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Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)

Stojanović, Ksenija; Jovančićević, Branimir; Vitorović, Dragomir K.; Golovko, Yulia; Pevneva, Galina S.; Golovko, Anatoly Kuzmich

(Belgrade : Serbian Chemical Society, 2007)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Jovančićević, Branimir
AU  - Vitorović, Dragomir K.
AU  - Golovko, Yulia
AU  - Pevneva, Galina S.
AU  - Golovko, Anatoly Kuzmich
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4300
AB  - Twenty three crude oils from the Serbian part of the Pannonian Basin (14 from the Vojvodina Province and 9 from the Drmno Depression) were investigated, aimed at an evaluation of oil-oil maturity correlation parameters based on the distribution and abundance of saturated biomarkers and alkylarene constituents. Factor and cluster analyses were used for this purpose. Factor analyses using varimax rotation were first run separately, i.e., of maturity parameters based on the abundance of (a) n-alkanes and isoprenoids, (b) steranes and triterpanes, (c) alkylnaphthalenes, and (d) alkylphenanthrenes. These analyses yielded 9 important "maturity factors". Eight of them, showing higher than 30 % of variance, were further involved in another factor analysis, as well as in cluster analysis using the Ward method. In this way, all maturity parameters based on saturated biomarkers and alkylarenes were evaluated and ranged, considering the fact that the observed factors represented their linear combinations. The results showed that in the correlation of crude oils from the Serbian part of the Pannonian Basin, the most important were maturity parameters based on isomerization reactions involving one methyl group in thermodynamically less stable α-methylnaphthalenes, ethylnaphthalenes, dimethylnaphthalenes and methylphenanthrenes, and their change into more stable isomers with the methyl group in the β-position in the aromatic ring. Processes constituting high loadings factor 2 and factor 3 parameters were also defined. Hierarchy between the "factors" and parameters were controlled, and approved, by cluster analysis using the Ward method. Finally, the investigated crude oils were correlated by factor and cluster analyses, using all the important "maturity factors". Differences in maturity were observed between the Vojvodina and Drmno Depression crude oils, as well as between oils originating from South Banat, North Banat and the Velebit oil field (Vojvodina locality).
AB  - У овом раду је, применом новог приступа у факторској и кластерској анализи, евалуиран значај матурационих параметара заснованих на расподели и обилности засићених биомаркера и алкиларена у корелацији нафта–нафта на примеру 23 узорка сировe нафтe из дела Панонског басена у Србији (14 са локалитета у Војводини и 9 из депресије Дрмно). Факторске анализе су, уз примену varimax ротације, најпре извођене посебно са матура- ционим параметрима израчунатим из расподеле и обилности (а) n-алкана и изопреноидних алифатичних алкана, (б) стерана и тритерпана, (в) алкилнафталена и (г) алкилфенантрена. Ове анализе резултирале су са 9 значајних “матурационих фактора”. Осам од њих, који су показивали проценат варијације већи од 30 %, укључени су у нову факторску и кластерску анализу, уз примену Ward методе. На тај начин су сви матурациони параметри засновани на расподели и обилности засићених биомаркера и алкиларена били процењени и рангирани, имајући у виду чињеницу да фактори предстваљају њихове линеарне комбинације. Резултати су показали да су за корелацију нафти из дела Панонског басена у Србији најзначајанији матурациони параметри засновани на изомеризацији једне алкил-групе из α- у термодина- мички стабилније β-положаје на ароматичном прстену метилнафталена, етилнафталена, ди- метилнафталена, триметилнафталена и метилфенантрена. Такође, одређени су параметри/ти- пови матурационих реакција који су у великој мери дефинисали факторе 2 и 3. Редослед и сагласност између фактора, односно параметара, проверена је и потврђена кластерском ана- лизом уз примену Ward методе. Коначно, испитивани узорци сирове нафте су корелисани помоћу факторске и кластерске анализе, користећи све значајне “матурационе факторе”. Раз- лике у степену термичке зрелости уочене су како између узорака из Војводине и депресије Дрмно, тако и између узорака из Војводине који потичу из лежишта јужног Баната, северног Баната и нафтног поља Велебит.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)
T1  - Евалуација матурационих параметара заснованих на засићеним и  ароматичним угљоводоницима у корелацији нафта-нафта (југоисточни део панонског басена , Србија)
VL  - 72
IS  - 12
SP  - 1237
EP  - 1254
DO  - 10.2298/JSC0712237S
ER  - 
@article{
author = "Stojanović, Ksenija and Jovančićević, Branimir and Vitorović, Dragomir K. and Golovko, Yulia and Pevneva, Galina S. and Golovko, Anatoly Kuzmich",
year = "2007",
