TY  - JOUR
AU  - Stevanović, Jelena
AU  - Petrović, Srđan
AU  - Tadić, Nenad
AU  - Cvetanović, Katarina
AU  - Silva, Ana G.
AU  - Vasiljević-Radović, Dana
AU  - Sarajlić, Milija
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5809
AB  - TiO2 and CeO2 are well known as oxygen sensing materials. Despite high sensitivity, the actual utilization of these materials in gas detection remains limited. Research conducted over the last two decades has revealed synergistic effects of TiO2-CeO2 mixed oxides that have the potential to improve some aspects of oxygen monitoring. However, there are no studies on the sensing properties of the TiO2-CeO2 obtained by mechanochemical treatment. We have tested the applicability of the mechanochemically treated TiO2-CeO2 for oxygen detection and presented the results in this study. The sensing layers are prepared as a porous structure by screen printing a thick film on a commercial substrate. The obtained structures were exposed to various O2 concentrations. The results of electrical measurements showed that TiO2-CeO2 films have a significantly lower resistance than pure oxide films. Mixtures of composition TiO2:CeO2 = 0.8:0.2, ground for 100 min, have the lowest electrical resistance among the tested materials. Mixtures of composition TiO2:CeO2 = 0.5:0.5 and ground for 100 min proved to be the most sensitive. The operating temperature can be as low as 320 °C, which places this sensor in the class of semiconductor sensors working at relatively lower temperatures.
PB  - Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)
T2  - Sensors
T1  - Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor
VL  - 23
IS  - 3
SP  - 1313
DO  - 10.3390/s23031313
ER  - 

@article{
author = "Stevanović, Jelena and Petrović, Srđan and Tadić, Nenad and Cvetanović, Katarina and Silva, Ana G. and Vasiljević-Radović, Dana and Sarajlić, Milija",
year = "2023",
abstract = "TiO2 and CeO2 are well known as oxygen sensing materials. Despite high sensitivity, the actual utilization of these materials in gas detection remains limited. Research conducted over the last two decades has revealed synergistic effects of TiO2-CeO2 mixed oxides that have the potential to improve some aspects of oxygen monitoring. However, there are no studies on the sensing properties of the TiO2-CeO2 obtained by mechanochemical treatment. We have tested the applicability of the mechanochemically treated TiO2-CeO2 for oxygen detection and presented the results in this study. The sensing layers are prepared as a porous structure by screen printing a thick film on a commercial substrate. The obtained structures were exposed to various O2 concentrations. The results of electrical measurements showed that TiO2-CeO2 films have a significantly lower resistance than pure oxide films. Mixtures of composition TiO2:CeO2 = 0.8:0.2, ground for 100 min, have the lowest electrical resistance among the tested materials. Mixtures of composition TiO2:CeO2 = 0.5:0.5 and ground for 100 min proved to be the most sensitive. The operating temperature can be as low as 320 °C, which places this sensor in the class of semiconductor sensors working at relatively lower temperatures.",
publisher = "Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)",
journal = "Sensors",
title = "Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor",
volume = "23",
number = "3",
pages = "1313",
doi = "10.3390/s23031313"
}

Stevanović, J., Petrović, S., Tadić, N., Cvetanović, K., Silva, A. G., Vasiljević-Radović, D.,& Sarajlić, M.. (2023). Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor. in Sensors
Switzerland : Multidisciplinary Digital Publishing Institute (MDPI)., 23(3), 1313.
https://doi.org/10.3390/s23031313

Stevanović J, Petrović S, Tadić N, Cvetanović K, Silva AG, Vasiljević-Radović D, Sarajlić M. Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor. in Sensors. 2023;23(3):1313.
doi:10.3390/s23031313 .

Stevanović, Jelena, Petrović, Srđan, Tadić, Nenad, Cvetanović, Katarina, Silva, Ana G., Vasiljević-Radović, Dana, Sarajlić, Milija, "Mechanochemical Synthesis of TiO2-CeO2 Mixed Oxides Utilized as a Screen-Printed Sensing Material for Oxygen Sensor" in Sensors, 23, no. 3 (2023):1313,
https://doi.org/10.3390/s23031313 . .

