TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Grgur, Branimir N.
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije E.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2018
AB  - A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation
VL  - 81
IS  - 4
SP  - 419
EP  - 431
DO  - 10.2298/JSC150805083T
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Grgur, Branimir N. and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Onjia, Antonije E.",
year = "2016",
abstract = "A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation",
volume = "81",
number = "4",
pages = "419-431",
doi = "10.2298/JSC150805083T"
}

Tomković, T., Radovanović, F., Grgur, B. N., Nastasović, A., Vasiljević-Radović, D.,& Onjia, A. E.. (2016). Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 81(4), 419-431.
https://doi.org/10.2298/JSC150805083T

Tomković T, Radovanović F, Grgur BN, Nastasović A, Vasiljević-Radović D, Onjia AE. Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society. 2016;81(4):419-431.
doi:10.2298/JSC150805083T .

Tomković, Tanja, Radovanović, Filip, Grgur, Branimir N., Nastasović, Aleksandra, Vasiljević-Radović, Dana, Onjia, Antonije E., "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation" in Journal of the Serbian Chemical Society, 81, no. 4 (2016):419-431,
https://doi.org/10.2298/JSC150805083T . .

TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Markovic, Jelena
AU  - Grgur, Branimir N.
AU  - Onjia, Antonije E.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1748
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - European Polymer Journal
T1  - Solid phase extraction membranes with submicron multifunctional adsorbent particles
VL  - 63
SP  - 90
EP  - 100
DO  - 10.1016/j.eurpolymj.2014.12.015
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Markovic, Jelena and Grgur, Branimir N. and Onjia, Antonije E.",
year = "2015",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "European Polymer Journal",
title = "Solid phase extraction membranes with submicron multifunctional adsorbent particles",
volume = "63",
pages = "90-100",
doi = "10.1016/j.eurpolymj.2014.12.015"
}

Tomković, T., Radovanović, F., Nastasović, A., Vasiljević-Radović, D., Markovic, J., Grgur, B. N.,& Onjia, A. E.. (2015). Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal
Oxford : Pergamon-Elsevier Science Ltd., 63, 90-100.
https://doi.org/10.1016/j.eurpolymj.2014.12.015

Tomković T, Radovanović F, Nastasović A, Vasiljević-Radović D, Markovic J, Grgur BN, Onjia AE. Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal. 2015;63:90-100.
doi:10.1016/j.eurpolymj.2014.12.015 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Markovic, Jelena, Grgur, Branimir N., Onjia, Antonije E., "Solid phase extraction membranes with submicron multifunctional adsorbent particles" in European Polymer Journal, 63 (2015):90-100,
https://doi.org/10.1016/j.eurpolymj.2014.12.015 . .

TY  - DATA
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Tomković, Tanja
AU  - Vasiljević-Radović, Dana
AU  - Nešić, Aleksandra
AU  - Veličković, Sava
AU  - Onjia, Antonije
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7533
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Elsevier, Amsterdam
T2  - Reactive & Functional Polymers
T1  - Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007
UR  - https://hdl.handle.net/21.15107/rcub_cer_7533
ER  - 

@misc{
author = "Radovanović, Filip and Nastasović, Aleksandra and Tomković, Tanja and Vasiljević-Radović, Dana and Nešić, Aleksandra and Veličković, Sava and Onjia, Antonije",
year = "2014",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Elsevier, Amsterdam",
journal = "Reactive & Functional Polymers",
title = "Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007",
url = "https://hdl.handle.net/21.15107/rcub_cer_7533"
}

Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S.,& Onjia, A.. (2014). Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007. in Reactive & Functional Polymers
Elsevier, Amsterdam..
https://hdl.handle.net/21.15107/rcub_cer_7533

Radovanović F, Nastasović A, Tomković T, Vasiljević-Radović D, Nešić A, Veličković S, Onjia A. Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007. in Reactive & Functional Polymers. 2014;.
https://hdl.handle.net/21.15107/rcub_cer_7533 .

Radovanović, Filip, Nastasović, Aleksandra, Tomković, Tanja, Vasiljević-Radović, Dana, Nešić, Aleksandra, Veličković, Sava, Onjia, Antonije, "Supplementary materials for the article: Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S., Onjia, A., 2014. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. Reactive and Functional Polymers 77, 1–10. https://doi.org/10.1016/j.reactfunctpolym.2014.01.007" in Reactive & Functional Polymers (2014),
https://hdl.handle.net/21.15107/rcub_cer_7533 .

