TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Bajat, Jelena
AU  - Jokić, Bojan
AU  - Panić, Vladimir
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1975
AB  - Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.
PB  - Springer, New York
T2  - Journal of Solid State Electrochemistry
T1  - Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium
VL  - 20
IS  - 1
SP  - 293
EP  - 303
DO  - 10.1007/s10008-015-3040-3
ER  - 

@article{
author = "Gulicovski, Jelena and Bajat, Jelena and Jokić, Bojan and Panić, Vladimir and Mišković-Stanković, Vesna and Milonjić, Slobodan K.",
year = "2016",
abstract = "Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.",
publisher = "Springer, New York",
journal = "Journal of Solid State Electrochemistry",
title = "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium",
volume = "20",
number = "1",
pages = "293-303",
doi = "10.1007/s10008-015-3040-3"
}

Gulicovski, J., Bajat, J., Jokić, B., Panić, V., Mišković-Stanković, V.,& Milonjić, S. K.. (2016). Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry
Springer, New York., 20(1), 293-303.
https://doi.org/10.1007/s10008-015-3040-3

Gulicovski J, Bajat J, Jokić B, Panić V, Mišković-Stanković V, Milonjić SK. Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry. 2016;20(1):293-303.
doi:10.1007/s10008-015-3040-3 .

Gulicovski, Jelena, Bajat, Jelena, Jokić, Bojan, Panić, Vladimir, Mišković-Stanković, Vesna, Milonjić, Slobodan K., "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium" in Journal of Solid State Electrochemistry, 20, no. 1 (2016):293-303,
https://doi.org/10.1007/s10008-015-3040-3 . .

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Bajat, Jelena
AU  - Mišković-Stanković, Vesna
AU  - Jokić, Bojan
AU  - Panić, Vladimir
AU  - Milonjić, Slobodan
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3442
AB  - CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, pre­viously prepared by forced hydrolysis of Ce(NO3)4. The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coa­tings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are sub­jected to more pronounced diffusion limitations in com­parison to the processes below passive aluminum oxide film, as the consequence of the formation of highly com­pact protective coating. The results show that the deposi­tion of ceria coatings is an effective way to improve corro­sion resistance for aluminum.
PB  - International Association of Physical Chemists (IAPC)
T2  - Journal of Electrochemical Science and Engineering
T1  - Cerium oxide as conversion coating for the corrosion protection of aluminum
VL  - 3
IS  - 4
SP  - 151
EP  - 156
DO  - 10.5599/jese.2013.0037
ER  - 

@article{
author = "Gulicovski, Jelena and Bajat, Jelena and Mišković-Stanković, Vesna and Jokić, Bojan and Panić, Vladimir and Milonjić, Slobodan",
year = "2013",
abstract = "CeO2 coatings were formed on the aluminum after Al surface preparation, by dripping the ceria sol, pre­viously prepared by forced hydrolysis of Ce(NO3)4. The anticorrosive properties of ceria coatings were investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to 0.03% NaCl. The morphology of the coa­tings was examined by the scanning electron microscopy (SEM). EIS data indicated considerably larger corrosion resistance of CeO2-coated aluminum than for bare Al. The corrosion processes on Al below CeO2 coating are sub­jected to more pronounced diffusion limitations in com­parison to the processes below passive aluminum oxide film, as the consequence of the formation of highly com­pact protective coating. The results show that the deposi­tion of ceria coatings is an effective way to improve corro­sion resistance for aluminum.",
publisher = "International Association of Physical Chemists (IAPC)",
journal = "Journal of Electrochemical Science and Engineering",
title = "Cerium oxide as conversion coating for the corrosion protection of aluminum",
volume = "3",
number = "4",
pages = "151-156",
doi = "10.5599/jese.2013.0037"
}

Gulicovski, J., Bajat, J., Mišković-Stanković, V., Jokić, B., Panić, V.,& Milonjić, S.. (2013). Cerium oxide as conversion coating for the corrosion protection of aluminum. in Journal of Electrochemical Science and Engineering
International Association of Physical Chemists (IAPC)., 3(4), 151-156.
https://doi.org/10.5599/jese.2013.0037

Gulicovski J, Bajat J, Mišković-Stanković V, Jokić B, Panić V, Milonjić S. Cerium oxide as conversion coating for the corrosion protection of aluminum. in Journal of Electrochemical Science and Engineering. 2013;3(4):151-156.
doi:10.5599/jese.2013.0037 .

Gulicovski, Jelena, Bajat, Jelena, Mišković-Stanković, Vesna, Jokić, Bojan, Panić, Vladimir, Milonjić, Slobodan, "Cerium oxide as conversion coating for the corrosion protection of aluminum" in Journal of Electrochemical Science and Engineering, 3, no. 4 (2013):151-156,
https://doi.org/10.5599/jese.2013.0037 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mitrić, Miodrag
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolic, Branislav Z.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/638
AB  - Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.
PB  - Royal Soc Chemistry, Cambridge
T2  - Physical Chemistry Chemical Physics
T1  - The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties
VL  - 12
IS  - 27
SP  - 7521
EP  - 7528
DO  - 10.1039/b921582d
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mitrić, Miodrag and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolic, Branislav Z.",
year = "2010",
abstract = "Electrochemical properties of sol-gel processed Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings on titanium substrate were investigated using cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy and compared to the properties of Ti(0.6)Ru(0.4)O(2) coating. The role of iridium oxide in the improvement of the electrocatalytic, capacitive and stability properties of titanium anodes activated by a RuO(2)-TiO(2) coating is discussed. The oxide sols were prepared by forced hydrolysis of the metal chlorides. The characterization by dynamic light scattering and X-ray diffraction showed that polydisperse oxide sols were obtained with the particles tending to form agglomerates. The presence of IrO(2) causes a suppression of the X-ray diffraction peaks of TiO(2) and RuO(2) in the sol-gel prepared Ti(0.6)Ir(0.4)O(2) and Ti(0.6)Ru(0.3)Ir(0.1)O(2) coatings. The IrO(2)-containing coatings had an enhanced charge storage ability and activity for the oxygen evolution reaction (OER) in comparison to Ti(0.6)Ru(0.4)O(2) coating. The voltammogram of the Ti(0.6)Ir(0.4)O(2)/Ti electrode showed well-resolved peaks related to Ir redox transitions, which are responsible for the enhanced charge storage ability of IrO(2)-containing coatings. Redox transitions of Ir were also registered in the high-frequency domain of the ac impedance spectra of the coatings as a semicircle with characteristics insensitive to the electrolyte composition and to the electrode potential prior to OER. However, the semicircle characteristics were different for the two IrO(2)-containing coatings, as well as at potentials outside the OER in comparison to those at which the OER occurs.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Physical Chemistry Chemical Physics",
title = "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties",
volume = "12",
number = "27",
pages = "7521-7528",
doi = "10.1039/b921582d"
}

Panić, V., Dekanski, A., Mitrić, M., Milonjić, S. K., Mišković-Stanković, V.,& Nikolic, B. Z.. (2010). The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics
Royal Soc Chemistry, Cambridge., 12(27), 7521-7528.
https://doi.org/10.1039/b921582d

Panić V, Dekanski A, Mitrić M, Milonjić SK, Mišković-Stanković V, Nikolic BZ. The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties. in Physical Chemistry Chemical Physics. 2010;12(27):7521-7528.
doi:10.1039/b921582d .