abstract = "Twenty three crude oils from the Serbian part of the Pannonian Basin (14 from the Vojvodina Province and 9 from the Drmno Depression) were investigated, aimed at an evaluation of oil-oil maturity correlation parameters based on the distribution and abundance of saturated biomarkers and alkylarene constituents. Factor and cluster analyses were used for this purpose. Factor analyses using varimax rotation were first run separately, i.e., of maturity parameters based on the abundance of (a) n-alkanes and isoprenoids, (b) steranes and triterpanes, (c) alkylnaphthalenes, and (d) alkylphenanthrenes. These analyses yielded 9 important "maturity factors". Eight of them, showing higher than 30 % of variance, were further involved in another factor analysis, as well as in cluster analysis using the Ward method. In this way, all maturity parameters based on saturated biomarkers and alkylarenes were evaluated and ranged, considering the fact that the observed factors represented their linear combinations. The results showed that in the correlation of crude oils from the Serbian part of the Pannonian Basin, the most important were maturity parameters based on isomerization reactions involving one methyl group in thermodynamically less stable α-methylnaphthalenes, ethylnaphthalenes, dimethylnaphthalenes and methylphenanthrenes, and their change into more stable isomers with the methyl group in the β-position in the aromatic ring. Processes constituting high loadings factor 2 and factor 3 parameters were also defined. Hierarchy between the "factors" and parameters were controlled, and approved, by cluster analysis using the Ward method. Finally, the investigated crude oils were correlated by factor and cluster analyses, using all the important "maturity factors". Differences in maturity were observed between the Vojvodina and Drmno Depression crude oils, as well as between oils originating from South Banat, North Banat and the Velebit oil field (Vojvodina locality)., У овом раду је, применом новог приступа у факторској и кластерској анализи, евалуиран значај матурационих параметара заснованих на расподели и обилности засићених биомаркера и алкиларена у корелацији нафта–нафта на примеру 23 узорка сировe нафтe из дела Панонског басена у Србији (14 са локалитета у Војводини и 9 из депресије Дрмно). Факторске анализе су, уз примену varimax ротације, најпре извођене посебно са матура- ционим параметрима израчунатим из расподеле и обилности (а) n-алкана и изопреноидних алифатичних алкана, (б) стерана и тритерпана, (в) алкилнафталена и (г) алкилфенантрена. Ове анализе резултирале су са 9 значајних “матурационих фактора”. Осам од њих, који су показивали проценат варијације већи од 30 %, укључени су у нову факторску и кластерску анализу, уз примену Ward методе. На тај начин су сви матурациони параметри засновани на расподели и обилности засићених биомаркера и алкиларена били процењени и рангирани, имајући у виду чињеницу да фактори предстваљају њихове линеарне комбинације. Резултати су показали да су за корелацију нафти из дела Панонског басена у Србији најзначајанији матурациони параметри засновани на изомеризацији једне алкил-групе из α- у термодина- мички стабилније β-положаје на ароматичном прстену метилнафталена, етилнафталена, ди- метилнафталена, триметилнафталена и метилфенантрена. Такође, одређени су параметри/ти- пови матурационих реакција који су у великој мери дефинисали факторе 2 и 3. Редослед и сагласност између фактора, односно параметара, проверена је и потврђена кластерском ана- лизом уз примену Ward методе. Коначно, испитивани узорци сирове нафте су корелисани помоћу факторске и кластерске анализе, користећи све значајне “матурационе факторе”. Раз- лике у степену термичке зрелости уочене су како између узорака из Војводине и депресије Дрмно, тако и између узорака из Војводине који потичу из лежишта јужног Баната, северног Баната и нафтног поља Велебит.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia), Евалуација матурационих параметара заснованих на засићеним и  ароматичним угљоводоницима у корелацији нафта-нафта (југоисточни део панонског басена , Србија)",
volume = "72",
number = "12",
pages = "1237-1254",
doi = "10.2298/JSC0712237S"
}
Stojanović, K., Jovančićević, B., Vitorović, D. K., Golovko, Y., Pevneva, G. S.,& Golovko, A. K.. (2007). Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia). in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 72(12), 1237-1254.
https://doi.org/10.2298/JSC0712237S
Stojanović K, Jovančićević B, Vitorović DK, Golovko Y, Pevneva GS, Golovko AK. Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia). in Journal of the Serbian Chemical Society. 2007;72(12):1237-1254.
doi:10.2298/JSC0712237S .
Stojanović, Ksenija, Jovančićević, Branimir, Vitorović, Dragomir K., Golovko, Yulia, Pevneva, Galina S., Golovko, Anatoly Kuzmich, "Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1237-1254,
https://doi.org/10.2298/JSC0712237S . .
5
7
9