TY  - JOUR
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Tomković, Tanja
AU  - Vasiljević-Radović, Dana
AU  - Nešić, Aleksandra
AU  - Veličković, Sava J.
AU  - Onjia, Antonije E.
PY  - 2014
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1517
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Elsevier
T2  - Reactive and Functional Polymers
T1  - Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate
VL  - 77
SP  - 1
EP  - 10
DO  - 10.1016/j.reactfunctpolym.2014.01.007
ER  - 

@article{
author = "Radovanović, Filip and Nastasović, Aleksandra and Tomković, Tanja and Vasiljević-Radović, Dana and Nešić, Aleksandra and Veličković, Sava J. and Onjia, Antonije E.",
year = "2014",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked glycidyl methacrylate copolymer were prepared by a combination of a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. As the concentration of polymerizable monomers increased the original macrovoid structure was replaced by a hybrid morphology with microglobules typical of macroporous methacrylate adsorbers embedded within microporous structure with no significant effects on water permeability. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of Orange G solution at low transmembrane pressures was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Elsevier",
journal = "Reactive and Functional Polymers",
title = "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate",
volume = "77",
pages = "1-10",
doi = "10.1016/j.reactfunctpolym.2014.01.007"
}

Radovanović, F., Nastasović, A., Tomković, T., Vasiljević-Radović, D., Nešić, A., Veličković, S. J.,& Onjia, A. E.. (2014). Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive and Functional Polymers
Elsevier., 77, 1-10.
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007

Radovanović F, Nastasović A, Tomković T, Vasiljević-Radović D, Nešić A, Veličković SJ, Onjia AE. Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate. in Reactive and Functional Polymers. 2014;77:1-10.
doi:10.1016/j.reactfunctpolym.2014.01.007 .

Radovanović, Filip, Nastasović, Aleksandra, Tomković, Tanja, Vasiljević-Radović, Dana, Nešić, Aleksandra, Veličković, Sava J., Onjia, Antonije E., "Novel membrane adsorbers incorporating functionalized polyglycidyl methacrylate" in Reactive and Functional Polymers, 77 (2014):1-10,
https://doi.org/10.1016/j.reactfunctpolym.2014.01.007 . .

TY  - CONF
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Marković, Jelena
AU  - Ekmeščić, Bojana
AU  - Vidojković, Sonja
AU  - Onjia, Antonije E.
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/784
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2857
AB  - Novel polyethersulfone membranes with integrated submicron adsorbent particles were prepared by combining photoirradiation with liquid phase inversion. These particles consist of cross-linked poly(glycidyl methacrylate-co-acrylamido-2-methylpropane sulfonic acid), pGMA-AMPS. After membrane preparation, the epoxide groups were reacted with diethylene triamine to incorporate amine functionalities. Membranes were characterized using FTIR-ATR, SEM and dynamic adsorption of copper from a dilute solution. Effects of monomer concentrations on the properties and separation performance of membrane adsorbers are presented.
PB  - Belgrade, Serbia : Society of Physical Chemists of Serbia
C3  - Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture
SP  - 787
EP  - 790
UR  - https://hdl.handle.net/21.15107/rcub_dais_784
ER  - 

@conference{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Marković, Jelena and Ekmeščić, Bojana and Vidojković, Sonja and Onjia, Antonije E.",
year = "2014",
abstract = "Novel polyethersulfone membranes with integrated submicron adsorbent particles were prepared by combining photoirradiation with liquid phase inversion. These particles consist of cross-linked poly(glycidyl methacrylate-co-acrylamido-2-methylpropane sulfonic acid), pGMA-AMPS. After membrane preparation, the epoxide groups were reacted with diethylene triamine to incorporate amine functionalities. Membranes were characterized using FTIR-ATR, SEM and dynamic adsorption of copper from a dilute solution. Effects of monomer concentrations on the properties and separation performance of membrane adsorbers are presented.",
publisher = "Belgrade, Serbia : Society of Physical Chemists of Serbia",
journal = "Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture",
pages = "787-790",
url = "https://hdl.handle.net/21.15107/rcub_dais_784"
}

Tomković, T., Radovanović, F., Nastasović, A., Marković, J., Ekmeščić, B., Vidojković, S.,& Onjia, A. E.. (2014). Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture. in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Belgrade, Serbia : Society of Physical Chemists of Serbia., 787-790.
https://hdl.handle.net/21.15107/rcub_dais_784

Tomković T, Radovanović F, Nastasović A, Marković J, Ekmeščić B, Vidojković S, Onjia AE. Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture. in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2014;:787-790.
https://hdl.handle.net/21.15107/rcub_dais_784 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Marković, Jelena, Ekmeščić, Bojana, Vidojković, Sonja, Onjia, Antonije E., "Polyethersulfone membranes with integrated adsorbent particles for heavy metals capture" in Proceedings of the 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry (2014):787-790,
https://hdl.handle.net/21.15107/rcub_dais_784 .

