Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200175 (Institut tehničkih nauka SANU, Beograd) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200175 (Институт техничких наука САНУ, Београд) (sr)
Authors

Publications

Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer

Labus, Nebojsa; Krstić, Jugoslav; Matijašević, Srđan; Pavlović, Vladimir

(Belgrade : Association for ETRAN Society, 2023)

TY  - JOUR
AU  - Labus, Nebojsa
AU  - Krstić, Jugoslav
AU  - Matijašević, Srđan
AU  - Pavlović, Vladimir
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7187
AB  - Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed.
AB  - Смеша прахова састављена од ZnO, Mn2O3 (MnCO3) и Fe2O3 комбинацијепрахова је показивала ламинацију током пресовања. Поливинил алкохол (PVA) икомбинација PVA са полиетилен гликолом (PEG) који је додат као пластификатор, сууведени као полимерно везиво за пресовање оксидних прахова. Везиво је уведено такошто је формирана суспензија смеше различитих оксида прахова у полимерномраствору. Концентрације полимера и састави су варирани. Уклањањем растварачадобијени су нови материјали који се састоје од честица оксида повезаних полимерима.Ови хибридни материјали окарактерисани су методама ометене тоталне рефлексијефурије трансформисане инфрацрвене спектроскопије (ATR-FTIR) као идиференцијалне термичке анализе (DTA). Микроструктура је посматранатрансмисоном електронском микроскопијом (TEM). Оксид-полимер материјали супресовани на притиску од 200 MPa и ширење испреска током грејања је праћено у температурском опсегу од собне до 550ºC употребом дилатометра. Нађено је да PVAформира графт полимер са PEG и да постоји специфична интеракција полимера саповршином честица оксида.
PB  - Belgrade : Association for ETRAN Society
T2  - Science of Sintering
T1  - Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer
VL  - 55
SP  - 189
EP  - 2023
DO  - 10.2298/SOS220828005L
ER  - 
@article{
author = "Labus, Nebojsa and Krstić, Jugoslav and Matijašević, Srđan and Pavlović, Vladimir",
year = "2023",
abstract = "Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed., Смеша прахова састављена од ZnO, Mn2O3 (MnCO3) и Fe2O3 комбинацијепрахова је показивала ламинацију током пресовања. Поливинил алкохол (PVA) икомбинација PVA са полиетилен гликолом (PEG) који је додат као пластификатор, сууведени као полимерно везиво за пресовање оксидних прахова. Везиво је уведено такошто је формирана суспензија смеше различитих оксида прахова у полимерномраствору. Концентрације полимера и састави су варирани. Уклањањем растварачадобијени су нови материјали који се састоје од честица оксида повезаних полимерима.Ови хибридни материјали окарактерисани су методама ометене тоталне рефлексијефурије трансформисане инфрацрвене спектроскопије (ATR-FTIR) као идиференцијалне термичке анализе (DTA). Микроструктура је посматранатрансмисоном електронском микроскопијом (TEM). Оксид-полимер материјали супресовани на притиску од 200 MPa и ширење испреска током грејања је праћено у температурском опсегу од собне до 550ºC употребом дилатометра. Нађено је да PVAформира графт полимер са PEG и да постоји специфична интеракција полимера саповршином честица оксида.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "Science of Sintering",
title = "Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer",
volume = "55",
pages = "189-2023",
doi = "10.2298/SOS220828005L"
}
Labus, N., Krstić, J., Matijašević, S.,& Pavlović, V.. (2023). Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer. in Science of Sintering
Belgrade : Association for ETRAN Society., 55, 189-2023.
https://doi.org/10.2298/SOS220828005L
Labus N, Krstić J, Matijašević S, Pavlović V. Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer. in Science of Sintering. 2023;55:189-2023.
doi:10.2298/SOS220828005L .
Labus, Nebojsa, Krstić, Jugoslav, Matijašević, Srđan, Pavlović, Vladimir, "Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer" in Science of Sintering, 55 (2023):189-2023,
https://doi.org/10.2298/SOS220828005L . .

Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants

Pantović Pavlović, Marijana; Ignjatović, Nenad; Panić, Vladimir; Mirkov, Ivana; Kulaš, Jelena; Malešević, Anastasija; Pavlović, Miroslav

(Basel, Switzerland : MDPI, 2023)

TY  - JOUR
AU  - Pantović Pavlović, Marijana
AU  - Ignjatović, Nenad
AU  - Panić, Vladimir
AU  - Mirkov, Ivana
AU  - Kulaš, Jelena
AU  - Malešević, Anastasija
AU  - Pavlović, Miroslav
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6556
AB  - The aim of this work is in situ anodization/anaphoretic deposition of a nano amorphous calcium phosphate (ACP)/chitosan oligosaccharide lactate (ChOL) multifunctional hybrid coating decorated with selenium (Se) on a titanium substrate and in vivo investigation of its immunomodulatory and anti-inflammatory effect. Investigating phenomena at the implant–tissue interface of interest for controlled inflammation and immunomodulation was also the aim of the research. In our earlier research, we designed coatings based on ACP and ChOL on titanium with anticorrosive, antibacterial and biocompatible properties, while in the presented results we show that selenium addition makes this coating an immunomodulator. The immunomodulatory effect of the novel hybrid coating is characterized by the examination of the functional aspects in the tissue around the implant (in vivo): proinflammatory cytokines’ gene expression, M1 (iNOS) and M2 (Arg1) macrophages, fibrous capsule formation (TGF-β) and vascularization (VEGF). The EDS, FTIR and XRD analyses prove the formation of a ACP/ChOL/Se multifunctional hybrid coating on Ti and the presence of Se. A higher M2/M1 macrophage ratio in the ACP/ChOL/Se-coated implants compared to pure titanium implants (a higher level of Arg1 expression) is noted at all time points examined (after 7, 14 and 28 days). Lower inflammation measured by gene expression of proinflammatory cytokines IL-1β and TNF, lower expression of TGF-β in the surrounding tissue and higher IL-6 expression (solely at day 7 post-implantation) is noted in presence of the ACP/ChOL/Se-coated implants.
PB  - Basel, Switzerland : MDPI
T2  - Journal of Functional Biomaterials
T1  - Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants
VL  - 14
IS  - 4
SP  - 227
DO  - 10.3390/jfb14040227
ER  - 
@article{
author = "Pantović Pavlović, Marijana and Ignjatović, Nenad and Panić, Vladimir and Mirkov, Ivana and Kulaš, Jelena and Malešević, Anastasija and Pavlović, Miroslav",
year = "2023",
abstract = "The aim of this work is in situ anodization/anaphoretic deposition of a nano amorphous calcium phosphate (ACP)/chitosan oligosaccharide lactate (ChOL) multifunctional hybrid coating decorated with selenium (Se) on a titanium substrate and in vivo investigation of its immunomodulatory and anti-inflammatory effect. Investigating phenomena at the implant–tissue interface of interest for controlled inflammation and immunomodulation was also the aim of the research. In our earlier research, we designed coatings based on ACP and ChOL on titanium with anticorrosive, antibacterial and biocompatible properties, while in the presented results we show that selenium addition makes this coating an immunomodulator. The immunomodulatory effect of the novel hybrid coating is characterized by the examination of the functional aspects in the tissue around the implant (in vivo): proinflammatory cytokines’ gene expression, M1 (iNOS) and M2 (Arg1) macrophages, fibrous capsule formation (TGF-β) and vascularization (VEGF). The EDS, FTIR and XRD analyses prove the formation of a ACP/ChOL/Se multifunctional hybrid coating on Ti and the presence of Se. A higher M2/M1 macrophage ratio in the ACP/ChOL/Se-coated implants compared to pure titanium implants (a higher level of Arg1 expression) is noted at all time points examined (after 7, 14 and 28 days). Lower inflammation measured by gene expression of proinflammatory cytokines IL-1β and TNF, lower expression of TGF-β in the surrounding tissue and higher IL-6 expression (solely at day 7 post-implantation) is noted in presence of the ACP/ChOL/Se-coated implants.",
publisher = "Basel, Switzerland : MDPI",
journal = "Journal of Functional Biomaterials",
title = "Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants",
volume = "14",
number = "4",
pages = "227",
doi = "10.3390/jfb14040227"
}
Pantović Pavlović, M., Ignjatović, N., Panić, V., Mirkov, I., Kulaš, J., Malešević, A.,& Pavlović, M.. (2023). Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants. in Journal of Functional Biomaterials
Basel, Switzerland : MDPI., 14(4), 227.
https://doi.org/10.3390/jfb14040227
Pantović Pavlović M, Ignjatović N, Panić V, Mirkov I, Kulaš J, Malešević A, Pavlović M. Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants. in Journal of Functional Biomaterials. 2023;14(4):227.
doi:10.3390/jfb14040227 .
Pantović Pavlović, Marijana, Ignjatović, Nenad, Panić, Vladimir, Mirkov, Ivana, Kulaš, Jelena, Malešević, Anastasija, Pavlović, Miroslav, "Immunomodulatory Effects Mediated by Nano Amorphous Calcium Phosphate/Chitosan Oligosaccharide Lactate Coatings Decorated with Selenium on Titanium Implants" in Journal of Functional Biomaterials, 14, no. 4 (2023):227,
https://doi.org/10.3390/jfb14040227 . .
2
2

Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use

Pavlović, Miroslav; Pantović-Pavlović, Marijana

(Podgorica, Crna Gora : Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine, 2023)

TY  - CONF
AU  - Pavlović, Miroslav
AU  - Pantović-Pavlović, Marijana
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7033
AB  - Background: Titanium (Ti) is widely used in medical and dental implants. Calcium phosphate (CPs) coatings enhance Ti implants' osteoinductive properties, and additives further improve these coatings. Recently, a nano amorphous calcium phosphate (nACP) coating decorated with chitosane oligolactate (ChOL) and selenium (Se) showed immunomodulatory effects. This study investigates the surface morphology, composition, bioactivity, mechanical properties, and Se release mechanism of the nACP/ChOL/Se hybrid coating on Ti substrates. Amorphous calcium phosphate (ACP) was synthesized, and the ACP/ChOL/Se hybrid coating was deposited on Ti substrates using in situ anaphoretic deposition. Surface morphology was analyzed using SEM, AFM, XRD, and FTIR. The distribution of Se within the coating was examined with EDS. Bioactivity was evaluated in simulated body fluid (SBF), and adhesion was tested using a scratch test method. In vitro testing determined the release mechanism of Se. SEM images illustrated the surface morphology, while AFM provided a detailed analysis of surface roughness. XRD analysis revealed structural and phase composition, and EDS confirmed Se distribution within the coating. The coating exhibited bioactivity in SBF and showed good adhesion according to the scratch test. In vitro testing uncovered the release mechanism of Se from the coating. This study successfully characterized the surface morphology, composition, bioactivity, and Se release mechanism of the
nACP/ChOL/Se hybrid coating on Ti substrates, offering insights for developing immunomodulatory coatings for medical and dental applications.
PB  - Podgorica, Crna Gora : Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine
C3  - Proceedings - Fifth International Symposium on Corrosion and Materials Protection, Environmental Protection and Protection Against Fire, September 26-29, Bar, Montenegro
T1  - Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use
SP  - 22
EP  - 46
UR  - https://hdl.handle.net/21.15107/rcub_cer_7033
ER  - 
@conference{
author = "Pavlović, Miroslav and Pantović-Pavlović, Marijana",
year = "2023",
abstract = "Background: Titanium (Ti) is widely used in medical and dental implants. Calcium phosphate (CPs) coatings enhance Ti implants' osteoinductive properties, and additives further improve these coatings. Recently, a nano amorphous calcium phosphate (nACP) coating decorated with chitosane oligolactate (ChOL) and selenium (Se) showed immunomodulatory effects. This study investigates the surface morphology, composition, bioactivity, mechanical properties, and Se release mechanism of the nACP/ChOL/Se hybrid coating on Ti substrates. Amorphous calcium phosphate (ACP) was synthesized, and the ACP/ChOL/Se hybrid coating was deposited on Ti substrates using in situ anaphoretic deposition. Surface morphology was analyzed using SEM, AFM, XRD, and FTIR. The distribution of Se within the coating was examined with EDS. Bioactivity was evaluated in simulated body fluid (SBF), and adhesion was tested using a scratch test method. In vitro testing determined the release mechanism of Se. SEM images illustrated the surface morphology, while AFM provided a detailed analysis of surface roughness. XRD analysis revealed structural and phase composition, and EDS confirmed Se distribution within the coating. The coating exhibited bioactivity in SBF and showed good adhesion according to the scratch test. In vitro testing uncovered the release mechanism of Se from the coating. This study successfully characterized the surface morphology, composition, bioactivity, and Se release mechanism of the
nACP/ChOL/Se hybrid coating on Ti substrates, offering insights for developing immunomodulatory coatings for medical and dental applications.",
publisher = "Podgorica, Crna Gora : Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine",
journal = "Proceedings - Fifth International Symposium on Corrosion and Materials Protection, Environmental Protection and Protection Against Fire, September 26-29, Bar, Montenegro",
title = "Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use",
pages = "22-46",
url = "https://hdl.handle.net/21.15107/rcub_cer_7033"
}
Pavlović, M.,& Pantović-Pavlović, M.. (2023). Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use. in Proceedings - Fifth International Symposium on Corrosion and Materials Protection, Environmental Protection and Protection Against Fire, September 26-29, Bar, Montenegro
Podgorica, Crna Gora : Crnogorsko društvo za koroziju, zaštitu materijala i zaštitu životne sredine., 22-46.
https://hdl.handle.net/21.15107/rcub_cer_7033
Pavlović M, Pantović-Pavlović M. Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use. in Proceedings - Fifth International Symposium on Corrosion and Materials Protection, Environmental Protection and Protection Against Fire, September 26-29, Bar, Montenegro. 2023;:22-46.
https://hdl.handle.net/21.15107/rcub_cer_7033 .
Pavlović, Miroslav, Pantović-Pavlović, Marijana, "Novel Immunomodulatory and Anti-inflammatory Nano Amorphous Calcium Phosphate@Chitosan Oligolactate coatings on titanium substrate for potential medical and dental use" in Proceedings - Fifth International Symposium on Corrosion and Materials Protection, Environmental Protection and Protection Against Fire, September 26-29, Bar, Montenegro (2023):22-46,
https://hdl.handle.net/21.15107/rcub_cer_7033 .

Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid

Batinić, Petar M.; Đorđević, Verica; Obradović, Nataša S.; Krstić, Aleksandar D.; Stevanović, Sanja; Balanč, Bojana; Marković, Smilja; Pjanović, Rada; Mijin, Dušan; Bugarski, Branko

(Wiley, 2023)

TY  - JOUR
AU  - Batinić, Petar M.
AU  - Đorđević, Verica
AU  - Obradović, Nataša S.
AU  - Krstić, Aleksandar D.
AU  - Stevanović, Sanja
AU  - Balanč, Bojana
AU  - Marković, Smilja
AU  - Pjanović, Rada
AU  - Mijin, Dušan
AU  - Bugarski, Branko
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6422
AB  - Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.
PB  - Wiley
T2  - European Journal of Lipid Science and Technology
T1  - Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid
SP  - 2200169
DO  - 10.1002/ejlt.202200169
ER  - 
@article{
author = "Batinić, Petar M. and Đorđević, Verica and Obradović, Nataša S. and Krstić, Aleksandar D. and Stevanović, Sanja and Balanč, Bojana and Marković, Smilja and Pjanović, Rada and Mijin, Dušan and Bugarski, Branko",
year = "2023",
abstract = "Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.",
publisher = "Wiley",
journal = "European Journal of Lipid Science and Technology",
title = "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid",
pages = "2200169",
doi = "10.1002/ejlt.202200169"
}
Batinić, P. M., Đorđević, V., Obradović, N. S., Krstić, A. D., Stevanović, S., Balanč, B., Marković, S., Pjanović, R., Mijin, D.,& Bugarski, B.. (2023). Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology
Wiley., 2200169.
https://doi.org/10.1002/ejlt.202200169
Batinić PM, Đorđević V, Obradović NS, Krstić AD, Stevanović S, Balanč B, Marković S, Pjanović R, Mijin D, Bugarski B. Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology. 2023;:2200169.
doi:10.1002/ejlt.202200169 .
Batinić, Petar M., Đorđević, Verica, Obradović, Nataša S., Krstić, Aleksandar D., Stevanović, Sanja, Balanč, Bojana, Marković, Smilja, Pjanović, Rada, Mijin, Dušan, Bugarski, Branko, "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid" in European Journal of Lipid Science and Technology (2023):2200169,
https://doi.org/10.1002/ejlt.202200169 . .
1
1

Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid

Batinić, Petar M.; Đorđević, Verica; Obradović, Nataša S.; Krstić, Aleksandar D.; Stevanović, Sanja; Balanč, Bojana; Marković, Smilja; Pjanović, Rada; Mijin, Dušan; Bugarski, Branko

(Wiley, 2023)

TY  - JOUR
AU  - Batinić, Petar M.
AU  - Đorđević, Verica
AU  - Obradović, Nataša S.
AU  - Krstić, Aleksandar D.
AU  - Stevanović, Sanja
AU  - Balanč, Bojana
AU  - Marković, Smilja
AU  - Pjanović, Rada
AU  - Mijin, Dušan
AU  - Bugarski, Branko
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6421
AB  - Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.
PB  - Wiley
T2  - European Journal of Lipid Science and Technology
T1  - Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid
SP  - 2200169
DO  - 10.1002/ejlt.202200169
ER  - 
@article{
author = "Batinić, Petar M. and Đorđević, Verica and Obradović, Nataša S. and Krstić, Aleksandar D. and Stevanović, Sanja and Balanč, Bojana and Marković, Smilja and Pjanović, Rada and Mijin, Dušan and Bugarski, Branko",
year = "2023",
abstract = "Liposome-encapsulated folic acid was incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of carboxymethyl cellulose and solagum (9:1 w/w) using the film-forming cast solution method. Histidine was used to increase solubility for folic acid in liposomes (1-5 mg/ml), and propylene glycol was used as a film plasticizer (2.6 mas%). The obtained films (50-60 µm tick) containing 3.12-20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films were scrutinized. Folic acid gave yellow color to the films and contributed to stronger chemical bonds which resulted in improved strength of the film. Liposomes prolonged the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degraded homogeneity of the films, which could be ascribed to its agglomeration within the film matrix as revealed by AFM. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg/ml liposome-encapsulated folic acid is recommended from the point of view of release kinetics determined by its solubility.  Practical application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.",
publisher = "Wiley",
journal = "European Journal of Lipid Science and Technology",
title = "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid",
pages = "2200169",
doi = "10.1002/ejlt.202200169"
}
Batinić, P. M., Đorđević, V., Obradović, N. S., Krstić, A. D., Stevanović, S., Balanč, B., Marković, S., Pjanović, R., Mijin, D.,& Bugarski, B.. (2023). Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology
Wiley., 2200169.
https://doi.org/10.1002/ejlt.202200169
Batinić PM, Đorđević V, Obradović NS, Krstić AD, Stevanović S, Balanč B, Marković S, Pjanović R, Mijin D, Bugarski B. Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid. in European Journal of Lipid Science and Technology. 2023;:2200169.
doi:10.1002/ejlt.202200169 .
Batinić, Petar M., Đorđević, Verica, Obradović, Nataša S., Krstić, Aleksandar D., Stevanović, Sanja, Balanč, Bojana, Marković, Smilja, Pjanović, Rada, Mijin, Dušan, Bugarski, Branko, "Polymer‐lipid matrice based on carboxymethyl cellulose/solagum and liposomes for controlled release of folic acid" in European Journal of Lipid Science and Technology (2023):2200169,
https://doi.org/10.1002/ejlt.202200169 . .
1
1

A Novel Two-Step Electrochemical Deposition Method for Sn-Pd Electrocatalyst Synthesis for a Potential Application in Direct Ethanol Fuel Cells

Lović, Jelena; Eraković Pantović, Sanja; Rakočević, Lazar; Ignjatović, Nenad L.; Dimitrijević, Silvana; Nikolić, Nebojša D.

(MDPI, 2023)

TY  - JOUR
AU  - Lović, Jelena
AU  - Eraković Pantović, Sanja
AU  - Rakočević, Lazar
AU  - Ignjatović, Nenad L.
AU  - Dimitrijević, Silvana
AU  - Nikolić, Nebojša D.
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5515
AB  - Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for 
potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current 
density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.
PB  - MDPI
T2  - Processes
T1  - A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells
VL  - 11
IS  - 1
SP  - 120
DO  - 10.3390/pr11010120
ER  - 
@article{
author = "Lović, Jelena and Eraković Pantović, Sanja and Rakočević, Lazar and Ignjatović, Nenad L. and Dimitrijević, Silvana and Nikolić, Nebojša D.",
year = "2023",
abstract = "Sn-Pd electrocatalysts with a constant atomic ratio of 60 at.% Sn‒40 at.% Pd suitable for 
potential application in direct ethanol fuel cells were synthesized using a novel two-step electrodeposition method. First, Sn was electrodeposited in various forms of dendrites, from spear-like and needle-like to individual fern-like dendrites to a network of intertwined fern-like dendrites, by varying the cathodic potential and then performing electrodeposition of Pd at a constant current 
density in the second step. A morphological and elemental analysis of Sn and Sn-Pd electrocatalysts was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) techniques, while the size of Sn dendrites was analyzed using the particle size distribution (PSD) method. Cyclic voltammetry (CV) and chronoamperometry were applied in order to study the catalytic behavior of Sn-Pd electrocatalysts in the ethanol oxidation reaction (EOR), while CO stripping was used to estimate the antipoisoning capability of the electrocatalysts. The Sn surface morphology of the sub-layer was highly correlated with the electrocatalytic activity of the examined Sn-Pd electrocatalysts. The high activity it presented towards the EOR showed the suitability of the Sn-Pd electrocatalyst constructed from individual fern-like Sn dendrites as a sub-layer. Compared to Pd alone, this Sn-Pd catalyst showed more than 3 times higher activity and improved EOR kinetics. This enhancement in the catalytic activity of the Sn-Pd electrocatalysts is attributed to both the morphological characteristics of Sn as a sub-layer and the bifunctional effect.",
publisher = "MDPI",
journal = "Processes",
title = "A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells",
volume = "11",
number = "1",
pages = "120",
doi = "10.3390/pr11010120"
}
Lović, J., Eraković Pantović, S., Rakočević, L., Ignjatović, N. L., Dimitrijević, S.,& Nikolić, N. D.. (2023). A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells. in Processes
MDPI., 11(1), 120.
https://doi.org/10.3390/pr11010120
Lović J, Eraković Pantović S, Rakočević L, Ignjatović NL, Dimitrijević S, Nikolić ND. A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells. in Processes. 2023;11(1):120.
doi:10.3390/pr11010120 .
Lović, Jelena, Eraković Pantović, Sanja, Rakočević, Lazar, Ignjatović, Nenad L., Dimitrijević, Silvana, Nikolić, Nebojša D., "A Novel Two-Step Electrochemical Deposition Method for  Sn-Pd Electrocatalyst Synthesis for a Potential Application in  Direct Ethanol Fuel Cells" in Processes, 11, no. 1 (2023):120,
https://doi.org/10.3390/pr11010120 . .
2

Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications

Pantović-Pavlović, Marijana; Ignjatović, Nenad; Panić, Vladimir; Pavlović, Miroslav M.

