na goloj površini hroma i aktivira rastvaranje pasivnog sloja, tako da se struja pasivacije povećava sa dodatkom NaCl. Uticaj NaCl je toliko veliki, da pri koncentracijama većim od 3M, razaranje pasivnog sloja postaje brzo, da se Cr za vreme od nekoliko sekundi aktivira i tada se uočava samo jedan stabilni korozioni potencijal E corr.2 . Nije uočena pojava pitinga u prisustvu NaCl, sve do potencijala u transpasivnoj oblasti.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Influence of chloride ions on the open circuit potentials of chromium in deaerated sulfuric acid solutions
T1  - Uticaj hloridnih jona na potencijal otvorenog kola hroma u deaerisanim rastvorima sumporne kiseline
VL  - 71
IS  - 11
SP  - 1187
EP  - 1194
DO  - 10.2298/JSC0611187J
ER  - 

@article{
author = "Jegdić, Bore and Dražić, Dragutin M. and Popić, Jovan P.",
year = "2006",
abstract = "Open circuit potential measurements and cyclic voltammetry of chromium in deaerated aqueous H2SO4 solution of pH 1 without and containing NaCl in the concentration range 0.5 - 4 M revealed that chromium exhibits two stable open circuit potentials having the character of a Wagner-Traud corrosion potential. One, E corr.1, was established on the passive surface formed by exposing Cr previously to air or passivated potentiostacially in a controlled manner, and the second one, E corr,2, at the bare Cr surface obtained by prolonged cathodic activation. There is a small difference in the E corr,1 values as a function of the passive layer properties. Addition of NaCl accelerates the hydrogen evolution reaction on the passive surface to some extent, while the same reaction on the bare surface was not affected by NaCl. On the other hand, presence of NaCl accelerates the anodic reaction on the bare surface, and it activates the dissolution of the passive layer so that the passive currents increase with addition of NaCl. This effect is so large that at concentration of NaCl larger than 3 M, the destruction of the passive layer was so fast that in a matter of seconds the Cr was activated, and the only one stable corrosion potential observed was E corr.2. No pitting of Cr in the presence of NaCl was observed up to the transpassive potentials., Merenja potencijala otvorenog kola, kao i merenja primenom ciklične voltametrije u deaerisanim vodenim rastvorima H 2SO4, pH1, bez i sa dodatkom NaCl u koncentracionom opsegu 0,5-4M, otkrila su da hrom pokazuje dva stabilna potencijala otvorenog kola koji imaju osobine Wagner-Traud-ovog korozionog potencijala. Jedan korozioni potencijal, E corr.1 , se uspostavljao na pasiviranoj površini, koja se formira prethodnim izlaganjem Cr vazduhu, ili poteciostatskim pasiviranjem na kontrolisan način, a drugi, E corr.2 , se obrazovao na goloj površini Cr koja je formirana katodnom aktivacijom u dovoljno dugom periodu vremena. Postoji izvesna mala razlika u vrednostima E corr.1 kao funkcija osobina pasivnog sloja. Dodatak NaCl u određenoj meri ubrzava reakciju izdvajanja vodonika na pasiviranoj površini, dok NaCl nema uticaja na istu reakciju na goloj površini Cr. Sa druge strane prisustvo NaCl ubrzava anodnu reakciju na goloj površini hroma i aktivira rastvaranje pasivnog sloja, tako da se struja pasivacije povećava sa dodatkom NaCl. Uticaj NaCl je toliko veliki, da pri koncentracijama većim od 3M, razaranje pasivnog sloja postaje brzo, da se Cr za vreme od nekoliko sekundi aktivira i tada se uočava samo jedan stabilni korozioni potencijal E corr.2 . Nije uočena pojava pitinga u prisustvu NaCl, sve do potencijala u transpasivnoj oblasti.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Influence of chloride ions on the open circuit potentials of chromium in deaerated sulfuric acid solutions, Uticaj hloridnih jona na potencijal otvorenog kola hroma u deaerisanim rastvorima sumporne kiseline",
volume = "71",
number = "11",
pages = "1187-1194",
doi = "10.2298/JSC0611187J"
}

Jegdić, B., Dražić, D. M.,& Popić, J. P.. (2006). Influence of chloride ions on the open circuit potentials of chromium in deaerated sulfuric acid solutions. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 71(11), 1187-1194.
https://doi.org/10.2298/JSC0611187J

Jegdić B, Dražić DM, Popić JP. Influence of chloride ions on the open circuit potentials of chromium in deaerated sulfuric acid solutions. in Journal of the Serbian Chemical Society. 2006;71(11):1187-1194.
doi:10.2298/JSC0611187J .

Jegdić, Bore, Dražić, Dragutin M., Popić, Jovan P., "Influence of chloride ions on the open circuit potentials of chromium in deaerated sulfuric acid solutions" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1187-1194,
https://doi.org/10.2298/JSC0611187J . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, Branislav
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/275
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
AB  - Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
T1  - Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom
VL  - 71
IS  - 11
SP  - 1173
EP  - 1186
DO  - 10.2298/JSC0611173P
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, Branislav",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass., Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route, Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom",
volume = "71",
number = "11",
pages = "1173-1186",
doi = "10.2298/JSC0611173P"
}

Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 71(11), 1173-1186.
https://doi.org/10.2298/JSC0611173P

Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić B. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
doi:10.2298/JSC0611173P .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, Branislav, "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://doi.org/10.2298/JSC0611173P . .