Panić, Vladimir, Dekanski, Aleksandar, Mitrić, Miodrag, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolic, Branislav Z., "The effect of the addition of colloidal iridium oxide into sol-gel obtained titanium and ruthenium oxide coatings on titanium on their electrochemical properties" in Physical Chemistry Chemical Physics, 12, no. 27 (2010):7521-7528,
https://doi.org/10.1039/b921582d . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
AU  - Nikolic, Branislav Z.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/676
AB  - The electrochemical characteristics of Ti0.6Ir0.4O2/Ti and Ti0.6Ru0.4O2/Ti anodes prepared by the sol-gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H2SO4 solution indicate that Ti0.6Ir0.4O2/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 VSCE, this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti0.6Ru0.4O2/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti0.6Ir0.4O2/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti0.6Ru0.4O2/ /Ti electrode behaved like a capacitor over a wider potential range than the Ti0.6Ir0.4O2/Ti electrode, with fully-developed pseudocapacitive properties at potentials positive to 0.60 VSCE. However, the impedance characteristics of the Ti0.6Ir0.4O2/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior.
AB  - U radu su ispitivane elektrohemijske karakteristike Ti0,6Ir0,4O2/Ti i Ti0,6Ru0,4O2/Ti anoda dobijenih sol-gel postupkom iz oksidnih solova sintetisanih forsiranom hidrolizom odgovarajućih hlorida metala. Voltametrijske karakteristike u rastvoru H2SO4 ukazuju na više izraženo pseudokapacitivno ponašanje Ti0,6Ir0,4O2/Ti elektrode koje je posledica površinskih redoks prelaza u čvrstom stanju uz učešće protona. Na potencijalima negativnijim od 0,0 VZKE ova elektroda pokazuje slabu provodnost i aktivnost, dok voltametrijskim ponašanjem Ti0,6Ru0,4O2/Ti elektrode dominira prodor protona u strukturu oksida. Ti0,6Ir0,4O2/Ti anoda je elektrokatalitički aktivnija za reakciju izdvajanja kiseonika, dok su anode sličnih aktivnosti za reakciju izdvajanja hlora. Impedansne karakteristike formiranih anoda pokazuju da se Ti0,6Ru0,4O2/Ti elektroda ponaša slično kondenzatoru u širem opsegu potencijala nego što je to slučaj sa Ti0,6Ir0,4O2/Ti elektrodom, sa potpuno razvijenim pseudokapacitivnim svojstvima na potencijalima pozitivnijim od 0,60 VZKE. S druge strane, za Ti0,6Ir0,4O2/Ti elektrodu se uočava prelaz sa karakteristika sličnih otporniku na karakteristike slične kondenzatoru sa porastom potencijala elektrode.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure
T1  - Razlike u elektrohemijskom ponašanju oksida rutenijuma i iridijuma u elektrokatalitičkim prevlakama aktiviranih titanskih anoda dobijenih sol-gel postupkom
VL  - 75
IS  - 10
SP  - 1413
EP  - 1420
DO  - 10.2298/JSC100310078P
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Milonjić, Slobodan K. and Nikolic, Branislav Z.",
year = "2010",
abstract = "The electrochemical characteristics of Ti0.6Ir0.4O2/Ti and Ti0.6Ru0.4O2/Ti anodes prepared by the sol-gel procedure from the corresponding oxide sols, obtained by force hydrolysis of the corresponding metal chlorides, were compared. The voltammetric properties in H2SO4 solution indicate that Ti0.6Ir0.4O2/Ti has more pronounced pseudocapacitive characteristics, caused by proton-assisted, solid state surface redox transitions of the oxide. At potentials negative to 0.0 VSCE, this electrode is of poor conductivity and activity, while the voltammetric behavior of the Ti0.6Ru0.4O2/Ti electrode is governed by proton injection/ejection into the oxide structure. The Ti0.6Ir0.4O2/Ti electrode had a higher electrocatalytical activity for oxygen evolution, while the investigated anodes were of similar activity for chlorine evolution. The potential dependence of the impedance characteristics showed that the Ti0.6Ru0.4O2/ /Ti electrode behaved like a capacitor over a wider potential range than the Ti0.6Ir0.4O2/Ti electrode, with fully-developed pseudocapacitive properties at potentials positive to 0.60 VSCE. However, the impedance characteristics of the Ti0.6Ir0.4O2/Ti electrode changed with increasing potential from resistor-like to capacitor-like behavior., U radu su ispitivane elektrohemijske karakteristike Ti0,6Ir0,4O2/Ti i Ti0,6Ru0,4O2/Ti anoda dobijenih sol-gel postupkom iz oksidnih solova sintetisanih forsiranom hidrolizom odgovarajućih hlorida metala. Voltametrijske karakteristike u rastvoru H2SO4 ukazuju na više izraženo pseudokapacitivno ponašanje Ti0,6Ir0,4O2/Ti elektrode koje je posledica površinskih redoks prelaza u čvrstom stanju uz učešće protona. Na potencijalima negativnijim od 0,0 VZKE ova elektroda pokazuje slabu provodnost i aktivnost, dok voltametrijskim ponašanjem Ti0,6Ru0,4O2/Ti elektrode dominira prodor protona u strukturu oksida. Ti0,6Ir0,4O2/Ti anoda je elektrokatalitički aktivnija za reakciju izdvajanja kiseonika, dok su anode sličnih aktivnosti za reakciju izdvajanja hlora. Impedansne karakteristike formiranih anoda pokazuju da se Ti0,6Ru0,4O2/Ti elektroda ponaša slično kondenzatoru u širem opsegu potencijala nego što je to slučaj sa Ti0,6Ir0,4O2/Ti elektrodom, sa potpuno razvijenim pseudokapacitivnim svojstvima na potencijalima pozitivnijim od 0,60 VZKE. S druge strane, za Ti0,6Ir0,4O2/Ti elektrodu se uočava prelaz sa karakteristika sličnih otporniku na karakteristike slične kondenzatoru sa porastom potencijala elektrode.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure, Razlike u elektrohemijskom ponašanju oksida rutenijuma i iridijuma u elektrokatalitičkim prevlakama aktiviranih titanskih anoda dobijenih sol-gel postupkom",
volume = "75",
number = "10",
pages = "1413-1420",
doi = "10.2298/JSC100310078P"
}

Panić, V., Dekanski, A., Mišković-Stanković, V., Milonjić, S. K.,& Nikolic, B. Z.. (2010). Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 75(10), 1413-1420.
https://doi.org/10.2298/JSC100310078P

Panić V, Dekanski A, Mišković-Stanković V, Milonjić SK, Nikolic BZ. Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2010;75(10):1413-1420.
doi:10.2298/JSC100310078P .

Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Milonjić, Slobodan K., Nikolic, Branislav Z., "Differences in the electrochemical behavior of ruthenium and iridium oxide in electrocatalytic coatings of activated titanium anodes prepared by the sol-gel procedure" in Journal of the Serbian Chemical Society, 75, no. 10 (2010):1413-1420,
https://doi.org/10.2298/JSC100310078P . .

TY  - JOUR
AU  - Lazarević, Slavica
AU  - Janković-Častvan, Ivona
AU  - Jovanović, Dušan
AU  - Milonjić, Slobodan
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4122
AB  - The adsorption mechanisms of Pb2+, Cd2+ and Sr2+ ions on natural sepiolite and the influence of acid treatment on the adsorption capacity of sepiolite were investigated. The point of zero charge, pHpzc, is 7.4 ± 0.1 for natural sepiolite and 6.9 ± 0.1 for partially acid-activated sepiolite. The shift of the pHpzc of sepiolites toward lower pH values in solutions of Pb2+ and Cd2+ ions indicates that specific adsorption of these cations on natural and acid-activated sepiolites occurred, which was more pronounced for Pb2+ ions than for Cd2+ ions. There was no shift of the pHpzc in solution containing Sr2+ ions, suggesting that specific adsorption of this cation did not occur. The affinity for ion exchange with the Mg2+ ions from the sepiolite structure was the highest for Pb2+ ions, then Cd2+, whereas the affinity for Sr2+ ions was negligible. The adsorption isotherms suggest that the sequence of the efficiency of the sepiolites adsorption is Pb2+ > Cd2+ > Sr2+. The retention of Pb2+ and Cd2+ ions by sepiolite occurs dominantly by specific adsorption and exchange of Mg2+ ions from the sepiolite structure. The concentration in the external outer sphere of the Stern layer by electrostatic forces is the dominant mechanism for the retention of Sr2+ ions on the surface of sepiolites. Despite increases in the surface areas upon acid activation, improvements in the adsorption were not observed, as a result of the decreasing number of Mg-OH groups, as main centers for specific adsorption, and the number of Mg2+ ions available for ion exchange with Pb2+, Cd2+ and Sr2+ ions. The removal of Mg-OH groups from the sepiolite also resulted in a decrease in the point of zero charge and an increase of the relative surface acidity, from 2.6 ± 0.1 for the natural to 6.4 ± 0.1 for the acid-activated sepiolite.
PB  - Elsevier
T2  - Applied Clay Science
T1  - Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites
VL  - 37
IS  - 1-2
SP  - 47
EP  - 57
DO  - 10.1016/j.clay.2006.11.008
ER  - 

