Golovko, Anatoly Kuzmich

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Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)

Stojanović, Ksenija; Jovančićević, Branimir; Vitorović, Dragomir K.; Golovko, Yulia; Pevneva, Galina S.; Golovko, Anatoly Kuzmich

(Belgrade : Serbian Chemical Society, 2007)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Jovančićević, Branimir
AU  - Vitorović, Dragomir K.
AU  - Golovko, Yulia
AU  - Pevneva, Galina S.
AU  - Golovko, Anatoly Kuzmich
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4300
AB  - Twenty three crude oils from the Serbian part of the Pannonian Basin (14 from the Vojvodina Province and 9 from the Drmno Depression) were investigated, aimed at an evaluation of oil-oil maturity correlation parameters based on the distribution and abundance of saturated biomarkers and alkylarene constituents. Factor and cluster analyses were used for this purpose. Factor analyses using varimax rotation were first run separately, i.e., of maturity parameters based on the abundance of (a) n-alkanes and isoprenoids, (b) steranes and triterpanes, (c) alkylnaphthalenes, and (d) alkylphenanthrenes. These analyses yielded 9 important "maturity factors". Eight of them, showing higher than 30 % of variance, were further involved in another factor analysis, as well as in cluster analysis using the Ward method. In this way, all maturity parameters based on saturated biomarkers and alkylarenes were evaluated and ranged, considering the fact that the observed factors represented their linear combinations. The results showed that in the correlation of crude oils from the Serbian part of the Pannonian Basin, the most important were maturity parameters based on isomerization reactions involving one methyl group in thermodynamically less stable α-methylnaphthalenes, ethylnaphthalenes, dimethylnaphthalenes and methylphenanthrenes, and their change into more stable isomers with the methyl group in the β-position in the aromatic ring. Processes constituting high loadings factor 2 and factor 3 parameters were also defined. Hierarchy between the "factors" and parameters were controlled, and approved, by cluster analysis using the Ward method. Finally, the investigated crude oils were correlated by factor and cluster analyses, using all the important "maturity factors". Differences in maturity were observed between the Vojvodina and Drmno Depression crude oils, as well as between oils originating from South Banat, North Banat and the Velebit oil field (Vojvodina locality).
AB  - У овом раду је, применом новог приступа у факторској и кластерској анализи, евалуиран значај матурационих параметара заснованих на расподели и обилности засићених биомаркера и алкиларена у корелацији нафта–нафта на примеру 23 узорка сировe нафтe из дела Панонског басена у Србији (14 са локалитета у Војводини и 9 из депресије Дрмно). Факторске анализе су, уз примену varimax ротације, најпре извођене посебно са матура- ционим параметрима израчунатим из расподеле и обилности (а) n-алкана и изопреноидних алифатичних алкана, (б) стерана и тритерпана, (в) алкилнафталена и (г) алкилфенантрена. Ове анализе резултирале су са 9 значајних “матурационих фактора”. Осам од њих, који су показивали проценат варијације већи од 30 %, укључени су у нову факторску и кластерску анализу, уз примену Ward методе. На тај начин су сви матурациони параметри засновани на расподели и обилности засићених биомаркера и алкиларена били процењени и рангирани, имајући у виду чињеницу да фактори предстваљају њихове линеарне комбинације. Резултати су показали да су за корелацију нафти из дела Панонског басена у Србији најзначајанији матурациони параметри засновани на изомеризацији једне алкил-групе из α- у термодина- мички стабилније β-положаје на ароматичном прстену метилнафталена, етилнафталена, ди- метилнафталена, триметилнафталена и метилфенантрена. Такође, одређени су параметри/ти- пови матурационих реакција који су у великој мери дефинисали факторе 2 и 3. Редослед и сагласност између фактора, односно параметара, проверена је и потврђена кластерском ана- лизом уз примену Ward методе. Коначно, испитивани узорци сирове нафте су корелисани помоћу факторске и кластерске анализе, користећи све значајне “матурационе факторе”. Раз- лике у степену термичке зрелости уочене су како између узорака из Војводине и депресије Дрмно, тако и између узорака из Војводине који потичу из лежишта јужног Баната, северног Баната и нафтног поља Велебит.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)
T1  - Евалуација матурационих параметара заснованих на засићеним и  ароматичним угљоводоницима у корелацији нафта-нафта (југоисточни део панонског басена , Србија)
VL  - 72
IS  - 12
SP  - 1237
EP  - 1254
DO  - 10.2298/JSC0712237S
ER  - 
@article{
author = "Stojanović, Ksenija and Jovančićević, Branimir and Vitorović, Dragomir K. and Golovko, Yulia and Pevneva, Galina S. and Golovko, Anatoly Kuzmich",
year = "2007",
