Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine

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Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine (en)
Геохемијска испитивања у функцији проналажења нових лежишта фосилних горива и заштите животне средине (sr)
Geohemijska ispitivanja u funkciji pronalaženja novih ležišta fosilnih goriva i zaštite životne sredine (sr_RS)
Authors

Publications

Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction

Dević, Gordana

(Taylor & Francis Inc, Philadelphia, 2016)

TY  - JOUR
AU  - Dević, Gordana
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1876
AB  - Eight samples of powdered brown coal (Krepoljin coal basin, Miocene age) were successively extracted by two extractants at room temperature: bidistilled water, Me1, and 2 M MgCl2 solution, Me2. Large amounts of Ni and Zn are leached from the coal deposit by water. On the contrary, no significant amounts of Pb and Cu are washed under normal conditions. Also, the mobility of Zn and Ni especially depends, to a high extent, on ionic strength. It can be assumed that the humic acids co-extracted during water leaching, Me1, and being a highly competitive ligand for metal ions, will act as a disturbing agent in metal speciation procedure in coals. This assumption is supported by the obtained significant correlation between the Me1:Me2 ratio and the humic acid complex stability constants.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction
VL  - 38
IS  - 13
SP  - 1912
EP  - 1917
DO  - 10.1080/15567036.2014.975297
ER  - 
@article{
author = "Dević, Gordana",
year = "2016",
abstract = "Eight samples of powdered brown coal (Krepoljin coal basin, Miocene age) were successively extracted by two extractants at room temperature: bidistilled water, Me1, and 2 M MgCl2 solution, Me2. Large amounts of Ni and Zn are leached from the coal deposit by water. On the contrary, no significant amounts of Pb and Cu are washed under normal conditions. Also, the mobility of Zn and Ni especially depends, to a high extent, on ionic strength. It can be assumed that the humic acids co-extracted during water leaching, Me1, and being a highly competitive ligand for metal ions, will act as a disturbing agent in metal speciation procedure in coals. This assumption is supported by the obtained significant correlation between the Me1:Me2 ratio and the humic acid complex stability constants.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction",
volume = "38",
number = "13",
pages = "1912-1917",
doi = "10.1080/15567036.2014.975297"
}
Dević, G.. (2016). Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 38(13), 1912-1917.
https://doi.org/10.1080/15567036.2014.975297
Dević G. Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2016;38(13):1912-1917.
doi:10.1080/15567036.2014.975297 .
Dević, Gordana, "Characterization of eluted metal ions by sequential extraction from Krepoljin coal basin, Serbia: Mechanisms of metal interaction" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 38, no. 13 (2016):1912-1917,
https://doi.org/10.1080/15567036.2014.975297 . .
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An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin

Dević, Gordana

(Taylor & Francis Inc, Philadelphia, 2015)

TY  - JOUR
AU  - Dević, Gordana
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1793
AB  - The characteristics of early diagenetic processes, which influenced the composition of the organic matter of coals from the Krepoljin coal basin, Serbia, Miocene age was assessed by statistical correlation analysis and multivariate principal component analysis. The complexity of processes in a coal-forming sedimentary environment has been paid special attention to obtain the most possible reliable interpretation of these early diagenetic processes and, therefore, this investigation was performed by applying principal component analysis. The principal components, which are defining the coals and promoting individual early diagenetic processes, were the precursor materials and environmental factor, respectively, represented by higher plants, algae, and molds-expressed by the relative contents of the Cs-29-, Cs-28-, Cs-27-steranes, respectively, and the content of organic sulphur-Sorg, average content 166 +/- 101 mu mole/g. The main and highly interrelated effects of the higher plant material were as follows: (i) increase of the sulphur content of coal organic matter, (ii) promoter of sulphate reducing conditions, and (iii) establishment of the H/C- and N/C-ratios of organic matter. Pyrite formed by the participation of Sorg.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin
VL  - 37
IS  - 23
SP  - 2559
EP  - 2566
DO  - 10.1080/15567036.2012.724147
ER  - 
@article{
author = "Dević, Gordana",
year = "2015",
abstract = "The characteristics of early diagenetic processes, which influenced the composition of the organic matter of coals from the Krepoljin coal basin, Serbia, Miocene age was assessed by statistical correlation analysis and multivariate principal component analysis. The complexity of processes in a coal-forming sedimentary environment has been paid special attention to obtain the most possible reliable interpretation of these early diagenetic processes and, therefore, this investigation was performed by applying principal component analysis. The principal components, which are defining the coals and promoting individual early diagenetic processes, were the precursor materials and environmental factor, respectively, represented by higher plants, algae, and molds-expressed by the relative contents of the Cs-29-, Cs-28-, Cs-27-steranes, respectively, and the content of organic sulphur-Sorg, average content 166 +/- 101 mu mole/g. The main and highly interrelated effects of the higher plant material were as follows: (i) increase of the sulphur content of coal organic matter, (ii) promoter of sulphate reducing conditions, and (iii) establishment of the H/C- and N/C-ratios of organic matter. Pyrite formed by the participation of Sorg.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin",
volume = "37",
number = "23",
pages = "2559-2566",
doi = "10.1080/15567036.2012.724147"
}
Dević, G.. (2015). An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 37(23), 2559-2566.
https://doi.org/10.1080/15567036.2012.724147
Dević G. An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2015;37(23):2559-2566.
doi:10.1080/15567036.2012.724147 .
Dević, Gordana, "An Assessment of the Chemical Characteristics of Early Diagenetic Processes in a Geologically Well-defined Brown Coal Basin" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 37, no. 23 (2015):2559-2566,
https://doi.org/10.1080/15567036.2012.724147 . .
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Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia

Dević, Gordana; Popovic, Zoran V.

(Elsevier, 2013)

TY  - JOUR
AU  - Dević, Gordana
AU  - Popovic, Zoran V.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1273
AB  - We investigated early diagenetic processes of the extractable organic matter from the Miocene freshwater sequence, which consists of coal fragments in clays, sandstones and shales alternating with continuous brown coal layers. We examined eight coals, thirteen sediments and three non-coaly underground layers. The molecular assemblages of the identified aliphatic hydrocarbons in the Krepoljin Basin reflect the abundance of plant taxa as precursors or participants in the early diagenetic stage. The data provide insight into the conditions prevailing in the lakes and bogs during early diagenesis. The dominance of diterpanes indicates that the prevalent of the organic matter was of gymnosperous origin. The hopanoid contents are considered to reflect microbial activity. That the organic matter in the Miocene Krepoljin Coal Basin is immature was confirmed by the presence of biolipids such as beta beta-hopanes, C-27 17 beta (H)-trisnorhopane. Saturated and aromatized abietanes, pimaranes and phyllocladanes, the most abundant compounds in all samples, indicate a predominantly higher plant input related to the Coniferous group, but identification of the individual plant families was not possible. beta-Amyrin and other triterpenoid-derived triaromatic and triaromatic C-ring cleaved hydrocarbons with triterpenoid structures are thought to be characteristic for angiosperms. Unsaturated compounds, Delta(2)-triterpanes, early intermediaries in the diagenetic transformation of angiosperms also indicate a low degree of sediment maturity. Crown Copyright
PB  - Elsevier
T2  - International Journal of Coal Geology
T1  - Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia
VL  - 105
SP  - 48
EP  - 59
DO  - 10.1016/j.coal.2012.11.010
ER  - 
@article{
author = "Dević, Gordana and Popovic, Zoran V.",
year = "2013",
abstract = "We investigated early diagenetic processes of the extractable organic matter from the Miocene freshwater sequence, which consists of coal fragments in clays, sandstones and shales alternating with continuous brown coal layers. We examined eight coals, thirteen sediments and three non-coaly underground layers. The molecular assemblages of the identified aliphatic hydrocarbons in the Krepoljin Basin reflect the abundance of plant taxa as precursors or participants in the early diagenetic stage. The data provide insight into the conditions prevailing in the lakes and bogs during early diagenesis. The dominance of diterpanes indicates that the prevalent of the organic matter was of gymnosperous origin. The hopanoid contents are considered to reflect microbial activity. That the organic matter in the Miocene Krepoljin Coal Basin is immature was confirmed by the presence of biolipids such as beta beta-hopanes, C-27 17 beta (H)-trisnorhopane. Saturated and aromatized abietanes, pimaranes and phyllocladanes, the most abundant compounds in all samples, indicate a predominantly higher plant input related to the Coniferous group, but identification of the individual plant families was not possible. beta-Amyrin and other triterpenoid-derived triaromatic and triaromatic C-ring cleaved hydrocarbons with triterpenoid structures are thought to be characteristic for angiosperms. Unsaturated compounds, Delta(2)-triterpanes, early intermediaries in the diagenetic transformation of angiosperms also indicate a low degree of sediment maturity. Crown Copyright",
publisher = "Elsevier",
journal = "International Journal of Coal Geology",
title = "Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia",
volume = "105",
pages = "48-59",
doi = "10.1016/j.coal.2012.11.010"
}
Dević, G.,& Popovic, Z. V.. (2013). Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia. in International Journal of Coal Geology
Elsevier., 105, 48-59.
https://doi.org/10.1016/j.coal.2012.11.010
Dević G, Popovic ZV. Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia. in International Journal of Coal Geology. 2013;105:48-59.
doi:10.1016/j.coal.2012.11.010 .
Dević, Gordana, Popovic, Zoran V., "Biomarker and micropetrographic investigations of coal from the Krepoljin Brown Coal Basin Serbia" in International Journal of Coal Geology, 105 (2013):48-59,
https://doi.org/10.1016/j.coal.2012.11.010 . .
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Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation

Ilić, Mila; Antić, Mališa; Antić, Vesna; Schwarzbauer, Jan; Vrvić, Miroslav; Jovančićević, Branimir

(Springer Heidelberg, Heidelberg, 2011)

TY  - JOUR
AU  - Ilić, Mila
AU  - Antić, Mališa
AU  - Antić, Vesna
AU  - Schwarzbauer, Jan
AU  - Vrvić, Miroslav
AU  - Jovančićević, Branimir
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/889
AB  - Bioremediation potential of bacteria and fungi isolated from sludge samples has been investigated (Danube alluvium, Panevo, Serbia). Total isolated microorganisms were divided into three parts. One part was added with actidione antifungicide. The second part was added with streptomycin antibiotic. The third part was without additives. Paraffinic type of crude oil was a substrate for assessment of bioremediation potential. The simulated oil biodegradation lasted 30, 60 and 90 days. Parallel with that, the experiments with blind trial were conducted. Extracts were isolated from the samples with chloroform in a separate funnel. They were assayed for the group composition (alkanes, aromatics, alcohols and fatty acids) by column chromatography. Alkane fraction was analysed by gas chromatography-mass spectrometry (GC-MS). The most intense oil degradation was achieved in the experiments with bacteria, somewhat weaker with consortium of fungi and bacteria, and the weakest bioremediation potential in these experiments was shown by fungi.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Chemistry Letters
T1  - Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation
VL  - 9
IS  - 1
SP  - 133
EP  - 140
DO  - 10.1007/s10311-009-0257-3
ER  - 
@article{
author = "Ilić, Mila and Antić, Mališa and Antić, Vesna and Schwarzbauer, Jan and Vrvić, Miroslav and Jovančićević, Branimir",
year = "2011",
abstract = "Bioremediation potential of bacteria and fungi isolated from sludge samples has been investigated (Danube alluvium, Panevo, Serbia). Total isolated microorganisms were divided into three parts. One part was added with actidione antifungicide. The second part was added with streptomycin antibiotic. The third part was without additives. Paraffinic type of crude oil was a substrate for assessment of bioremediation potential. The simulated oil biodegradation lasted 30, 60 and 90 days. Parallel with that, the experiments with blind trial were conducted. Extracts were isolated from the samples with chloroform in a separate funnel. They were assayed for the group composition (alkanes, aromatics, alcohols and fatty acids) by column chromatography. Alkane fraction was analysed by gas chromatography-mass spectrometry (GC-MS). The most intense oil degradation was achieved in the experiments with bacteria, somewhat weaker with consortium of fungi and bacteria, and the weakest bioremediation potential in these experiments was shown by fungi.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Chemistry Letters",
title = "Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation",
volume = "9",
number = "1",
pages = "133-140",
doi = "10.1007/s10311-009-0257-3"
}
Ilić, M., Antić, M., Antić, V., Schwarzbauer, J., Vrvić, M.,& Jovančićević, B.. (2011). Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation. in Environmental Chemistry Letters
Springer Heidelberg, Heidelberg., 9(1), 133-140.
https://doi.org/10.1007/s10311-009-0257-3
Ilić M, Antić M, Antić V, Schwarzbauer J, Vrvić M, Jovančićević B. Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation. in Environmental Chemistry Letters. 2011;9(1):133-140.
doi:10.1007/s10311-009-0257-3 .
Ilić, Mila, Antić, Mališa, Antić, Vesna, Schwarzbauer, Jan, Vrvić, Miroslav, Jovančićević, Branimir, "Investigation of bioremediation potential of zymogenous bacteria and fungi for crude oil degradation" in Environmental Chemistry Letters, 9, no. 1 (2011):133-140,
https://doi.org/10.1007/s10311-009-0257-3 . .
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Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation

Šolević Knudsen, Tatjana; Novakovic, Milan; Ilić, Mila; Antić, Mališa; Vrvić, Miroslav; Jovančićević, Branimir

(Serbian Chemical Soc, Belgrade, 2011)

TY  - JOUR
AU  - Šolević Knudsen, Tatjana
AU  - Novakovic, Milan
AU  - Ilić, Mila
AU  - Antić, Mališa
AU  - Vrvić, Miroslav
AU  - Jovančićević, Branimir
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/909
AB  - The bioremediation potential of the aerobic zymogenous microorganisms in soil (Danube alluvium, Pančevo, Serbia) for crude oil biodegradation was investigated. A mixture of paraffinic types of oils was used as the substrate. The laboratory experiment of the simulated oil biodegradation lasted 15, 30, 45, 60 and 75 days. In parallel, an experiment with a control sample was conducted. Extracts were isolated from the samples with chloroform in a separation funnel. From these extracts, the hydrocarbons were isolated by column chromatography and analyzed by gas chromatography-mass spectrometry (GC-MS). n-Alkanes, isoprenoids, phenanthrene and its derivatives with one and two methyl groups were quantitatively analyzed. The ability and efficiency of zymogenous microorganisms in soil for crude oil bioremediation was assessed by comparison between the composition of samples which were exposed to the microorganisms and the control sample. The investigated microorganisms showed the highest bioremediation potential in the biodegradation of n-alkanes and isoprenoids. A considerably high bioremediation potential was confirmed in the biodegradation of phenanthrene and methyl phenanthrenes. Low bioremediation potential of these microorganisms was proven in the case of polycyclic alkanes of the sterane and triterpane types and dimethyl phenanthrenes.
AB  - Ispitivan je bioremedijacioni potencijal aerobnih zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte (aluvijalna ravan reke Dunav, Pančevo). Smeša sirovih nafti parafinskog tipa korišćena je kao supstrat. Laboratorijski eksperiment simulirane biodegradacije trajao je 15, 30, 45, 60 i 75 dana. Paralelno je rađen i eksperiment sa kontrolnim uzorkom. Ekstrakti su izolovani iz uzoraka hloroformom u levku za odvajanje. Iz ovih ekstrakata, ugljovodonici su izolovani hromatografijom na koloni i analizirani gasnohromatografski-masenospektrometrijski (GC-MS). n-Alkani, izoprenoidi, fenantren i njegovi derivati sa jednom i dve metil grupe kvantitativno su analizirani. Sposobnost i efikasnost zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte procenjena je poređenjem sastava uzoraka koji su bili izloženi mikroorganizmima i kontrolnog uzorka. Ispitivani mikroorganizmi pokazali su najviši bioremedijacioni potencijal u biodegradaciji n-alkana i izoprenoida. Visok biodegradacioni potencijal uočen je pri biodegradaciji fenantrena i metilfenantrena. Nizak bioremedijacioni potencijal ovih mikroorganizma dokazan je u slučaju policikličnih alkana tipa sterana i terpana, kao i dimetilfenantrena.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation
T1  - Ispitivanje bioremedijacionog potencijala aerobnih zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte
VL  - 76
IS  - 3
SP  - 425
EP  - 438
DO  - 10.2298/JSC100531033S
ER  - 
@article{
author = "Šolević Knudsen, Tatjana and Novakovic, Milan and Ilić, Mila and Antić, Mališa and Vrvić, Miroslav and Jovančićević, Branimir",
year = "2011",
abstract = "The bioremediation potential of the aerobic zymogenous microorganisms in soil (Danube alluvium, Pančevo, Serbia) for crude oil biodegradation was investigated. A mixture of paraffinic types of oils was used as the substrate. The laboratory experiment of the simulated oil biodegradation lasted 15, 30, 45, 60 and 75 days. In parallel, an experiment with a control sample was conducted. Extracts were isolated from the samples with chloroform in a separation funnel. From these extracts, the hydrocarbons were isolated by column chromatography and analyzed by gas chromatography-mass spectrometry (GC-MS). n-Alkanes, isoprenoids, phenanthrene and its derivatives with one and two methyl groups were quantitatively analyzed. The ability and efficiency of zymogenous microorganisms in soil for crude oil bioremediation was assessed by comparison between the composition of samples which were exposed to the microorganisms and the control sample. The investigated microorganisms showed the highest bioremediation potential in the biodegradation of n-alkanes and isoprenoids. A considerably high bioremediation potential was confirmed in the biodegradation of phenanthrene and methyl phenanthrenes. Low bioremediation potential of these microorganisms was proven in the case of polycyclic alkanes of the sterane and triterpane types and dimethyl phenanthrenes., Ispitivan je bioremedijacioni potencijal aerobnih zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte (aluvijalna ravan reke Dunav, Pančevo). Smeša sirovih nafti parafinskog tipa korišćena je kao supstrat. Laboratorijski eksperiment simulirane biodegradacije trajao je 15, 30, 45, 60 i 75 dana. Paralelno je rađen i eksperiment sa kontrolnim uzorkom. Ekstrakti su izolovani iz uzoraka hloroformom u levku za odvajanje. Iz ovih ekstrakata, ugljovodonici su izolovani hromatografijom na koloni i analizirani gasnohromatografski-masenospektrometrijski (GC-MS). n-Alkani, izoprenoidi, fenantren i njegovi derivati sa jednom i dve metil grupe kvantitativno su analizirani. Sposobnost i efikasnost zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte procenjena je poređenjem sastava uzoraka koji su bili izloženi mikroorganizmima i kontrolnog uzorka. Ispitivani mikroorganizmi pokazali su najviši bioremedijacioni potencijal u biodegradaciji n-alkana i izoprenoida. Visok biodegradacioni potencijal uočen je pri biodegradaciji fenantrena i metilfenantrena. Nizak bioremedijacioni potencijal ovih mikroorganizma dokazan je u slučaju policikličnih alkana tipa sterana i terpana, kao i dimetilfenantrena.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation, Ispitivanje bioremedijacionog potencijala aerobnih zimogenih mikroorganizama iz zemljišta u biodegradaciji sirove nafte",
volume = "76",
number = "3",
pages = "425-438",
doi = "10.2298/JSC100531033S"
}
Šolević Knudsen, T., Novakovic, M., Ilić, M., Antić, M., Vrvić, M.,& Jovančićević, B.. (2011). Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 76(3), 425-438.
https://doi.org/10.2298/JSC100531033S
Šolević Knudsen T, Novakovic M, Ilić M, Antić M, Vrvić M, Jovančićević B. Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation. in Journal of the Serbian Chemical Society. 2011;76(3):425-438.
doi:10.2298/JSC100531033S .
Šolević Knudsen, Tatjana, Novakovic, Milan, Ilić, Mila, Antić, Mališa, Vrvić, Miroslav, Jovančićević, Branimir, "Investigation of the bioremediation potential of aerobic zymogenous microorganisms in soil for crude oil biodegradation" in Journal of the Serbian Chemical Society, 76, no. 3 (2011):425-438,
https://doi.org/10.2298/JSC100531033S . .
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Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition

Šajnović, Aleksandra; Stojanović, Ksenija; Simić, V.; Pevneva, G. S.; Golovko, A. K.; Jovančićević, Branimir

(Maik Nauka/Interperiodica/Springer, New York, 2011)

TY  - JOUR
AU  - Šajnović, Aleksandra
AU  - Stojanović, Ksenija
AU  - Simić, V.
AU  - Pevneva, G. S.
AU  - Golovko, A. K.
AU  - Jovančićević, Branimir
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/780
AB  - Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks, determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect of Pt4+ and Ru3+ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment. The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases. The Pt4+ and Ru3+ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a temperature of 400A degrees C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during the thermolysis of immature kerogen, regardless of its type. The effect of the Pt4+ and Ru3+ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Geochemistry International
T1  - Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition
VL  - 49
IS  - 10
SP  - 1022
EP  - 1034
DO  - 10.1134/S0016702911100053
ER  - 
@article{
author = "Šajnović, Aleksandra and Stojanović, Ksenija and Simić, V. and Pevneva, G. S. and Golovko, A. K. and Jovančićević, Branimir",
year = "2011",
abstract = "Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks, determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect of Pt4+ and Ru3+ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment. The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases. The Pt4+ and Ru3+ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a temperature of 400A degrees C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during the thermolysis of immature kerogen, regardless of its type. The effect of the Pt4+ and Ru3+ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Geochemistry International",
title = "Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition",
volume = "49",
number = "10",
pages = "1022-1034",
doi = "10.1134/S0016702911100053"
}
Šajnović, A., Stojanović, K., Simić, V., Pevneva, G. S., Golovko, A. K.,& Jovančićević, B.. (2011). Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition. in Geochemistry International
Maik Nauka/Interperiodica/Springer, New York., 49(10), 1022-1034.
https://doi.org/10.1134/S0016702911100053
Šajnović A, Stojanović K, Simić V, Pevneva GS, Golovko AK, Jovančićević B. Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition. in Geochemistry International. 2011;49(10):1022-1034.
doi:10.1134/S0016702911100053 .
Šajnović, Aleksandra, Stojanović, Ksenija, Simić, V., Pevneva, G. S., Golovko, A. K., Jovančićević, Branimir, "Studying of liquid thermolysis products of various types of immature kerogen in sedimentary lacustrine rocks from the valjevo-Mionica basin, Serbia, and the effect of Pt4+ and Ru3+ ions on their yield and the hydrocarbon composition" in Geochemistry International, 49, no. 10 (2011):1022-1034,
https://doi.org/10.1134/S0016702911100053 . .

Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates

Stojanović, Ksenija; Kostic, A.; Šajnović, Aleksandra; Pevneva, G. S.; Golovko, A. K.; Jovančićević, Branimir

(Maik Nauka/Interperiodica/Springer, New York, 2011)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Kostic, A.
AU  - Šajnović, Aleksandra
AU  - Pevneva, G. S.
AU  - Golovko, A. K.
AU  - Jovančićević, Branimir
PY  - 2011
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/802
AB  - The possibility of using the data on the hydrocarbon composition obtained by analysis of hydrocarbon concentrates for geochemical studies has been shown on the example of Pannonian Basin (Serbia) crude oils of different genetic types and different degrees of thermal maturity and biodegradation. A high convergence of the values of geochemical parameters calculated on the basis of the composition of steranes and terpanes, alkylnaphthalenes, phenanthrenes, and dibenzothiophenenes in hydrocarbon concentrates and chromatographic fractions isolated from them has been found by correlation analysis.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Petroleum Chemistry
T1  - Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates
VL  - 51
IS  - 4
SP  - 243
EP  - 251
DO  - 10.1134/S0965544111040098
ER  - 
@article{
author = "Stojanović, Ksenija and Kostic, A. and Šajnović, Aleksandra and Pevneva, G. S. and Golovko, A. K. and Jovančićević, Branimir",
year = "2011",
abstract = "The possibility of using the data on the hydrocarbon composition obtained by analysis of hydrocarbon concentrates for geochemical studies has been shown on the example of Pannonian Basin (Serbia) crude oils of different genetic types and different degrees of thermal maturity and biodegradation. A high convergence of the values of geochemical parameters calculated on the basis of the composition of steranes and terpanes, alkylnaphthalenes, phenanthrenes, and dibenzothiophenenes in hydrocarbon concentrates and chromatographic fractions isolated from them has been found by correlation analysis.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Petroleum Chemistry",
title = "Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates",
volume = "51",
number = "4",
pages = "243-251",
doi = "10.1134/S0965544111040098"
}
Stojanović, K., Kostic, A., Šajnović, A., Pevneva, G. S., Golovko, A. K.,& Jovančićević, B.. (2011). Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates. in Petroleum Chemistry
Maik Nauka/Interperiodica/Springer, New York., 51(4), 243-251.
https://doi.org/10.1134/S0965544111040098
Stojanović K, Kostic A, Šajnović A, Pevneva GS, Golovko AK, Jovančićević B. Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates. in Petroleum Chemistry. 2011;51(4):243-251.
doi:10.1134/S0965544111040098 .
Stojanović, Ksenija, Kostic, A., Šajnović, Aleksandra, Pevneva, G. S., Golovko, A. K., Jovančićević, Branimir, "Validation of data on polycyclic biomarkers, naphthalenes, phenanthrenes, and alkyldibenzothiophenes obtained by gas chromatographic-mass spectrometric analysis of hydrocarbon concentrates" in Petroleum Chemistry, 51, no. 4 (2011):243-251,
https://doi.org/10.1134/S0965544111040098 . .

The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia)

Životić, Dragana; Jovančićević, Branimir; Schwarzbauer, Jan; Cvetković, Olga; Gržetić, Ivan; Ercegovac, Marko; Stojanović, Ksenija; Šajnović, Aleksandra

(Elsevier, 2010)

TY  - JOUR
AU  - Životić, Dragana
AU  - Jovančićević, Branimir
AU  - Schwarzbauer, Jan
AU  - Cvetković, Olga
AU  - Gržetić, Ivan
AU  - Ercegovac, Marko
AU  - Stojanović, Ksenija
AU  - Šajnović, Aleksandra
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/654
AB  - A petrological and organic geochemical study was performed on coal samples from the East field deposit, Bogovina Basin, Serbia. Fourteen coal samples were collected from different parts of the Main and Upper coal seams from fresh, working faces in the underground subbituminous coal mine. The Lower Miocene (?) coal of the East field is a typical humic coal with huminite, liptinite and inertinite concentrations of up to 81.4 vol.%, 16.1 vol.% and 13.5 vol.%, respectively. Densinite is the most abundant maceral with variable amounts of ulminite and gelinite. Sporinite and liptodetrinite are the most common macerals of the liptinite group. Exsudatinite was detected in the lower part of the Lower coal seam. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral matter consists mostly of clay minerals and carbonates. The mean random huminite reflectance (ulminite B) for the Main coal seam is 0.42 +/- 0.04%Rr, and 0.41 +/- 0.04%Rr for the Upper coal seam, which are typical for an immature to early mature stage of the organic matter. The distribution and abundance of n-alkanes and steranes indicates a significant contribution of epicuticular waxes from higher plants. High amount of phyllocladane-type diterpenoids (16 alpha(H)-phyllocladane) suggests that coal forming plants were conifer families Taxodiaceae, Podocarpaceae, Cupressaceae, Araucariaceae, Sciadopityaceae, and Phyllocladaceae, while a higher amount of pimarane and norpimarane suggests Pinaceae. Taxodiaceae, and Cupressaceae. The pristane/phytane (Pr/Ph) ratio implies variable anaerobic to oxic conditions during sedimentation. The distribution of the hopanes detected in the Bogovina East field coal indicates an immature to early mature stage of the organic matter, which is in agreement with huminite reflectance. The high coal sulphur contents from the East field are characteristic for slightly alkaline depositional environments generated by bentonite from the basement of the Main coal seam. The petrological observation and biomarker composition provide evidence for the generation of immature hydrocarbons which, most probably, originated from the resins and waxes of higher plants, mostly gymnosperms.
PB  - Elsevier
T2  - International Journal of Coal Geology
T1  - The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia)
VL  - 81
IS  - 4
SP  - 227
EP  - 241
DO  - 10.1016/j.coal.2009.07.012
ER  - 
@article{
author = "Životić, Dragana and Jovančićević, Branimir and Schwarzbauer, Jan and Cvetković, Olga and Gržetić, Ivan and Ercegovac, Marko and Stojanović, Ksenija and Šajnović, Aleksandra",
year = "2010",
abstract = "A petrological and organic geochemical study was performed on coal samples from the East field deposit, Bogovina Basin, Serbia. Fourteen coal samples were collected from different parts of the Main and Upper coal seams from fresh, working faces in the underground subbituminous coal mine. The Lower Miocene (?) coal of the East field is a typical humic coal with huminite, liptinite and inertinite concentrations of up to 81.4 vol.%, 16.1 vol.% and 13.5 vol.%, respectively. Densinite is the most abundant maceral with variable amounts of ulminite and gelinite. Sporinite and liptodetrinite are the most common macerals of the liptinite group. Exsudatinite was detected in the lower part of the Lower coal seam. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral matter consists mostly of clay minerals and carbonates. The mean random huminite reflectance (ulminite B) for the Main coal seam is 0.42 +/- 0.04%Rr, and 0.41 +/- 0.04%Rr for the Upper coal seam, which are typical for an immature to early mature stage of the organic matter. The distribution and abundance of n-alkanes and steranes indicates a significant contribution of epicuticular waxes from higher plants. High amount of phyllocladane-type diterpenoids (16 alpha(H)-phyllocladane) suggests that coal forming plants were conifer families Taxodiaceae, Podocarpaceae, Cupressaceae, Araucariaceae, Sciadopityaceae, and Phyllocladaceae, while a higher amount of pimarane and norpimarane suggests Pinaceae. Taxodiaceae, and Cupressaceae. The pristane/phytane (Pr/Ph) ratio implies variable anaerobic to oxic conditions during sedimentation. The distribution of the hopanes detected in the Bogovina East field coal indicates an immature to early mature stage of the organic matter, which is in agreement with huminite reflectance. The high coal sulphur contents from the East field are characteristic for slightly alkaline depositional environments generated by bentonite from the basement of the Main coal seam. The petrological observation and biomarker composition provide evidence for the generation of immature hydrocarbons which, most probably, originated from the resins and waxes of higher plants, mostly gymnosperms.",
publisher = "Elsevier",
journal = "International Journal of Coal Geology",
title = "The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia)",
volume = "81",
number = "4",
pages = "227-241",
doi = "10.1016/j.coal.2009.07.012"
}
Životić, D., Jovančićević, B., Schwarzbauer, J., Cvetković, O., Gržetić, I., Ercegovac, M., Stojanović, K.,& Šajnović, A.. (2010). The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia). in International Journal of Coal Geology
Elsevier., 81(4), 227-241.
https://doi.org/10.1016/j.coal.2009.07.012
Životić D, Jovančićević B, Schwarzbauer J, Cvetković O, Gržetić I, Ercegovac M, Stojanović K, Šajnović A. The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia). in International Journal of Coal Geology. 2010;81(4):227-241.
doi:10.1016/j.coal.2009.07.012 .
Životić, Dragana, Jovančićević, Branimir, Schwarzbauer, Jan, Cvetković, Olga, Gržetić, Ivan, Ercegovac, Marko, Stojanović, Ksenija, Šajnović, Aleksandra, "The petrographical and organic geochemical composition of coal from the East field, Bogovina Basin (Serbia)" in International Journal of Coal Geology, 81, no. 4 (2010):227-241,
https://doi.org/10.1016/j.coal.2009.07.012 . .
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Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima

Sakan, Sanja

(Универзитет у Београду, Хемијски факултет, 2010)