@article{
author = "Lazarević, Slavica and Janković-Častvan, Ivona and Jovanović, Dušan and Milonjić, Slobodan and Janaćković, Đorđe and Petrović, Rada",
year = "2007",
abstract = "The adsorption mechanisms of Pb2+, Cd2+ and Sr2+ ions on natural sepiolite and the influence of acid treatment on the adsorption capacity of sepiolite were investigated. The point of zero charge, pHpzc, is 7.4 ± 0.1 for natural sepiolite and 6.9 ± 0.1 for partially acid-activated sepiolite. The shift of the pHpzc of sepiolites toward lower pH values in solutions of Pb2+ and Cd2+ ions indicates that specific adsorption of these cations on natural and acid-activated sepiolites occurred, which was more pronounced for Pb2+ ions than for Cd2+ ions. There was no shift of the pHpzc in solution containing Sr2+ ions, suggesting that specific adsorption of this cation did not occur. The affinity for ion exchange with the Mg2+ ions from the sepiolite structure was the highest for Pb2+ ions, then Cd2+, whereas the affinity for Sr2+ ions was negligible. The adsorption isotherms suggest that the sequence of the efficiency of the sepiolites adsorption is Pb2+ > Cd2+ > Sr2+. The retention of Pb2+ and Cd2+ ions by sepiolite occurs dominantly by specific adsorption and exchange of Mg2+ ions from the sepiolite structure. The concentration in the external outer sphere of the Stern layer by electrostatic forces is the dominant mechanism for the retention of Sr2+ ions on the surface of sepiolites. Despite increases in the surface areas upon acid activation, improvements in the adsorption were not observed, as a result of the decreasing number of Mg-OH groups, as main centers for specific adsorption, and the number of Mg2+ ions available for ion exchange with Pb2+, Cd2+ and Sr2+ ions. The removal of Mg-OH groups from the sepiolite also resulted in a decrease in the point of zero charge and an increase of the relative surface acidity, from 2.6 ± 0.1 for the natural to 6.4 ± 0.1 for the acid-activated sepiolite.",
publisher = "Elsevier",
journal = "Applied Clay Science",
title = "Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites",
volume = "37",
number = "1-2",
pages = "47-57",
doi = "10.1016/j.clay.2006.11.008"
}

Lazarević, S., Janković-Častvan, I., Jovanović, D., Milonjić, S., Janaćković, Đ.,& Petrović, R.. (2007). Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites. in Applied Clay Science
Elsevier., 37(1-2), 47-57.
https://doi.org/10.1016/j.clay.2006.11.008

Lazarević S, Janković-Častvan I, Jovanović D, Milonjić S, Janaćković Đ, Petrović R. Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites. in Applied Clay Science. 2007;37(1-2):47-57.
doi:10.1016/j.clay.2006.11.008 .

Lazarević, Slavica, Janković-Častvan, Ivona, Jovanović, Dušan, Milonjić, Slobodan, Janaćković, Đorđe, Petrović, Rada, "Adsorption of Pb2+, Cd2+ and Sr2+ ions onto natural and acid-activated sepiolites" in Applied Clay Science, 37, no. 1-2 (2007):47-57,
https://doi.org/10.1016/j.clay.2006.11.008 . .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
AU  - Milonjić, Slobodan K.
AU  - Jovanović, Slobodan M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/328
AB  - The possibility of polymer characterization by inverse gas chromatography (IGC) was illustrated with the study of sorption properties of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, synthesized by suspension copolymerization, and copolymer modified with ethylene diamine, PGME-en. The data collected from IGC experiments at infinite dilution are used for the calculation of the thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the acid/base constants. .
AB  - U okviru rada prikazane su mogućnosti korišćenja inverzne gasne hromatografije (IGC) za karakterizaciju polimera. Umreženi makroporozni kopolimer glicidilmetakrilata, GMA, i etilenglikoldimetakrilata, EGDMA, poli (GMA-co-EGDMA) sintetizovan je suspenzionom kopolimerizacijom, a zatim modifikovan reakcijom sa etilendiaminom. Uzorcima polaznog i modifikovanog kopolimera, poli(GMA-co-EGDMA)-en, su pri nultoj prekrivenosti određeni termodinamički parametri adsorpcije, disperzivna komponenta slobodne površinske energije i kiselo/bazna svojstva.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Application of inverse gas chromatography for polymer characterization
T1  - Primena inverzne gasne hromatografije za karakterizaciju polimera
VL  - 61
IS  - 6
SP  - 342
EP  - 349
DO  - 10.2298/HEMIND0706342N
ER  - 

@article{
author = "Nastasović, Aleksandra and Onjia, Antonije E. and Milonjić, Slobodan K. and Jovanović, Slobodan M.",
year = "2007",
abstract = "The possibility of polymer characterization by inverse gas chromatography (IGC) was illustrated with the study of sorption properties of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, synthesized by suspension copolymerization, and copolymer modified with ethylene diamine, PGME-en. The data collected from IGC experiments at infinite dilution are used for the calculation of the thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the acid/base constants. ., U okviru rada prikazane su mogućnosti korišćenja inverzne gasne hromatografije (IGC) za karakterizaciju polimera. Umreženi makroporozni kopolimer glicidilmetakrilata, GMA, i etilenglikoldimetakrilata, EGDMA, poli (GMA-co-EGDMA) sintetizovan je suspenzionom kopolimerizacijom, a zatim modifikovan reakcijom sa etilendiaminom. Uzorcima polaznog i modifikovanog kopolimera, poli(GMA-co-EGDMA)-en, su pri nultoj prekrivenosti određeni termodinamički parametri adsorpcije, disperzivna komponenta slobodne površinske energije i kiselo/bazna svojstva.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Application of inverse gas chromatography for polymer characterization, Primena inverzne gasne hromatografije za karakterizaciju polimera",
volume = "61",
number = "6",
pages = "342-349",
doi = "10.2298/HEMIND0706342N"
}

Nastasović, A., Onjia, A. E., Milonjić, S. K.,& Jovanović, S. M.. (2007). Application of inverse gas chromatography for polymer characterization. in Hemijska industrija
Association of Chemical Engineers of Serbia., 61(6), 342-349.
https://doi.org/10.2298/HEMIND0706342N

Nastasović A, Onjia AE, Milonjić SK, Jovanović SM. Application of inverse gas chromatography for polymer characterization. in Hemijska industrija. 2007;61(6):342-349.
doi:10.2298/HEMIND0706342N .