Sesquiterpene lactones from Achillea crithmifolia

Milosavljević, Slobodan; Aljančić, Ivana; Macura, Slobodan; Milinković, Darinka; Stefanović, Milutin

(Elsevier, 1991)

TY  - JOUR
AU  - Milosavljević, Slobodan
AU  - Aljančić, Ivana
AU  - Macura, Slobodan
AU  - Milinković, Darinka
AU  - Stefanović, Milutin
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4376
AB  - The isolation of guaianolides rupicolin-A, rupicolin-B, their acetates and a new germacranolide 1β,10α-epoxy-3β,9β-diacetoxy-11α,13-dihydrocostunolide, identified by means of PS DQF COSY and PS NOESY, from Achillea crithmifolia is reported. A flavonoid jaceidin was also isolated from the same extract.
PB  - Elsevier
T2  - Phytochemistry
T1  - Sesquiterpene lactones from Achillea crithmifolia
VL  - 30
IS  - 10
SP  - 3464
EP  - 3466
DO  - 10.1016/0031-9422(91)83232-A
ER  - 
@article{
author = "Milosavljević, Slobodan and Aljančić, Ivana and Macura, Slobodan and Milinković, Darinka and Stefanović, Milutin",
year = "1991",
abstract = "The isolation of guaianolides rupicolin-A, rupicolin-B, their acetates and a new germacranolide 1β,10α-epoxy-3β,9β-diacetoxy-11α,13-dihydrocostunolide, identified by means of PS DQF COSY and PS NOESY, from Achillea crithmifolia is reported. A flavonoid jaceidin was also isolated from the same extract.",
publisher = "Elsevier",
journal = "Phytochemistry",
title = "Sesquiterpene lactones from Achillea crithmifolia",
volume = "30",
number = "10",
pages = "3464-3466",
doi = "10.1016/0031-9422(91)83232-A"
}
Milosavljević, S., Aljančić, I., Macura, S., Milinković, D.,& Stefanović, M.. (1991). Sesquiterpene lactones from Achillea crithmifolia. in Phytochemistry
Elsevier., 30(10), 3464-3466.
https://doi.org/10.1016/0031-9422(91)83232-A
Milosavljević S, Aljančić I, Macura S, Milinković D, Stefanović M. Sesquiterpene lactones from Achillea crithmifolia. in Phytochemistry. 1991;30(10):3464-3466.
doi:10.1016/0031-9422(91)83232-A .
Milosavljević, Slobodan, Aljančić, Ivana, Macura, Slobodan, Milinković, Darinka, Stefanović, Milutin, "Sesquiterpene lactones from Achillea crithmifolia" in Phytochemistry, 30, no. 10 (1991):3464-3466,
https://doi.org/10.1016/0031-9422(91)83232-A . .
20
22

The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential

Popov, Konstantin I.; Pavlović, Miomir G.; Remović, G. Ž.