TY  - THES
AU  - Sakan, Sanja
PY  - 2010
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=869
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:7261/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=37902351
UR  - http://nardus.mpn.gov.rs/123456789/3476
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2574
AB  - Моbilizаciја mikrоеlеmеnаtа y biоsfеru pоd uticајеm lјudskе аktivnоsti je pоstаlа vаžаn prоcеs u gеоhеmiјskоm ciklusu оvih еlеmеnаtа. To je pоstаlо pоsеbnо izrаžеnо u urbаnim srеdinаmа, gdе sе iz rаzličitih izvоrа оslоbаđајu vеlikе kоličinе tоksičnih еlеmеnаtа u аtmоsfеru, vоdеnе tоkоvе, zеmlјištе i sеdimеnt. Sа pоvеćаnjеm еmisiје оvih еlеmеnаtа, pоvеćаvајu sе i njihоvе prirоdnе kоncеntrаciје u svim srеdinаmа. Ha tај nаčin tоksični еlеmеnti pоstајu znаčајni trаsеri zаgаđеnjа živоtiе srеdinе. Dеtаlјnоm аnаlizоm uzоrаkа sеdimеntа, primеnоm mеtоdе еlеmеntаrnе аnаlizе, grаnulоmеtriјskе i rеndgеnskе difrаkciоnе аnаlizе, mеtоdе sеkvеnciјаlnе еkstrаkciје, kао i primеnоm kоmbinоvаnоg еkоhеmiјskоg i gеоhеmiјskоg pristupа u intеrprеtаciјi dоbiјеnih rеzultаtа, kојim je оbuhvаćеnа аnаlizа rеzultаtа dоbiјеnih mеtоdоm sеkvеnciјаlnе еkstrаciје, diskusiја о rаspоdеli еlеmеnаtа no lоkаlitеtimа i dubinаmа, primеnа mеtоdе gеоhеmiјskоg nоrmirаnjа, оdrеđivаnjе fоnskih kоncеntrаciја u sеdimеntimа, оdrеđivаnjе fаktоrа оbоgаćеnjа i stаtističkа оbrаdа lоdаtаkа, u оvоm rаdu je izvеdеnо idеntifikоvаnjе i difеrеnciјаciја аntrоpоgеnоg uticаја i prirоdnоg fоnа tоksičnih i pоtеnciјаlnо tоksičnih mikrоеlеmеnаtа u rеčnоm sеdimеntu Тisе i аluviјаlnоm sеdimеntu Dunаvа, izvršеnа je prоcеnа njihоvоg аntrоpоgеnоg pоrеklа i kvаntifikоvаnjе аntrоpоgеnоg udеlа i dеfinisаni su mоgući izvоri kоntаminаciје u ispitivаnim sеdimеntimа.Аnаlizоm rеzultаtа kоntаminаciје аluviјаlnоg sеdimеntа Dunаvа u Pаnčеvu je pоkаzаnо dа je sа pоvеćаnjеm rаstојаnjа оd Rаfinеriје, аntrоpоgеni uticај nа sаdržај еlеmеnаtа slаbi i pоstаје znаčајniја gеоhеmiјskа kоntrоlа. Rаzdvојеni su uticајi dvа dоprinоsа kоја znаčајnо оdrеđuјu sаdržај ispitivаnih mikrоеlеmеnаtа i tо: аntrоpоgеni unоs Cr, Zn, Cd, Ni, V i Pb kао pоslеdicа uticаја blizinе industriјskоg kоmplеksа, dоkје pоrеklо Cu i Pb pоvеzаnо sа pоstојаnjеm drugih lоkаlnih izvоrа kоntаminаciје i uticајеm sаоbrаćаја, prvеnstvеnо еmisiјаmа iz аutоmоbilа. Sеdimеnt rеkе Тisе prеdstаvlја rеzеrvоаr zа аkumulаciјu tоksičnih i pоtеnciјаlnо tоksičnih еlеmеnаtа iz оkоlnih urbаnih i industriјskih srеdinа, kао i аkumulаciјu еlеmеnаtа kојi su dоnеti rеkоm Тisоm, uslеd еmisiје u zеmlјаmа iz njеnоg slivа. U sеdimеntu оvе rеkеје оdrеđеn vеći sаdržај Cu, Cr, Zn, Pb, Cd, As i Hg i mаnjе V i Ni u оdnоsu nа sеdimеnt njеnih lritоkа.
AB  - Mobilization of microelements in the biosphere under the influence of human activities has become an important process in the geochemical cycle of these elements. It has become particularly pronounced in urban areas, where different sources release large amounts of toxic elements in the atmosphere, waterways, soil and sediment. With increasing emission of these elements increases and their concentration in all natural environments. In this way, toxic elements become important tacers of environmental pollution.Detailed analysis of sediment samples, using methods of elementary analysis, granulometric and X-ray diffraction analysis, sequential extraction methods, and applying the combined ecochemical and geochemical approach to the interpretation of results, which included analysis of the results obtained by the method of sequential extraction, discussion on the distribution of elements by localities and depths, the application of geochemical normalization, determination background concentration, the determination of enrichment factors and statistical analysis, in this thesis was conducted to identify and differentiation of natural and anthropogenic influences of toxic and potentially toxic microelements in the Tisza river sediments and alluvial sediments of the Danube, was made assessment of their anthropogenic origin and quantification of anthropogenic contribution and defined a possible sources of contamination in the sediments. The analysis results of contamination Danube alluvial sediments from Pančevo was shown that with increasing distance from refineries, anthropogenic impact on the content elements weakens and becomes more important geochemical control. Separated by two contributions, which impacts significantly determine the content of microelements: anthropogenic input Cr, Zn, Cd, Ni, V and Pb as a result of the proximity of the impact of industrial complexes, while the origin of Cu and Pb associated with the existence of other local sources of contamination and the influence of traffic, primarily emissions from cars. Tisa river sediment is a reservoir for the accumulation of toxic and potentially toxic elements from the surrounding urban and industrial areas, and accumulation of elements in the Tisa river sediment, due to emissions from countries in its basin. The sediments of this river is determined by a higher content of Cu, Cr, Zn, Pb, Cd, As and Hg and less V and Ni in relation to the sediment of its tributaries.
PB  - Универзитет у Београду, Хемијски факултет
T2  - Универзитет у Београду
T1  - Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima
T1  - A new approach in the use of microelements as tracers for identification and differentiation of natural and anthropogenic impacts in the sediments
DO  - 10.2298/BG20100608SAKAN
UR  - https://hdl.handle.net/21.15107/rcub_nardus_3476
ER  - 
@phdthesis{
author = "Sakan, Sanja",
year = "2010",
abstract = "Моbilizаciја mikrоеlеmеnаtа y biоsfеru pоd uticајеm lјudskе аktivnоsti je pоstаlа vаžаn prоcеs u gеоhеmiјskоm ciklusu оvih еlеmеnаtа. To je pоstаlо pоsеbnо izrаžеnо u urbаnim srеdinаmа, gdе sе iz rаzličitih izvоrа оslоbаđајu vеlikе kоličinе tоksičnih еlеmеnаtа u аtmоsfеru, vоdеnе tоkоvе, zеmlјištе i sеdimеnt. Sа pоvеćаnjеm еmisiје оvih еlеmеnаtа, pоvеćаvајu sе i njihоvе prirоdnе kоncеntrаciје u svim srеdinаmа. Ha tај nаčin tоksični еlеmеnti pоstајu znаčајni trаsеri zаgаđеnjа živоtiе srеdinе. Dеtаlјnоm аnаlizоm uzоrаkа sеdimеntа, primеnоm mеtоdе еlеmеntаrnе аnаlizе, grаnulоmеtriјskе i rеndgеnskе difrаkciоnе аnаlizе, mеtоdе sеkvеnciјаlnе еkstrаkciје, kао i primеnоm kоmbinоvаnоg еkоhеmiјskоg i gеоhеmiјskоg pristupа u intеrprеtаciјi dоbiјеnih rеzultаtа, kојim je оbuhvаćеnа аnаlizа rеzultаtа dоbiјеnih mеtоdоm sеkvеnciјаlnе еkstrаciје, diskusiја о rаspоdеli еlеmеnаtа no lоkаlitеtimа i dubinаmа, primеnа mеtоdе gеоhеmiјskоg nоrmirаnjа, оdrеđivаnjе fоnskih kоncеntrаciја u sеdimеntimа, оdrеđivаnjе fаktоrа оbоgаćеnjа i stаtističkа оbrаdа lоdаtаkа, u оvоm rаdu je izvеdеnо idеntifikоvаnjе i difеrеnciјаciја аntrоpоgеnоg uticаја i prirоdnоg fоnа tоksičnih i pоtеnciјаlnо tоksičnih mikrоеlеmеnаtа u rеčnоm sеdimеntu Тisе i аluviјаlnоm sеdimеntu Dunаvа, izvršеnа je prоcеnа njihоvоg аntrоpоgеnоg pоrеklа i kvаntifikоvаnjе аntrоpоgеnоg udеlа i dеfinisаni su mоgući izvоri kоntаminаciје u ispitivаnim sеdimеntimа.Аnаlizоm rеzultаtа kоntаminаciје аluviјаlnоg sеdimеntа Dunаvа u Pаnčеvu je pоkаzаnо dа je sа pоvеćаnjеm rаstојаnjа оd Rаfinеriје, аntrоpоgеni uticај nа sаdržај еlеmеnаtа slаbi i pоstаје znаčајniја gеоhеmiјskа kоntrоlа. Rаzdvојеni su uticајi dvа dоprinоsа kоја znаčајnо оdrеđuјu sаdržај ispitivаnih mikrоеlеmеnаtа i tо: аntrоpоgеni unоs Cr, Zn, Cd, Ni, V i Pb kао pоslеdicа uticаја blizinе industriјskоg kоmplеksа, dоkје pоrеklо Cu i Pb pоvеzаnо sа pоstојаnjеm drugih lоkаlnih izvоrа kоntаminаciје i uticајеm sаоbrаćаја, prvеnstvеnо еmisiјаmа iz аutоmоbilа. Sеdimеnt rеkе Тisе prеdstаvlја rеzеrvоаr zа аkumulаciјu tоksičnih i pоtеnciјаlnо tоksičnih еlеmеnаtа iz оkоlnih urbаnih i industriјskih srеdinа, kао i аkumulаciјu еlеmеnаtа kојi su dоnеti rеkоm Тisоm, uslеd еmisiје u zеmlјаmа iz njеnоg slivа. U sеdimеntu оvе rеkеје оdrеđеn vеći sаdržај Cu, Cr, Zn, Pb, Cd, As i Hg i mаnjе V i Ni u оdnоsu nа sеdimеnt njеnih lritоkа., Mobilization of microelements in the biosphere under the influence of human activities has become an important process in the geochemical cycle of these elements. It has become particularly pronounced in urban areas, where different sources release large amounts of toxic elements in the atmosphere, waterways, soil and sediment. With increasing emission of these elements increases and their concentration in all natural environments. In this way, toxic elements become important tacers of environmental pollution.Detailed analysis of sediment samples, using methods of elementary analysis, granulometric and X-ray diffraction analysis, sequential extraction methods, and applying the combined ecochemical and geochemical approach to the interpretation of results, which included analysis of the results obtained by the method of sequential extraction, discussion on the distribution of elements by localities and depths, the application of geochemical normalization, determination background concentration, the determination of enrichment factors and statistical analysis, in this thesis was conducted to identify and differentiation of natural and anthropogenic influences of toxic and potentially toxic microelements in the Tisza river sediments and alluvial sediments of the Danube, was made assessment of their anthropogenic origin and quantification of anthropogenic contribution and defined a possible sources of contamination in the sediments. The analysis results of contamination Danube alluvial sediments from Pančevo was shown that with increasing distance from refineries, anthropogenic impact on the content elements weakens and becomes more important geochemical control. Separated by two contributions, which impacts significantly determine the content of microelements: anthropogenic input Cr, Zn, Cd, Ni, V and Pb as a result of the proximity of the impact of industrial complexes, while the origin of Cu and Pb associated with the existence of other local sources of contamination and the influence of traffic, primarily emissions from cars. Tisa river sediment is a reservoir for the accumulation of toxic and potentially toxic elements from the surrounding urban and industrial areas, and accumulation of elements in the Tisa river sediment, due to emissions from countries in its basin. The sediments of this river is determined by a higher content of Cu, Cr, Zn, Pb, Cd, As and Hg and less V and Ni in relation to the sediment of its tributaries.",
publisher = "Универзитет у Београду, Хемијски факултет",
journal = "Универзитет у Београду",
title = "Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima, A new approach in the use of microelements as tracers for identification and differentiation of natural and anthropogenic impacts in the sediments",
doi = "10.2298/BG20100608SAKAN",
url = "https://hdl.handle.net/21.15107/rcub_nardus_3476"
}
Sakan, S.. (2010). Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima. in Универзитет у Београду
Универзитет у Београду, Хемијски факултет..
https://doi.org/10.2298/BG20100608SAKAN
https://hdl.handle.net/21.15107/rcub_nardus_3476
Sakan S. Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima. in Универзитет у Београду. 2010;.
doi:10.2298/BG20100608SAKAN
https://hdl.handle.net/21.15107/rcub_nardus_3476 .
Sakan, Sanja, "Novi pristup u korišćenju mikroelemenata kao trasera za identifikaciju i diferencijaciju antropogenog uticaja i prirodnog fona u sedimentima" in Универзитет у Београду (2010),
https://doi.org/10.2298/BG20100608SAKAN .,
https://hdl.handle.net/21.15107/rcub_nardus_3476 .
1

Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone

Relić, Dubravka; Đorđević, Dragana; Popović, Aleksandar R.; Jadranin, Milka; Polić, Predrag

(Springer, Dordrecht, 2010)