TY  - CONF
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Radovanović, Filip
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/802
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2846
AB  - A series of polyethersulfone membranes with integrated cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were synthesized using a combination of the traditional immersion precipitation process for making membranes and photopolymerization. Negative charges were introduced using AMPS as a reactive monomer. Presence of sulfonic groups was confirmed by FTIR-ATR spectra. Changes in membrane morphology as a function of AMPS concentration in the casting solution were investigated by SEM. Membrane charge was evaluated from streaming potential measurements using a specially constructed device. Dynamic adsorption of Rhodamine B was used to demonstrate effects of monomer concentration on the properties and separation performance.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Thirteenth Young Researchers' Conference Materials Sciences and Engineering December 10-12, 2014, Belgrade, Serbia
T1  - Dynamic adsorption of Rhodamine B from dilute aqueous solutions using negatively-charged membrane adsorbers
SP  - 40
EP  - 40
UR  - https://hdl.handle.net/21.15107/rcub_dais_802
ER  - 

@conference{
author = "Tomković, Tanja and Nastasović, Aleksandra and Radovanović, Filip",
year = "2014",
abstract = "A series of polyethersulfone membranes with integrated cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were synthesized using a combination of the traditional immersion precipitation process for making membranes and photopolymerization. Negative charges were introduced using AMPS as a reactive monomer. Presence of sulfonic groups was confirmed by FTIR-ATR spectra. Changes in membrane morphology as a function of AMPS concentration in the casting solution were investigated by SEM. Membrane charge was evaluated from streaming potential measurements using a specially constructed device. Dynamic adsorption of Rhodamine B was used to demonstrate effects of monomer concentration on the properties and separation performance.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Thirteenth Young Researchers' Conference Materials Sciences and Engineering December 10-12, 2014, Belgrade, Serbia",
title = "Dynamic adsorption of Rhodamine B from dilute aqueous solutions using negatively-charged membrane adsorbers",
pages = "40-40",
url = "https://hdl.handle.net/21.15107/rcub_dais_802"
}

Tomković, T., Nastasović, A.,& Radovanović, F.. (2014). Dynamic adsorption of Rhodamine B from dilute aqueous solutions using negatively-charged membrane adsorbers. in Program and the Book of Abstracts / Thirteenth Young Researchers' Conference Materials Sciences and Engineering December 10-12, 2014, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 40-40.
https://hdl.handle.net/21.15107/rcub_dais_802

Tomković T, Nastasović A, Radovanović F. Dynamic adsorption of Rhodamine B from dilute aqueous solutions using negatively-charged membrane adsorbers. in Program and the Book of Abstracts / Thirteenth Young Researchers' Conference Materials Sciences and Engineering December 10-12, 2014, Belgrade, Serbia. 2014;:40-40.
https://hdl.handle.net/21.15107/rcub_dais_802 .