(Switzerland : Springer Nature, 1991)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Pavlović, Miomir G.
AU  - Remović, G. Ž.
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4368
AB  - It is well known that the deposition conditions such as
bath composition, hydrodynamic regime, temperature,
current density, exhibit a strong effect on the grain size
and the morphology of electrodeposited metal powder
particles [1, 2]. On the other hand it has been shown
recently [3] that similar effects can be obtained by
changing only the shape of the current overpotential
waves in metal powder electrodeposition at a periodically
changing rate with other conditions constant.
This is in accordance with Ibl's observation [4] that, at
one and the same average deposition rate (current
density), it is possible to create a number of different
deposition conditions in the pulsating regimes.
In square-wave pulsating overpotential electrolysis
the overpotential amplitude, frequency of pulsation
and pause-to-pulse ratio can be varied independently.
The purpose of this work is to discuss the effect of the
last parameter on the morphology of electrodeposited
metal powder particles on the basis of the existing
experimental evidence.
PB  - Switzerland : Springer Nature
T2  - Journal of Applied Electrochemistry
T1  - The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential
VL  - 21
IS  - 8
SP  - 743
EP  - 745
DO  - 10.1007/BF01034056
ER  - 
@article{
author = "Popov, Konstantin I. and Pavlović, Miomir G. and Remović, G. Ž.",
year = "1991",
abstract = "It is well known that the deposition conditions such as
bath composition, hydrodynamic regime, temperature,
current density, exhibit a strong effect on the grain size
and the morphology of electrodeposited metal powder
particles [1, 2]. On the other hand it has been shown
recently [3] that similar effects can be obtained by
changing only the shape of the current overpotential
waves in metal powder electrodeposition at a periodically
changing rate with other conditions constant.
This is in accordance with Ibl's observation [4] that, at
one and the same average deposition rate (current
density), it is possible to create a number of different
deposition conditions in the pulsating regimes.
In square-wave pulsating overpotential electrolysis
the overpotential amplitude, frequency of pulsation
and pause-to-pulse ratio can be varied independently.
The purpose of this work is to discuss the effect of the
last parameter on the morphology of electrodeposited
metal powder particles on the basis of the existing
experimental evidence.",
publisher = "Switzerland : Springer Nature",
journal = "Journal of Applied Electrochemistry",
title = "The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential",
volume = "21",
number = "8",
pages = "743-745",
doi = "10.1007/BF01034056"
}
Popov, K. I., Pavlović, M. G.,& Remović, G. Ž.. (1991). The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential. in Journal of Applied Electrochemistry
Switzerland : Springer Nature., 21(8), 743-745.
https://doi.org/10.1007/BF01034056
Popov KI, Pavlović MG, Remović GŽ. The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential. in Journal of Applied Electrochemistry. 1991;21(8):743-745.
doi:10.1007/BF01034056 .
Popov, Konstantin I., Pavlović, Miomir G., Remović, G. Ž., "The effect of the pause-to-pulse ratio on the morphology of metal powder particles electrodeposited by square-wave pulsating overpotential" in Journal of Applied Electrochemistry, 21, no. 8 (1991):743-745,
https://doi.org/10.1007/BF01034056 . .
11
11

Electrodeposition of silver powder by pulsating and reversing currents

Popov, Konstantin I.; Mitrović, B. A.; Pavlović, Miomir G.; Toperić, B.V.