TY  - JOUR
AU  - Mudrinić, Tihana
AU  - Petrović, Srđan
AU  - Krstić, Jugoslav
AU  - Milovanović, Biljana
AU  - Pavlović, Stefan
AU  - Banković, Predrag
AU  - Milutinović Nikolić, Aleksandra
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5308
AB  - The main goals of this study are: i) employ the electrochemical methods as alternative methods for alumina-supported cobalt (Co-A) surface characterization; ii) investigate the electro-catalytic activity of different cobalt phases toward glucose, and iii) implement the mechanochemical approach for the synthesis of the fourth generation of glucose sensing materials. Co3O4 and alumina were either manual grinded (Co3O4-A) or ball-milled (CoAl2O4-A) with different amounts of cobalt in CoAl2O4-A. The final products were characterized by XRF, LDPSA, XRD and TPR. The electrodes were prepared in the form of the carbon paste electrode and tested in supporting electrolyte (1 M NaOH) as well as in a glucose-containing solution. The CV, EIS, and chronoamperometry were used for electrochemical measurements. TPR revealed the formation of CoAl2O4 during the ball milling process. Different cobalt phases significantly affected the electrochemical responses. Higher activity of CoAl2O4-A toward glucose oxidation in comparison with Co3O4-A was ascribed to tetrahedral Co2+ ion acting as the active site in glucose oxidation. In addition, results convinced employing the scarcely employed mechanochemical synthesis protocols for obtaining glucose-sensing materials. Finally, it was proven that electrochemical techniques can be harnessed as alternative, new, powerful methods for Co-A surface characterization.
PB  - Elsevier
T2  - Surfaces and Interfaces
T1  - Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing
IS  - 102356
DO  - 10.1016/j.surfin.2022.102356
ER  - 

@article{
author = "Mudrinić, Tihana and Petrović, Srđan and Krstić, Jugoslav and Milovanović, Biljana and Pavlović, Stefan and Banković, Predrag and Milutinović Nikolić, Aleksandra",
year = "2022",
abstract = "The main goals of this study are: i) employ the electrochemical methods as alternative methods for alumina-supported cobalt (Co-A) surface characterization; ii) investigate the electro-catalytic activity of different cobalt phases toward glucose, and iii) implement the mechanochemical approach for the synthesis of the fourth generation of glucose sensing materials. Co3O4 and alumina were either manual grinded (Co3O4-A) or ball-milled (CoAl2O4-A) with different amounts of cobalt in CoAl2O4-A. The final products were characterized by XRF, LDPSA, XRD and TPR. The electrodes were prepared in the form of the carbon paste electrode and tested in supporting electrolyte (1 M NaOH) as well as in a glucose-containing solution. The CV, EIS, and chronoamperometry were used for electrochemical measurements. TPR revealed the formation of CoAl2O4 during the ball milling process. Different cobalt phases significantly affected the electrochemical responses. Higher activity of CoAl2O4-A toward glucose oxidation in comparison with Co3O4-A was ascribed to tetrahedral Co2+ ion acting as the active site in glucose oxidation. In addition, results convinced employing the scarcely employed mechanochemical synthesis protocols for obtaining glucose-sensing materials. Finally, it was proven that electrochemical techniques can be harnessed as alternative, new, powerful methods for Co-A surface characterization.",
publisher = "Elsevier",
journal = "Surfaces and Interfaces",
title = "Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing",
number = "102356",
doi = "10.1016/j.surfin.2022.102356"
}

Mudrinić, T., Petrović, S., Krstić, J., Milovanović, B., Pavlović, S., Banković, P.,& Milutinović Nikolić, A.. (2022). Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing. in Surfaces and Interfaces
Elsevier.(102356).
https://doi.org/10.1016/j.surfin.2022.102356

Mudrinić T, Petrović S, Krstić J, Milovanović B, Pavlović S, Banković P, Milutinović Nikolić A. Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing. in Surfaces and Interfaces. 2022;(102356).
doi:10.1016/j.surfin.2022.102356 .