(Split : Central and EasternEuropeanCommittee for Thermal Analysis and Calorimetry (CEEC-TAC), 2022)

TY  - CONF
AU  - Pantović-Pavlović, Marijana
AU  - Ignjatović, Nenad
AU  - Panić, Vladimir
AU  - Pavlović, Miroslav M.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5539
AB  - This paper deals with the issue of defining a new method of anodizing/anaphoretic deposition for the application of calcium phosphate and hybrid coatings based on calcium phosphate ceramics on titanium and anodized titanium coatings with improved properties. Hybrid coatings consisted of chitosan oligolactate (ChOL) and ChOL with Se as immunomodulatory oligoelement. The paper contributes to solving the problem of multi-stage pre-treatment and posttreatment of titanium and oxidized titanium surface to obtain a coating on the substrate, adhesion of the coating, antimicrobial and cytotoxic properties that occur in biomaterials, as well as reduced immune inflammatory response of the organism. It primarily deals with the creation and optimization of a new in situ anodizing/anaphoretic deposition process for obtaining multifunctional composite biomaterials. The in situ method results in improved adhesion bioactive coating, increased bioactivity and biocompatibility with increased antimicrobial properties and absence of cytotoxicity. The studied biomaterials have improved properties such as: corrosion resistance, absence of toxicity to the human body and adequate strength, which enables their potential use in medicine and dentistry. The aim of the research was to define new in situ anodizing/anaphoretic deposition process and adequate modification of process parameters for application of composite calcium phosphate coatings on titanium and its alloys, wherein innovation is reflected in combining calcium phosphate coating synthesis and surface modification by partially incorporating a ceramic coating into the crystalline structure of the substrate. The characterization of the coatings obtained in this manner was performed by various physico-chemical, biochemical and biological methods. These characterization techniques included: AFM, SEM, FE-SEM, roughness testing, XRD, FTIR, bioactivity, biocompatibility, cytotoxicity, antimicrobial activity and in vivo testing.
PB  - Split : Central and EasternEuropeanCommittee for Thermal Analysis and Calorimetry (CEEC-TAC)
C3  - Book of abstracts of the ISt Central and Eastern European Conference on Physical Chemistry and Materials Science (CEEC-PCMS1))
T1  - Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications
SP  - 44
EP  - 44
UR  - https://hdl.handle.net/21.15107/rcub_dais_13653
ER  - 
@conference{
author = "Pantović-Pavlović, Marijana and Ignjatović, Nenad and Panić, Vladimir and Pavlović, Miroslav M.",
year = "2022",
abstract = "This paper deals with the issue of defining a new method of anodizing/anaphoretic deposition for the application of calcium phosphate and hybrid coatings based on calcium phosphate ceramics on titanium and anodized titanium coatings with improved properties. Hybrid coatings consisted of chitosan oligolactate (ChOL) and ChOL with Se as immunomodulatory oligoelement. The paper contributes to solving the problem of multi-stage pre-treatment and posttreatment of titanium and oxidized titanium surface to obtain a coating on the substrate, adhesion of the coating, antimicrobial and cytotoxic properties that occur in biomaterials, as well as reduced immune inflammatory response of the organism. It primarily deals with the creation and optimization of a new in situ anodizing/anaphoretic deposition process for obtaining multifunctional composite biomaterials. The in situ method results in improved adhesion bioactive coating, increased bioactivity and biocompatibility with increased antimicrobial properties and absence of cytotoxicity. The studied biomaterials have improved properties such as: corrosion resistance, absence of toxicity to the human body and adequate strength, which enables their potential use in medicine and dentistry. The aim of the research was to define new in situ anodizing/anaphoretic deposition process and adequate modification of process parameters for application of composite calcium phosphate coatings on titanium and its alloys, wherein innovation is reflected in combining calcium phosphate coating synthesis and surface modification by partially incorporating a ceramic coating into the crystalline structure of the substrate. The characterization of the coatings obtained in this manner was performed by various physico-chemical, biochemical and biological methods. These characterization techniques included: AFM, SEM, FE-SEM, roughness testing, XRD, FTIR, bioactivity, biocompatibility, cytotoxicity, antimicrobial activity and in vivo testing.",
publisher = "Split : Central and EasternEuropeanCommittee for Thermal Analysis and Calorimetry (CEEC-TAC)",
journal = "Book of abstracts of the ISt Central and Eastern European Conference on Physical Chemistry and Materials Science (CEEC-PCMS1))",
title = "Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications",
pages = "44-44",
url = "https://hdl.handle.net/21.15107/rcub_dais_13653"
}
Pantović-Pavlović, M., Ignjatović, N., Panić, V.,& Pavlović, M. M.. (2022). Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications. in Book of abstracts of the ISt Central and Eastern European Conference on Physical Chemistry and Materials Science (CEEC-PCMS1))
Split : Central and EasternEuropeanCommittee for Thermal Analysis and Calorimetry (CEEC-TAC)., 44-44.
https://hdl.handle.net/21.15107/rcub_dais_13653
Pantović-Pavlović M, Ignjatović N, Panić V, Pavlović MM. Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications. in Book of abstracts of the ISt Central and Eastern European Conference on Physical Chemistry and Materials Science (CEEC-PCMS1)). 2022;:44-44.
https://hdl.handle.net/21.15107/rcub_dais_13653 .
Pantović-Pavlović, Marijana, Ignjatović, Nenad, Panić, Vladimir, Pavlović, Miroslav M., "Advanced hybrid composite coatings based on calcium phosphate on titanium for potential biomedical applications" in Book of abstracts of the ISt Central and Eastern European Conference on Physical Chemistry and Materials Science (CEEC-PCMS1)) (2022):44-44,
https://hdl.handle.net/21.15107/rcub_dais_13653 .

Novel Calcium Phosphate Coatings with Selenum on Titanium

Pantović-Pavlović, Marijana; Ignjatović, Nenad; Panić, Vladimir; Pavlović, Miroslav M.

(Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM, 2022)

TY  - CONF
AU  - Pantović-Pavlović, Marijana
AU  - Ignjatović, Nenad
AU  - Panić, Vladimir
AU  - Pavlović, Miroslav M.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5540
AB  - This paper deals with the deposition of calcium phosphate and hybrid coatings based on calcium phosphate ceramics on titanium with improved properties by in situ anodization/anaphoretic deposition process. Hybrid coatings consisted of chitosan oligolactate (ChOL) and ChOL with Se as immunomodulatory oligoelement. The paper contributes to solving the problem of multi-stage pre-treatment and post-treatment of titanium and oxidized titanium surface to obtain a coating on the substrate, adhesion of the coating, antimicrobial and cytotoxic properties that occur in biomaterials, as well as reduced immune inflammatory response of the organism. The in situ method results in improved adhesion bioactive coating, increased bioactivity and biocompatibility with increased antimicrobial properties and absence of cytotoxicity. The studied biomaterials have improved properties such as: corrosion resistance, absence of toxicity to the human body and adequate strength, which enables their potential use in medicine and dentistry. The innovation is reflected in combining calcium phosphate coating synthesis and surface modification by partially incorporating a ceramic coating into the crystalline structure of the substrate. The characterization of the coatings obtained in this manner was performed by various physico-chemical, biochemical and biological methods. These characterization techniques included: FE-SEM, XRD, FTIR, cytotoxicity and in vivo testing.
PB  - Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXIII YuCorr International Conference = XXIII YuCorr Međunarodna konferencija, May 16-19, 2022, Divčibare, Serbia
T1  - Novel Calcium Phosphate Coatings with Selenum on Titanium
SP  - poster-102
UR  - https://hdl.handle.net/21.15107/rcub_dais_13652
ER  - 
@conference{
author = "Pantović-Pavlović, Marijana and Ignjatović, Nenad and Panić, Vladimir and Pavlović, Miroslav M.",
year = "2022",
abstract = "This paper deals with the deposition of calcium phosphate and hybrid coatings based on calcium phosphate ceramics on titanium with improved properties by in situ anodization/anaphoretic deposition process. Hybrid coatings consisted of chitosan oligolactate (ChOL) and ChOL with Se as immunomodulatory oligoelement. The paper contributes to solving the problem of multi-stage pre-treatment and post-treatment of titanium and oxidized titanium surface to obtain a coating on the substrate, adhesion of the coating, antimicrobial and cytotoxic properties that occur in biomaterials, as well as reduced immune inflammatory response of the organism. The in situ method results in improved adhesion bioactive coating, increased bioactivity and biocompatibility with increased antimicrobial properties and absence of cytotoxicity. The studied biomaterials have improved properties such as: corrosion resistance, absence of toxicity to the human body and adequate strength, which enables their potential use in medicine and dentistry. The innovation is reflected in combining calcium phosphate coating synthesis and surface modification by partially incorporating a ceramic coating into the crystalline structure of the substrate. The characterization of the coatings obtained in this manner was performed by various physico-chemical, biochemical and biological methods. These characterization techniques included: FE-SEM, XRD, FTIR, cytotoxicity and in vivo testing.",
publisher = "Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXIII YuCorr International Conference = XXIII YuCorr Međunarodna konferencija, May 16-19, 2022, Divčibare, Serbia",
title = "Novel Calcium Phosphate Coatings with Selenum on Titanium",
pages = "poster-102",
url = "https://hdl.handle.net/21.15107/rcub_dais_13652"
}
Pantović-Pavlović, M., Ignjatović, N., Panić, V.,& Pavlović, M. M.. (2022). Novel Calcium Phosphate Coatings with Selenum on Titanium. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXIII YuCorr International Conference = XXIII YuCorr Međunarodna konferencija, May 16-19, 2022, Divčibare, Serbia
Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM., poster-102.
https://hdl.handle.net/21.15107/rcub_dais_13652
Pantović-Pavlović M, Ignjatović N, Panić V, Pavlović MM. Novel Calcium Phosphate Coatings with Selenum on Titanium. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXIII YuCorr International Conference = XXIII YuCorr Međunarodna konferencija, May 16-19, 2022, Divčibare, Serbia. 2022;:poster-102.
https://hdl.handle.net/21.15107/rcub_dais_13652 .
Pantović-Pavlović, Marijana, Ignjatović, Nenad, Panić, Vladimir, Pavlović, Miroslav M., "Novel Calcium Phosphate Coatings with Selenum on Titanium" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXIII YuCorr International Conference = XXIII YuCorr Međunarodna konferencija, May 16-19, 2022, Divčibare, Serbia (2022):poster-102,
https://hdl.handle.net/21.15107/rcub_dais_13652 .

The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes

Pagnacco, Maja; Marković, Smilja; Potočnik, Jelena; Krstić, Vesna; Tančić, Pavle; Mojović, Miloš; Mojović, Zorica

(The Electrochemical Society, 2022)

TY  - JOUR
AU  - Pagnacco, Maja
AU  - Marković, Smilja
AU  - Potočnik, Jelena
AU  - Krstić, Vesna
AU  - Tančić, Pavle
AU  - Mojović, Miloš
AU  - Mojović, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5387
AB  - Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.
PB  - The Electrochemical Society
T2  - Journal of Electrochemical Society
T1  - The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes
VL  - 169
IS  - 10
SP  - 106508
DO  - 10.1149/1945-7111/ac96ab
ER  - 
@article{
author = "Pagnacco, Maja and Marković, Smilja and Potočnik, Jelena and Krstić, Vesna and Tančić, Pavle and Mojović, Miloš and Mojović, Zorica",
year = "2022",
abstract = "Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.",
publisher = "The Electrochemical Society",
journal = "Journal of Electrochemical Society",
title = "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes",
volume = "169",
number = "10",
pages = "106508",
doi = "10.1149/1945-7111/ac96ab"
}
Pagnacco, M., Marković, S., Potočnik, J., Krstić, V., Tančić, P., Mojović, M.,& Mojović, Z.. (2022). The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society
The Electrochemical Society., 169(10), 106508.
https://doi.org/10.1149/1945-7111/ac96ab
Pagnacco M, Marković S, Potočnik J, Krstić V, Tančić P, Mojović M, Mojović Z. The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society. 2022;169(10):106508.
doi:10.1149/1945-7111/ac96ab .
Pagnacco, Maja, Marković, Smilja, Potočnik, Jelena, Krstić, Vesna, Tančić, Pavle, Mojović, Miloš, Mojović, Zorica, "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes" in Journal of Electrochemical Society, 169, no. 10 (2022):106508,
https://doi.org/10.1149/1945-7111/ac96ab . .
1
1

The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes

Pagnacco, Maja; Marković, Smilja; Potočnik, Jelena; Krstić, Vesna; Tančić, Pavle; Mojović, Miloš; Mojović, Zorica

(The Electrochemical Society, 2022)