Nastasović, Aleksandra, Onjia, Antonije E., Milonjić, Slobodan K., Jovanović, Slobodan M., "Application of inverse gas chromatography for polymer characterization" in Hemijska industrija, 61, no. 6 (2007):342-349,
https://doi.org/10.2298/HEMIND0706342N . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B. Ž.
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3413
AB  - Electrocatalytic properties of
RuO
2
/Ti
anode with different coating masses, which are prepared by
the alkoxide sol–gel procedure, are investigated in chlorine and oxygen evolution reactions by polarization
measurements and electrochemical impedance spectroscopy in
H
2
SO
4
and NaCl electrolytes. According to
polarization measurements, the activity of anodes at overpotentials below 100 mV is independent of coating
mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine
evolution reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered
in low-frequency domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V
(SCE). The observed impedance behavior is discussed with respect to the activity model for activated titanium
anodes in chlorine evolution reaction involving formation of gas channels within porous coating structure. Gas
channels enhance the mass transfer rate similarly to the forced convection, which also increases the activity of
anode. This is more pronounced for the anode of greater coating mass due to its more compact surface structure.
The more compact structure appears to be beneficial for gas channels formation.
PB  - Springer
T2  - Russian Journal of Electrochemistry
T1  - Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions
VL  - 42
IS  - 10
SP  - 1055
EP  - 1060
DO  - 10.1134/S1023193506100107
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, B. Ž.",
year = "2006",
abstract = "Electrocatalytic properties of
RuO
2
/Ti
anode with different coating masses, which are prepared by
the alkoxide sol–gel procedure, are investigated in chlorine and oxygen evolution reactions by polarization
measurements and electrochemical impedance spectroscopy in
H
2
SO
4
and NaCl electrolytes. According to
polarization measurements, the activity of anodes at overpotentials below 100 mV is independent of coating
mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine
evolution reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered
in low-frequency domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V
(SCE). The observed impedance behavior is discussed with respect to the activity model for activated titanium
anodes in chlorine evolution reaction involving formation of gas channels within porous coating structure. Gas
channels enhance the mass transfer rate similarly to the forced convection, which also increases the activity of
anode. This is more pronounced for the anode of greater coating mass due to its more compact surface structure.
The more compact structure appears to be beneficial for gas channels formation.",
publisher = "Springer",
journal = "Russian Journal of Electrochemistry",
title = "Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions",
volume = "42",
number = "10",
pages = "1055-1060",
doi = "10.1134/S1023193506100107"
}

Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B. Ž.. (2006). Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions. in Russian Journal of Electrochemistry
Springer., 42(10), 1055-1060.
https://doi.org/10.1134/S1023193506100107

Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić BŽ. Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions. in Russian Journal of Electrochemistry. 2006;42(10):1055-1060.
doi:10.1134/S1023193506100107 .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, B. Ž., "Electrocatalytic Activity of Sol–Gel-Prepared RuO 2 /Ti Anode in Chlorine and Oxygen Evolution Reactions" in Russian Journal of Electrochemistry, 42, no. 10 (2006):1055-1060,
https://doi.org/10.1134/S1023193506100107 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, Branislav
PY  - 2006
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/275
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
AB  - Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
T1  - Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom
VL  - 71
IS  - 11
SP  - 1173
EP  - 1186
DO  - 10.2298/JSC0611173P
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, Branislav",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical properties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass., Titanske anode sa aktivnom prevlakom od oksida rutenijuma dve različite debljine, formirane su od oksida dobijenog hidrolizom rutenijum(III)-etoksida u etanolskom rastvoru ("ink" metoda). Morfologija dobijenog oksida ispitivana je skenirajućom elektronskom mikroskopijom. Ispitivana su elektrohemijska svojstva formiranih anoda, koja podrazumevaju ciklično-voltametrijsko ponašanje u rastvorima H 2SO4 i NaCl, aktivnost u reakcijama izdvajanja hlora i kiseonika, impedansno pona- šanje i stabilnost tokom elektrolize razblaženih rastvora hlorida. Karakteristike dobijenih anoda upoređene su sa karakteristikama anode formirane sol-gel postupkom iz oksidnog sola dobijenog forsiranom hidrolizom rutenijum(III)-hlorida u kiseloj sredini (5 mol dm-3HCl). Anode formirane alkoksidnim postupkom imaju veću kapacitivnost i aktivnost za reakciju izdvajanja hlora od anode dobijene sol-gel postupkom iz neorganskog sola. Rezultati testa stabilnosti u rastvoru hlorida pokazuju da je iskorišćenje aktivnog materijala prevlake takođe bolje kod anoda dobijenih alkoksidnim postupkom, naročito za anodu sa manjom debljinom prevlake. Rezultati ukazuju na to da u mehanizmu gubitka aktivnosti anoda dobijenih alkoksidnim postupkom elektrohemijsko rastvaranje oksida rutenijuma sa površine prevlake preovlađuje u odnosu na rast izolatorskog sloja oksida titana u međufazi prevlaka/ titanska podloga. Efekt rastvaranja RuO2 sa površine je izraženiji kod prevlake veće debljine.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route, Aktivnost i stabilnost titanskih anoda sa prevlakom od oksida rutenijuma dobijenom alkoksidnim postupkom",
volume = "71",
number = "11",
pages = "1173-1186",
doi = "10.2298/JSC0611173P"
}

Panić, V., Dekanski, A., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 71(11), 1173-1186.
https://doi.org/10.2298/JSC0611173P

Panić V, Dekanski A, Milonjić SK, Mišković-Stanković V, Nikolić B. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
doi:10.2298/JSC0611173P .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, Branislav, "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://doi.org/10.2298/JSC0611173P . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan
AU  - Nikolić, Branislav
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4134
AB  - The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was investigated. The loss of electrocatalytic activity was registered by an accelerated stability test in 0.50 mol dm-3 NaCl electrolyte, while the changes in the electrochemical properties were monitored during the stability test by cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy in 1.0 mol dm-3 HClO 4 and in 0.50 mol dm-3 NaCl. The changes in anode behavior suggest that the essential cause for the deactivation of the anode prepared by the sol-gel procedure is the formation of an insulating TiO 2-rich layer at the coating surface due to the continuous dissolution of the Ru active species. However, the growth of the insulating TiO2 layer in the coating/Ti substrate interphase mainly causes deactivation of the thermally prepared anode. The deactivation mechanism appeared to be the consequence of the different morphology of the coatings prepared by two different procedures.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure
VL  - 579
IS  - 1
SP  - 67
EP  - 76
DO  - 10.1016/j.jelechem.2005.01.026
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Milonjić, Slobodan and Nikolić, Branislav",
year = "2005",
abstract = "The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was investigated. The loss of electrocatalytic activity was registered by an accelerated stability test in 0.50 mol dm-3 NaCl electrolyte, while the changes in the electrochemical properties were monitored during the stability test by cyclic voltammetry, polarization measurements and electrochemical impedance spectroscopy in 1.0 mol dm-3 HClO 4 and in 0.50 mol dm-3 NaCl. The changes in anode behavior suggest that the essential cause for the deactivation of the anode prepared by the sol-gel procedure is the formation of an insulating TiO 2-rich layer at the coating surface due to the continuous dissolution of the Ru active species. However, the growth of the insulating TiO2 layer in the coating/Ti substrate interphase mainly causes deactivation of the thermally prepared anode. The deactivation mechanism appeared to be the consequence of the different morphology of the coatings prepared by two different procedures.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure",
volume = "579",
number = "1",
pages = "67-76",
doi = "10.1016/j.jelechem.2005.01.026"
}

Panić, V., Dekanski, A., Mišković-Stanković, V., Milonjić, S.,& Nikolić, B.. (2005). On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure. in Journal of Electroanalytical Chemistry
Elsevier., 579(1), 67-76.
https://doi.org/10.1016/j.jelechem.2005.01.026

Panić V, Dekanski A, Mišković-Stanković V, Milonjić S, Nikolić B. On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure. in Journal of Electroanalytical Chemistry. 2005;579(1):67-76.
doi:10.1016/j.jelechem.2005.01.026 .

Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Milonjić, Slobodan, Nikolić, Branislav, "On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure" in Journal of Electroanalytical Chemistry, 579, no. 1 (2005):67-76,
https://doi.org/10.1016/j.jelechem.2005.01.026 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Gojković, Snežana Lj.
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolic, B
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/193
AB  - The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.
PB  - Trans Tech Publications Ltd, Durnten-Zurich
T2  - Current Research in Advanced Materials and Processes
T1  - Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure
VL  - 494
SP  - 235
EP  - 240
DO  - 10.4028/www.scientific.net/MSF.494.235
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Gojković, Snežana Lj. and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolic, B",
year = "2005",
abstract = "The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcano (R) XC-72 R with solid phase of RuOxHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion (R) layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.",
publisher = "Trans Tech Publications Ltd, Durnten-Zurich",
journal = "Current Research in Advanced Materials and Processes",
title = "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure",
volume = "494",
pages = "235-240",
doi = "10.4028/www.scientific.net/MSF.494.235"
}

Panić, V., Dekanski, A., Gojković, S. Lj., Milonjić, S. K., Mišković-Stanković, V.,& Nikolic, B.. (2005). Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Current Research in Advanced Materials and Processes
Trans Tech Publications Ltd, Durnten-Zurich., 494, 235-240.
https://doi.org/10.4028/www.scientific.net/MSF.494.235

Panić V, Dekanski A, Gojković SL, Milonjić SK, Mišković-Stanković V, Nikolic B. Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Current Research in Advanced Materials and Processes. 2005;494:235-240.
doi:10.4028/www.scientific.net/MSF.494.235 .