TY  - JOUR
AU  - Relić, Dubravka
AU  - Đorđević, Dragana
AU  - Popović, Aleksandar R.
AU  - Jadranin, Milka
AU  - Polić, Predrag
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/674
AB  - Thirty-five alluvial sediments of the River Danube and 12 groundwater samples were taken within the Panevo Oil Refinery (Serbia). The results for groundwater samples exceed European primary drinking water standards for Fe (obtained results, > 200 mu g/l) and Mn (obtained results, > 50 mu g/l), while the levels of the trace metals are below the thresholds for drinking water quality. Sediments were treated by sequential extraction procedure with five different solutions, each having a higher extraction capacity than the previous one. We also wanted to determine the possible relationships among trace metals and between sediment properties and elemental concentrations. These solutions partitioned metals into CH(3)COONH(4) extractable (F1); HCl carbonate extractable and NH(2)OH center dot HCl easily reducible (F2); (NH(4))(2)C(2)O(4)/H(2)C(2)O(4) moderately reducible (F3); H(2)O(2)-HNO(3) organic/sulfide extractable fractions (F4); and HCl acid-soluble residue (F5). The sum of trace metals Ni, Pb, Cu, and Zn associated with the first two fractions (exchangeable, carbonate, and easily reducible) is significant and extremely important because it represents the proportion of heavy metals that can be easily remobilized by changes in environmental conditions such as pH, redox potential, salinity, etc. Sediments located nearer the groundwater flow are exposed to stronger groundwater fluctuation and had a higher quantity of amorphous and less stable substrates of trace metals. Principal component analysis was used to understand and visualize the associations between the trace metals and certain geological forms within analyzed sediments. The observed association between Cr with total sulfur and Mn from the acid-soluble residue could indicate that Cr is in the form of reduced, less toxic Cr(III), which is from the ecochemical point of view very important.
PB  - Springer, Dordrecht
T2  - Environmental Monitoring and Assessment
T1  - Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone
VL  - 171
IS  - 1-4
SP  - 229
EP  - 248
DO  - 10.1007/s10661-009-1274-1
ER  - 
@article{
author = "Relić, Dubravka and Đorđević, Dragana and Popović, Aleksandar R. and Jadranin, Milka and Polić, Predrag",
year = "2010",
abstract = "Thirty-five alluvial sediments of the River Danube and 12 groundwater samples were taken within the Panevo Oil Refinery (Serbia). The results for groundwater samples exceed European primary drinking water standards for Fe (obtained results, > 200 mu g/l) and Mn (obtained results, > 50 mu g/l), while the levels of the trace metals are below the thresholds for drinking water quality. Sediments were treated by sequential extraction procedure with five different solutions, each having a higher extraction capacity than the previous one. We also wanted to determine the possible relationships among trace metals and between sediment properties and elemental concentrations. These solutions partitioned metals into CH(3)COONH(4) extractable (F1); HCl carbonate extractable and NH(2)OH center dot HCl easily reducible (F2); (NH(4))(2)C(2)O(4)/H(2)C(2)O(4) moderately reducible (F3); H(2)O(2)-HNO(3) organic/sulfide extractable fractions (F4); and HCl acid-soluble residue (F5). The sum of trace metals Ni, Pb, Cu, and Zn associated with the first two fractions (exchangeable, carbonate, and easily reducible) is significant and extremely important because it represents the proportion of heavy metals that can be easily remobilized by changes in environmental conditions such as pH, redox potential, salinity, etc. Sediments located nearer the groundwater flow are exposed to stronger groundwater fluctuation and had a higher quantity of amorphous and less stable substrates of trace metals. Principal component analysis was used to understand and visualize the associations between the trace metals and certain geological forms within analyzed sediments. The observed association between Cr with total sulfur and Mn from the acid-soluble residue could indicate that Cr is in the form of reduced, less toxic Cr(III), which is from the ecochemical point of view very important.",
publisher = "Springer, Dordrecht",
journal = "Environmental Monitoring and Assessment",
title = "Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone",
volume = "171",
number = "1-4",
pages = "229-248",
doi = "10.1007/s10661-009-1274-1"
}
Relić, D., Đorđević, D., Popović, A. R., Jadranin, M.,& Polić, P.. (2010). Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone. in Environmental Monitoring and Assessment
Springer, Dordrecht., 171(1-4), 229-248.
https://doi.org/10.1007/s10661-009-1274-1
Relić D, Đorđević D, Popović AR, Jadranin M, Polić P. Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone. in Environmental Monitoring and Assessment. 2010;171(1-4):229-248.
doi:10.1007/s10661-009-1274-1 .
Relić, Dubravka, Đorđević, Dragana, Popović, Aleksandar R., Jadranin, Milka, Polić, Predrag, "Fractionation and potential mobility of trace metals in Danube alluvial aquifer within an industrialized zone" in Environmental Monitoring and Assessment, 171, no. 1-4 (2010):229-248,
https://doi.org/10.1007/s10661-009-1274-1 . .
17
19
21

Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia

Šajnović, Aleksandra; Stojanović, Ksenija; Pevneva, G. S.; Golovko, A. K.; Jovančićević, Branimir

(Maik Nauka/Interperiodica/Springer, New York, 2010)

TY  - JOUR
AU  - Šajnović, Aleksandra
AU  - Stojanović, Ksenija
AU  - Pevneva, G. S.
AU  - Golovko, A. K.
AU  - Jovančićević, Branimir
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/673
AB  - This paper reports an investigation of 60 samples of lacustrine sedimentary rocks of Neogene age lying at depths of 0-400 m in the Valjevo-Mionica Basin, Serbia. The goal of the study was to determine the origin and type of primary organic matter (OM), the degree of thermal alteration, the generation potential of OM from the rocks of this basin, and conditions in the sedimentation environment during the formation of the rocks. The potential of OM of the rocks was estimated on the basis of the thermolysis of a representative sample after its preliminary debituminization. Using data on C(org) and bitumen contents and S1, S2, and HI Rock-Eval pyrolysis parameters, the samples were divided into three groups. The first and second groups include rocks recovered from depths up to 200 m, and the third group comprises samples from depths of 200-400 m. The investigation of the inorganic constituents of the rocks and biomarker composition showed that the samples of each of these groups were formed under significantly different climatic conditions, which influenced both the composition of primary organic matter and the conditions of the sedimentation environment, which eventually affected the abundance and quality of OM in the rocks. The yield of the liquid fraction and concentration of hydrocarbons obtained during the thermolysis of the debituminized sample of the first group (showing the highest C(org) content), the character of n-alkane and sterane distribution in the saturated fraction of thermolysis products, and the thermal maturity indices calculated from the composition of steranes supported the high generation potential of OM from these rocks.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Geochemistry International
T1  - Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia
VL  - 48
IS  - 7
SP  - 678
EP  - 694
DO  - 10.1134/S0016702910070050
ER  - 
@article{
author = "Šajnović, Aleksandra and Stojanović, Ksenija and Pevneva, G. S. and Golovko, A. K. and Jovančićević, Branimir",
year = "2010",
abstract = "This paper reports an investigation of 60 samples of lacustrine sedimentary rocks of Neogene age lying at depths of 0-400 m in the Valjevo-Mionica Basin, Serbia. The goal of the study was to determine the origin and type of primary organic matter (OM), the degree of thermal alteration, the generation potential of OM from the rocks of this basin, and conditions in the sedimentation environment during the formation of the rocks. The potential of OM of the rocks was estimated on the basis of the thermolysis of a representative sample after its preliminary debituminization. Using data on C(org) and bitumen contents and S1, S2, and HI Rock-Eval pyrolysis parameters, the samples were divided into three groups. The first and second groups include rocks recovered from depths up to 200 m, and the third group comprises samples from depths of 200-400 m. The investigation of the inorganic constituents of the rocks and biomarker composition showed that the samples of each of these groups were formed under significantly different climatic conditions, which influenced both the composition of primary organic matter and the conditions of the sedimentation environment, which eventually affected the abundance and quality of OM in the rocks. The yield of the liquid fraction and concentration of hydrocarbons obtained during the thermolysis of the debituminized sample of the first group (showing the highest C(org) content), the character of n-alkane and sterane distribution in the saturated fraction of thermolysis products, and the thermal maturity indices calculated from the composition of steranes supported the high generation potential of OM from these rocks.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Geochemistry International",
title = "Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia",
volume = "48",
number = "7",
pages = "678-694",
doi = "10.1134/S0016702910070050"
}
Šajnović, A., Stojanović, K., Pevneva, G. S., Golovko, A. K.,& Jovančićević, B.. (2010). Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia. in Geochemistry International
Maik Nauka/Interperiodica/Springer, New York., 48(7), 678-694.
https://doi.org/10.1134/S0016702910070050
Šajnović A, Stojanović K, Pevneva GS, Golovko AK, Jovančićević B. Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia. in Geochemistry International. 2010;48(7):678-694.
doi:10.1134/S0016702910070050 .
Šajnović, Aleksandra, Stojanović, Ksenija, Pevneva, G. S., Golovko, A. K., Jovančićević, Branimir, "Origin, organic geochemistry, and estimation of the generation potential of Neogene lacustrine sediments from the Valjevo-Mionica Basin, Serbia" in Geochemistry International, 48, no. 7 (2010):678-694,
https://doi.org/10.1134/S0016702910070050 . .
1
1
1

Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia

Stojanović, Ksenija; Šajnović, Aleksandra; Sabo, Tibor; Golovko, Anatoly; Jovančićević, Branimir