Mudrinić, Tihana, Petrović, Srđan, Krstić, Jugoslav, Milovanović, Biljana, Pavlović, Stefan, Banković, Predrag, Milutinović Nikolić, Aleksandra, "Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing" in Surfaces and Interfaces, no. 102356 (2022),
https://doi.org/10.1016/j.surfin.2022.102356 . .

TY  - JOUR
AU  - Mudrinić, Tihana
AU  - Petrović, Srđan
AU  - Krstić, Jugoslav
AU  - Milovanović, Biljana
AU  - Pavlović, Stefan
AU  - Banković, Predrag
AU  - Milutinović Nikolić, Aleksandra
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5616
AB  - The main goals of this study are: i) employ the electrochemical methods as alternative methods for alumina-supported cobalt (Co-A) surface characterization; ii) investigate the electro-catalytic activity of different cobalt phases toward glucose, and iii) implement the mechanochemical approach for the synthesis of the fourth generation of glucose sensing materials. Co3O4 and alumina were either manual grinded (Co3O4-A) or ball-milled (CoAl2O4-A) with different amounts of cobalt in CoAl2O4-A. The final products were characterized by XRF, LDPSA, XRD and TPR. The electrodes were prepared in the form of the carbon paste electrode and tested in supporting electrolyte (1 M NaOH) as well as in a glucose-containing solution. The CV, EIS, and chronoamperometry were used for electrochemical measurements. TPR revealed the formation of CoAl2O4 during the ball milling process. Different cobalt phases significantly affected the electrochemical responses. Higher activity of CoAl2O4-A toward glucose oxidation in comparison with Co3O4-A was ascribed to tetrahedral Co2+ ion acting as the active site in glucose oxidation. In addition, results convinced employing the scarcely employed mechanochemical synthesis protocols for obtaining glucose-sensing materials. Finally, it was proven that electrochemical techniques can be harnessed as alternative, new, powerful methods for Co-A surface characterization.
PB  - Elsevier
T2  - Surfaces and Interfaces
T1  - Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing
IS  - 102356
DO  - 10.1016/j.surfin.2022.102356
ER  - 

@article{
author = "Mudrinić, Tihana and Petrović, Srđan and Krstić, Jugoslav and Milovanović, Biljana and Pavlović, Stefan and Banković, Predrag and Milutinović Nikolić, Aleksandra",
year = "2022",
abstract = "The main goals of this study are: i) employ the electrochemical methods as alternative methods for alumina-supported cobalt (Co-A) surface characterization; ii) investigate the electro-catalytic activity of different cobalt phases toward glucose, and iii) implement the mechanochemical approach for the synthesis of the fourth generation of glucose sensing materials. Co3O4 and alumina were either manual grinded (Co3O4-A) or ball-milled (CoAl2O4-A) with different amounts of cobalt in CoAl2O4-A. The final products were characterized by XRF, LDPSA, XRD and TPR. The electrodes were prepared in the form of the carbon paste electrode and tested in supporting electrolyte (1 M NaOH) as well as in a glucose-containing solution. The CV, EIS, and chronoamperometry were used for electrochemical measurements. TPR revealed the formation of CoAl2O4 during the ball milling process. Different cobalt phases significantly affected the electrochemical responses. Higher activity of CoAl2O4-A toward glucose oxidation in comparison with Co3O4-A was ascribed to tetrahedral Co2+ ion acting as the active site in glucose oxidation. In addition, results convinced employing the scarcely employed mechanochemical synthesis protocols for obtaining glucose-sensing materials. Finally, it was proven that electrochemical techniques can be harnessed as alternative, new, powerful methods for Co-A surface characterization.",
publisher = "Elsevier",
journal = "Surfaces and Interfaces",
title = "Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing",
number = "102356",
doi = "10.1016/j.surfin.2022.102356"
}

Mudrinić, T., Petrović, S., Krstić, J., Milovanović, B., Pavlović, S., Banković, P.,& Milutinović Nikolić, A.. (2022). Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing. in Surfaces and Interfaces
Elsevier.(102356).
https://doi.org/10.1016/j.surfin.2022.102356

Mudrinić T, Petrović S, Krstić J, Milovanović B, Pavlović S, Banković P, Milutinović Nikolić A. Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing. in Surfaces and Interfaces. 2022;(102356).
doi:10.1016/j.surfin.2022.102356 .