TY  - JOUR
AU  - Pagnacco, Maja
AU  - Marković, Smilja
AU  - Potočnik, Jelena
AU  - Krstić, Vesna
AU  - Tančić, Pavle
AU  - Mojović, Miloš
AU  - Mojović, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5553
AB  - Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.
PB  - The Electrochemical Society
T2  - Journal of Electrochemical Society
T1  - The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes
VL  - 169
IS  - 10
SP  - 106508
DO  - 10.1149/1945-7111/ac96ab
ER  - 
@article{
author = "Pagnacco, Maja and Marković, Smilja and Potočnik, Jelena and Krstić, Vesna and Tančić, Pavle and Mojović, Miloš and Mojović, Zorica",
year = "2022",
abstract = "Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.",
publisher = "The Electrochemical Society",
journal = "Journal of Electrochemical Society",
title = "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes",
volume = "169",
number = "10",
pages = "106508",
doi = "10.1149/1945-7111/ac96ab"
}
Pagnacco, M., Marković, S., Potočnik, J., Krstić, V., Tančić, P., Mojović, M.,& Mojović, Z.. (2022). The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society
The Electrochemical Society., 169(10), 106508.
https://doi.org/10.1149/1945-7111/ac96ab
Pagnacco M, Marković S, Potočnik J, Krstić V, Tančić P, Mojović M, Mojović Z. The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society. 2022;169(10):106508.
doi:10.1149/1945-7111/ac96ab .
Pagnacco, Maja, Marković, Smilja, Potočnik, Jelena, Krstić, Vesna, Tančić, Pavle, Mojović, Miloš, Mojović, Zorica, "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes" in Journal of Electrochemical Society, 169, no. 10 (2022):106508,
https://doi.org/10.1149/1945-7111/ac96ab . .
1
1

Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards

Batas-Bjelić, Ilija; Anđelković, Uroš; Stojanović, Boban; Georgijević, Milosav

(Belgrade : University of Belgrade - Faculty of Physical Chemistry, 2022)

TY  - CONF
AU  - Batas-Bjelić, Ilija
AU  - Anđelković, Uroš
AU  - Stojanović, Boban
AU  - Georgijević, Milosav
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5497
AB  - Energy systems of the future should enable transition to clean energy and reduction of CO2 emission. Various options are under consideration and research. One direction of development are photovoltaic, and rechargeable batteries used to store the electricity needed for vehicles and stationary systems (1,2). At the current technological level and market attractiveness among rechargeable batteries significant group are those based on lithium. EU production of raw materials for all batteries is about 1%. Growing demand for lithium are expected in 2050 to be 10-50 times higher than 2018. A lithium deficit in the market is expected (3,4). The companies are searching new locations for lithium mining and production facilities in order to compensate for the deficit.The mineral named Jadarit found in Serbia, contains lithium, sodium, boron and silica. Estimated reserves of Jadarit are of low significance for World production of lithium, but may be significant at EU level and for Serbian economy. Certain companies are interested to enter the production chain from Jadarit. These companies present the possibility for future industrial battery development in Serbia, which may lead innovative final products. They claim optimistic 3-15% increase of GDP (5). Public debate provided argumented shortcomings of currently proposed technology for lithium extraction from Jadarit (6). Major concerns are regarding permanent devastation of lush ecosystem, fertile soil, drinking water, air pollution. These non-monetary assets and their contribution to GDP should be monetized as sine qua non for objective cost-benefit analysis. Therefore, instead of polarization, public debate that identifies key critical points in technology of lithium extraction and its effects on human health and environment provides basis for future research that will develop new technologies capable to protect environment.
PB  - Belgrade : University of Belgrade - Faculty of Physical Chemistry
C3  - Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
T1  - Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards
UR  - https://hdl.handle.net/21.15107/rcub_dais_13012
ER  - 
@conference{
author = "Batas-Bjelić, Ilija and Anđelković, Uroš and Stojanović, Boban and Georgijević, Milosav",
year = "2022",
abstract = "Energy systems of the future should enable transition to clean energy and reduction of CO2 emission. Various options are under consideration and research. One direction of development are photovoltaic, and rechargeable batteries used to store the electricity needed for vehicles and stationary systems (1,2). At the current technological level and market attractiveness among rechargeable batteries significant group are those based on lithium. EU production of raw materials for all batteries is about 1%. Growing demand for lithium are expected in 2050 to be 10-50 times higher than 2018. A lithium deficit in the market is expected (3,4). The companies are searching new locations for lithium mining and production facilities in order to compensate for the deficit.The mineral named Jadarit found in Serbia, contains lithium, sodium, boron and silica. Estimated reserves of Jadarit are of low significance for World production of lithium, but may be significant at EU level and for Serbian economy. Certain companies are interested to enter the production chain from Jadarit. These companies present the possibility for future industrial battery development in Serbia, which may lead innovative final products. They claim optimistic 3-15% increase of GDP (5). Public debate provided argumented shortcomings of currently proposed technology for lithium extraction from Jadarit (6). Major concerns are regarding permanent devastation of lush ecosystem, fertile soil, drinking water, air pollution. These non-monetary assets and their contribution to GDP should be monetized as sine qua non for objective cost-benefit analysis. Therefore, instead of polarization, public debate that identifies key critical points in technology of lithium extraction and its effects on human health and environment provides basis for future research that will develop new technologies capable to protect environment.",
publisher = "Belgrade : University of Belgrade - Faculty of Physical Chemistry",
journal = "Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022",
title = "Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards",
url = "https://hdl.handle.net/21.15107/rcub_dais_13012"
}
Batas-Bjelić, I., Anđelković, U., Stojanović, B.,& Georgijević, M.. (2022). Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022
Belgrade : University of Belgrade - Faculty of Physical Chemistry..
https://hdl.handle.net/21.15107/rcub_dais_13012
Batas-Bjelić I, Anđelković U, Stojanović B, Georgijević M. Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards. in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022. 2022;.
https://hdl.handle.net/21.15107/rcub_dais_13012 .
Batas-Bjelić, Ilija, Anđelković, Uroš, Stojanović, Boban, Georgijević, Milosav, "Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards" in Contemporary batteries and supercapacitors : COIN2022 : program and book of abstracts / International Symposium Belgrade, June 1-2, 2022 (2022),
https://hdl.handle.net/21.15107/rcub_dais_13012 .

Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards

Batas-Bjelić, Ilija; Anđelković, Uroš; Stojanović, Boban; Georgijević, Milosav

(2022)

TY  - CONF
AU  - Batas-Bjelić, Ilija
AU  - Anđelković, Uroš
AU  - Stojanović, Boban
AU  - Georgijević, Milosav
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5498
AB  - Energy systems of the future should enable transition to clean energy and reduction of CO2 emission. Various options are under consideration and research. One direction of development are photovoltaic, and rechargeable batteries used to store the electricity needed for vehicles and stationary systems (1,2). At the current technological level and market attractiveness among rechargeable batteries significant group are those based on lithium. EU production of raw materials for all batteries is about 1%. Growing demand for lithium are expected in 2050 to be 10-50 times higher than 2018. A lithium deficit in the market is expected (3,4). The companies are searching new locations for lithium mining and production facilities in order to compensate for the deficit.The mineral named Jadarit found in Serbia, contains lithium, sodium, boron and silica. Estimated reserves of Jadarit are of low significance for World production of lithium, but may be significant at EU level and for Serbian economy. Certain companies are interested to enter the production chain from Jadarit. These companies present the possibility for future industrial battery development in Serbia, which may lead innovative final products. They claim optimistic 3-15% increase of GDP (5). Public debate provided argumented shortcomings of currently proposed technology for lithium extraction from Jadarit (6). Major concerns are regarding permanent devastation of lush ecosystem, fertile soil, drinking water, air pollution. These non-monetary assets and their contribution to GDP should be monetized as sine qua non for objective cost-benefit analysis. Therefore, instead of polarization, public debate that identifies key critical points in technology of lithium extraction and its effects on human health and environment provides basis for future research that will develop new technologies capable to protect environment.
T1  - Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards
UR  - https://hdl.handle.net/21.15107/rcub_cer_5498
ER  - 
@conference{
author = "Batas-Bjelić, Ilija and Anđelković, Uroš and Stojanović, Boban and Georgijević, Milosav",
year = "2022",
abstract = "Energy systems of the future should enable transition to clean energy and reduction of CO2 emission. Various options are under consideration and research. One direction of development are photovoltaic, and rechargeable batteries used to store the electricity needed for vehicles and stationary systems (1,2). At the current technological level and market attractiveness among rechargeable batteries significant group are those based on lithium. EU production of raw materials for all batteries is about 1%. Growing demand for lithium are expected in 2050 to be 10-50 times higher than 2018. A lithium deficit in the market is expected (3,4). The companies are searching new locations for lithium mining and production facilities in order to compensate for the deficit.The mineral named Jadarit found in Serbia, contains lithium, sodium, boron and silica. Estimated reserves of Jadarit are of low significance for World production of lithium, but may be significant at EU level and for Serbian economy. Certain companies are interested to enter the production chain from Jadarit. These companies present the possibility for future industrial battery development in Serbia, which may lead innovative final products. They claim optimistic 3-15% increase of GDP (5). Public debate provided argumented shortcomings of currently proposed technology for lithium extraction from Jadarit (6). Major concerns are regarding permanent devastation of lush ecosystem, fertile soil, drinking water, air pollution. These non-monetary assets and their contribution to GDP should be monetized as sine qua non for objective cost-benefit analysis. Therefore, instead of polarization, public debate that identifies key critical points in technology of lithium extraction and its effects on human health and environment provides basis for future research that will develop new technologies capable to protect environment.",
title = "Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards",
url = "https://hdl.handle.net/21.15107/rcub_cer_5498"
}
Batas-Bjelić, I., Anđelković, U., Stojanović, B.,& Georgijević, M.. (2022). Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards. .
https://hdl.handle.net/21.15107/rcub_cer_5498
Batas-Bjelić I, Anđelković U, Stojanović B, Georgijević M. Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards. 2022;.
https://hdl.handle.net/21.15107/rcub_cer_5498 .
Batas-Bjelić, Ilija, Anđelković, Uroš, Stojanović, Boban, Georgijević, Milosav, "Challenges in Sustainable Use of Lithium for Highly Innovative Final Products Created and Made in Serbia with EU Environmental Standards" (2022),
https://hdl.handle.net/21.15107/rcub_cer_5498 .

Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation

Jonović, Marko; Jugović, Branimir; Žuža, Milena; Đorđević, Verica; Milašinović, Nikola; Bugarski, Branko; Knežević-Jugović, Zorica

(MDPI, 2022)

TY  - JOUR
AU  - Jonović, Marko
AU  - Jugović, Branimir
AU  - Žuža, Milena
AU  - Đorđević, Verica
AU  - Milašinović, Nikola
AU  - Bugarski, Branko
AU  - Knežević-Jugović, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5239
AB  - The aim of this study was to investigate covalent immobilization of horseradish peroxidase (HRP) on magnetic nanoparticles (Mag) encapsulated in calcium alginate beads (MABs) for color degradation, combining easy and fast removal of biocatalyst from the reaction mixture due to its magnetic properties and strong binding due to surface alginate functional groups. MABs obtained by extrusion techniques were analyzed by optical microscopy, FEG-SEM and characterized regarding mechanical properties, magnetization and HRP binding. HRP with initial concentration of 10 mg/gcarrier was successfully covalently bonded on MABs (diameter ~1 mm, magnetite/alginate ratio 1:4), with protein loading of 8.9 mg/gcarrier, immobilization yield 96.9% and activity 32.8 U/g. Immobilized HRP on MABs (HRP-MABs) was then used to catalyze degradation of two anthraquinonic dyes, Acid Blue 225 (AB225) and Acid Violet 109 (AV109), as models for wastewater pollutants. HRP-MABs decolorized 77.3% and 76.1% of AV109 and AB225, respectively after 15 min under optimal conditions (0.097 mM H2O2, 200 mg of HRP-MABs (8.9 mg/gcarrier), 0.08 and 0.1 g/mg beads/dye ratio for AV109 and AB225, respectively). Biocatalyst was used for 7 repeated cycles retaining 75% and 51% of initial activity for AB225 and AV109, respectively, showing potential for use in large scale applications for colored wastewater treatment.
PB  - MDPI
T2  - Polymers
T1  - Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation
VL  - 14
IS  - 13
SP  - 2614
DO  - 10.3390/polym14132614
ER  - 
@article{
author = "Jonović, Marko and Jugović, Branimir and Žuža, Milena and Đorđević, Verica and Milašinović, Nikola and Bugarski, Branko and Knežević-Jugović, Zorica",
year = "2022",
abstract = "The aim of this study was to investigate covalent immobilization of horseradish peroxidase (HRP) on magnetic nanoparticles (Mag) encapsulated in calcium alginate beads (MABs) for color degradation, combining easy and fast removal of biocatalyst from the reaction mixture due to its magnetic properties and strong binding due to surface alginate functional groups. MABs obtained by extrusion techniques were analyzed by optical microscopy, FEG-SEM and characterized regarding mechanical properties, magnetization and HRP binding. HRP with initial concentration of 10 mg/gcarrier was successfully covalently bonded on MABs (diameter ~1 mm, magnetite/alginate ratio 1:4), with protein loading of 8.9 mg/gcarrier, immobilization yield 96.9% and activity 32.8 U/g. Immobilized HRP on MABs (HRP-MABs) was then used to catalyze degradation of two anthraquinonic dyes, Acid Blue 225 (AB225) and Acid Violet 109 (AV109), as models for wastewater pollutants. HRP-MABs decolorized 77.3% and 76.1% of AV109 and AB225, respectively after 15 min under optimal conditions (0.097 mM H2O2, 200 mg of HRP-MABs (8.9 mg/gcarrier), 0.08 and 0.1 g/mg beads/dye ratio for AV109 and AB225, respectively). Biocatalyst was used for 7 repeated cycles retaining 75% and 51% of initial activity for AB225 and AV109, respectively, showing potential for use in large scale applications for colored wastewater treatment.",
publisher = "MDPI",
journal = "Polymers",
title = "Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation",
volume = "14",
number = "13",
pages = "2614",
doi = "10.3390/polym14132614"
}
Jonović, M., Jugović, B., Žuža, M., Đorđević, V., Milašinović, N., Bugarski, B.,& Knežević-Jugović, Z.. (2022). Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation. in Polymers
MDPI., 14(13), 2614.
https://doi.org/10.3390/polym14132614
Jonović M, Jugović B, Žuža M, Đorđević V, Milašinović N, Bugarski B, Knežević-Jugović Z. Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation. in Polymers. 2022;14(13):2614.
doi:10.3390/polym14132614 .
Jonović, Marko, Jugović, Branimir, Žuža, Milena, Đorđević, Verica, Milašinović, Nikola, Bugarski, Branko, Knežević-Jugović, Zorica, "Immobilization of Horseradish Peroxidase on Magnetite-Alginate Beads to Enable Effective Strong Binding and Enzyme Recycling during Anthraquinone Dyes’ Degradation" in Polymers, 14, no. 13 (2022):2614,
https://doi.org/10.3390/polym14132614 . .
8
6

Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana; Mirković, Miljana; Pavlović, Vladimir; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(Belgrade : International Institute for the Science of Sintering, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana
AU  - Mirković, Miljana
AU  - Pavlović, Vladimir
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4356
AB  - Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.
PB  - Belgrade : International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction
VL  - 53
SP  - 1
EP  - 8
DO  - 10.2298/SOS2101001F
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana and Mirković, Miljana and Pavlović, Vladimir and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3 and Fe2O3 was used to produce a multiferroic heterostructure composite. Commercial BaTiO3 and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300 oC for 6 h. Sintering at 1300 oC for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19 and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3 phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3 with Fe2O3 resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature.",
publisher = "Belgrade : International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction",
volume = "53",
pages = "1-8",
doi = "10.2298/SOS2101001F"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J., Mirković, M., Pavlović, V., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering
Belgrade : International Institute for the Science of Sintering., 53, 1-8.
https://doi.org/10.2298/SOS2101001F
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović J, Mirković M, Pavlović V, Jeremić D, Vlahović B, Đorđević A. Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction. in Science of Sintering. 2021;53:1-8.
doi:10.2298/SOS2101001F .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana, Mirković, Miljana, Pavlović, Vladimir, Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic Heterostructure BaTiO3/ε-Fe2O3 Composite Obtained by in situ Reaction" in Science of Sintering, 53 (2021):1-8,
https://doi.org/10.2298/SOS2101001F . .
2
1

Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu

Pantović Pavlović, Marijana R.; Pavlović, Miroslav M.; Stevanović, Jasmina S.; Panić, Vladimir; Ignjatović, Nenad

(Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM, 2021)

TY  - CONF
AU  - Pantović Pavlović, Marijana R.
AU  - Pavlović, Miroslav M.
AU  - Stevanović, Jasmina S.
AU  - Panić, Vladimir
AU  - Ignjatović, Nenad
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5268
AB  - Kalcijum fosfati (CP), među kojima su amorfni kalcijum fosfat (ACP) i hidroksiapatit (HAp), zajedno sa slojevima Ti i TiO2, pronašli su ogromnu primenu u preventivnoj i regenerativnoj medicini zbog svoje odlične biokompatibilnosti, netoksičnih svojstava i sposobnosti da učestvuju u metaboličnim procesima organizama. U ovom radu je prikazana citotoksičnost multifunkcionalnih i hibridnih kompozitnih prevlaka amorfnog kalcijum fosfata (ACP) i hitozan laktata (ChOL) na ćelijskoj liniji humanih fibroblasta pluća MRC-5. ACP/TiO2 i ACP/TiO2/ChOL prevlake su taložene novim procesom in situ anodizacije/anaforetske depozicije pri konstantnom naponu od 60 V tokom 180 s na 25 ° C. Testovi citotoksičnosti pokazali su da nije bilo značajnog smanjenja preživljavanja zdravih ćelija MRC-5 u kompozitnim uzorcima Ti i ACP/TiO2, dok je došlo do povećanja broja viabilnih ćelija u uzorku ACP/TiO2/ChOL. Pokazano je poboljšanje ćelijske proliferacije, diferencijacije i viabilnosti ćelija. Uzorak koji sadrži ACP/TiO2/ChOL prevlaku pokazao je negativnu citotoksičnost u DET i u MTT testovima. Zabeležen je veći oporavak humanih ćelija fibroblasta pluća MRC-5 u poređenju sa kontrolnim uzorkom posle 48 h oporavka. Iz ovih rezultata može se zaključiti da multifunkcionalna kompozitna prevlaka ACP/TiO2/ChOL nije samo necitotoksična, već prisustvo ChOL-a u prevlaci poboljšava ćelijsku proliferaciju, diferencijaciju i viabilnost ćelija. Na osnovu dobijenih rezultata može se zaključiti da oba kompozitna materijala koji su korišćeni u studijama nisu citotoksični za korišćene ćelijske linije, te da 5 tež.% ChOL-a ima pozitivan efekat na netoksičnost materijala. Na osnovu prikazanih rezultata u ovom radu i prethodnih objavljenih rezultata fizičko-hemijskih i bioaktivnih svojstava kompozitnog materijala ACP/TiO2/ChOL, može se zaključiti da bi dalji razvoj, kao i potencijalne pretkliničke studije bili u velikoj meri opravdani.
AB  - Calcium phosphates (CP), amongst which amorphous calcium phosphate (ACP) and hydroxyapatite (HAp), along with Ti and TiO2 layers, have found vast applications in preventive and regenerative medicine due to their excellent biocompatibility, nontoxic properties and ability to participate in the normal metabolism of organisms. In this paper cytotoxicity of amorphous calcium phosphate (ACP) and chitosan lactate (ChOL) multifunctional and hybrid composite coatings on MRC-5 human lung fibroblast cell line is presented. ACP/TiO2 and ACP/TiO2/ChOL are deposited by coatings new in situ anodization/anaphoretic deposition process at constant voltage of 60 V for 180 s at 25 °C. Cytotoxicity tests showed that there was no significant decrease in the survival of healthy MRC-5 cells in the Ti and ACP/TiO2 composite samples, while there was an increase in the number of viable cells in the ACP/TiO2/ChOL sample. There is improved cell proliferation, differentiation and cell viability in the later. Sample containing ACP/TiO2/ChOL coating showed negative cytotoxicity in both DET and MTT tests. Greater recovery of MRC-5 human lung fibroblasts cells was observed compared to the control sample after 48 h of recovery. From these results, it can be concluded that not only the ACP/TiO2/ChOL multifunctional composite coating is non-cytotoxic, but the presence of ChOL in the coating improves cell proliferation, differentiation and cell viability. Based on the obtained results, it can be concluded that both composite materials used in the studies are non-cytotoxic to the cell lines used, and that 5 wt.% of ChOL has a positive effect on the non-toxicity of the material. Based on presented results in this paper and previous published results of the physicochemical and bioactive properties of the ACP/TiO2/ChOL composite material, it can be concluded that further development as well as potential preclinical studies would be largely justified.
PB  - Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM
C3  - Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia
T1  - Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu
T1  - Comparison of bioactivity, cytotoxicity, antimicrobial and corrosive behavior of ceramic coatings with and without polymer on titanium
SP  - INVITED-21
UR  - https://hdl.handle.net/21.15107/rcub_dais_12363
ER  - 
@conference{
author = "Pantović Pavlović, Marijana R. and Pavlović, Miroslav M. and Stevanović, Jasmina S. and Panić, Vladimir and Ignjatović, Nenad",
year = "2021",
abstract = "Kalcijum fosfati (CP), među kojima su amorfni kalcijum fosfat (ACP) i hidroksiapatit (HAp), zajedno sa slojevima Ti i TiO2, pronašli su ogromnu primenu u preventivnoj i regenerativnoj medicini zbog svoje odlične biokompatibilnosti, netoksičnih svojstava i sposobnosti da učestvuju u metaboličnim procesima organizama. U ovom radu je prikazana citotoksičnost multifunkcionalnih i hibridnih kompozitnih prevlaka amorfnog kalcijum fosfata (ACP) i hitozan laktata (ChOL) na ćelijskoj liniji humanih fibroblasta pluća MRC-5. ACP/TiO2 i ACP/TiO2/ChOL prevlake su taložene novim procesom in situ anodizacije/anaforetske depozicije pri konstantnom naponu od 60 V tokom 180 s na 25 ° C. Testovi citotoksičnosti pokazali su da nije bilo značajnog smanjenja preživljavanja zdravih ćelija MRC-5 u kompozitnim uzorcima Ti i ACP/TiO2, dok je došlo do povećanja broja viabilnih ćelija u uzorku ACP/TiO2/ChOL. Pokazano je poboljšanje ćelijske proliferacije, diferencijacije i viabilnosti ćelija. Uzorak koji sadrži ACP/TiO2/ChOL prevlaku pokazao je negativnu citotoksičnost u DET i u MTT testovima. Zabeležen je veći oporavak humanih ćelija fibroblasta pluća MRC-5 u poređenju sa kontrolnim uzorkom posle 48 h oporavka. Iz ovih rezultata može se zaključiti da multifunkcionalna kompozitna prevlaka ACP/TiO2/ChOL nije samo necitotoksična, već prisustvo ChOL-a u prevlaci poboljšava ćelijsku proliferaciju, diferencijaciju i viabilnost ćelija. Na osnovu dobijenih rezultata može se zaključiti da oba kompozitna materijala koji su korišćeni u studijama nisu citotoksični za korišćene ćelijske linije, te da 5 tež.% ChOL-a ima pozitivan efekat na netoksičnost materijala. Na osnovu prikazanih rezultata u ovom radu i prethodnih objavljenih rezultata fizičko-hemijskih i bioaktivnih svojstava kompozitnog materijala ACP/TiO2/ChOL, može se zaključiti da bi dalji razvoj, kao i potencijalne pretkliničke studije bili u velikoj meri opravdani., Calcium phosphates (CP), amongst which amorphous calcium phosphate (ACP) and hydroxyapatite (HAp), along with Ti and TiO2 layers, have found vast applications in preventive and regenerative medicine due to their excellent biocompatibility, nontoxic properties and ability to participate in the normal metabolism of organisms. In this paper cytotoxicity of amorphous calcium phosphate (ACP) and chitosan lactate (ChOL) multifunctional and hybrid composite coatings on MRC-5 human lung fibroblast cell line is presented. ACP/TiO2 and ACP/TiO2/ChOL are deposited by coatings new in situ anodization/anaphoretic deposition process at constant voltage of 60 V for 180 s at 25 °C. Cytotoxicity tests showed that there was no significant decrease in the survival of healthy MRC-5 cells in the Ti and ACP/TiO2 composite samples, while there was an increase in the number of viable cells in the ACP/TiO2/ChOL sample. There is improved cell proliferation, differentiation and cell viability in the later. Sample containing ACP/TiO2/ChOL coating showed negative cytotoxicity in both DET and MTT tests. Greater recovery of MRC-5 human lung fibroblasts cells was observed compared to the control sample after 48 h of recovery. From these results, it can be concluded that not only the ACP/TiO2/ChOL multifunctional composite coating is non-cytotoxic, but the presence of ChOL in the coating improves cell proliferation, differentiation and cell viability. Based on the obtained results, it can be concluded that both composite materials used in the studies are non-cytotoxic to the cell lines used, and that 5 wt.% of ChOL has a positive effect on the non-toxicity of the material. Based on presented results in this paper and previous published results of the physicochemical and bioactive properties of the ACP/TiO2/ChOL composite material, it can be concluded that further development as well as potential preclinical studies would be largely justified.",
publisher = "Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM",
journal = "Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia",
title = "Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu, Comparison of bioactivity, cytotoxicity, antimicrobial and corrosive behavior of ceramic coatings with and without polymer on titanium",
pages = "INVITED-21",
url = "https://hdl.handle.net/21.15107/rcub_dais_12363"
}
Pantović Pavlović, M. R., Pavlović, M. M., Stevanović, J. S., Panić, V.,& Ignjatović, N.. (2021). Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia
Beograd : Udruženje inženjera Srbije za koroziju i zaštitu materijala UISKOZAM., INVITED-21.
https://hdl.handle.net/21.15107/rcub_dais_12363
Pantović Pavlović MR, Pavlović MM, Stevanović JS, Panić V, Ignjatović N. Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu. in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia. 2021;:INVITED-21.
https://hdl.handle.net/21.15107/rcub_dais_12363 .
Pantović Pavlović, Marijana R., Pavlović, Miroslav M., Stevanović, Jasmina S., Panić, Vladimir, Ignjatović, Nenad, "Upoređivanje bioaktivnosti, citotoksičnosti, antimikrobnih i korozivnih svojstava keramičkih prevlaka sa i bez polimera na titanu" in Meeting point of the science and practice in the fields of corrosion, materials and environmental protection : proceedings = Stecište nauke i prakse u oblastima korozije, zaštite materijala i životne sredine : knjiga radova / XXII YuCorr International Conference = XXI YuCorr [Jugoslovenska korozija] Međunarodna konferencija, September 13-16, 2021, Tara Mountain, Serbia (2021):INVITED-21,
https://hdl.handle.net/21.15107/rcub_dais_12363 .

Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties

Pantović Pavlović, Marijana; Stanojević, Boris P.; Pavlović, Miroslav M.; Mihailović, Marija; Stevanović, Jasmina; Panić, Vladimir; Ignjatović, Nenad

(American Chemical Society (ACS), 2021)

TY  - JOUR
AU  - Pantović Pavlović, Marijana
AU  - Stanojević, Boris P.
AU  - Pavlović, Miroslav M.
AU  - Mihailović, Marija
AU  - Stevanović, Jasmina
AU  - Panić, Vladimir
AU  - Ignjatović, Nenad
PY  - 2021
UR  - https://dais.sanu.ac.rs/123456789/11739
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4793
AB  - The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. The coatings were obtained by new single-step in situ anodization of the substrate to generate TiO2 and the anaphoretic electrodeposition process of ACP and ChOL. The obtained coatings were around 300 ± 15 μm thick and consisted of two phases, namely, TiO2 and hybrid composite phases. Both ACP/TiO2 and ACP + ChOL/TiO2 have improved corrosion stability, whereas the ACP + ChOL/TiO2 coating showed better corrosion stability. It was shown that at the very start of the deposition process, the formation of the ChOL/TiO2 layer takes place predominantly, which is followed by the inclusion of ChOL into ACP with simultaneous growth of TiO2. This deposition mechanism resulted in the formation of strongly bonded uniform stable coating with high corrosion resistance. In vitro bioactivity was investigated by immersion of the samples in simulated body fluid (SBF). There is in-bone-like apatite formation on both ACP/TiO2 and ACP + ChOL/TiO2 surfaces upon immersion into SBF, which was proven by X-ray diffraction and Fourier transform infrared spectroscopy. While ACP/TiO2 shows no antibacterial activity, ACP + ChOL/TiO2 samples exhibited three- to fourfold decreases in the number of Staphylococcus aureus and Pseudomonas aeruginosa, respectively, after 420 min. The probable mechanism is binding ChOL with the bacterial cell wall, inhibiting its growth, altering the permeability of the cell membrane, and leading to bacterial death.
PB  - American Chemical Society (ACS)
T2  - ACS Biomaterials Science & Engineering
T1  - Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties
VL  - 7
IS  - 7
SP  - 3088
EP  - 3102
DO  - 10.1021/acsbiomaterials.1c00035
ER  - 
@article{
author = "Pantović Pavlović, Marijana and Stanojević, Boris P. and Pavlović, Miroslav M. and Mihailović, Marija and Stevanović, Jasmina and Panić, Vladimir and Ignjatović, Nenad",
year = "2021",
abstract = "The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. The coatings were obtained by new single-step in situ anodization of the substrate to generate TiO2 and the anaphoretic electrodeposition process of ACP and ChOL. The obtained coatings were around 300 ± 15 μm thick and consisted of two phases, namely, TiO2 and hybrid composite phases. Both ACP/TiO2 and ACP + ChOL/TiO2 have improved corrosion stability, whereas the ACP + ChOL/TiO2 coating showed better corrosion stability. It was shown that at the very start of the deposition process, the formation of the ChOL/TiO2 layer takes place predominantly, which is followed by the inclusion of ChOL into ACP with simultaneous growth of TiO2. This deposition mechanism resulted in the formation of strongly bonded uniform stable coating with high corrosion resistance. In vitro bioactivity was investigated by immersion of the samples in simulated body fluid (SBF). There is in-bone-like apatite formation on both ACP/TiO2 and ACP + ChOL/TiO2 surfaces upon immersion into SBF, which was proven by X-ray diffraction and Fourier transform infrared spectroscopy. While ACP/TiO2 shows no antibacterial activity, ACP + ChOL/TiO2 samples exhibited three- to fourfold decreases in the number of Staphylococcus aureus and Pseudomonas aeruginosa, respectively, after 420 min. The probable mechanism is binding ChOL with the bacterial cell wall, inhibiting its growth, altering the permeability of the cell membrane, and leading to bacterial death.",
publisher = "American Chemical Society (ACS)",
journal = "ACS Biomaterials Science & Engineering",
title = "Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties",
volume = "7",
number = "7",
pages = "3088-3102",
doi = "10.1021/acsbiomaterials.1c00035"
}
Pantović Pavlović, M., Stanojević, B. P., Pavlović, M. M., Mihailović, M., Stevanović, J., Panić, V.,& Ignjatović, N.. (2021). Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties. in ACS Biomaterials Science & Engineering
American Chemical Society (ACS)., 7(7), 3088-3102.
https://doi.org/10.1021/acsbiomaterials.1c00035
Pantović Pavlović M, Stanojević BP, Pavlović MM, Mihailović M, Stevanović J, Panić V, Ignjatović N. Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties. in ACS Biomaterials Science & Engineering. 2021;7(7):3088-3102.
doi:10.1021/acsbiomaterials.1c00035 .
Pantović Pavlović, Marijana, Stanojević, Boris P., Pavlović, Miroslav M., Mihailović, Marija, Stevanović, Jasmina, Panić, Vladimir, Ignjatović, Nenad, "Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties" in ACS Biomaterials Science & Engineering, 7, no. 7 (2021):3088-3102,
https://doi.org/10.1021/acsbiomaterials.1c00035 . .
2
16
1
14

Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties

Pantović Pavlović, Marijana; Stanojević, Boris P.; Pavlović, Miroslav M.; Mihailović, Marija; Stevanović, Jasmina; Panić, Vladimir; Ignjatović, Nenad

(American Chemical Society (ACS), 2021)

TY  - JOUR
AU  - Pantović Pavlović, Marijana
AU  - Stanojević, Boris P.
AU  - Pavlović, Miroslav M.
AU  - Mihailović, Marija
AU  - Stevanović, Jasmina
AU  - Panić, Vladimir
AU  - Ignjatović, Nenad
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4794
AB  - The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. The coatings were obtained by new single-step in situ anodization of the substrate to generate TiO2 and the anaphoretic electrodeposition process of ACP and ChOL. The obtained coatings were around 300 ± 15 μm thick and consisted of two phases, namely, TiO2 and hybrid composite phases. Both ACP/TiO2 and ACP + ChOL/TiO2 have improved corrosion stability, whereas the ACP + ChOL/TiO2 coating showed better corrosion stability. It was shown that at the very start of the deposition process, the formation of the ChOL/TiO2 layer takes place predominantly, which is followed by the inclusion of ChOL into ACP with simultaneous growth of TiO2. This deposition mechanism resulted in the formation of strongly bonded uniform stable coating with high corrosion resistance. In vitro bioactivity was investigated by immersion of the samples in simulated body fluid (SBF). There is in-bone-like apatite formation on both ACP/TiO2 and ACP + ChOL/TiO2 surfaces upon immersion into SBF, which was proven by X-ray diffraction and Fourier transform infrared spectroscopy. While ACP/TiO2 shows no antibacterial activity, ACP + ChOL/TiO2 samples exhibited three- to fourfold decreases in the number of Staphylococcus aureus and Pseudomonas aeruginosa, respectively, after 420 min. The probable mechanism is binding ChOL with the bacterial cell wall, inhibiting its growth, altering the permeability of the cell membrane, and leading to bacterial death.
PB  - American Chemical Society (ACS)
T2  - ACS Biomaterials Science & Engineering
T1  - Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties
VL  - 7
IS  - 7
SP  - 3088
EP  - 3102
DO  - 10.1021/acsbiomaterials.1c00035
ER  - 
@article{
author = "Pantović Pavlović, Marijana and Stanojević, Boris P. and Pavlović, Miroslav M. and Mihailović, Marija and Stevanović, Jasmina and Panić, Vladimir and Ignjatović, Nenad",
year = "2021",
abstract = "The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. The coatings were obtained by new single-step in situ anodization of the substrate to generate TiO2 and the anaphoretic electrodeposition process of ACP and ChOL. The obtained coatings were around 300 ± 15 μm thick and consisted of two phases, namely, TiO2 and hybrid composite phases. Both ACP/TiO2 and ACP + ChOL/TiO2 have improved corrosion stability, whereas the ACP + ChOL/TiO2 coating showed better corrosion stability. It was shown that at the very start of the deposition process, the formation of the ChOL/TiO2 layer takes place predominantly, which is followed by the inclusion of ChOL into ACP with simultaneous growth of TiO2. This deposition mechanism resulted in the formation of strongly bonded uniform stable coating with high corrosion resistance. In vitro bioactivity was investigated by immersion of the samples in simulated body fluid (SBF). There is in-bone-like apatite formation on both ACP/TiO2 and ACP + ChOL/TiO2 surfaces upon immersion into SBF, which was proven by X-ray diffraction and Fourier transform infrared spectroscopy. While ACP/TiO2 shows no antibacterial activity, ACP + ChOL/TiO2 samples exhibited three- to fourfold decreases in the number of Staphylococcus aureus and Pseudomonas aeruginosa, respectively, after 420 min. The probable mechanism is binding ChOL with the bacterial cell wall, inhibiting its growth, altering the permeability of the cell membrane, and leading to bacterial death.",
publisher = "American Chemical Society (ACS)",
journal = "ACS Biomaterials Science & Engineering",
title = "Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties",
volume = "7",
number = "7",
pages = "3088-3102",
doi = "10.1021/acsbiomaterials.1c00035"
}
Pantović Pavlović, M., Stanojević, B. P., Pavlović, M. M., Mihailović, M., Stevanović, J., Panić, V.,& Ignjatović, N.. (2021). Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties. in ACS Biomaterials Science & Engineering
American Chemical Society (ACS)., 7(7), 3088-3102.
https://doi.org/10.1021/acsbiomaterials.1c00035
Pantović Pavlović M, Stanojević BP, Pavlović MM, Mihailović M, Stevanović J, Panić V, Ignjatović N. Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties. in ACS Biomaterials Science & Engineering. 2021;7(7):3088-3102.
doi:10.1021/acsbiomaterials.1c00035 .
Pantović Pavlović, Marijana, Stanojević, Boris P., Pavlović, Miroslav M., Mihailović, Marija, Stevanović, Jasmina, Panić, Vladimir, Ignjatović, Nenad, "Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties" in ACS Biomaterials Science & Engineering, 7, no. 7 (2021):3088-3102,
https://doi.org/10.1021/acsbiomaterials.1c00035 . .
2
16
1
14

Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”

Pantović Pavlović, Marijana; Stanojević, Boris; Pavlović, Miroslav M.; Mihailović, Marija; Stevanović, Jasmina; Panić, Vladimir; Ignjatović, Nenad

(American Chemical Society (ACS), 2021)

TY  - DATA
AU  - Pantović Pavlović, Marijana
AU  - Stanojević, Boris
AU  - Pavlović, Miroslav M.
AU  - Mihailović, Marija
AU  - Stevanović, Jasmina
AU  - Panić, Vladimir
AU  - Ignjatović, Nenad
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4795
AB  - The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. Supplementary information: The ANOVA results of antimicrobial activity on S. aureus are shown in Table S1 and the ANOVA results of antimicrobial activity on P. aeruginosa are shown in Table S2. The analysis showed significant difference at the 5% level of confidence.
PB  - American Chemical Society (ACS)
T2  - ACS Biomaterials Science & Engineering
T1  - Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”
VL  - 7
IS  - 7
UR  - https://hdl.handle.net/21.15107/rcub_cer_4795
ER  - 
@misc{
author = "Pantović Pavlović, Marijana and Stanojević, Boris and Pavlović, Miroslav M. and Mihailović, Marija and Stevanović, Jasmina and Panić, Vladimir and Ignjatović, Nenad",
year = "2021",
abstract = "The aim of this work was to investigate corrosion resistivity, bioactivity, and antibacterial activity of novel nano-amorphous calcium phosphate (ACP) potentially multifunctional composite coatings with and without chitosan oligosaccharide lactate (ChOL), ACP + ChOL/TiO2 and ACP/TiO2 ACP + ChOL/TiO2, respectively, on the titanium substrate. Supplementary information: The ANOVA results of antimicrobial activity on S. aureus are shown in Table S1 and the ANOVA results of antimicrobial activity on P. aeruginosa are shown in Table S2. The analysis showed significant difference at the 5% level of confidence.",
publisher = "American Chemical Society (ACS)",
journal = "ACS Biomaterials Science & Engineering",
title = "Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”",
volume = "7",
number = "7",
url = "https://hdl.handle.net/21.15107/rcub_cer_4795"
}
Pantović Pavlović, M., Stanojević, B., Pavlović, M. M., Mihailović, M., Stevanović, J., Panić, V.,& Ignjatović, N.. (2021). Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”. in ACS Biomaterials Science & Engineering
American Chemical Society (ACS)., 7(7).
https://hdl.handle.net/21.15107/rcub_cer_4795
Pantović Pavlović M, Stanojević B, Pavlović MM, Mihailović M, Stevanović J, Panić V, Ignjatović N. Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”. in ACS Biomaterials Science & Engineering. 2021;7(7).
https://hdl.handle.net/21.15107/rcub_cer_4795 .
Pantović Pavlović, Marijana, Stanojević, Boris, Pavlović, Miroslav M., Mihailović, Marija, Stevanović, Jasmina, Panić, Vladimir, Ignjatović, Nenad, "Supplementary information for: “Anodizing/Anaphoretic Electrodeposition of Nano-Calcium Phosphate/Chitosan Lactate Multifunctional Coatings on Titanium with Advanced Corrosion Resistance, Bioactivity, and Antibacterial Properties.”" in ACS Biomaterials Science & Engineering, 7, no. 7 (2021),
https://hdl.handle.net/21.15107/rcub_cer_4795 .

Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition

Pantović Pavlović, Marijana; Pavlović, Miroslav M.; Kovačina, Jovanka; Stanojević, Boris P.; Stevanović, Jasmina S.; Panić, Vladimir; Ignjatović, Nenad L.

(Belgrade : Serbian Chemical Society, 2021)

TY  - JOUR
AU  - Pantović Pavlović, Marijana
AU  - Pavlović, Miroslav M.
AU  - Kovačina, Jovanka
AU  - Stanojević, Boris P.
AU  - Stevanović, Jasmina S.
AU  - Panić, Vladimir
AU  - Ignjatović, Nenad L.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4800
AB  - The cytotoxicity of amorphous calcium phosphate (ACP) and chitosan lactate (ChOL) multifunctional and hybrid composite coatings on MRC-5 human lung fibroblast cell line was elucidated. ACP/TiO2 and ACP/TiO2/ /ChOL were deposited onto Ti by a novel in situ anodization/anaphoretic process at constant voltage. Cytotoxicity tests showed that there was no significant decrease in the survival of healthy MRC-5 cells exposed to composite samples without chitosan lactate, while there was an increase in the number of viable cells in the sample containing ChOL. These findings show that there was improved cell proliferation, differentiation and cell viability in the ChOL-containing sample, which makes ACP/TiO2/ChOL coating a good candidate for applications in medicine and stomatology.
AB  - Приказани су резултати испитивања цитотоксичности мултифункционалних и хиб-
ридних композитних превлака на бази аморфног калцијум-фосфата (ACP) и хитозан-
-олиголактата (ChOL) на титану према MRC-5 ћелијској линији хуманих фибробласта
плућа. ACP/TiO2 и ACP/TiO2/ChOL су исталожени новим in situ поступком анодизације/
/анафоретског таложења под константним напоном од 60 V током 180 s на 25 °C. Тес-
тови цитотоксичности су показали да није дошло до значајног смањења преживљавања
здравих MRC-5 ћелија код композита који не садржи ChOL, док је код оних са додатим
ChOL дошло до повећања броја одрживих ћелија. Резултати показују да је побољшана
пролиферација, диференцијација и одрживост ћелија у узорку са ChOL, што овај узорак
чини добрим кандидатом за примену у медицини и стоматологији.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition
T1  - Citotoksičnost multifunkcionalnih kompozitnih prevlaka od amorfnog kalcijum-fosfata na titanu dobijenih in sity anodizacijom/anaforetskim taloženjem
VL  - 86
IS  - 6
SP  - 555
EP  - 559
DO  - 10.2298/JSC210211024P
ER  - 
@article{
author = "Pantović Pavlović, Marijana and Pavlović, Miroslav M. and Kovačina, Jovanka and Stanojević, Boris P. and Stevanović, Jasmina S. and Panić, Vladimir and Ignjatović, Nenad L.",
year = "2021",
abstract = "The cytotoxicity of amorphous calcium phosphate (ACP) and chitosan lactate (ChOL) multifunctional and hybrid composite coatings on MRC-5 human lung fibroblast cell line was elucidated. ACP/TiO2 and ACP/TiO2/ /ChOL were deposited onto Ti by a novel in situ anodization/anaphoretic process at constant voltage. Cytotoxicity tests showed that there was no significant decrease in the survival of healthy MRC-5 cells exposed to composite samples without chitosan lactate, while there was an increase in the number of viable cells in the sample containing ChOL. These findings show that there was improved cell proliferation, differentiation and cell viability in the ChOL-containing sample, which makes ACP/TiO2/ChOL coating a good candidate for applications in medicine and stomatology., Приказани су резултати испитивања цитотоксичности мултифункционалних и хиб-
ридних композитних превлака на бази аморфног калцијум-фосфата (ACP) и хитозан-
-олиголактата (ChOL) на титану према MRC-5 ћелијској линији хуманих фибробласта
плућа. ACP/TiO2 и ACP/TiO2/ChOL су исталожени новим in situ поступком анодизације/
/анафоретског таложења под константним напоном од 60 V током 180 s на 25 °C. Тес-
тови цитотоксичности су показали да није дошло до значајног смањења преживљавања
здравих MRC-5 ћелија код композита који не садржи ChOL, док је код оних са додатим
ChOL дошло до повећања броја одрживих ћелија. Резултати показују да је побољшана
пролиферација, диференцијација и одрживост ћелија у узорку са ChOL, што овај узорак
чини добрим кандидатом за примену у медицини и стоматологији.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition, Citotoksičnost multifunkcionalnih kompozitnih prevlaka od amorfnog kalcijum-fosfata na titanu dobijenih in sity anodizacijom/anaforetskim taloženjem",
volume = "86",
number = "6",
pages = "555-559",
doi = "10.2298/JSC210211024P"
}
Pantović Pavlović, M., Pavlović, M. M., Kovačina, J., Stanojević, B. P., Stevanović, J. S., Panić, V.,& Ignjatović, N. L.. (2021). Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 86(6), 555-559.
https://doi.org/10.2298/JSC210211024P
Pantović Pavlović M, Pavlović MM, Kovačina J, Stanojević BP, Stevanović JS, Panić V, Ignjatović NL. Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition. in Journal of the Serbian Chemical Society. 2021;86(6):555-559.
doi:10.2298/JSC210211024P .
Pantović Pavlović, Marijana, Pavlović, Miroslav M., Kovačina, Jovanka, Stanojević, Boris P., Stevanović, Jasmina S., Panić, Vladimir, Ignjatović, Nenad L., "Cytotoxicity of amorphous calcium phosphate multifunctional composite coatings on titanium obtained by in situ anodization/anaphoretic deposition" in Journal of the Serbian Chemical Society, 86, no. 6 (2021):555-559,
https://doi.org/10.2298/JSC210211024P . .
3
1
5

Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja

Mihailović, Marija; Jegdić, Bore; Jugović, Branimir; Kovačina, Jovanka; Radojković, Bojana; Patarić, Aleksandra; Jokić, Bojan

(Belgrade : University of Belgrade - Institute of Chemistry, Technology and Metallurgy, 2021)