(American Chemical Society (ACS), 2010)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Šajnović, Aleksandra
AU  - Sabo, Tibor
AU  - Golovko, Anatoly
AU  - Jovančićević, Branimir
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/701
AB  - The generative potential of a Neogene shale from Valjevo-Mionica Basin (Serbia) was investigated using conventional pyrolysis and pyrolysis in the presence of Pt(IV)- and Ru(III)-ions at temperatures 250 and 400 degrees C. Total liquid pyrolysate and hydrocarbon yields obtained in pyrolytic experiments, group composition of liquid pyrolysates, and distributions of saturated biomarkers and alkylaromatics in pyrolysates showed that the shale is in a catagenetic stage and may be a source of liquid hydrocarbons. It was estimated that similar shales found at a depth of 2300-2900 m would become active oil generating source rock where the minimum temperature necessary for catagenetic hydrocarbon generation is between 103 and 107 degrees C. The used metal ions, demonstrated significant positive effects on the yields of total liquid pyrolysate and corresponding hydrocarbons, at both temperatures 250 and 400 degrees C. Comparison of the results of alkylaromatics maturity parameters with maturity ratios calculated from distribution and abundance of saturated biomarkers showed that the metal ions had much greater influence on maturity changes on planar aromatic systems than on isomerizations in the molecules of polycyclic alkalies. The influence of Pt(IV)- and Ru(III)-ions on the distribution of saturated biomarkers in liquid pyrolysates is the same at both temperatures. The used metal ions have greater impact on kerogen degradation, which directly reflects on the increase in the quantity of hydrocarbons, than on isomerization reactions: moretanes --> hopanes, hopanes --> neohopanes and 5 alpha(H)14 alpha(H)17 alpha(H)20(R)-steranes --> 5 alpha(H)14 alpha(H)17 alpha(H)20(S)-steranes. Interactions between the used metal ions and aromatic systems during pyrolysis depend on temperature. Pt(IV)- and Ru(III)-ions demonstrated significant catalytic effect on maturation changes in both naphthalene and phenanthrene isomers during pyrolysis at 400 degrees C. Catalytic effects of Pt(IV)-ion on maturation changes in alkylnaphthalenes and Ru(III)-ion on maturation changes in alkylphenanthrenes were observed at 250 degrees C, which is caused by the different coordination properties of these metal ions.
PB  - American Chemical Society (ACS)
T2  - Energy & Fuels
T1  - Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia
VL  - 24
IS  - 8
SP  - 4357
EP  - 4368
DO  - 10.1021/ef100466f
ER  - 
@article{
author = "Stojanović, Ksenija and Šajnović, Aleksandra and Sabo, Tibor and Golovko, Anatoly and Jovančićević, Branimir",
year = "2010",
abstract = "The generative potential of a Neogene shale from Valjevo-Mionica Basin (Serbia) was investigated using conventional pyrolysis and pyrolysis in the presence of Pt(IV)- and Ru(III)-ions at temperatures 250 and 400 degrees C. Total liquid pyrolysate and hydrocarbon yields obtained in pyrolytic experiments, group composition of liquid pyrolysates, and distributions of saturated biomarkers and alkylaromatics in pyrolysates showed that the shale is in a catagenetic stage and may be a source of liquid hydrocarbons. It was estimated that similar shales found at a depth of 2300-2900 m would become active oil generating source rock where the minimum temperature necessary for catagenetic hydrocarbon generation is between 103 and 107 degrees C. The used metal ions, demonstrated significant positive effects on the yields of total liquid pyrolysate and corresponding hydrocarbons, at both temperatures 250 and 400 degrees C. Comparison of the results of alkylaromatics maturity parameters with maturity ratios calculated from distribution and abundance of saturated biomarkers showed that the metal ions had much greater influence on maturity changes on planar aromatic systems than on isomerizations in the molecules of polycyclic alkalies. The influence of Pt(IV)- and Ru(III)-ions on the distribution of saturated biomarkers in liquid pyrolysates is the same at both temperatures. The used metal ions have greater impact on kerogen degradation, which directly reflects on the increase in the quantity of hydrocarbons, than on isomerization reactions: moretanes --> hopanes, hopanes --> neohopanes and 5 alpha(H)14 alpha(H)17 alpha(H)20(R)-steranes --> 5 alpha(H)14 alpha(H)17 alpha(H)20(S)-steranes. Interactions between the used metal ions and aromatic systems during pyrolysis depend on temperature. Pt(IV)- and Ru(III)-ions demonstrated significant catalytic effect on maturation changes in both naphthalene and phenanthrene isomers during pyrolysis at 400 degrees C. Catalytic effects of Pt(IV)-ion on maturation changes in alkylnaphthalenes and Ru(III)-ion on maturation changes in alkylphenanthrenes were observed at 250 degrees C, which is caused by the different coordination properties of these metal ions.",
publisher = "American Chemical Society (ACS)",
journal = "Energy & Fuels",
title = "Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia",
volume = "24",
number = "8",
pages = "4357-4368",
doi = "10.1021/ef100466f"
}
Stojanović, K., Šajnović, A., Sabo, T., Golovko, A.,& Jovančićević, B.. (2010). Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia. in Energy & Fuels
American Chemical Society (ACS)., 24(8), 4357-4368.
https://doi.org/10.1021/ef100466f
Stojanović K, Šajnović A, Sabo T, Golovko A, Jovančićević B. Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia. in Energy & Fuels. 2010;24(8):4357-4368.
doi:10.1021/ef100466f .
Stojanović, Ksenija, Šajnović, Aleksandra, Sabo, Tibor, Golovko, Anatoly, Jovančićević, Branimir, "Pyrolysis and Catalyzed Pyrolysis in the Investigation of a Neogene Shale Potential from Valjevo-Mionica Basin, Serbia" in Energy & Fuels, 24, no. 8 (2010):4357-4368,
https://doi.org/10.1021/ef100466f . .
5
8
9

Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport

Đorđević, Dragana; Tosic, Ivana; Unkasevic, Miroslava; Duraskovic, Pavle

(Springer Heidelberg, Heidelberg, 2010)

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Tosic, Ivana
AU  - Unkasevic, Miroslava
AU  - Duraskovic, Pavle
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/717
AB  - Precipitation samples collected from 1995 to 2000 at meteorological station in the eastern outskirts of Herceg Novi (Montenegro) were analysed on Na(+), K(+), Mg(2+), Ca(2+), Cl(-), SO(4) (2-), NO(3) (-) and NH(4) (+). Four-day backward trajectory simulations were conducted during the precipitation period to investigate the regional transport of main ions and their deposition in the region of the southeastern Adriatic Sea. The air mass trajectories were classified into six trajectory categories by the origin and direction of their approach to Herceg Novi. A bottle and funnel with a small net between them was used for sampling at a height of 1.5 m above the ground. The concentrations of Cl(-), NO(3) (-), NH(4) (+) and SO(4) (2-) were determined spectrophotometrically, the concentrations of Na(+) and K(+) were determined by the FAES method and the concentrations of Mg(2+) and Ca(2+) by the FAAS method. The factor analysis technique (PCA analysis) based on the calculation of the factors was employed to differentiate the contribution of emission sources to the content of the main ions in the precipitation. The obtained data sets were processed using the SPSS 11.5 statistical program. The Hybrid Single-Particle Lagrangian Integrated Trajectory model was used to study the air origin for the city of Herceg Novi (42A degrees 27'N, 18A degrees 33'E), Montenegro. The following origins of the air masses were considered: northern Europe (NE), eastern Europe-northeastern Europe (EE-NE); eastern Mediterranean-southeastern Europe (EM-SE); Africa-Central Mediterranean (A-CM); western Mediterranean (WM); western Europe-Central Europe (WE-CE) and undefined. The heights and frequencies of precipitation coming by air masses from northern Europe and eastern-northeastern Europe are the lowest. On the contrary, the heights and frequencies of precipitation coming by air masses from the western Mediterranean (36.6%) and Africa and the Central Mediterranean (30.6%) are the highest. The sea salt components (Na(+), Cl(-), Mg(2+)) are significantly correlated, except for air masses originating from the northern and eastern European regions. Significant correlations between SO(4) (2-) and NO(3) (-) are found in air masses coming from the western Europe and North Africa, over the Mediterranean. The highest volume-weighted mean (VWM) of: SO(4) (2-) , NH(4) (+) and Mg(2+) are for precipitation from EE-NE while the highest values of VWM of Cl (-) are from WM and of K(+) are from WE-CE. Long-range transport of Sahara dust is confirmed. For better estimation of origins of water-soluble ions in precipitation expanding list of analysis on anions of organic acids, such as HCOO(-), CH(3)COO(-), and C(2)H(2)COO(-), could be indicative of volatile organic compounds emitted by vegetation but also traffic. The chemical composition of precipitation together with a study of air backward trajectories is the proper tool for tracking the long-range transport of water-soluble ions and estimating transboundary pollution.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport
VL  - 17
IS  - 9
SP  - 1591
EP  - 1598
DO  - 10.1007/s11356-010-0346-7
ER  - 
@article{
author = "Đorđević, Dragana and Tosic, Ivana and Unkasevic, Miroslava and Duraskovic, Pavle",
year = "2010",
abstract = "Precipitation samples collected from 1995 to 2000 at meteorological station in the eastern outskirts of Herceg Novi (Montenegro) were analysed on Na(+), K(+), Mg(2+), Ca(2+), Cl(-), SO(4) (2-), NO(3) (-) and NH(4) (+). Four-day backward trajectory simulations were conducted during the precipitation period to investigate the regional transport of main ions and their deposition in the region of the southeastern Adriatic Sea. The air mass trajectories were classified into six trajectory categories by the origin and direction of their approach to Herceg Novi. A bottle and funnel with a small net between them was used for sampling at a height of 1.5 m above the ground. The concentrations of Cl(-), NO(3) (-), NH(4) (+) and SO(4) (2-) were determined spectrophotometrically, the concentrations of Na(+) and K(+) were determined by the FAES method and the concentrations of Mg(2+) and Ca(2+) by the FAAS method. The factor analysis technique (PCA analysis) based on the calculation of the factors was employed to differentiate the contribution of emission sources to the content of the main ions in the precipitation. The obtained data sets were processed using the SPSS 11.5 statistical program. The Hybrid Single-Particle Lagrangian Integrated Trajectory model was used to study the air origin for the city of Herceg Novi (42A degrees 27'N, 18A degrees 33'E), Montenegro. The following origins of the air masses were considered: northern Europe (NE), eastern Europe-northeastern Europe (EE-NE); eastern Mediterranean-southeastern Europe (EM-SE); Africa-Central Mediterranean (A-CM); western Mediterranean (WM); western Europe-Central Europe (WE-CE) and undefined. The heights and frequencies of precipitation coming by air masses from northern Europe and eastern-northeastern Europe are the lowest. On the contrary, the heights and frequencies of precipitation coming by air masses from the western Mediterranean (36.6%) and Africa and the Central Mediterranean (30.6%) are the highest. The sea salt components (Na(+), Cl(-), Mg(2+)) are significantly correlated, except for air masses originating from the northern and eastern European regions. Significant correlations between SO(4) (2-) and NO(3) (-) are found in air masses coming from the western Europe and North Africa, over the Mediterranean. The highest volume-weighted mean (VWM) of: SO(4) (2-) , NH(4) (+) and Mg(2+) are for precipitation from EE-NE while the highest values of VWM of Cl (-) are from WM and of K(+) are from WE-CE. Long-range transport of Sahara dust is confirmed. For better estimation of origins of water-soluble ions in precipitation expanding list of analysis on anions of organic acids, such as HCOO(-), CH(3)COO(-), and C(2)H(2)COO(-), could be indicative of volatile organic compounds emitted by vegetation but also traffic. The chemical composition of precipitation together with a study of air backward trajectories is the proper tool for tracking the long-range transport of water-soluble ions and estimating transboundary pollution.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport",
volume = "17",
number = "9",
pages = "1591-1598",
doi = "10.1007/s11356-010-0346-7"
}
Đorđević, D., Tosic, I., Unkasevic, M.,& Duraskovic, P.. (2010). Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 17(9), 1591-1598.
https://doi.org/10.1007/s11356-010-0346-7
Đorđević D, Tosic I, Unkasevic M, Duraskovic P. Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport. in Environmental Science and Pollution Research. 2010;17(9):1591-1598.
doi:10.1007/s11356-010-0346-7 .
Đorđević, Dragana, Tosic, Ivana, Unkasevic, Miroslava, Duraskovic, Pavle, "Water-soluble main ions in precipitation over the southeastern Adriatic region: chemical composition and long-range transport" in Environmental Science and Pollution Research, 17, no. 9 (2010):1591-1598,
https://doi.org/10.1007/s11356-010-0346-7 . .
10
8
10

Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia)

Stojanović, Ksenija; Jovančićević, Branimir; Šajnović, Aleksandra; Sabo, Tibor; Vitorović, Dragomir; Schwarzbauer, Jan; Golovko, Anatoly