(Springer Nature Switzerland AG 2020, 1991)

TY  - JOUR
AU  - Popov, Konstantin I.
AU  - Mitrović, B. A.
AU  - Pavlović, Miomir G.
AU  - Toperić, B.V.
PY  - 1991
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4395
AB  - The effect of the shape of the current wave and frequency in silver deposition by pulsating and reversing currents on the morphology of powder particles were investigated. The possibility of obtaining particles with different properties, depending on conditions of electrolysis, was demonstrated.
PB  - Springer Nature Switzerland AG 2020
T2  - Journal of Applied Electrochemistry
T1  - Electrodeposition of silver powder by pulsating and reversing currents
VL  - 21
IS  - 1
SP  - 50
EP  - 54
DO  - 10.1007/BF01103829
ER  - 
@article{
author = "Popov, Konstantin I. and Mitrović, B. A. and Pavlović, Miomir G. and Toperić, B.V.",
year = "1991",
abstract = "The effect of the shape of the current wave and frequency in silver deposition by pulsating and reversing currents on the morphology of powder particles were investigated. The possibility of obtaining particles with different properties, depending on conditions of electrolysis, was demonstrated.",
publisher = "Springer Nature Switzerland AG 2020",
journal = "Journal of Applied Electrochemistry",
title = "Electrodeposition of silver powder by pulsating and reversing currents",
volume = "21",
number = "1",
pages = "50-54",
doi = "10.1007/BF01103829"
}
Popov, K. I., Mitrović, B. A., Pavlović, M. G.,& Toperić, B.V.. (1991). Electrodeposition of silver powder by pulsating and reversing currents. in Journal of Applied Electrochemistry
Springer Nature Switzerland AG 2020., 21(1), 50-54.
https://doi.org/10.1007/BF01103829
Popov KI, Mitrović BA, Pavlović MG, Toperić B. Electrodeposition of silver powder by pulsating and reversing currents. in Journal of Applied Electrochemistry. 1991;21(1):50-54.
doi:10.1007/BF01103829 .
Popov, Konstantin I., Mitrović, B. A., Pavlović, Miomir G., Toperić, B.V., "Electrodeposition of silver powder by pulsating and reversing currents" in Journal of Applied Electrochemistry, 21, no. 1 (1991):50-54,
https://doi.org/10.1007/BF01103829 . .
7
7

Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium

Došen-Mićović, Ljiljana; Žigman, Vida I.

(Royal Society of Chemistry, 1985)

TY  - JOUR
AU  - Došen-Mićović, Ljiljana
AU  - Žigman, Vida I.
PY  - 1985
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4502
AB  - The reaction-field theory based on dipole and quadrupole interactions has been generalized, yielding an expression for the energy as a function of point dipole and quadrupole position and orientation within a spherical cavity in a dielectric medium. The effect of displacement of molecular dipole and quadrupole, from the centre of the solute cavity, on the conformational free energy in solution has been investigated for some halogenocyclohexanes, cyclohexanones, and ethers.
PB  - Royal Society of Chemistry
T2  - Journal of the Chemical Society, Perkin Transactions 2
T1  - Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium
IS  - 5
SP  - 625
EP  - 631
DO  - 10.1039/P29850000625
ER  - 
@article{
author = "Došen-Mićović, Ljiljana and Žigman, Vida I.",
year = "1985",
abstract = "The reaction-field theory based on dipole and quadrupole interactions has been generalized, yielding an expression for the energy as a function of point dipole and quadrupole position and orientation within a spherical cavity in a dielectric medium. The effect of displacement of molecular dipole and quadrupole, from the centre of the solute cavity, on the conformational free energy in solution has been investigated for some halogenocyclohexanes, cyclohexanones, and ethers.",
publisher = "Royal Society of Chemistry",
journal = "Journal of the Chemical Society, Perkin Transactions 2",
title = "Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium",
number = "5",
pages = "625-631",
doi = "10.1039/P29850000625"
}
Došen-Mićović, L.,& Žigman, V. I.. (1985). Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium. in Journal of the Chemical Society, Perkin Transactions 2
Royal Society of Chemistry.(5), 625-631.
https://doi.org/10.1039/P29850000625
Došen-Mićović L, Žigman VI. Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium. in Journal of the Chemical Society, Perkin Transactions 2. 1985;(5):625-631.
doi:10.1039/P29850000625 .
Došen-Mićović, Ljiljana, Žigman, Vida I., "Solvent effect on conformational equilibria. Solvation energy as a function of solute position and orientation within a cavity in a dielectric medium" in Journal of the Chemical Society, Perkin Transactions 2, no. 5 (1985):625-631,
https://doi.org/10.1039/P29850000625 . .
11
9

Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces

Marković, Nenad M.; Adžić, Radoslav R.

(Elsevier, 1984)

TY  - JOUR
AU  - Marković, Nenad M.
AU  - Adžić, Radoslav R.
PY  - 1984
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4432
AB  - The electrocrystallization of thin anodic films on metal electrodes continues
 provoke interest since the original work of Bewick et al. [1]. These
studies have been focused on the film formation on mercury [1--3] and
amalgam electrodes [4,5]. Perhaps the most exact information about layer
growth has been obtained for these systems. There is no data on this type
of film formation on foreign single crystal substrates. In this note we report
a study of the formation of thallium oxide monolayer on single crystal gold
electrodes with the (100), (110) and (111) orientations. It has been found
that this two-dimensional (2D) film formation is highly dependent on the
crystallographic orientation of gold surfaces.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces
VL  - 163
IS  - 1-2
SP  - 427
EP  - 443
DO  - 10.1016/S0022-0728(84)80073-X
ER  - 
@article{
author = "Marković, Nenad M. and Adžić, Radoslav R.",
year = "1984",
abstract = "The electrocrystallization of thin anodic films on metal electrodes continues
 provoke interest since the original work of Bewick et al. [1]. These
studies have been focused on the film formation on mercury [1--3] and
amalgam electrodes [4,5]. Perhaps the most exact information about layer
growth has been obtained for these systems. There is no data on this type
of film formation on foreign single crystal substrates. In this note we report
a study of the formation of thallium oxide monolayer on single crystal gold
electrodes with the (100), (110) and (111) orientations. It has been found
that this two-dimensional (2D) film formation is highly dependent on the
crystallographic orientation of gold surfaces.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces",
volume = "163",
number = "1-2",
pages = "427-443",
doi = "10.1016/S0022-0728(84)80073-X"
}
Marković, N. M.,& Adžić, R. R.. (1984). Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces. in Journal of Electroanalytical Chemistry
Elsevier., 163(1-2), 427-443.
https://doi.org/10.1016/S0022-0728(84)80073-X
Marković NM, Adžić RR. Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces. in Journal of Electroanalytical Chemistry. 1984;163(1-2):427-443.
doi:10.1016/S0022-0728(84)80073-X .
Marković, Nenad M., Adžić, Radoslav R., "Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces" in Journal of Electroanalytical Chemistry, 163, no. 1-2 (1984):427-443,
https://doi.org/10.1016/S0022-0728(84)80073-X . .
5

Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds

Mihailović, Milhailo Lj.; Lorenc, Ljubinka B.; Pavlović, Vladimir D.; Führer, Hermann

(Wiley-Blackwell, 1981)