Panić, Vladimir, Dekanski, Aleksandar, Gojković, Snežana Lj., Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolic, B, "Morphology and capacitive properties of [RuOxHy/low-surface area carbon black] composite materials prepared by sol-gel procedure" in Current Research in Advanced Materials and Processes, 494 (2005):235-240,
https://doi.org/10.4028/www.scientific.net/MSF.494.235 . .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
AU  - Milonjić, Slobodan K.
AU  - Vuković, Zorica
AU  - Jovanovic, SM
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/186
AB  - Inverse gas chromatography under finite surface coverage conditions (IGC-FC) was used for the investigation of sorption of hexane, benzene, chloroform and tetrahydrofuran on macroporous crosslinked poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)], poly(GMA-co-EGDMA), and copolymer modified with ethylene diamine, EDA, poly(GMA-co-EGDMA)-en, in the temperature range 333-363 K. Two poly(GMA-co-EGDMA) samples with different porosity parameters were synthesized by suspension copolymerization and modified using a ring-opening reaction of the pendant epoxy groups with EDA. The specific surface areas of the initial and modified copolymer samples were determined by the BET method from low temperature nitro- gen adsorption isotherms (77 K). The adsorption isotherms determined from chromatographic peaks of adsorbates were analyzed using the BET theoretical model and used for estimation of the surface area, isosteric heat of adsorption and the adsorption energy distribution on the surface of the initial and modified copolymer samples. It was observed that the adsorbate nature and the properties of the solid surface of the initial and modified copolymer governed the uptake of adsorbate by the copolymer. The deviations observed for the Sa values obtained by the BET method from the low temperature nitrogen adsorption isotherms and hexane was attributed not only to the difference in molecule size, but also to the specific polymer-adsorbate interactions. The isosteric heat of adsorption approached a constant value with increasing adsorbate loading. A large variation in the shapes of the q(st)-alpha curves resulted from strong acid-base interactions, as well as dissolution phenomena. Of the four studied adsorbates, chloroform was shown to have the greatest affinity towards the surface of the investigated polymer samples.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Macromolecular Materials and Engineering
T1  - Characterization of glycidyl methacrylate based copolymers by inverse gas chromatography under finite surface coverage
VL  - 290
IS  - 9
SP  - 884
EP  - 890
DO  - 10.1002/mame.200500137
ER  - 

@article{
author = "Nastasović, Aleksandra and Onjia, Antonije E. and Milonjić, Slobodan K. and Vuković, Zorica and Jovanovic, SM",
year = "2005",
abstract = "Inverse gas chromatography under finite surface coverage conditions (IGC-FC) was used for the investigation of sorption of hexane, benzene, chloroform and tetrahydrofuran on macroporous crosslinked poly[(glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)], poly(GMA-co-EGDMA), and copolymer modified with ethylene diamine, EDA, poly(GMA-co-EGDMA)-en, in the temperature range 333-363 K. Two poly(GMA-co-EGDMA) samples with different porosity parameters were synthesized by suspension copolymerization and modified using a ring-opening reaction of the pendant epoxy groups with EDA. The specific surface areas of the initial and modified copolymer samples were determined by the BET method from low temperature nitro- gen adsorption isotherms (77 K). The adsorption isotherms determined from chromatographic peaks of adsorbates were analyzed using the BET theoretical model and used for estimation of the surface area, isosteric heat of adsorption and the adsorption energy distribution on the surface of the initial and modified copolymer samples. It was observed that the adsorbate nature and the properties of the solid surface of the initial and modified copolymer governed the uptake of adsorbate by the copolymer. The deviations observed for the Sa values obtained by the BET method from the low temperature nitrogen adsorption isotherms and hexane was attributed not only to the difference in molecule size, but also to the specific polymer-adsorbate interactions. The isosteric heat of adsorption approached a constant value with increasing adsorbate loading. A large variation in the shapes of the q(st)-alpha curves resulted from strong acid-base interactions, as well as dissolution phenomena. Of the four studied adsorbates, chloroform was shown to have the greatest affinity towards the surface of the investigated polymer samples.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Macromolecular Materials and Engineering",
title = "Characterization of glycidyl methacrylate based copolymers by inverse gas chromatography under finite surface coverage",
volume = "290",
number = "9",
pages = "884-890",
doi = "10.1002/mame.200500137"
}

Nastasović, A., Onjia, A. E., Milonjić, S. K., Vuković, Z.,& Jovanovic, S.. (2005). Characterization of glycidyl methacrylate based copolymers by inverse gas chromatography under finite surface coverage. in Macromolecular Materials and Engineering
Wiley-V C H Verlag Gmbh, Weinheim., 290(9), 884-890.
https://doi.org/10.1002/mame.200500137

Nastasović A, Onjia AE, Milonjić SK, Vuković Z, Jovanovic S. Characterization of glycidyl methacrylate based copolymers by inverse gas chromatography under finite surface coverage. in Macromolecular Materials and Engineering. 2005;290(9):884-890.
doi:10.1002/mame.200500137 .

Nastasović, Aleksandra, Onjia, Antonije E., Milonjić, Slobodan K., Vuković, Zorica, Jovanovic, SM, "Characterization of glycidyl methacrylate based copolymers by inverse gas chromatography under finite surface coverage" in Macromolecular Materials and Engineering, 290, no. 9 (2005):884-890,
https://doi.org/10.1002/mame.200500137 . .

TY  - CONF
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Gojković, S.
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna
AU  - Nikolić, B.
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/225
AB  - The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcan® XC-72 R with solid phase of RuO xHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl 3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion® layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.
C3  - Materials Science Forum
T1  - Morphology and capacitive properties of [RuOxH y/low-surface area carbon black] composite materials prepared by sol-gel procedure
VL  - 494
SP  - 235
EP  - 240
DO  - 10.4028/www.scientific.net/MSF.494.235
ER  - 

@conference{
author = "Panić, Vladimir and Dekanski, Aleksandar and Gojković, S. and Milonjić, Slobodan K. and Mišković-Stanković, Vesna and Nikolić, B.",
year = "2005",
abstract = "The morphology and the capacitive properties of carbon supported hydrous ruthenium oxide (RuOxHy/C), prepared by impregnation of low-surface area carbon black Vulcan® XC-72 R with solid phase of RuO xHy sol, were investigated by scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The oxide sols of different ageing times, prepared by forced hydrolysis of RuCl 3, were used for composite preparation. The prepared composites show considerably higher capacitance values in acid electrolyte if compared to carbon black support. Microscopic investigations show that the extent of impregnation and the composite surface appearance depend on ageing time. The composite capacitance increases with ageing time of oxide sol. A gradual decrease in capacitance of thermally untreated composite with charging/discharging cycles was registered, which appears to be related to the extent of impregnation, too. Electrochemical impedance spectroscopy measurements indicate an in-depth capacitance distribution through the composite layer. It was found that Nafion® layer, used to ensure the adhesion of the composite layer to the current collector, influenced the composite impedance behavior, especially on the oxide-rich parts of the composite surface.",
journal = "Materials Science Forum",
title = "Morphology and capacitive properties of [RuOxH y/low-surface area carbon black] composite materials prepared by sol-gel procedure",
volume = "494",
pages = "235-240",
doi = "10.4028/www.scientific.net/MSF.494.235"
}

Panić, V., Dekanski, A., Gojković, S., Milonjić, S. K., Mišković-Stanković, V.,& Nikolić, B.. (2005). Morphology and capacitive properties of [RuOxH y/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Materials Science Forum, 494, 235-240.
https://doi.org/10.4028/www.scientific.net/MSF.494.235

Panić V, Dekanski A, Gojković S, Milonjić SK, Mišković-Stanković V, Nikolić B. Morphology and capacitive properties of [RuOxH y/low-surface area carbon black] composite materials prepared by sol-gel procedure. in Materials Science Forum. 2005;494:235-240.
doi:10.4028/www.scientific.net/MSF.494.235 .