(Elsevier Sci Ltd, Oxford, 2009)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Jovančićević, Branimir
AU  - Šajnović, Aleksandra
AU  - Sabo, Tibor
AU  - Vitorović, Dragomir
AU  - Schwarzbauer, Jan
AU  - Golovko, Anatoly
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/554
AB  - This paper is aimed at investigating the origin and geological history of the biodegraded Gaj (Serbia) crude oil, based on comparison of biomarkers, particularly alkylaromatics, in crude oil maltene fraction, with those in the liquid raw asphaltene pyrolysis products. The content of asphaltenes in crude oils being generally very low, expecting a higher yield of pyrolysate, pyrolysis of raw asphaltenes was also carried out in the presence of Pt(IV)- and Ru(III)-ions. The used metal ions demonstrated positive effects on the yields of total liquid pyrolysate and corresponding hydrocarbons. Occluded maltene and asphaltene pyrolysis products showed that metal ions had considerably stronger effect on maturation changes in naphthalene and phenanthrene rings than in polycyclic alkanes. The values of maturity parameters observed in maltenes and pyrolysates suggested this crude oil to have been expelled from the source before the "oil window" maximum. The investigated sample of the Gaj crude oil was shown to be in the 4th stage of bio-degradation scale and to have originated from source rocks poor in clays, most probably carbonates, with significant contribution of algae to oil precursor biomass, deposited under a stratified saline water column.
PB  - Elsevier Sci Ltd, Oxford
T2  - Fuel
T1  - Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia)
VL  - 88
IS  - 2
SP  - 287
EP  - 296
DO  - 10.1016/j.fuel.2008.09.014
ER  - 
@article{
author = "Stojanović, Ksenija and Jovančićević, Branimir and Šajnović, Aleksandra and Sabo, Tibor and Vitorović, Dragomir and Schwarzbauer, Jan and Golovko, Anatoly",
year = "2009",
abstract = "This paper is aimed at investigating the origin and geological history of the biodegraded Gaj (Serbia) crude oil, based on comparison of biomarkers, particularly alkylaromatics, in crude oil maltene fraction, with those in the liquid raw asphaltene pyrolysis products. The content of asphaltenes in crude oils being generally very low, expecting a higher yield of pyrolysate, pyrolysis of raw asphaltenes was also carried out in the presence of Pt(IV)- and Ru(III)-ions. The used metal ions demonstrated positive effects on the yields of total liquid pyrolysate and corresponding hydrocarbons. Occluded maltene and asphaltene pyrolysis products showed that metal ions had considerably stronger effect on maturation changes in naphthalene and phenanthrene rings than in polycyclic alkanes. The values of maturity parameters observed in maltenes and pyrolysates suggested this crude oil to have been expelled from the source before the "oil window" maximum. The investigated sample of the Gaj crude oil was shown to be in the 4th stage of bio-degradation scale and to have originated from source rocks poor in clays, most probably carbonates, with significant contribution of algae to oil precursor biomass, deposited under a stratified saline water column.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Fuel",
title = "Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia)",
volume = "88",
number = "2",
pages = "287-296",
doi = "10.1016/j.fuel.2008.09.014"
}
Stojanović, K., Jovančićević, B., Šajnović, A., Sabo, T., Vitorović, D., Schwarzbauer, J.,& Golovko, A.. (2009). Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia). in Fuel
Elsevier Sci Ltd, Oxford., 88(2), 287-296.
https://doi.org/10.1016/j.fuel.2008.09.014
Stojanović K, Jovančićević B, Šajnović A, Sabo T, Vitorović D, Schwarzbauer J, Golovko A. Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia). in Fuel. 2009;88(2):287-296.
doi:10.1016/j.fuel.2008.09.014 .
Stojanović, Ksenija, Jovančićević, Branimir, Šajnović, Aleksandra, Sabo, Tibor, Vitorović, Dragomir, Schwarzbauer, Jan, Golovko, Anatoly, "Pyrolysis and Pt(IV)- and Ru(III)-ion catalyzed pyrolysis of asphaltenes in organic geochemical investigation of a biodegraded crude oil (Gaj, Serbia)" in Fuel, 88, no. 2 (2009):287-296,
https://doi.org/10.1016/j.fuel.2008.09.014 . .
8
9
10

pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis

Popović, Aleksandar R.; Đorđević, Dragana

(Taylor & Francis Inc, Philadelphia, 2009)

TY  - JOUR
AU  - Popović, Aleksandar R.
AU  - Đorđević, Dragana
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/542
AB  - Trace and major elements in coal ash particles from dump of "Nikola Tesla A" power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while "aged" ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Energy Sources, Part A: Recovery, Utilization and Environmental Effects
T1  - pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis
VL  - 31
IS  - 17
SP  - 1553
EP  - 1560
DO  - 10.1080/15567030802094003
ER  - 
@article{
author = "Popović, Aleksandar R. and Đorđević, Dragana",
year = "2009",
abstract = "Trace and major elements in coal ash particles from dump of "Nikola Tesla A" power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while "aged" ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",
title = "pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis",
volume = "31",
number = "17",
pages = "1553-1560",
doi = "10.1080/15567030802094003"
}
Popović, A. R.,& Đorđević, D.. (2009). pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Taylor & Francis Inc, Philadelphia., 31(17), 1553-1560.
https://doi.org/10.1080/15567030802094003
Popović AR, Đorđević D. pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis. in Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 2009;31(17):1553-1560.
doi:10.1080/15567030802094003 .
Popović, Aleksandar R., Đorđević, Dragana, "pH-Dependent Leaching of Dump Coal Ash-Retrospective Environmental Analysis" in Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 31, no. 17 (2009):1553-1560,
https://doi.org/10.1080/15567030802094003 . .
11
12
12

Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)

Šajnović, Aleksandra; Stojanović, Ksenija; Jovančićević, Branimir; Cvetković, Olga

(Elsevier Gmbh, Urban & Fischer Verlag, Jena, 2008)

TY  - JOUR
AU  - Šajnović, Aleksandra
AU  - Stojanović, Ksenija
AU  - Jovančićević, Branimir
AU  - Cvetković, Olga
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/394
AB  - In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0-400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals or 15-75 m (A), 75-200 m (B) and 360-400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators. The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C-25 are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C-25 content. Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C-17 content compared to n-C-17, and phytane compared to n-C-18. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C-26 (hypersaline depositional environment), or isoprenoid C-25 and n-alkane C-22 for high alkalinity environment. This study showed that Sq/n-C-26 ratio can be used to assess the quality of organic substance in immature lacustrine sediments.
PB  - Elsevier Gmbh, Urban & Fischer Verlag, Jena
T2  - Chemie Der Erde-Geochemistry
T1  - Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)
VL  - 68
IS  - 4
SP  - 395
EP  - 411
DO  - 10.1016/j.chemer.2008.04.003
ER  - 
@article{
author = "Šajnović, Aleksandra and Stojanović, Ksenija and Jovančićević, Branimir and Cvetković, Olga",
year = "2008",
abstract = "In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0-400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals or 15-75 m (A), 75-200 m (B) and 360-400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators. The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C-25 are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C-25 content. Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C-17 content compared to n-C-17, and phytane compared to n-C-18. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C-26 (hypersaline depositional environment), or isoprenoid C-25 and n-alkane C-22 for high alkalinity environment. This study showed that Sq/n-C-26 ratio can be used to assess the quality of organic substance in immature lacustrine sediments.",
publisher = "Elsevier Gmbh, Urban & Fischer Verlag, Jena",
journal = "Chemie Der Erde-Geochemistry",
title = "Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)",
volume = "68",
number = "4",
pages = "395-411",
doi = "10.1016/j.chemer.2008.04.003"
}
Šajnović, A., Stojanović, K., Jovančićević, B.,& Cvetković, O.. (2008). Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia). in Chemie Der Erde-Geochemistry
Elsevier Gmbh, Urban & Fischer Verlag, Jena., 68(4), 395-411.
https://doi.org/10.1016/j.chemer.2008.04.003
Šajnović A, Stojanović K, Jovančićević B, Cvetković O. Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia). in Chemie Der Erde-Geochemistry. 2008;68(4):395-411.
doi:10.1016/j.chemer.2008.04.003 .
Šajnović, Aleksandra, Stojanović, Ksenija, Jovančićević, Branimir, Cvetković, Olga, "Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)" in Chemie Der Erde-Geochemistry, 68, no. 4 (2008):395-411,
https://doi.org/10.1016/j.chemer.2008.04.003 . .
8
8
8

Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia

Životić, Dragana; Wehner, Herman; Cvetković, Olga; Jovančićević, Branimir; Gržetić, Ivan; Scheeder, Georg; Vidal, Angelika; Šajnović, Aleksandra; Ercegovac, Marko; Simić, Vladimir

(Elsevier, 2008)

TY  - JOUR
AU  - Životić, Dragana
AU  - Wehner, Herman
AU  - Cvetković, Olga
AU  - Jovančićević, Branimir
AU  - Gržetić, Ivan
AU  - Scheeder, Georg
AU  - Vidal, Angelika
AU  - Šajnović, Aleksandra
AU  - Ercegovac, Marko
AU  - Simić, Vladimir
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/411
AB  - A petrological, organic geochemical and geochemical study was performed on coal samples from the Soko Mine, Soko Banja basin, Serbia. Ten coal and two carbonaceous clay samples were collected from fresh, working faces in the underground brown coal mine from different parts of the main coal seam. The Lower Miocene, low-rank coal of the Soko Mine is a typical humic coal with huminite concentrations of up to 76.2 vol.%, liptinite less than 14 vol.% and inertinite less than 11 vol.%. Ulminite is the most abundant maceral with variable amounts of densinite and clay minerals. Sporinite and resinite are the most common macerals of the liptinite group. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral-bituminous groundmass identified in some coal samples, and carbonaceous marly clay, indicate sub-aquatic origin and strong bacterial decomposition. The mean random huminite reflectance (ulminite B) for the main coal seam is 0.40 +/- 0.05% Rr, which is typical for an immature to early mature stage of organic matter. The extract yields from the coal of the Soko Banja basin ranges from 9413 to 14,096 ppm, in which alkanes constituted 1.02-0.1%, aromatics 1.3-14.7%, asphaltenes 28.1-76.2% and resins 20.2-43.5%. The saturated hydrocarbon fractions included n-C-15 to n-C-32, with an odd carbon number that predominate in almost all the samples. The contents of n-C-27 and n-C-29 alkanes are extremely high in some samples, as a contribution of epicuticular waxes from higher plants. Acyclic isoprenoid hydrocarbons are minor constituents in the aliphatic fraction, and the pristane/phytane (Pr/Ph) ratio varies between 0.56 and 3.13, which implies anaerobic to oxic conditions during sedimentation. The most abundant diterpanes were abietane, dehydroabietane and 16 alpha(H)-phyllocladane. In samples from the upper part of the coal seam, diterpanes are the dominant constituents of the alkane fraction. Polycyclic alkanes of the triterpane type are important constituents of alkane fractions. The occurrence of beta beta- and alpha beta-type hopanes from C-27 to C-31, but without C-28, is typical for the Soko Banja coals. The major and trace elements in the coal were analysed using X-ray fluorescence (XRF), and inductively coupled plasma-mass spectrometry (ICP-MS). In comparison with world lignites, using the geometric mean value, the coal from the Soko Banja Basin has a high content of strontium (306.953 mg/kg). Higher values than the world lignites were obtained for Mo (3.614 mg/kg), Ni(8.119 mg/kg), Se (0.884 mg/kg), U (2.642 mg/kg) and W (0.148 mg/kg). Correlation analysis shows inorganic affinity for almost all the major and trace elements, except for S, which has an organic affinity.
PB  - Elsevier
T2  - International Journal of Coal Geology
T1  - Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia
VL  - 73
IS  - 3-4
SP  - 285
EP  - 306
DO  - 10.1016/j.coal.2007.07.001
ER  - 
@article{
author = "Životić, Dragana and Wehner, Herman and Cvetković, Olga and Jovančićević, Branimir and Gržetić, Ivan and Scheeder, Georg and Vidal, Angelika and Šajnović, Aleksandra and Ercegovac, Marko and Simić, Vladimir",
year = "2008",
abstract = "A petrological, organic geochemical and geochemical study was performed on coal samples from the Soko Mine, Soko Banja basin, Serbia. Ten coal and two carbonaceous clay samples were collected from fresh, working faces in the underground brown coal mine from different parts of the main coal seam. The Lower Miocene, low-rank coal of the Soko Mine is a typical humic coal with huminite concentrations of up to 76.2 vol.%, liptinite less than 14 vol.% and inertinite less than 11 vol.%. Ulminite is the most abundant maceral with variable amounts of densinite and clay minerals. Sporinite and resinite are the most common macerals of the liptinite group. Inertodetrinite is the most abundant maceral of the inertinite group. The mineral-bituminous groundmass identified in some coal samples, and carbonaceous marly clay, indicate sub-aquatic origin and strong bacterial decomposition. The mean random huminite reflectance (ulminite B) for the main coal seam is 0.40 +/- 0.05% Rr, which is typical for an immature to early mature stage of organic matter. The extract yields from the coal of the Soko Banja basin ranges from 9413 to 14,096 ppm, in which alkanes constituted 1.02-0.1%, aromatics 1.3-14.7%, asphaltenes 28.1-76.2% and resins 20.2-43.5%. The saturated hydrocarbon fractions included n-C-15 to n-C-32, with an odd carbon number that predominate in almost all the samples. The contents of n-C-27 and n-C-29 alkanes are extremely high in some samples, as a contribution of epicuticular waxes from higher plants. Acyclic isoprenoid hydrocarbons are minor constituents in the aliphatic fraction, and the pristane/phytane (Pr/Ph) ratio varies between 0.56 and 3.13, which implies anaerobic to oxic conditions during sedimentation. The most abundant diterpanes were abietane, dehydroabietane and 16 alpha(H)-phyllocladane. In samples from the upper part of the coal seam, diterpanes are the dominant constituents of the alkane fraction. Polycyclic alkanes of the triterpane type are important constituents of alkane fractions. The occurrence of beta beta- and alpha beta-type hopanes from C-27 to C-31, but without C-28, is typical for the Soko Banja coals. The major and trace elements in the coal were analysed using X-ray fluorescence (XRF), and inductively coupled plasma-mass spectrometry (ICP-MS). In comparison with world lignites, using the geometric mean value, the coal from the Soko Banja Basin has a high content of strontium (306.953 mg/kg). Higher values than the world lignites were obtained for Mo (3.614 mg/kg), Ni(8.119 mg/kg), Se (0.884 mg/kg), U (2.642 mg/kg) and W (0.148 mg/kg). Correlation analysis shows inorganic affinity for almost all the major and trace elements, except for S, which has an organic affinity.",
publisher = "Elsevier",
journal = "International Journal of Coal Geology",
title = "Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia",
volume = "73",
number = "3-4",
pages = "285-306",
doi = "10.1016/j.coal.2007.07.001"
}
Životić, D., Wehner, H., Cvetković, O., Jovančićević, B., Gržetić, I., Scheeder, G., Vidal, A., Šajnović, A., Ercegovac, M.,& Simić, V.. (2008). Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia. in International Journal of Coal Geology
Elsevier., 73(3-4), 285-306.
https://doi.org/10.1016/j.coal.2007.07.001
Životić D, Wehner H, Cvetković O, Jovančićević B, Gržetić I, Scheeder G, Vidal A, Šajnović A, Ercegovac M, Simić V. Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia. in International Journal of Coal Geology. 2008;73(3-4):285-306.
doi:10.1016/j.coal.2007.07.001 .
Životić, Dragana, Wehner, Herman, Cvetković, Olga, Jovančićević, Branimir, Gržetić, Ivan, Scheeder, Georg, Vidal, Angelika, Šajnović, Aleksandra, Ercegovac, Marko, Simić, Vladimir, "Petrological, organic geochemical and geochemical characteristics of coal from the Soko mine, Serbia" in International Journal of Coal Geology, 73, no. 3-4 (2008):285-306,
https://doi.org/10.1016/j.coal.2007.07.001 . .
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Comparison of two methods for removal of arsenic from potable water