TY  - JOUR
AU  - Mihailović, Milhailo Lj.
AU  - Lorenc, Ljubinka B.
AU  - Pavlović, Vladimir D.
AU  - Führer, Hermann
PY  - 1981
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4424
AB  - It was found that analysis of the 1H‐NMR. signals (at 360 (preferably) and/or 100 MHz) of the protons at C (4) and of the equatorial α‐proton at C (6), particularly when these are located in the 2–3 ppm region and therefore convenient for detection and identification, may be of valuable aid in the structural and configurational characterization of 5‐hydroxy‐ and 5‐acetoxy‐steroids (unsubstituted or containing a hydroxy or acyloxy substituent at C (3)).
PB  - Wiley-Blackwell
T2  - Helvetica Chimica Acta
T1  - Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds
VL  - 64
IS  - 4
SP  - 1032
EP  - 1039
DO  - 10.1002/hlca.19810640409
ER  - 
@article{
author = "Mihailović, Milhailo Lj. and Lorenc, Ljubinka B. and Pavlović, Vladimir D. and Führer, Hermann",
year = "1981",
abstract = "It was found that analysis of the 1H‐NMR. signals (at 360 (preferably) and/or 100 MHz) of the protons at C (4) and of the equatorial α‐proton at C (6), particularly when these are located in the 2–3 ppm region and therefore convenient for detection and identification, may be of valuable aid in the structural and configurational characterization of 5‐hydroxy‐ and 5‐acetoxy‐steroids (unsubstituted or containing a hydroxy or acyloxy substituent at C (3)).",
publisher = "Wiley-Blackwell",
journal = "Helvetica Chimica Acta",
title = "Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds",
volume = "64",
number = "4",
pages = "1032-1039",
doi = "10.1002/hlca.19810640409"
}
Mihailović, M. Lj., Lorenc, L. B., Pavlović, V. D.,& Führer, H.. (1981). Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds. in Helvetica Chimica Acta
Wiley-Blackwell., 64(4), 1032-1039.
https://doi.org/10.1002/hlca.19810640409
Mihailović ML, Lorenc LB, Pavlović VD, Führer H. Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds. in Helvetica Chimica Acta. 1981;64(4):1032-1039.
doi:10.1002/hlca.19810640409 .
Mihailović, Milhailo Lj., Lorenc, Ljubinka B., Pavlović, Vladimir D., Führer, Hermann, "Some Observations Concerning 1H‐NMR. Spectra of 5‐hydroxy‐ and 5‐acetoxy‐steroid compounds" in Helvetica Chimica Acta, 64, no. 4 (1981):1032-1039,
https://doi.org/10.1002/hlca.19810640409 . .
2
1

The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane

Došen-Mićović, Ljiljana; Jeremić, Dragoslav; Allinger, Norman L.

(Elsevier, 1981)

TY  - JOUR
AU  - Došen-Mićović, Ljiljana
AU  - Jeremić, Dragoslav
AU  - Allinger, Norman L.
PY  - 1981
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4423
AB  - Two of the stereoisomers of the title compound were prepared and their dipole moments were measured. For the r-1,c-3-dichloro-t-5-methylcyclohexane, the free energy difference between conformers with axial-axial (aa) and equatorial-equatorial (ee) chlorines was measured by a variable temperature NMR method, and the value found was 1.3 ± 0.2 Kcal/mol-1 (in acetone) favoring the latter. Molecular mechanics studies show that the solvation energy and the electrostatics are of major importance in understanding this equilibrium. Calculations show the effect of the methyl group is essentially additive, and give for cis-1,3-dichlorocyclohexane itself ee{measured angle}aa DH+ 3.0 kcal mol-1 (acetone).
PB  - Elsevier
T2  - Tetrahedron
T1  - The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane
VL  - 37
IS  - 20
SP  - 3455
EP  - 3461
DO  - 10.1016/S0040-4020(01)98859-3
ER  - 
@article{
author = "Došen-Mićović, Ljiljana and Jeremić, Dragoslav and Allinger, Norman L.",
year = "1981",
abstract = "Two of the stereoisomers of the title compound were prepared and their dipole moments were measured. For the r-1,c-3-dichloro-t-5-methylcyclohexane, the free energy difference between conformers with axial-axial (aa) and equatorial-equatorial (ee) chlorines was measured by a variable temperature NMR method, and the value found was 1.3 ± 0.2 Kcal/mol-1 (in acetone) favoring the latter. Molecular mechanics studies show that the solvation energy and the electrostatics are of major importance in understanding this equilibrium. Calculations show the effect of the methyl group is essentially additive, and give for cis-1,3-dichlorocyclohexane itself ee{measured angle}aa DH+ 3.0 kcal mol-1 (acetone).",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane",
volume = "37",
number = "20",
pages = "3455-3461",
doi = "10.1016/S0040-4020(01)98859-3"
}
Došen-Mićović, L., Jeremić, D.,& Allinger, N. L.. (1981). The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane. in Tetrahedron
Elsevier., 37(20), 3455-3461.
https://doi.org/10.1016/S0040-4020(01)98859-3
Došen-Mićović L, Jeremić D, Allinger NL. The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane. in Tetrahedron. 1981;37(20):3455-3461.
doi:10.1016/S0040-4020(01)98859-3 .
Došen-Mićović, Ljiljana, Jeremić, Dragoslav, Allinger, Norman L., "The conformational equilibrium of 1,3-dichloro-5-methylcyclohexane" in Tetrahedron, 37, no. 20 (1981):3455-3461,
https://doi.org/10.1016/S0040-4020(01)98859-3 . .
4
6