Tomković, Tanja, Nastasović, Aleksandra, Radovanović, Filip, "Dynamic adsorption of Rhodamine B from dilute aqueous solutions using negatively-charged membrane adsorbers" in Program and the Book of Abstracts / Thirteenth Young Researchers' Conference Materials Sciences and Engineering December 10-12, 2014, Belgrade, Serbia (2014):40-40,
https://hdl.handle.net/21.15107/rcub_dais_802 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Veličković, Sava
AU  - Nešić, Aleksandra
AU  - Onjia, Antonije E.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/796
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2841
AB  - Polyethersulfone (PES) is frequently used for high-performance ultrafiltration membranes. Functionalization of PES membranes is required to introduce new groups for specific applications, such as affinity membranes for bioseparations [1]. Functionalization methods include bulk modification of PES material, blending of PES with another material, or surface modification of PES membranes [2]. In this work a novel method for introducing functional groups in asymmetric PES membranes is presented [3]. A cast film comprising PES, glycidyl methacrylate (GMA) and a common solvent was exposed to UV irradiation to form a gel of crosslinked polyGMA. The gel was then immersed in a water bath to create an asymmetric membrane with crosslinked polyGMA particles, as shown in Fig. 1. A simple treatment of these membranes with diethylene triamine was used to open the epoxide rings in polyGMA particles and introduce amine functional groups. The effects of monomer concentrations on the properties and separation performance of these novel membrane adsorbers will be presented.
PB  - Belgrade : Serbian Chemical Society
C3  - 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
T1  - Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles
SP  - 128
EP  - 128
UR  - https://hdl.handle.net/21.15107/rcub_dais_796
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Veličković, Sava and Nešić, Aleksandra and Onjia, Antonije E.",
year = "2013",
abstract = "Polyethersulfone (PES) is frequently used for high-performance ultrafiltration membranes. Functionalization of PES membranes is required to introduce new groups for specific applications, such as affinity membranes for bioseparations [1]. Functionalization methods include bulk modification of PES material, blending of PES with another material, or surface modification of PES membranes [2]. In this work a novel method for introducing functional groups in asymmetric PES membranes is presented [3]. A cast film comprising PES, glycidyl methacrylate (GMA) and a common solvent was exposed to UV irradiation to form a gel of crosslinked polyGMA. The gel was then immersed in a water bath to create an asymmetric membrane with crosslinked polyGMA particles, as shown in Fig. 1. A simple treatment of these membranes with diethylene triamine was used to open the epoxide rings in polyGMA particles and introduce amine functional groups. The effects of monomer concentrations on the properties and separation performance of these novel membrane adsorbers will be presented.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts",
title = "Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles",
pages = "128-128",
url = "https://hdl.handle.net/21.15107/rcub_dais_796"
}

Radovanović, F., Tomković, T., Nastasović, A., Veličković, S., Nešić, A.,& Onjia, A. E.. (2013). Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
Belgrade : Serbian Chemical Society., 128-128.
https://hdl.handle.net/21.15107/rcub_dais_796

Radovanović F, Tomković T, Nastasović A, Veličković S, Nešić A, Onjia AE. Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts. 2013;:128-128.
https://hdl.handle.net/21.15107/rcub_dais_796 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Veličković, Sava, Nešić, Aleksandra, Onjia, Antonije E., "Asymmetric polyethersulfone membranes with crosslinked poly(glycidyl methacrylate) particles" in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts (2013):128-128,
https://hdl.handle.net/21.15107/rcub_dais_796 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Veličković, Sava
AU  - Nešić, Aleksandra
AU  - Onjia, Antonije E.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/797
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2855
AB  - Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.
PB  - Belgrade : Serbian Chemical Society
C3  - 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
T1  - Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization
SP  - 131
EP  - 131
UR  - https://hdl.handle.net/21.15107/rcub_dais_797
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Veličković, Sava and Nešić, Aleksandra and Onjia, Antonije E.",
year = "2013",
abstract = "Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts",
title = "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization",
pages = "131-131",
url = "https://hdl.handle.net/21.15107/rcub_dais_797"
}

Radovanović, F., Tomković, T., Nastasović, A., Veličković, S., Nešić, A.,& Onjia, A. E.. (2013). Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
Belgrade : Serbian Chemical Society., 131-131.
https://hdl.handle.net/21.15107/rcub_dais_797

Radovanović F, Tomković T, Nastasović A, Veličković S, Nešić A, Onjia AE. Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts. 2013;:131-131.
https://hdl.handle.net/21.15107/rcub_dais_797 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Veličković, Sava, Nešić, Aleksandra, Onjia, Antonije E., "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization" in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts (2013):131-131,
https://hdl.handle.net/21.15107/rcub_dais_797 .

TY  - CONF
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije E.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/799
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2854
AB  - Membrane adsorption has started to replace fixed bed chromatography for separation and purification of small quantities of valuable species in biotechnology and related areas. Membrane functionalization is usually required to introduce affinity groups for these applications. In this work novel membranes adsorbers were prepared by combining liquid phase inversion with photopolymerization of the solution comprising polyethersulfone, glycidyl methacrylate, sodium salt of 2-acrylamido-2-methylpropane sulfonic acid and a cross-linker. Membranes were characterized using SEM, AFM, FTIR, titration and water permeability measurements. Dynamic adsorption of Toluidine blue as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption.
PB  - Belgrade, Serbia : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
T1  - Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)
SP  - 38
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_dais_799
ER  - 