Manojlović, Dragan; Popara, A.; Dojčinović, Biljana; Nikolić, A.; Obradović, Bratislav M.; Kuraica, Milorad M.; Purić, J.

(2008)

TY  - JOUR
AU  - Manojlović, Dragan
AU  - Popara, A.
AU  - Dojčinović, Biljana
AU  - Nikolić, A.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Purić, J.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/453
AB  - Arsenic, well known of its toxicity, is present in potable water in many areas in the world, as well as in underground water used for water supply in Vojvodina, a region in Serbia. Its removal from raw water is necessary before distribution. In this work two methods of arsenic removal from water are compared. First method is water ozonation by introducing ozone in water and then filtration. Second method is treatment of water in plasma reactor and then filtration. High efficiency of the second method was confirmed by low concentration of arsenic in filtrate (below detection limit).
T2  - Vacuum
T1  - Comparison of two methods for removal of arsenic from potable water
VL  - 83
IS  - 1
SP  - 142
EP  - 145
DO  - 10.1016/j.vacuum.2008.03.045
ER  - 
@article{
author = "Manojlović, Dragan and Popara, A. and Dojčinović, Biljana and Nikolić, A. and Obradović, Bratislav M. and Kuraica, Milorad M. and Purić, J.",
year = "2008",
abstract = "Arsenic, well known of its toxicity, is present in potable water in many areas in the world, as well as in underground water used for water supply in Vojvodina, a region in Serbia. Its removal from raw water is necessary before distribution. In this work two methods of arsenic removal from water are compared. First method is water ozonation by introducing ozone in water and then filtration. Second method is treatment of water in plasma reactor and then filtration. High efficiency of the second method was confirmed by low concentration of arsenic in filtrate (below detection limit).",
journal = "Vacuum",
title = "Comparison of two methods for removal of arsenic from potable water",
volume = "83",
number = "1",
pages = "142-145",
doi = "10.1016/j.vacuum.2008.03.045"
}
Manojlović, D., Popara, A., Dojčinović, B., Nikolić, A., Obradović, B. M., Kuraica, M. M.,& Purić, J.. (2008). Comparison of two methods for removal of arsenic from potable water. in Vacuum, 83(1), 142-145.
https://doi.org/10.1016/j.vacuum.2008.03.045
Manojlović D, Popara A, Dojčinović B, Nikolić A, Obradović BM, Kuraica MM, Purić J. Comparison of two methods for removal of arsenic from potable water. in Vacuum. 2008;83(1):142-145.
doi:10.1016/j.vacuum.2008.03.045 .
Manojlović, Dragan, Popara, A., Dojčinović, Biljana, Nikolić, A., Obradović, Bratislav M., Kuraica, Milorad M., Purić, J., "Comparison of two methods for removal of arsenic from potable water" in Vacuum, 83, no. 1 (2008):142-145,
https://doi.org/10.1016/j.vacuum.2008.03.045 . .
16
16
20

Plasma assisted degradation of phenol solutions

Dojčinović, Biljana; Manojlović, Dragan; Roglić, Goran; Obradović, Bratislav M.; Kuraica, Milorad M.; Purić, J.

(2008)

TY  - JOUR
AU  - Dojčinović, Biljana
AU  - Manojlović, Dragan
AU  - Roglić, Goran
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Purić, J.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/452
AB  - Solutions of 2-chlorophenol, 4-chlorophenol and 2,6-dichlorophenol in bidistilled and water from the river Danube were treated in plasma reactor. In this reactor, based on coaxial dielectric barrier discharge at atmospheric pressure, plasma is formed over a thin layer of treated water. After one pass through the reactor, starting chlorophenols concentration of 20 mg/l was diminished up to 95%. Kinetics of the chlorophenols degradation was monitored by High Pressure Liquid Chromatography method (HPLC).
T2  - Vacuum
T1  - Plasma assisted degradation of phenol solutions
VL  - 83
IS  - 1
SP  - 234
EP  - 237
DO  - 10.1016/j.vacuum.2008.04.003
ER  - 
@article{
author = "Dojčinović, Biljana and Manojlović, Dragan and Roglić, Goran and Obradović, Bratislav M. and Kuraica, Milorad M. and Purić, J.",
year = "2008",
abstract = "Solutions of 2-chlorophenol, 4-chlorophenol and 2,6-dichlorophenol in bidistilled and water from the river Danube were treated in plasma reactor. In this reactor, based on coaxial dielectric barrier discharge at atmospheric pressure, plasma is formed over a thin layer of treated water. After one pass through the reactor, starting chlorophenols concentration of 20 mg/l was diminished up to 95%. Kinetics of the chlorophenols degradation was monitored by High Pressure Liquid Chromatography method (HPLC).",
journal = "Vacuum",
title = "Plasma assisted degradation of phenol solutions",
volume = "83",
number = "1",
pages = "234-237",
doi = "10.1016/j.vacuum.2008.04.003"
}
Dojčinović, B., Manojlović, D., Roglić, G., Obradović, B. M., Kuraica, M. M.,& Purić, J.. (2008). Plasma assisted degradation of phenol solutions. in Vacuum, 83(1), 234-237.
https://doi.org/10.1016/j.vacuum.2008.04.003
Dojčinović B, Manojlović D, Roglić G, Obradović BM, Kuraica MM, Purić J. Plasma assisted degradation of phenol solutions. in Vacuum. 2008;83(1):234-237.
doi:10.1016/j.vacuum.2008.04.003 .
Dojčinović, Biljana, Manojlović, Dragan, Roglić, Goran, Obradović, Bratislav M., Kuraica, Milorad M., Purić, J., "Plasma assisted degradation of phenol solutions" in Vacuum, 83, no. 1 (2008):234-237,
https://doi.org/10.1016/j.vacuum.2008.04.003 . .
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25
30

In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis

Đinović, Jasna M.; Popović, Aleksandar R.

(Elsevier, 2007)

TY  - JOUR
AU  - Đinović, Jasna M.
AU  - Popović, Aleksandar R.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4251
AB  - The aim of this study was to establish the real in situ influence of coal ash and slag transport and storage on the quality of neighboring surface and ground waters by applying correlation statistic analysis. It was found that the waste waters from the coal ash dump do not have any influence on the quality of the Danube river water. The Danube and the waste waters, however, influence the quality of the ground waters of the Petka spring. Changes in the concentrations of elements in the Danube or in the waste waters can have immediate or delayed impact on the quality of the spring waters. The immediate impact has calcium, magnesium, zinc, copper, vanadium, cobalt from Danube; magnesium, vanadium from overflow and drainage waters; copper from drainage water. And the delayed impact has calcium, magnesium, vanadium and silicon from the Danube waters, cobalt from drainage waters, chromium and silicon from overflow waters and magnesium and vanadium from both overflow and drainage waters.
PB  - Elsevier
T2  - Fuel
T1  - In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis
VL  - 86
IS  - 1-2
SP  - 218
EP  - 226
DO  - 10.1016/j.fuel.2006.06.014
ER  - 
@article{
author = "Đinović, Jasna M. and Popović, Aleksandar R.",
year = "2007",
abstract = "The aim of this study was to establish the real in situ influence of coal ash and slag transport and storage on the quality of neighboring surface and ground waters by applying correlation statistic analysis. It was found that the waste waters from the coal ash dump do not have any influence on the quality of the Danube river water. The Danube and the waste waters, however, influence the quality of the ground waters of the Petka spring. Changes in the concentrations of elements in the Danube or in the waste waters can have immediate or delayed impact on the quality of the spring waters. The immediate impact has calcium, magnesium, zinc, copper, vanadium, cobalt from Danube; magnesium, vanadium from overflow and drainage waters; copper from drainage water. And the delayed impact has calcium, magnesium, vanadium and silicon from the Danube waters, cobalt from drainage waters, chromium and silicon from overflow waters and magnesium and vanadium from both overflow and drainage waters.",
publisher = "Elsevier",
journal = "Fuel",
title = "In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis",
volume = "86",
number = "1-2",
pages = "218-226",
doi = "10.1016/j.fuel.2006.06.014"
}
Đinović, J. M.,& Popović, A. R.. (2007). In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis. in Fuel
Elsevier., 86(1-2), 218-226.
https://doi.org/10.1016/j.fuel.2006.06.014
Đinović JM, Popović AR. In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis. in Fuel. 2007;86(1-2):218-226.
doi:10.1016/j.fuel.2006.06.014 .
Đinović, Jasna M., Popović, Aleksandar R., "In situ influence of coal ash dump on the quality of neighboring surface and ground waters by applying correlation statistic analysis" in Fuel, 86, no. 1-2 (2007):218-226,
https://doi.org/10.1016/j.fuel.2006.06.014 . .
10
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