Mudrinić, Tihana, Petrović, Srđan, Krstić, Jugoslav, Milovanović, Biljana, Pavlović, Stefan, Banković, Predrag, Milutinović Nikolić, Aleksandra, "Electrochemical approach to the surface characterization of mechanochemically synthesized alumina-supported cobalt applicable in glucose sensing" in Surfaces and Interfaces, no. 102356 (2022),
https://doi.org/10.1016/j.surfin.2022.102356 . .

TY  - CONF
AU  - Mudrinić, Tihana
AU  - Milovanović, Biljana
AU  - Marinović, Sanja
AU  - Petrović, Srđan
AU  - Krstić, Jugoslav
AU  - Banković, Predrag
AU  - Milutinović Nikolić, Aleksandra
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6359
AB  - In recent years, mineral oxides (i.e. zeolite, alumina and clay minerals)-supported non-precious transition metals have extensively studied as highly promising sustainable and green glucose-sensing materials (Mudrinić, 2019). The reason for that is their low cost, easiness of synthesis, low negative environmental impact, and desirable electrochemical properties toward glucose oxidation. 
It is widely accepted that the catalytic activity of the mineral oxides-supported cobalt is strongly influenced by cobalt-mineral oxide interaction. As a consequence of this interaction different cobalt oxides (Wang, 1991) could be formed: Co3O4-contains both cobalt ions in tetrahedral (Co2+Td) and octahedral (Co3+Oh) coordination and CoAl2O4-contains only Co2+Td. However, little is known about the catalytic activity of these cobalt oxides (i.e. cobalt ions) in the reaction of the electro-oxidation of glucose. 
In this work, cobalt oxides in both tetrahedral (Co2+Td) and octahedral (Co3+Oh) coordination and with only Co2+Td were synthesized on aluminum pillared clay (AP) and alumina (A). The obtained materials were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and temperature-programmed reduction (TPR). Electrochemical measurements were performed in alkaline solution with and without glucose using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). TPR and XPS along with the results of electrochemical measurements in alkaline solutions without glucose confirmed the successful synthesis of the different cobalt oxides on both AP and A. The electrochemical measurements in glucose-containing solutions showed the enhanced electrocatalytic activity of AP and A with Co2+Td in comparison to their counterparts with both Co2+Td and Co3+Oh.  This result suggested that the Co2+Td acted as the main active site for the glucose oxidation.
PB  - The clay mineral society
C3  - Scientific research abstracts - AIPEA - 17th International Clay Conference (ICC 2022), 25-29 July, Istanbul, Turkey
T1  - Electrocatalytic activity of different cobalt oxides supported on mineral oxides toward glucose oxidation
SP  - 331
EP  - 331
UR  - https://hdl.handle.net/21.15107/rcub_cer_6359
ER  - 