TY  - GEN
AU  - Mihailović, Marija
AU  - Jegdić, Bore
AU  - Jugović, Branimir
AU  - Kovačina, Jovanka
AU  - Radojković, Bojana
AU  - Patarić, Aleksandra
AU  - Jokić, Bojan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4864
AB  - Praćenje pojave i brzine korozije, nastanak termičkih oksida na površini metalnih delova eletroenergetskog postrojenјa, kao i način njihovog otklanjanja na način koji je tehnološki pogodan, ekonomski pristupačan i ekološki opravdan prikazan je u ovom tehničkom rešenju Ispitivanjem je ustanovljeno da su metalni delovi na kojima se javlja korozija izrađeni od na nerđajućeg čelika AISI 304, pa je pojava korozije i termičkih oksida praćena je u odnosu na to, kao i sastav prašine sa kojom su metalni delovi u kontaktu. Pojava termičkih oksida na površini nerđajućih čelika posledica je povišene temperature na mestu zavarivanja metalnih delova.Merena je vrednost pH oba rastvora: etalonskog i zasićenog rastvoru prašine iz pogona.Sastav uzoraka prašine određen je FTIR metodom, pa su na osnovu prisutnih jona u rastvoru definisana ostala ispitivanja.Određivan je korozioni potencijal Ekor, vrednost otpora polarizacije Rp, kao i gustina struje korozije jkor. Sva ispitivanja nerđajućeg čelika u etalonskom rastvoru i u zasićenom rastvoru prašine iz pogona firme naručioca, rađena su za 1 sat i u toku 25 dana.Kao rezultat svih istražoivanja, date su tehnološke preporuke i način otklanjanja korozije i termičkih oksida.Rešenje je prodato naručuicu u toku 2020.godine, a od januara 2021.godine primenjeno u postrojenju naručioca, ELNOS BL d.o.o., koji su izjavom potvrdili primenu ovog tehničkog rešenja u svom poslovanju.
AB  - Monitoring the occurrence and rate of corrosion, the formation of thermal oxides on the surface of metal parts of the power plant, as well as the method of their elimination in a way that is technologically suitable, economically affordable and environmentally justified is shown in this technical solution. It has been established that the metal elements affected by corrosion were made from stainless steel AISI 304. Accordingly, the occurrence of corrosion and thermal oxides was monitored based on the material and the composition of the dust with which the metal parts are in contact. The emergence of thermal oxides on the surface of stainless steels is a consequence of the elevated temperature at the welding site.The pH value of both solutions was measured: standard and saturated solution of dust from the plant. The composition of the dust samples was determined by FTIR. The other tests were defined based on the ions present in the solution.The corrosion potential, the value of the polarization resistance, as well as the corrosion current density were determined. All tests of stainless steel in the standard solution and in the saturated solution of dust were performed for one hour within a span of 25 days.Technological recommendations on how to eliminate corrosion and thermal oxides are provided.The solution has been applied since January 2021 by ELNOS BL d.o.o.
PB  - Belgrade : University of Belgrade - Institute of Chemistry, Technology and Metallurgy
T1  - Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja
T1  - Possibility of removal of corrosion and thermal oxides on metal parts of electric power plant
UR  - https://hdl.handle.net/21.15107/rcub_dais_11630
ER  - 
@misc{
author = "Mihailović, Marija and Jegdić, Bore and Jugović, Branimir and Kovačina, Jovanka and Radojković, Bojana and Patarić, Aleksandra and Jokić, Bojan",
year = "2021",
abstract = "Praćenje pojave i brzine korozije, nastanak termičkih oksida na površini metalnih delova eletroenergetskog postrojenјa, kao i način njihovog otklanjanja na način koji je tehnološki pogodan, ekonomski pristupačan i ekološki opravdan prikazan je u ovom tehničkom rešenju Ispitivanjem je ustanovljeno da su metalni delovi na kojima se javlja korozija izrađeni od na nerđajućeg čelika AISI 304, pa je pojava korozije i termičkih oksida praćena je u odnosu na to, kao i sastav prašine sa kojom su metalni delovi u kontaktu. Pojava termičkih oksida na površini nerđajućih čelika posledica je povišene temperature na mestu zavarivanja metalnih delova.Merena je vrednost pH oba rastvora: etalonskog i zasićenog rastvoru prašine iz pogona.Sastav uzoraka prašine određen je FTIR metodom, pa su na osnovu prisutnih jona u rastvoru definisana ostala ispitivanja.Određivan je korozioni potencijal Ekor, vrednost otpora polarizacije Rp, kao i gustina struje korozije jkor. Sva ispitivanja nerđajućeg čelika u etalonskom rastvoru i u zasićenom rastvoru prašine iz pogona firme naručioca, rađena su za 1 sat i u toku 25 dana.Kao rezultat svih istražoivanja, date su tehnološke preporuke i način otklanjanja korozije i termičkih oksida.Rešenje je prodato naručuicu u toku 2020.godine, a od januara 2021.godine primenjeno u postrojenju naručioca, ELNOS BL d.o.o., koji su izjavom potvrdili primenu ovog tehničkog rešenja u svom poslovanju., Monitoring the occurrence and rate of corrosion, the formation of thermal oxides on the surface of metal parts of the power plant, as well as the method of their elimination in a way that is technologically suitable, economically affordable and environmentally justified is shown in this technical solution. It has been established that the metal elements affected by corrosion were made from stainless steel AISI 304. Accordingly, the occurrence of corrosion and thermal oxides was monitored based on the material and the composition of the dust with which the metal parts are in contact. The emergence of thermal oxides on the surface of stainless steels is a consequence of the elevated temperature at the welding site.The pH value of both solutions was measured: standard and saturated solution of dust from the plant. The composition of the dust samples was determined by FTIR. The other tests were defined based on the ions present in the solution.The corrosion potential, the value of the polarization resistance, as well as the corrosion current density were determined. All tests of stainless steel in the standard solution and in the saturated solution of dust were performed for one hour within a span of 25 days.Technological recommendations on how to eliminate corrosion and thermal oxides are provided.The solution has been applied since January 2021 by ELNOS BL d.o.o.",
publisher = "Belgrade : University of Belgrade - Institute of Chemistry, Technology and Metallurgy",
title = "Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja, Possibility of removal of corrosion and thermal oxides on metal parts of electric power plant",
url = "https://hdl.handle.net/21.15107/rcub_dais_11630"
}
Mihailović, M., Jegdić, B., Jugović, B., Kovačina, J., Radojković, B., Patarić, A.,& Jokić, B.. (2021). Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja. 
Belgrade : University of Belgrade - Institute of Chemistry, Technology and Metallurgy..
https://hdl.handle.net/21.15107/rcub_dais_11630
Mihailović M, Jegdić B, Jugović B, Kovačina J, Radojković B, Patarić A, Jokić B. Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja. 2021;.
https://hdl.handle.net/21.15107/rcub_dais_11630 .
Mihailović, Marija, Jegdić, Bore, Jugović, Branimir, Kovačina, Jovanka, Radojković, Bojana, Patarić, Aleksandra, Jokić, Bojan, "Ispitivanje i otklanјanјe pojave korozije i termičkih oksida na metalnim delovima elektroenergetskog postojenja" (2021),
https://hdl.handle.net/21.15107/rcub_dais_11630 .

Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins

Jonović, Marko; Žuža, Milena; Đorđević, Verica; Šekuljica, Nataša; Milivojević, Milan; Jugović, Branimir; Bugarski, Branko; Knežević-Jugović, Zorica

(MDPI, 2021)

TY  - JOUR
AU  - Jonović, Marko
AU  - Žuža, Milena
AU  - Đorđević, Verica
AU  - Šekuljica, Nataša
AU  - Milivojević, Milan
AU  - Jugović, Branimir
AU  - Bugarski, Branko
AU  - Knežević-Jugović, Zorica
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4834
AB  - Enzymatic hydrolysis of food proteins is convenient method to improve their functional properties and physiological activity. Herein, the successful covalent attachment of alcalase on alginate micron and submicron beads using the carbodiimide based chemistry reaction and the subsequent application of the beads for egg white and soy proteins hydrolysis were studied. In addition to the electrostatic extrusion technique (EE) previously used by others, the potential utilization of a novel ultrasonic spray atomization technique without drying (UA) and with drying (UAD) for alginate submicron beads production has been attempted. The immobilization parameters were optimized on microbeads obtained by EE technique (803 +/- 23 mu m) with respect to enzyme loading and alcalase activity. UA and UAD techniques resulted in much smaller particles (607 +/- 103 nm and 394 +/- 51 nm in diameter, respectively), enabling even higher enzyme loading of 671.6 +/- 4 mg g(-1) on the carrier and the highest immobilized alcalase activity of 2716.1 IU g(-1) in the standard reaction. The UAD biocatalyst exhibited also better performances in the real food system based on egg white or soy proteins. It has been shown that the immobilized alcalase can be reused in seven successive soy protein hydrolysis cycles with a little decrease in the activity.
PB  - MDPI
T2  - Catalysts
T1  - Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins
VL  - 11
IS  - 3
SP  - 305
DO  - 10.3390/catal11030305
ER  - 
@article{
author = "Jonović, Marko and Žuža, Milena and Đorđević, Verica and Šekuljica, Nataša and Milivojević, Milan and Jugović, Branimir and Bugarski, Branko and Knežević-Jugović, Zorica",
year = "2021",
abstract = "Enzymatic hydrolysis of food proteins is convenient method to improve their functional properties and physiological activity. Herein, the successful covalent attachment of alcalase on alginate micron and submicron beads using the carbodiimide based chemistry reaction and the subsequent application of the beads for egg white and soy proteins hydrolysis were studied. In addition to the electrostatic extrusion technique (EE) previously used by others, the potential utilization of a novel ultrasonic spray atomization technique without drying (UA) and with drying (UAD) for alginate submicron beads production has been attempted. The immobilization parameters were optimized on microbeads obtained by EE technique (803 +/- 23 mu m) with respect to enzyme loading and alcalase activity. UA and UAD techniques resulted in much smaller particles (607 +/- 103 nm and 394 +/- 51 nm in diameter, respectively), enabling even higher enzyme loading of 671.6 +/- 4 mg g(-1) on the carrier and the highest immobilized alcalase activity of 2716.1 IU g(-1) in the standard reaction. The UAD biocatalyst exhibited also better performances in the real food system based on egg white or soy proteins. It has been shown that the immobilized alcalase can be reused in seven successive soy protein hydrolysis cycles with a little decrease in the activity.",
publisher = "MDPI",
journal = "Catalysts",
title = "Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins",
volume = "11",
number = "3",
pages = "305",
doi = "10.3390/catal11030305"
}
Jonović, M., Žuža, M., Đorđević, V., Šekuljica, N., Milivojević, M., Jugović, B., Bugarski, B.,& Knežević-Jugović, Z.. (2021). Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins. in Catalysts
MDPI., 11(3), 305.
https://doi.org/10.3390/catal11030305
Jonović M, Žuža M, Đorđević V, Šekuljica N, Milivojević M, Jugović B, Bugarski B, Knežević-Jugović Z. Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins. in Catalysts. 2021;11(3):305.
doi:10.3390/catal11030305 .
Jonović, Marko, Žuža, Milena, Đorđević, Verica, Šekuljica, Nataša, Milivojević, Milan, Jugović, Branimir, Bugarski, Branko, Knežević-Jugović, Zorica, "Immobilized Alcalase on Micron- and Submicron-Sized Alginate Beads as a Potential Biocatalyst for Hydrolysis of Food Proteins" in Catalysts, 11, no. 3 (2021):305,
https://doi.org/10.3390/catal11030305 . .
5
6

Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis

Filipović, Suzana; Anđelković, Ljubica; Jeremić, Dejan; Vulić, Predrag; Nikolić, Aleksandar S.; Marković, Smilja; Paunović, Vesna; Lević, Steva; Pavlović, Vladimir B.

(International Institute for the Science of Sintering, 2020)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Anđelković, Ljubica
AU  - Jeremić, Dejan
AU  - Vulić, Predrag
AU  - Nikolić, Aleksandar S.
AU  - Marković, Smilja
AU  - Paunović, Vesna
AU  - Lević, Steva
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3709
AB  - Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.
PB  - International Institute for the Science of Sintering
T2  - Science of Sintering
T1  - Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis
VL  - 52
SP  - 257
EP  - 268
DO  - 10.2298/SOS2003257F
ER  - 
@article{
author = "Filipović, Suzana and Anđelković, Ljubica and Jeremić, Dejan and Vulić, Predrag and Nikolić, Aleksandar S. and Marković, Smilja and Paunović, Vesna and Lević, Steva and Pavlović, Vladimir B.",
year = "2020",
abstract = "Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180 degrees C, and within a variety of frequencies. Curie temperature was detected at 130 degrees C.",
publisher = "International Institute for the Science of Sintering",
journal = "Science of Sintering",
title = "Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis",
volume = "52",
pages = "257-268",
doi = "10.2298/SOS2003257F"
}
Filipović, S., Anđelković, L., Jeremić, D., Vulić, P., Nikolić, A. S., Marković, S., Paunović, V., Lević, S.,& Pavlović, V. B.. (2020). Structure and Properties of Nanocrystalline Tetragonal BaTiO3 Prepared by Combustion Solid State Synthesis. in Science of Sintering
International Institute for the Science of Sintering., 52, 257-268.
https://doi.org/10.2298/SOS2003257F
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