Panić, Vladimir, Dekanski, Aleksandar, Gojković, S., Milonjić, Slobodan K., Mišković-Stanković, Vesna, Nikolić, B., "Morphology and capacitive properties of [RuOxH y/low-surface area carbon black] composite materials prepared by sol-gel procedure" in Materials Science Forum, 494 (2005):235-240,
https://doi.org/10.4028/www.scientific.net/MSF.494.235 . .

TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
AU  - Milonjić, Slobodan K.
AU  - Jovanovic, SM
PY  - 2005
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/188
AB  - Macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine (EDA). Inverse gas chromatography (IGC) at infinite dilution was applied to determine the thermodynamic interactions of PGME and modified copolymer, PGME-en. The specific surface areas of the initial and modified copolymer samples were determined by the BET method, from low-temperature nitrogen adsorption isotherms. The specific retention volumes, Vg, of 10 organic compounds of different chemical nature and polarity (nonpolar, donor, or acceptor) were determined in the temperature range 333-413 K. The weight fraction activity coefficients of test sorbates, ohm(infinity)(1), and Flory-Huggins interaction parameters, chi(infinity)(12), were calculated and discussed in terms of interactions of sorbates with PGME and PGME-en. Also, the partial molar free energy, Delta G(1)(S), partial molar heat of mixing, Delta H-1(infinity), sorption molar free energy, Delta G(1)(S), sorption enthalpy Delta H-1(S), and sorption entropy, Delta S-S(1), were calculated. Glass transitions in PGME and PGME-en, determined from IGC data, were observed in the temperature range 373-393 K and 363-373 K, respectively.
PB  - Wiley, Hoboken
T2  - Journal of Polymer Science Part B-Polymer Physics
T1  - Determination of thermodynamic properties of macroporous glycidyl methacrylate-based copolymers by inverse gas chromatography
VL  - 43
IS  - 18
SP  - 2524
EP  - 2533
DO  - 10.1002/polb.20538
ER  - 

@article{
author = "Nastasović, Aleksandra and Onjia, Antonije E. and Milonjić, Slobodan K. and Jovanovic, SM",
year = "2005",
abstract = "Macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and modified by ring-opening reaction of the pendant epoxy groups with ethylene diamine (EDA). Inverse gas chromatography (IGC) at infinite dilution was applied to determine the thermodynamic interactions of PGME and modified copolymer, PGME-en. The specific surface areas of the initial and modified copolymer samples were determined by the BET method, from low-temperature nitrogen adsorption isotherms. The specific retention volumes, Vg, of 10 organic compounds of different chemical nature and polarity (nonpolar, donor, or acceptor) were determined in the temperature range 333-413 K. The weight fraction activity coefficients of test sorbates, ohm(infinity)(1), and Flory-Huggins interaction parameters, chi(infinity)(12), were calculated and discussed in terms of interactions of sorbates with PGME and PGME-en. Also, the partial molar free energy, Delta G(1)(S), partial molar heat of mixing, Delta H-1(infinity), sorption molar free energy, Delta G(1)(S), sorption enthalpy Delta H-1(S), and sorption entropy, Delta S-S(1), were calculated. Glass transitions in PGME and PGME-en, determined from IGC data, were observed in the temperature range 373-393 K and 363-373 K, respectively.",
publisher = "Wiley, Hoboken",
journal = "Journal of Polymer Science Part B-Polymer Physics",
title = "Determination of thermodynamic properties of macroporous glycidyl methacrylate-based copolymers by inverse gas chromatography",
volume = "43",
number = "18",
pages = "2524-2533",
doi = "10.1002/polb.20538"
}

Nastasović, A., Onjia, A. E., Milonjić, S. K.,& Jovanovic, S.. (2005). Determination of thermodynamic properties of macroporous glycidyl methacrylate-based copolymers by inverse gas chromatography. in Journal of Polymer Science Part B-Polymer Physics
Wiley, Hoboken., 43(18), 2524-2533.
https://doi.org/10.1002/polb.20538

Nastasović A, Onjia AE, Milonjić SK, Jovanovic S. Determination of thermodynamic properties of macroporous glycidyl methacrylate-based copolymers by inverse gas chromatography. in Journal of Polymer Science Part B-Polymer Physics. 2005;43(18):2524-2533.
doi:10.1002/polb.20538 .

Nastasović, Aleksandra, Onjia, Antonije E., Milonjić, Slobodan K., Jovanovic, SM, "Determination of thermodynamic properties of macroporous glycidyl methacrylate-based copolymers by inverse gas chromatography" in Journal of Polymer Science Part B-Polymer Physics, 43, no. 18 (2005):2524-2533,
https://doi.org/10.1002/polb.20538 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Mišković-Stanković, Vesna
AU  - Milonjić, Slobodan K.
AU  - Nikolić, Branislav Ž.
PY  - 2003
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/96
AB  - In order to understand the role of TiO2 in the deactivation mechanism of an active RuO2–TiO2 coating, an additional TiO2 layer was introduced in the support coating interphase of regular Ti//[RuO2–TiO2 anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2–TiO2 coatings, which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot obtained by electrochemical impedance spectroscopy, for a regular RuO2–TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed. The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TiO2 layer at different position within RuO2–TiO2 coating.
AB  - U cilju ispitivanja uloge titan-oksida u deaktivaciji RuO2–TiO2 prevlake na titanskoj podlozi, ispitivane su osobine anoda sa dodatnim slojem TiO2 u međufazi podloga prevlaka, odnosno na površini prevlake. Elektrohemijsko ponašanje ovih upoređeno je sa ponašanjem anoda sa uobičajenom RuO2–TiO2 prevlakom, kao i sa onima koje su bile podvrgnute ubrzanom testu stabilnosti. Pojava polukruga u visoko-frekventnoj oblasti u dijagramima u kompleksnoj ravni, koja je registrovana spektroskopijom elektrohemijske impedancije za uobičajene RuO2–TiO2 prevlake, a koja je posledica obogaćivanja prevlake sa TiO2 tokom njene deaktivacije, nije uočena kod anoda sa dodatim TiO2 slojem. Dodati TiO2 slojevi povećavaju omsku otpornost prevlake i utiču na impedancijsko ponašanje pri niskim frekvencijama. Za analizu impedancijskog ponašanja prevlaka sa dodatim TiO2 slojevima kao i uobičajenih RuO2–TiO2 prevlaka koje su deaktivirane korišćena su slična ekvivalentna električna kola.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure
T1  - Uloga koncentracionog profila titan-oksida u elektrohemijskom ponašanju RuO2-TiO2 prevlaka dobijenih sol-gel postupkom
VL  - 68
IS  - 12
SP  - 979
EP  - 988
DO  - 10.2298/0352-51390312979P
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Mišković-Stanković, Vesna and Milonjić, Slobodan K. and Nikolić, Branislav Ž.",
year = "2003",
abstract = "In order to understand the role of TiO2 in the deactivation mechanism of an active RuO2–TiO2 coating, an additional TiO2 layer was introduced in the support coating interphase of regular Ti//[RuO2–TiO2 anode in one case and on the surface of the coating in the other. The electrochemical behavior of these, with TiO2 enriched, anodes was compared with the behavior of anodes with regular RuO2–TiO2 coatings, which were subjected to an accelerated stability test. A high-frequency semicircle in the complex plane plot obtained by electrochemical impedance spectroscopy, for a regular RuO2–TiO2 coating corresponds to TiO2 enrichment in the coating as a consequence of anode corrosion. In the case of the coatings with additional TiO2 layers, a high-frequency semicircle was not observed. The additional TiO2 layers increase the coating overall resistance and influence the coating impedance behavior at low frequencies. Similar equivalent electrical circuits were used to analyze the impedance behavior of coatings having an additional TiO2 layer at different position within RuO2–TiO2 coating., U cilju ispitivanja uloge titan-oksida u deaktivaciji RuO2–TiO2 prevlake na titanskoj podlozi, ispitivane su osobine anoda sa dodatnim slojem TiO2 u međufazi podloga prevlaka, odnosno na površini prevlake. Elektrohemijsko ponašanje ovih upoređeno je sa ponašanjem anoda sa uobičajenom RuO2–TiO2 prevlakom, kao i sa onima koje su bile podvrgnute ubrzanom testu stabilnosti. Pojava polukruga u visoko-frekventnoj oblasti u dijagramima u kompleksnoj ravni, koja je registrovana spektroskopijom elektrohemijske impedancije za uobičajene RuO2–TiO2 prevlake, a koja je posledica obogaćivanja prevlake sa TiO2 tokom njene deaktivacije, nije uočena kod anoda sa dodatim TiO2 slojem. Dodati TiO2 slojevi povećavaju omsku otpornost prevlake i utiču na impedancijsko ponašanje pri niskim frekvencijama. Za analizu impedancijskog ponašanja prevlaka sa dodatim TiO2 slojevima kao i uobičajenih RuO2–TiO2 prevlaka koje su deaktivirane korišćena su slična ekvivalentna električna kola.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure, Uloga koncentracionog profila titan-oksida u elektrohemijskom ponašanju RuO2-TiO2 prevlaka dobijenih sol-gel postupkom",
volume = "68",
number = "12",
pages = "979-988",
doi = "10.2298/0352-51390312979P"
}