@conference{
author = "Mudrinić, Tihana and Milovanović, Biljana and Marinović, Sanja and Petrović, Srđan and Krstić, Jugoslav and Banković, Predrag and Milutinović Nikolić, Aleksandra",
year = "2022",
abstract = "In recent years, mineral oxides (i.e. zeolite, alumina and clay minerals)-supported non-precious transition metals have extensively studied as highly promising sustainable and green glucose-sensing materials (Mudrinić, 2019). The reason for that is their low cost, easiness of synthesis, low negative environmental impact, and desirable electrochemical properties toward glucose oxidation. 
It is widely accepted that the catalytic activity of the mineral oxides-supported cobalt is strongly influenced by cobalt-mineral oxide interaction. As a consequence of this interaction different cobalt oxides (Wang, 1991) could be formed: Co3O4-contains both cobalt ions in tetrahedral (Co2+Td) and octahedral (Co3+Oh) coordination and CoAl2O4-contains only Co2+Td. However, little is known about the catalytic activity of these cobalt oxides (i.e. cobalt ions) in the reaction of the electro-oxidation of glucose. 
In this work, cobalt oxides in both tetrahedral (Co2+Td) and octahedral (Co3+Oh) coordination and with only Co2+Td were synthesized on aluminum pillared clay (AP) and alumina (A). The obtained materials were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and temperature-programmed reduction (TPR). Electrochemical measurements were performed in alkaline solution with and without glucose using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). TPR and XPS along with the results of electrochemical measurements in alkaline solutions without glucose confirmed the successful synthesis of the different cobalt oxides on both AP and A. The electrochemical measurements in glucose-containing solutions showed the enhanced electrocatalytic activity of AP and A with Co2+Td in comparison to their counterparts with both Co2+Td and Co3+Oh.  This result suggested that the Co2+Td acted as the main active site for the glucose oxidation.",
publisher = "The clay mineral society",
journal = "Scientific research abstracts - AIPEA - 17th International Clay Conference (ICC 2022), 25-29 July, Istanbul, Turkey",
title = "Electrocatalytic activity of different cobalt oxides supported on mineral oxides toward glucose oxidation",
pages = "331-331",
url = "https://hdl.handle.net/21.15107/rcub_cer_6359"
}

Mudrinić, T., Milovanović, B., Marinović, S., Petrović, S., Krstić, J., Banković, P.,& Milutinović Nikolić, A.. (2022). Electrocatalytic activity of different cobalt oxides supported on mineral oxides toward glucose oxidation. in Scientific research abstracts - AIPEA - 17th International Clay Conference (ICC 2022), 25-29 July, Istanbul, Turkey
The clay mineral society., 331-331.
https://hdl.handle.net/21.15107/rcub_cer_6359

Mudrinić T, Milovanović B, Marinović S, Petrović S, Krstić J, Banković P, Milutinović Nikolić A. Electrocatalytic activity of different cobalt oxides supported on mineral oxides toward glucose oxidation. in Scientific research abstracts - AIPEA - 17th International Clay Conference (ICC 2022), 25-29 July, Istanbul, Turkey. 2022;:331-331.
https://hdl.handle.net/21.15107/rcub_cer_6359 .

Mudrinić, Tihana, Milovanović, Biljana, Marinović, Sanja, Petrović, Srđan, Krstić, Jugoslav, Banković, Predrag, Milutinović Nikolić, Aleksandra, "Electrocatalytic activity of different cobalt oxides supported on mineral oxides toward glucose oxidation" in Scientific research abstracts - AIPEA - 17th International Clay Conference (ICC 2022), 25-29 July, Istanbul, Turkey (2022):331-331,
https://hdl.handle.net/21.15107/rcub_cer_6359 .