A novel procedure for the aromatization of ring a in 19-nortestosterone

Mihalilović, M.Lj.; Foršek, Jože; Lorenc, Ljubinka B.

(Elsevier, 1977)

TY  - JOUR
AU  - Mihalilović, M.Lj.
AU  - Foršek, Jože
AU  - Lorenc, Ljubinka B.
PY  - 1977
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4581
AB  - A convenient, 40% overall yield synthesis of 2,3,17β-triacetoxy-1,3,5(10)-estratriene is described, which involves epoxidation of 19-nortestosterone and subsequent acetylation, lead tetra-acetate acetoxylation of the so-formed 17β-acetoxy-4β,5-epoxy-5β-estran-3-one, and aromatization of ring A, by means of acidic alumina, of the resulting 2α and 2β epimers of 2,17β-diacetoxy-4β,5-epoxy-5β-estran-3-one.
PB  - Elsevier
T2  - Tetrahedron
T1  - A novel procedure for the aromatization of ring a in 19-nortestosterone
VL  - 33
IS  - 2
SP  - 235
EP  - 237
DO  - 10.1016/0040-4020(77)80132-4
ER  - 
@article{
author = "Mihalilović, M.Lj. and Foršek, Jože and Lorenc, Ljubinka B.",
year = "1977",
abstract = "A convenient, 40% overall yield synthesis of 2,3,17β-triacetoxy-1,3,5(10)-estratriene is described, which involves epoxidation of 19-nortestosterone and subsequent acetylation, lead tetra-acetate acetoxylation of the so-formed 17β-acetoxy-4β,5-epoxy-5β-estran-3-one, and aromatization of ring A, by means of acidic alumina, of the resulting 2α and 2β epimers of 2,17β-diacetoxy-4β,5-epoxy-5β-estran-3-one.",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "A novel procedure for the aromatization of ring a in 19-nortestosterone",
volume = "33",
number = "2",
pages = "235-237",
doi = "10.1016/0040-4020(77)80132-4"
}
Mihalilović, M.Lj., Foršek, J.,& Lorenc, L. B.. (1977). A novel procedure for the aromatization of ring a in 19-nortestosterone. in Tetrahedron
Elsevier., 33(2), 235-237.
https://doi.org/10.1016/0040-4020(77)80132-4
Mihalilović M, Foršek J, Lorenc LB. A novel procedure for the aromatization of ring a in 19-nortestosterone. in Tetrahedron. 1977;33(2):235-237.
doi:10.1016/0040-4020(77)80132-4 .
Mihalilović, M.Lj., Foršek, Jože, Lorenc, Ljubinka B., "A novel procedure for the aromatization of ring a in 19-nortestosterone" in Tetrahedron, 33, no. 2 (1977):235-237,
https://doi.org/10.1016/0040-4020(77)80132-4 . .
3
9
9