abstract = "Twenty three crude oils from the Serbian part of the Pannonian Basin (14 from the Vojvodina Province and 9 from the Drmno Depression) were investigated, aimed at an evaluation of oil-oil maturity correlation parameters based on the distribution and abundance of saturated biomarkers and alkylarene constituents. Factor and cluster analyses were used for this purpose. Factor analyses using varimax rotation were first run separately, i.e., of maturity parameters based on the abundance of (a) n-alkanes and isoprenoids, (b) steranes and triterpanes, (c) alkylnaphthalenes, and (d) alkylphenanthrenes. These analyses yielded 9 important "maturity factors". Eight of them, showing higher than 30 % of variance, were further involved in another factor analysis, as well as in cluster analysis using the Ward method. In this way, all maturity parameters based on saturated biomarkers and alkylarenes were evaluated and ranged, considering the fact that the observed factors represented their linear combinations. The results showed that in the correlation of crude oils from the Serbian part of the Pannonian Basin, the most important were maturity parameters based on isomerization reactions involving one methyl group in thermodynamically less stable α-methylnaphthalenes, ethylnaphthalenes, dimethylnaphthalenes and methylphenanthrenes, and their change into more stable isomers with the methyl group in the β-position in the aromatic ring. Processes constituting high loadings factor 2 and factor 3 parameters were also defined. Hierarchy between the "factors" and parameters were controlled, and approved, by cluster analysis using the Ward method. Finally, the investigated crude oils were correlated by factor and cluster analyses, using all the important "maturity factors". Differences in maturity were observed between the Vojvodina and Drmno Depression crude oils, as well as between oils originating from South Banat, North Banat and the Velebit oil field (Vojvodina locality)., У овом раду је, применом новог приступа у факторској и кластерској анализи, евалуиран значај матурационих параметара заснованих на расподели и обилности засићених биомаркера и алкиларена у корелацији нафта–нафта на примеру 23 узорка сировe нафтe из дела Панонског басена у Србији (14 са локалитета у Војводини и 9 из депресије Дрмно). Факторске анализе су, уз примену varimax ротације, најпре извођене посебно са матура- ционим параметрима израчунатим из расподеле и обилности (а) n-алкана и изопреноидних алифатичних алкана, (б) стерана и тритерпана, (в) алкилнафталена и (г) алкилфенантрена. Ове анализе резултирале су са 9 значајних “матурационих фактора”. Осам од њих, који су показивали проценат варијације већи од 30 %, укључени су у нову факторску и кластерску анализу, уз примену Ward методе. На тај начин су сви матурациони параметри засновани на расподели и обилности засићених биомаркера и алкиларена били процењени и рангирани, имајући у виду чињеницу да фактори предстваљају њихове линеарне комбинације. Резултати су показали да су за корелацију нафти из дела Панонског басена у Србији најзначајанији матурациони параметри засновани на изомеризацији једне алкил-групе из α- у термодина- мички стабилније β-положаје на ароматичном прстену метилнафталена, етилнафталена, ди- метилнафталена, триметилнафталена и метилфенантрена. Такође, одређени су параметри/ти- пови матурационих реакција који су у великој мери дефинисали факторе 2 и 3. Редослед и сагласност између фактора, односно параметара, проверена је и потврђена кластерском ана- лизом уз примену Ward методе. Коначно, испитивани узорци сирове нафте су корелисани помоћу факторске и кластерске анализе, користећи све значајне “матурационе факторе”. Раз- лике у степену термичке зрелости уочене су како између узорака из Војводине и депресије Дрмно, тако и између узорака из Војводине који потичу из лежишта јужног Баната, северног Баната и нафтног поља Велебит.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia), Евалуација матурационих параметара заснованих на засићеним и  ароматичним угљоводоницима у корелацији нафта-нафта (југоисточни део панонског басена , Србија)",
volume = "72",
number = "12",
pages = "1237-1254",
doi = "10.2298/JSC0712237S"
}
Stojanović, K., Jovančićević, B., Vitorović, D. K., Golovko, Y., Pevneva, G. S.,& Golovko, A. K.. (2007). Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia). in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 72(12), 1237-1254.
https://doi.org/10.2298/JSC0712237S
Stojanović K, Jovančićević B, Vitorović DK, Golovko Y, Pevneva GS, Golovko AK. Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia). in Journal of the Serbian Chemical Society. 2007;72(12):1237-1254.
doi:10.2298/JSC0712237S .
Stojanović, Ksenija, Jovančićević, Branimir, Vitorović, Dragomir K., Golovko, Yulia, Pevneva, Galina S., Golovko, Anatoly Kuzmich, "Evaluation of saturated and aromatic hydrocarbons oil-oil maturity correlation parameters (SE Pannonian Basin, Serbia)" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1237-1254,
https://doi.org/10.2298/JSC0712237S . .
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Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool

Stojanović, Ksenija; Jovančićević, Branimir; Pevneva, Galina S.; Golovko, Julia A.; Golovko, Anatoly Kuzmich; Pfendt, Petar A.