TY  - CONF
AU  - Mudrinić, Tihana
AU  - Milovanović, Biljana
AU  - Petrović, Srđan
AU  - Pavlović, Stefan
AU  - Banković, Predrag
AU  - Milutinović Nikolić, Aleksandra
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5305
AB  - Recently the focus of electrochemical glucose sensing is on the fabrication of enzyme-free electrodes based on non-precious transition metal oxides, especially cobalt oxide [1]. To our best knowledge, these materials were primarily prepared by conventional methods using solutions, while the solvent-free mechanochemical approach was scarcely reported. Therefore, in this work Co3O4 supported on alumina (Co3O4/Al2O3) were prepared by ball milling using different milling times (0.5, 1, and 2 h) and Co3O4 contents (4, 8, and 16 wt. %). Ball to powder ratio was 30:1 and the rotation speed was 300 rpm. The electrodes based on the synthesized material were prepared in the form of a carbon paste electrodes (CP-Co3O4/Al2O3). The particle size distribution, phase, and chemical composition of the obtained materials were determined using LDPSA, XRPD, and XRF, respectively. The electrochemical performance of the CP-Co3O4/A12O3 electrode was tested in an alkaline solution containing glucose using cyclovoltammetry (CV) and chronoamperometry (ChA). CV revealed that milling time affected the electrochemical response. The highest current response was obtained with material milled for 1 h. Both ChA and CV confirmed that the electrochemical performance was further improved by increasing cobalt content. The CP electrode-based mechanochemically prepared samples showed enhanced performance in comparison to hand mixed Co3O4 and alumina. The beneficial effect of ball milling was attributed to the high dispersion of cobalt oxides over alumina even for large cobalt loadings without agglomeration. The obtained experimental results proved that the solvent-free mechanochemical approach is a promising synthetic route for obtaining green and sustainable glucose-sensing material for the fourth generation.
PB  - Calgary, Italy :  University of Cagliari
PB  - COST Action CA18112
C3  - Book of abstracts - 10th International Conference on Mechanochemistry and Mechanical Alloying
T1  - Mechanochemical approach for non-enzymatic sensing materials
UR  - https://hdl.handle.net/21.15107/rcub_cer_5305
ER  - 

@conference{
author = "Mudrinić, Tihana and Milovanović, Biljana and Petrović, Srđan and Pavlović, Stefan and Banković, Predrag and Milutinović Nikolić, Aleksandra",
year = "2022",
abstract = "Recently the focus of electrochemical glucose sensing is on the fabrication of enzyme-free electrodes based on non-precious transition metal oxides, especially cobalt oxide [1]. To our best knowledge, these materials were primarily prepared by conventional methods using solutions, while the solvent-free mechanochemical approach was scarcely reported. Therefore, in this work Co3O4 supported on alumina (Co3O4/Al2O3) were prepared by ball milling using different milling times (0.5, 1, and 2 h) and Co3O4 contents (4, 8, and 16 wt. %). Ball to powder ratio was 30:1 and the rotation speed was 300 rpm. The electrodes based on the synthesized material were prepared in the form of a carbon paste electrodes (CP-Co3O4/Al2O3). The particle size distribution, phase, and chemical composition of the obtained materials were determined using LDPSA, XRPD, and XRF, respectively. The electrochemical performance of the CP-Co3O4/A12O3 electrode was tested in an alkaline solution containing glucose using cyclovoltammetry (CV) and chronoamperometry (ChA). CV revealed that milling time affected the electrochemical response. The highest current response was obtained with material milled for 1 h. Both ChA and CV confirmed that the electrochemical performance was further improved by increasing cobalt content. The CP electrode-based mechanochemically prepared samples showed enhanced performance in comparison to hand mixed Co3O4 and alumina. The beneficial effect of ball milling was attributed to the high dispersion of cobalt oxides over alumina even for large cobalt loadings without agglomeration. The obtained experimental results proved that the solvent-free mechanochemical approach is a promising synthetic route for obtaining green and sustainable glucose-sensing material for the fourth generation.",
publisher = "Calgary, Italy :  University of Cagliari, COST Action CA18112",
journal = "Book of abstracts - 10th International Conference on Mechanochemistry and Mechanical Alloying",
title = "Mechanochemical approach for non-enzymatic sensing materials",
url = "https://hdl.handle.net/21.15107/rcub_cer_5305"
}

Mudrinić, T., Milovanović, B., Petrović, S., Pavlović, S., Banković, P.,& Milutinović Nikolić, A.. (2022). Mechanochemical approach for non-enzymatic sensing materials. in Book of abstracts - 10th International Conference on Mechanochemistry and Mechanical Alloying
Calgary, Italy :  University of Cagliari..
https://hdl.handle.net/21.15107/rcub_cer_5305

Mudrinić T, Milovanović B, Petrović S, Pavlović S, Banković P, Milutinović Nikolić A. Mechanochemical approach for non-enzymatic sensing materials. in Book of abstracts - 10th International Conference on Mechanochemistry and Mechanical Alloying. 2022;.
https://hdl.handle.net/21.15107/rcub_cer_5305 .

