Solid phase extraction membranes with submicron multifunctional adsorbent particles
Само за регистроване кориснике
2015
Аутори
Tomković, TanjaRadovanović, Filip
Nastasović, Aleksandra
Vasiljević-Radović, Dana
Markovic, Jelena
Grgur, Branimir N.
Onjia, Antonije E.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membrane...s demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.
Кључне речи:
Membrane formation / Photoirradiation / Sulfonic acid / Epoxide functionality / AminationИзвор:
European Polymer Journal, 2015, 63, 90-100Издавач:
- Oxford : Pergamon-Elsevier Science Ltd
Финансирање / пројекти:
- Микро, нано-системи и сензори за примену у електропривреди, процесној индустрији и заштити животне средине (RS-MESTD-Technological Development (TD or TR)-32008)
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
DOI: 10.1016/j.eurpolymj.2014.12.015
ISSN: 0014-3057
WoS: 000348878800011
Scopus: 2-s2.0-84942510082
Институција/група
IHTMTY - JOUR AU - Tomković, Tanja AU - Radovanović, Filip AU - Nastasović, Aleksandra AU - Vasiljević-Radović, Dana AU - Markovic, Jelena AU - Grgur, Branimir N. AU - Onjia, Antonije E. PY - 2015 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1748 AB - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - European Polymer Journal T1 - Solid phase extraction membranes with submicron multifunctional adsorbent particles VL - 63 SP - 90 EP - 100 DO - 10.1016/j.eurpolymj.2014.12.015 ER -
@article{ author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra and Vasiljević-Radović, Dana and Markovic, Jelena and Grgur, Branimir N. and Onjia, Antonije E.", year = "2015", abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "European Polymer Journal", title = "Solid phase extraction membranes with submicron multifunctional adsorbent particles", volume = "63", pages = "90-100", doi = "10.1016/j.eurpolymj.2014.12.015" }
Tomković, T., Radovanović, F., Nastasović, A., Vasiljević-Radović, D., Markovic, J., Grgur, B. N.,& Onjia, A. E.. (2015). Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal Oxford : Pergamon-Elsevier Science Ltd., 63, 90-100. https://doi.org/10.1016/j.eurpolymj.2014.12.015
Tomković T, Radovanović F, Nastasović A, Vasiljević-Radović D, Markovic J, Grgur BN, Onjia AE. Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal. 2015;63:90-100. doi:10.1016/j.eurpolymj.2014.12.015 .
Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra, Vasiljević-Radović, Dana, Markovic, Jelena, Grgur, Branimir N., Onjia, Antonije E., "Solid phase extraction membranes with submicron multifunctional adsorbent particles" in European Polymer Journal, 63 (2015):90-100, https://doi.org/10.1016/j.eurpolymj.2014.12.015 . .