Panić, V., Dekanski, A., Mišković-Stanković, V., Milonjić, S. K.,& Nikolić, B. Ž.. (2003). The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 68(12), 979-988.
https://doi.org/10.2298/0352-51390312979P

Panić V, Dekanski A, Mišković-Stanković V, Milonjić SK, Nikolić BŽ. The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2003;68(12):979-988.
doi:10.2298/0352-51390312979P .

Panić, Vladimir, Dekanski, Aleksandar, Mišković-Stanković, Vesna, Milonjić, Slobodan K., Nikolić, Branislav Ž., "The role of the concentration profile of titanium oxide on the electrochemical behavior of RuO2-TiO2 coatings obtained by the sol-gel procedure" in Journal of the Serbian Chemical Society, 68, no. 12 (2003):979-988,
https://doi.org/10.2298/0352-51390312979P . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Vidaković, Tanja
AU  - Gojković, Suzana
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan
AU  - Nikolić, Branislav
PY  - 2003
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4091
AB  - Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000® (BP) and Vulcan® XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 °C. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 °C, while the low-intensity peak at 2θ position that corresponds to the most intensive peak of the rutile structure was registered at 450 °C. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g−1 of composite was registered for RuOxHy supported on BP and calcined at 300 °C while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOxHy composite is highly porous while BP-supported one is more compact.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol
VL  - 48
SP  - 3805
EP  - 3813
DO  - 10.1016/S0013-4686(03)00514-0
ER  - 

@article{
author = "Panić, Vladimir and Vidaković, Tanja and Gojković, Suzana and Dekanski, Aleksandar and Milonjić, Slobodan and Nikolić, Branislav",
year = "2003",
abstract = "Preparation of RuOxHy/carbon black nanocomposite material was performed by the impregnation method starting from RuOxHy sol as a precursor. Black Pearls 2000® (BP) and Vulcan® XC-72 R (XC) were used as supporting materials. Samples of the composite were calcined in nitrogen atmosphere at temperatures from 130 to 450 °C. Chemical and structural characterization of the precursor and the composites was performed by using energy-dispersive X-ray fluorescence spectroscopy (EDXRFS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). These techniques showed that the oxide impregnated into carbon support is hydrous and amorphous. The amorphous structure is maintained if the composite is calcined up to 300 °C, while the low-intensity peak at 2θ position that corresponds to the most intensive peak of the rutile structure was registered at 450 °C. The capacitance of the composite was determined using cyclic voltammetry. It was found that the capacitance is dependent on calcination temperature and surface area of the carbon black support. The highest specific capacitance of about 700 F g−1 of composite was registered for RuOxHy supported on BP and calcined at 300 °C while four times lower values was obtained for RuOxHy supported on XC. The capacitance measurements indicated that XC-supported RuOxHy composite is highly porous while BP-supported one is more compact.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol",
volume = "48",
pages = "3805-3813",
doi = "10.1016/S0013-4686(03)00514-0"
}

Panić, V., Vidaković, T., Gojković, S., Dekanski, A., Milonjić, S.,& Nikolić, B.. (2003). The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta
Elsevier., 48, 3805-3813.
https://doi.org/10.1016/S0013-4686(03)00514-0

Panić V, Vidaković T, Gojković S, Dekanski A, Milonjić S, Nikolić B. The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol. in Electrochimica Acta. 2003;48:3805-3813.
doi:10.1016/S0013-4686(03)00514-0 .

Panić, Vladimir, Vidaković, Tanja, Gojković, Suzana, Dekanski, Aleksandar, Milonjić, Slobodan, Nikolić, Branislav, "The properties of carbon-supported hydrous ruthenium oxide obtained from RuOxHy sol" in Electrochimica Acta, 48 (2003):3805-3813,
https://doi.org/10.1016/S0013-4686(03)00514-0 . .

TY  - JOUR
AU  - Mitrović, Dejan
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, Radoslav
AU  - Nikolić, Branislav
PY  - 2001
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/26
AB  - The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller.
AB  - U radu je ispitivan uticaj metanola, etanola, 1-propanola i 2-propanola, dodatih u disperznu sredinu RuO2-TiO2 smeše solova, na elektrohemijski aktivnu površinu i elektrokatalitičku aktivnost za reakciju izdvajanja hlora (RIH) RuO2-TiO2/Ti elektroda dobijenih sol-gel postupkom. Elektrohemijski aktivna površina ispitivana je metodom ciklične voltametrije, dok je aktivnost za RIH ispitivana polarizacionim merenjima. Takođe je i ubrzanim testom stabilnosti ispitivana postojanost dobijenih oksidnih prevlaka. Utvrđeno je da osobine dobijenih anoda zavise od broja ugljenikovih atoma u molekulu dodatog alkohola i vremena proteklog od pripreme smeše alkohola i solova do nanošenja smeše na titanski nosač. Uočeno je da dodatak alkohola prouzrokuje povećanje aktivnosti anoda za RIH u odnosu na anode dobijene bez dodavanja alkohola. Istovremeno, anode dobijene dodavanjem alkohola su manje stabilne od anoda dobijenih bez dodavanja alkohola.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes
T1  - Uticaj sastava disperzne sredine oksidnih solova na elektrokatalitičku aktivnost RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom
VL  - 66
IS  - 11-12
SP  - 847
EP  - 857
UR  - https://hdl.handle.net/21.15107/rcub_cer_26
ER  - 