Mudrinić, Tihana, Milovanović, Biljana, Petrović, Srđan, Pavlović, Stefan, Banković, Predrag, Milutinović Nikolić, Aleksandra, "Mechanochemical approach for non-enzymatic sensing materials" in Book of abstracts - 10th International Conference on Mechanochemistry and Mechanical Alloying (2022),
https://hdl.handle.net/21.15107/rcub_cer_5305 .

TY  - JOUR
AU  - Yan, Luo-bin
AU  - Petrović, Srđan
AU  - Huang, Cheng
AU  - Xie, Chun-xia
AU  - Zong, Hui-ming
AU  - Kašanin-Grubin, Milica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5475
AB  - Quantifying rock weathering processes, especially in ways of nondisturbance and on-site investigation, is one of the most critical tasks in predicting rocks erosion rates and understanding the sediment transportation. We proposed a more reproducible approach to test how image analysis can quantify the changes in the size and shape of fragments during the weathering process. Four artificial models were designed to select suitable metrics among over 20 parameters. To validate the efficiency of image analysis, we analyzed rocks from badlands in Nanxiong Basin, Southeast China, under three different ranges of temperature differences (TD) during cyclic wetting and drying (WD). Our results show that TDs can accelerate the disintegration rate, and even if there is only a 20°C difference in the range of TDs, an apparent difference in fragment size was observed. Moreover, the shape of fragments became more round as the increasing number of cyclic treatments, and for samples that went through the same number of treatments, the larger the temperature difference, the more round the shape became. All that serves as another evidence for landscape evolution response to climatic warming.
PB  - Springer Nature
T2  - Journal of Mountain Science
T1  - Effect of temperature on mudstone disintegration process revealed with image analysis
VL  - 19
IS  - 7
SP  - 2126
EP  - 2135
DO  - 10.1007/s11629-021-7268-3
ER  - 

@article{
author = "Yan, Luo-bin and Petrović, Srđan and Huang, Cheng and Xie, Chun-xia and Zong, Hui-ming and Kašanin-Grubin, Milica",
year = "2022",
abstract = "Quantifying rock weathering processes, especially in ways of nondisturbance and on-site investigation, is one of the most critical tasks in predicting rocks erosion rates and understanding the sediment transportation. We proposed a more reproducible approach to test how image analysis can quantify the changes in the size and shape of fragments during the weathering process. Four artificial models were designed to select suitable metrics among over 20 parameters. To validate the efficiency of image analysis, we analyzed rocks from badlands in Nanxiong Basin, Southeast China, under three different ranges of temperature differences (TD) during cyclic wetting and drying (WD). Our results show that TDs can accelerate the disintegration rate, and even if there is only a 20°C difference in the range of TDs, an apparent difference in fragment size was observed. Moreover, the shape of fragments became more round as the increasing number of cyclic treatments, and for samples that went through the same number of treatments, the larger the temperature difference, the more round the shape became. All that serves as another evidence for landscape evolution response to climatic warming.",
publisher = "Springer Nature",
journal = "Journal of Mountain Science",
title = "Effect of temperature on mudstone disintegration process revealed with image analysis",
volume = "19",
number = "7",
pages = "2126-2135",
doi = "10.1007/s11629-021-7268-3"
}

Yan, L., Petrović, S., Huang, C., Xie, C., Zong, H.,& Kašanin-Grubin, M.. (2022). Effect of temperature on mudstone disintegration process revealed with image analysis. in Journal of Mountain Science
Springer Nature., 19(7), 2126-2135.
https://doi.org/10.1007/s11629-021-7268-3

Yan L, Petrović S, Huang C, Xie C, Zong H, Kašanin-Grubin M. Effect of temperature on mudstone disintegration process revealed with image analysis. in Journal of Mountain Science. 2022;19(7):2126-2135.
doi:10.1007/s11629-021-7268-3 .