@conference{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Onjia, Antonije E.",
year = "2013",
abstract = "Membrane adsorption has started to replace fixed bed chromatography for separation and purification of small quantities of valuable species in biotechnology and related areas. Membrane functionalization is usually required to introduce affinity groups for these applications. In this work novel membranes adsorbers were prepared by combining liquid phase inversion with photopolymerization of the solution comprising polyethersulfone, glycidyl methacrylate, sodium salt of 2-acrylamido-2-methylpropane sulfonic acid and a cross-linker. Membranes were characterized using SEM, AFM, FTIR, titration and water permeability measurements. Dynamic adsorption of Toluidine blue as a model dye was used to demonstrate suitability of these novel membranes for membrane adsorption.",
publisher = "Belgrade, Serbia : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia",
title = "Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)",
pages = "38-38",
url = "https://hdl.handle.net/21.15107/rcub_dais_799"
}

Tomković, T., Radovanović, F., Nastasović, A., Vasiljević-Radović, D.,& Onjia, A. E.. (2013). Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid). in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
Belgrade, Serbia : Institute of Technical Sciences of SASA., 38-38.
https://hdl.handle.net/21.15107/rcub_dais_799

Tomković T, Radovanović F, Nastasović A, Vasiljević-Radović D, Onjia AE. Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid). in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia. 2013;:38-38.
https://hdl.handle.net/21.15107/rcub_dais_799 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Onjia, Antonije E., "Novel membrane adsorbers incorporating cross-linked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid)" in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia (2013):38-38,
https://hdl.handle.net/21.15107/rcub_dais_799 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Obradov, Marko
AU  - Jakšić, Zoran
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/805
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2600
AB  - Affinity-based devices utilizing plasmonic effects belong to the most sensitive chemical sensors. A membrane having a form which coincides with the distribution of surface electromagnetic waves coupled with collective oscillations of electron gas in the conductive part of the sensor represents an important building block for plasmonics. A way to boost selectivity of a plasmonic sensor is to functionalize such membrane and either to apply it on the sensor surface or even to use it as a stand-alone platform for sensing. In this work we considered a possibility to prepare multifunctional membranes for plasmonic sensing. In our experiments selectivity enhancement was achieved through the use of glycidyl methacrylate whose epoxy group is readily converted to a desired affinity group (e.g. amine, thiol, pyridine, dithiocarbamate) to preferently capture a targeted species. Further plasmonic functionalization was obtained by forming a thin hydrogel film through copolymerization of glycidyl methacrylate with mono- and multi-functional methacrylates and then incorporating silver nanoparticles within these nanocomposites. These plasmonic nanoparticles were produced either photochemically or by chemical reduction. Different schemes for plasmonic sensor selectivity enhancement using multifunctionalized glycidyl methacrylate membranes are considered.
C3  - Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.
T1  - Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity
SP  - MO2.5.1
EP  - MO2.5.5
UR  - https://hdl.handle.net/21.15107/rcub_dais_805
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Obradov, Marko and Jakšić, Zoran",
year = "2013",
abstract = "Affinity-based devices utilizing plasmonic effects belong to the most sensitive chemical sensors. A membrane having a form which coincides with the distribution of surface electromagnetic waves coupled with collective oscillations of electron gas in the conductive part of the sensor represents an important building block for plasmonics. A way to boost selectivity of a plasmonic sensor is to functionalize such membrane and either to apply it on the sensor surface or even to use it as a stand-alone platform for sensing. In this work we considered a possibility to prepare multifunctional membranes for plasmonic sensing. In our experiments selectivity enhancement was achieved through the use of glycidyl methacrylate whose epoxy group is readily converted to a desired affinity group (e.g. amine, thiol, pyridine, dithiocarbamate) to preferently capture a targeted species. Further plasmonic functionalization was obtained by forming a thin hydrogel film through copolymerization of glycidyl methacrylate with mono- and multi-functional methacrylates and then incorporating silver nanoparticles within these nanocomposites. These plasmonic nanoparticles were produced either photochemically or by chemical reduction. Different schemes for plasmonic sensor selectivity enhancement using multifunctionalized glycidyl methacrylate membranes are considered.",
journal = "Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.",
title = "Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity",
pages = "MO2.5.1-MO2.5.5",
url = "https://hdl.handle.net/21.15107/rcub_dais_805"
}

Radovanović, F., Tomković, T., Nastasović, A., Obradov, M.,& Jakšić, Z.. (2013). Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity. in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013., MO2.5.1-MO2.5.5.
https://hdl.handle.net/21.15107/rcub_dais_805

Radovanović F, Tomković T, Nastasović A, Obradov M, Jakšić Z. Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity. in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013.. 2013;:MO2.5.1-MO2.5.5.
https://hdl.handle.net/21.15107/rcub_dais_805 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Obradov, Marko, Jakšić, Zoran, "Nanoplasmonic multifunctionalization of glycidyl methacrylate hydrogel membranes for adsorption-based Chemical Sensors with Enhanced Selectivity" in Elektronski zbornik radova 57. konferencije ETRAN, Zlatibor, 3-6. juna 2013. (2013):MO2.5.1-MO2.5.5,
https://hdl.handle.net/21.15107/rcub_dais_805 .

TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra
AU  - Jakšić, Zoran
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/798
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2601
AB  - Plasmonics is the basis for a novel generation of adsorption-based ultrasensitive (bio) chemical sensors. In nanoplasmonic sensors one utilizes nanocomposites typically in the form of thin films, comprising metal nanoparticles or ordered metal-dielectrics (plasmonic crystals). In this work we investigated thin functionalized hydrogel films with embedded silver nanoparticles. These films were prepared by copolymerizing glycidyl methacrylate with mono and multifunctional methacrylates using UV irradiation. The epoxy group in glycidyl methacrylate can then be converted by chemical means into a desired functionality to capture the targeted analyte. Silver nanoparticles were either photochemically generated in situ, or were introduced into hydrogels by chemical reduction. Differences in morphology and performance of these nanocomposites were investigated andwill be discussed.
PB  - Banja Luka : Academy of Sciences and Arts of the Republic of Srpska
C3  - Sixth International Scientific Conference Contemporary Materials 2013, Banja Luka, July 4 to 6, 2013: Programme
C3  - Шести међународни научни скуп Савремени материјали 2013, Бања Лука, 4−6. јулa 2013. године: програм рада
T1  - Silver nanoparticles within functionalized hydrogels for plasmonic (bio)chemical sensors
SP  - 62
EP  - 62
UR  - https://hdl.handle.net/21.15107/rcub_dais_798
ER  - 

@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra and Jakšić, Zoran",
year = "2013",
abstract = "Plasmonics is the basis for a novel generation of adsorption-based ultrasensitive (bio) chemical sensors. In nanoplasmonic sensors one utilizes nanocomposites typically in the form of thin films, comprising metal nanoparticles or ordered metal-dielectrics (plasmonic crystals). In this work we investigated thin functionalized hydrogel films with embedded silver nanoparticles. These films were prepared by copolymerizing glycidyl methacrylate with mono and multifunctional methacrylates using UV irradiation. The epoxy group in glycidyl methacrylate can then be converted by chemical means into a desired functionality to capture the targeted analyte. Silver nanoparticles were either photochemically generated in situ, or were introduced into hydrogels by chemical reduction. Differences in morphology and performance of these nanocomposites were investigated andwill be discussed.",
publisher = "Banja Luka : Academy of Sciences and Arts of the Republic of Srpska",
journal = "Sixth International Scientific Conference Contemporary Materials 2013, Banja Luka, July 4 to 6, 2013: Programme, Шести међународни научни скуп Савремени материјали 2013, Бања Лука, 4−6. јулa 2013. године: програм рада",
title = "Silver nanoparticles within functionalized hydrogels for plasmonic (bio)chemical sensors",
pages = "62-62",
url = "https://hdl.handle.net/21.15107/rcub_dais_798"
}

Radovanović, F., Tomković, T., Nastasović, A.,& Jakšić, Z.. (2013). Silver nanoparticles within functionalized hydrogels for plasmonic (bio)chemical sensors. in Sixth International Scientific Conference Contemporary Materials 2013, Banja Luka, July 4 to 6, 2013: Programme
Banja Luka : Academy of Sciences and Arts of the Republic of Srpska., 62-62.
https://hdl.handle.net/21.15107/rcub_dais_798

Radovanović F, Tomković T, Nastasović A, Jakšić Z. Silver nanoparticles within functionalized hydrogels for plasmonic (bio)chemical sensors. in Sixth International Scientific Conference Contemporary Materials 2013, Banja Luka, July 4 to 6, 2013: Programme. 2013;:62-62.
https://hdl.handle.net/21.15107/rcub_dais_798 .

Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra, Jakšić, Zoran, "Silver nanoparticles within functionalized hydrogels for plasmonic (bio)chemical sensors" in Sixth International Scientific Conference Contemporary Materials 2013, Banja Luka, July 4 to 6, 2013: Programme (2013):62-62,
https://hdl.handle.net/21.15107/rcub_dais_798 .