(Elsevier, 2001)

TY  - JOUR
AU  - Stojanović, Ksenija
AU  - Jovančićević, Branimir
AU  - Pevneva, Galina S.
AU  - Golovko, Julia A.
AU  - Golovko, Anatoly Kuzmich
AU  - Pfendt, Petar A.
PY  - 2001
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4337
AB  - A correlation analysis of maturation parameters was carried out on 14 crude oil samples from nine oil fields on Sakhalin Island (Russia). The oils were taken from reservoir rocks of Miocene age at depths ranging from 73 to 2841 m. On the basis of GC analysis of the alkane fraction (n-alkanes and the isoprenoid alkanes pristane and phytane) as well as on the basis of the abundance of demethylated hopanes (GC-MS analysis, m/z 177), it is assumed that the oils are either biodegraded or are a mixture of biodegraded and nonbiodegraded oils. Therefore, their maturation is assessed on the basis of the distribution and abundance of tricyclic aromatic hydrocarbons that are more resistant to biodegradation than alkane-type biological markers. The oils may be classified into three groups on the basis of the well-established maturation parameter MPI 3: highly mature (group I), moderately mature (group II) and immature (group III). The correlation analysis shows that the percentage of phenanthrene [P] in the tricyclic aromatic fraction of the oils of the Sakhalin oil fields can be used as a maturation parameter. The highly mature oils (group I) were found to have a [P] value of more than 14%; the moderately mature oils (group II) have values of 7-14%, and the immature oils (group III) a value of less than 7%. The very good correlation between MPI 3 and [P] also indicates that parallel to methylphenanthrene isomerization, dealkylation also occurs in the reservoir rocks. By correlation analysis it is shown that these reactions are, to a great extent, determined by the depth of the reservoir rocks.
PB  - Elsevier
T2  - Organic Geochemistry
T1  - Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool
VL  - 32
IS  - 5
SP  - 721
EP  - 731
DO  - 10.1016/S0146-6380(01)00004-3
ER  - 
@article{
author = "Stojanović, Ksenija and Jovančićević, Branimir and Pevneva, Galina S. and Golovko, Julia A. and Golovko, Anatoly Kuzmich and Pfendt, Petar A.",
year = "2001",
abstract = "A correlation analysis of maturation parameters was carried out on 14 crude oil samples from nine oil fields on Sakhalin Island (Russia). The oils were taken from reservoir rocks of Miocene age at depths ranging from 73 to 2841 m. On the basis of GC analysis of the alkane fraction (n-alkanes and the isoprenoid alkanes pristane and phytane) as well as on the basis of the abundance of demethylated hopanes (GC-MS analysis, m/z 177), it is assumed that the oils are either biodegraded or are a mixture of biodegraded and nonbiodegraded oils. Therefore, their maturation is assessed on the basis of the distribution and abundance of tricyclic aromatic hydrocarbons that are more resistant to biodegradation than alkane-type biological markers. The oils may be classified into three groups on the basis of the well-established maturation parameter MPI 3: highly mature (group I), moderately mature (group II) and immature (group III). The correlation analysis shows that the percentage of phenanthrene [P] in the tricyclic aromatic fraction of the oils of the Sakhalin oil fields can be used as a maturation parameter. The highly mature oils (group I) were found to have a [P] value of more than 14%; the moderately mature oils (group II) have values of 7-14%, and the immature oils (group III) a value of less than 7%. The very good correlation between MPI 3 and [P] also indicates that parallel to methylphenanthrene isomerization, dealkylation also occurs in the reservoir rocks. By correlation analysis it is shown that these reactions are, to a great extent, determined by the depth of the reservoir rocks.",
publisher = "Elsevier",
journal = "Organic Geochemistry",
title = "Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool",
volume = "32",
number = "5",
pages = "721-731",
doi = "10.1016/S0146-6380(01)00004-3"
}
Stojanović, K., Jovančićević, B., Pevneva, G. S., Golovko, J. A., Golovko, A. K.,& Pfendt, P. A.. (2001). Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool. in Organic Geochemistry
Elsevier., 32(5), 721-731.
https://doi.org/10.1016/S0146-6380(01)00004-3
Stojanović K, Jovančićević B, Pevneva GS, Golovko JA, Golovko AK, Pfendt PA. Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool. in Organic Geochemistry. 2001;32(5):721-731.
doi:10.1016/S0146-6380(01)00004-3 .
Stojanović, Ksenija, Jovančićević, Branimir, Pevneva, Galina S., Golovko, Julia A., Golovko, Anatoly Kuzmich, Pfendt, Petar A., "Maturity assessment of oils from the Sakhalin oil fields in Russia: Phenanthrene content as a tool" in Organic Geochemistry, 32, no. 5 (2001):721-731,
https://doi.org/10.1016/S0146-6380(01)00004-3 . .
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