@article{
author = "Mitrović, Dejan and Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, Branislav",
year = "2001",
abstract = "The influence of the addition of methanol, ethanol, 1-propanol and 2-propanol to the dispersing medium of a mixture of RuO2 and TiO2 sols on the electrochemically active surface area for proton exchange, as well as on the electrocatalytic activity for the chlorine evolution reaction (CER) of RuO2-TiO2/Ti electrode obtained by sol-gel procedure was investigated. The electrochemically active surface area was examined by cyclic voltammetry, while the analysis of the activity for the CER was performed by polarization measurements. The stability of the obtained anode coatings was also checked by an accelerated stability test. The anode properties depend on the number of C atoms in the alcohol molecule, as well as on the elapsed time between the preparation of the sols/alcohol mixture and its application onto the titanium support. The addition of alcohol increased the activity of the anodes for the CER, compared to those prepared without the addition, but their stability was smaller., U radu je ispitivan uticaj metanola, etanola, 1-propanola i 2-propanola, dodatih u disperznu sredinu RuO2-TiO2 smeše solova, na elektrohemijski aktivnu površinu i elektrokatalitičku aktivnost za reakciju izdvajanja hlora (RIH) RuO2-TiO2/Ti elektroda dobijenih sol-gel postupkom. Elektrohemijski aktivna površina ispitivana je metodom ciklične voltametrije, dok je aktivnost za RIH ispitivana polarizacionim merenjima. Takođe je i ubrzanim testom stabilnosti ispitivana postojanost dobijenih oksidnih prevlaka. Utvrđeno je da osobine dobijenih anoda zavise od broja ugljenikovih atoma u molekulu dodatog alkohola i vremena proteklog od pripreme smeše alkohola i solova do nanošenja smeše na titanski nosač. Uočeno je da dodatak alkohola prouzrokuje povećanje aktivnosti anoda za RIH u odnosu na anode dobijene bez dodavanja alkohola. Istovremeno, anode dobijene dodavanjem alkohola su manje stabilne od anoda dobijenih bez dodavanja alkohola.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes, Uticaj sastava disperzne sredine oksidnih solova na elektrokatalitičku aktivnost RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom",
volume = "66",
number = "11-12",
pages = "847-857",
url = "https://hdl.handle.net/21.15107/rcub_cer_26"
}

Mitrović, D., Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B.. (2001). The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 66(11-12), 847-857.
https://hdl.handle.net/21.15107/rcub_cer_26

Mitrović D, Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić B. The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes. in Journal of the Serbian Chemical Society. 2001;66(11-12):847-857.
https://hdl.handle.net/21.15107/rcub_cer_26 .

Mitrović, Dejan, Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, Branislav, "The effect of the composition of the dispersing medium of oxide sols on the electrocatalytic activity of sol-gel obtained RuO2-TiO2/Ti anodes" in Journal of the Serbian Chemical Society, 66, no. 11-12 (2001):847-857,
https://hdl.handle.net/21.15107/rcub_cer_26 .

TY  - JOUR
AU  - Panić, Vesna
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, Radoslav
AU  - Nikolić, B.
PY  - 2000
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/17
AB  - The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.
AB  - U radu je ispitivan uticaj dodavanja etanola odnosno izopropanola u disperznu sredinu smeše solova TiO2 i RuO2 na morfologiju i elektrohemijske osobine aktiviranih titanskih anoda dobijenih sol-gel postupkom. Osobine ovako dobijenih anoda su poređene kako međusobno tako i sa osobinama anoda dobijenih termičkim postupkom iz hlorida rutenijuma i titana. Morfologija anodnih prevlaka ispitivana je skenirajućom tunelskom mikroskopijom, a elektrohemijsko ponašanje cikličnom voltametrijom i polarizacionim merenjima. Stabilnost anoda u paralelnim reakcijama izdvajanja kiseonika i hlora ispitivana je ubrzanim testom stabilnosti. Uočeno je da morfologija, elektrokatalitička aktivnost i stabilnost dobijenih anoda zavisi od vrste dodatog alkohola.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure
T1  - Uticaj prisustva alkohola u disperznoj sredini oksidnih solova ha osobine RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom
VL  - 65
IS  - 9
SP  - 649
EP  - 660
DO  - 10.2298/JSC0009649P
ER  - 

@article{
author = "Panić, Vesna and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, B.",
year = "2000",
abstract = "The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated., U radu je ispitivan uticaj dodavanja etanola odnosno izopropanola u disperznu sredinu smeše solova TiO2 i RuO2 na morfologiju i elektrohemijske osobine aktiviranih titanskih anoda dobijenih sol-gel postupkom. Osobine ovako dobijenih anoda su poređene kako međusobno tako i sa osobinama anoda dobijenih termičkim postupkom iz hlorida rutenijuma i titana. Morfologija anodnih prevlaka ispitivana je skenirajućom tunelskom mikroskopijom, a elektrohemijsko ponašanje cikličnom voltametrijom i polarizacionim merenjima. Stabilnost anoda u paralelnim reakcijama izdvajanja kiseonika i hlora ispitivana je ubrzanim testom stabilnosti. Uočeno je da morfologija, elektrokatalitička aktivnost i stabilnost dobijenih anoda zavisi od vrste dodatog alkohola.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure, Uticaj prisustva alkohola u disperznoj sredini oksidnih solova ha osobine RuO2-TiO2/Ti anoda dobijenih sol-gel postupkom",
volume = "65",
number = "9",
pages = "649-660",
doi = "10.2298/JSC0009649P"
}

Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B.. (2000). The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 65(9), 649-660.
https://doi.org/10.2298/JSC0009649P

Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić B. The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2000;65(9):649-660.
doi:10.2298/JSC0009649P .

Panić, Vesna, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, B., "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure" in Journal of the Serbian Chemical Society, 65, no. 9 (2000):649-660,
https://doi.org/10.2298/JSC0009649P . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan
AU  - Atanasoski, Radoslav
AU  - Nikolić, Branislav
PY  - 2000
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4089
AB  - The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2+60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction of obtained anodes was studied. The electrochemical (active) surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and stability of obtained anodes for the chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 and TiO2 sol particle size was established.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure
VL  - 46
SP  - 415
EP  - 421
DO  - 10.1016/S0013-4686(00)00600-9
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan and Atanasoski, Radoslav and Nikolić, Branislav",
year = "2000",
abstract = "The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2+60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction of obtained anodes was studied. The electrochemical (active) surface area of the anode coatings was examined by cyclic voltammetry. The electrocatalytic activity and stability of obtained anodes for the chlorine evolution reaction were investigated by polarization measurements and accelerated stability test. The dependence of electrochemical properties of obtained activated titanium anodes on RuO2 and TiO2 sol particle size was established.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure",
volume = "46",
pages = "415-421",
doi = "10.1016/S0013-4686(00)00600-9"
}

Panić, V., Dekanski, A., Milonjić, S., Atanasoski, R.,& Nikolić, B.. (2000). The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure. in Electrochimica Acta
Elsevier., 46, 415-421.
https://doi.org/10.1016/S0013-4686(00)00600-9

Panić V, Dekanski A, Milonjić S, Atanasoski R, Nikolić B. The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure. in Electrochimica Acta. 2000;46:415-421.
doi:10.1016/S0013-4686(00)00600-9 .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan, Atanasoski, Radoslav, Nikolić, Branislav, "The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure" in Electrochimica Acta, 46 (2000):415-421,
https://doi.org/10.1016/S0013-4686(00)00600-9 . .

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, Radoslav
AU  - Nikolić, Branislav Ž.
PY  - 1999
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4078
AB  - TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis
at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which
the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was
examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron
microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to
obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was
applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows
a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition
method.
PB  - Elsevier
T2  - Colloids and Surfaces A: Physicochemical and Engineering Aspects
T1  - RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction
VL  - 157
IS  - 1-3
SP  - 269
EP  - 274
DO  - 10.1016/S0927-7757(99)00094-1
ER  - 

@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, Branislav Ž.",
year = "1999",
abstract = "TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis
at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which
the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was
examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron
microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to
obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was
applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows
a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition
method.",
publisher = "Elsevier",
journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",
title = "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction",
volume = "157",
number = "1-3",
pages = "269-274",
doi = "10.1016/S0927-7757(99)00094-1"
}

Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (1999). RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects
Elsevier., 157(1-3), 269-274.
https://doi.org/10.1016/S0927-7757(99)00094-1

Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić BŽ. RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1999;157(1-3):269-274.
doi:10.1016/S0927-7757(99)00094-1 .

Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, Branislav Ž., "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction" in Colloids and Surfaces A: Physicochemical and Engineering Aspects, 157, no. 1-3 (1999):269-274,
https://doi.org/10.1016/S0927-7757(99)00094-1 . .