Yan, Luo-bin, Petrović, Srđan, Huang, Cheng, Xie, Chun-xia, Zong, Hui-ming, Kašanin-Grubin, Milica, "Effect of temperature on mudstone disintegration process revealed with image analysis" in Journal of Mountain Science, 19, no. 7 (2022):2126-2135,
https://doi.org/10.1007/s11629-021-7268-3 . .

TY  - CONF
AU  - Mudrinić, Tihana
AU  - Petrović, Srđan
AU  - Krstić, Jugoslav
AU  - Milovanović, Biljana
AU  - Pavlović, Stefan
AU  - Milutinović Nikolić, Aleksandra
AU  - Banković, Predrag
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4780
AB  - This work describes the possible application of cyclic voltammetry (CV) for obtaining information  about  cobalt  phases  onto  alumina supported  cobalt  catalysts.Starting  from  the  same  amount  of  ingredients,  two  catalysts  with  different  phases  of  cobalt  were  prepared:  Co3O4-A  obtained  by  manual  grinding  of  Co3O4  and alumina  in  an  agate  mortar  and  CoAl2O4-A  obtained  mechanochemically  using  a  planetary  ball  mill.The  final  productswere characterized  by  the  temperature-programmed  reduction  (TPR)  and  CV.  The  TPR  profile  of  Co3O4-A  showed  peaks  between  200–500°C  characteristic  of  Co3O4  reduction,  while  the  profile  of  CoAl2O4-A  was  altered  in  the  whole  temperature  region  and  especially  by  the  appearance  of  new  peaks  in  the  region  of  temperatures  of  600–900oC.This  result  indicated  that  a  certain  amount  ofhard-to-reduce  cobalt  aluminate  is  generated  during  milling.  CVin  alkaline  solution  revealed  that  theoxidation/reduction  of  cobalt  in  CoAl2O4-Aoccurred  at  more  negative  potentials  compared  with  cobalt  in  Co3O4-A.Negative  shift  of  peak  potential  well  correlated  with  the  appearance  of  high-temperature  TPR  peak  and  could  be  ascribed  to  the cobalt phase which has lower tendency to get reduced. These findings encourage the idea of using the CV as low cost and rapid assay for distinguishing the cobalt phases onto alumina.
PB  - Belgrade: Serbian Ceramic Society
C3  - Program and the Book of Abstracts - The 9th Serbian Ceramics Society Conference ''Advanced Ceramics and Application'', Belgrade
T1  - Electrochemical characterization of cobalt phases onto alumina supported cobalt catalyst
SP  - 85
EP  - 85
UR  - https://hdl.handle.net/21.15107/rcub_cer_4780
ER  - 

@conference{
author = "Mudrinić, Tihana and Petrović, Srđan and Krstić, Jugoslav and Milovanović, Biljana and Pavlović, Stefan and Milutinović Nikolić, Aleksandra and Banković, Predrag",
year = "2021",
abstract = "This work describes the possible application of cyclic voltammetry (CV) for obtaining information  about  cobalt  phases  onto  alumina supported  cobalt  catalysts.Starting  from  the  same  amount  of  ingredients,  two  catalysts  with  different  phases  of  cobalt  were  prepared:  Co3O4-A  obtained  by  manual  grinding  of  Co3O4  and alumina  in  an  agate  mortar  and  CoAl2O4-A  obtained  mechanochemically  using  a  planetary  ball  mill.The  final  productswere characterized  by  the  temperature-programmed  reduction  (TPR)  and  CV.  The  TPR  profile  of  Co3O4-A  showed  peaks  between  200–500°C  characteristic  of  Co3O4  reduction,  while  the  profile  of  CoAl2O4-A  was  altered  in  the  whole  temperature  region  and  especially  by  the  appearance  of  new  peaks  in  the  region  of  temperatures  of  600–900oC.This  result  indicated  that  a  certain  amount  ofhard-to-reduce  cobalt  aluminate  is  generated  during  milling.  CVin  alkaline  solution  revealed  that  theoxidation/reduction  of  cobalt  in  CoAl2O4-Aoccurred  at  more  negative  potentials  compared  with  cobalt  in  Co3O4-A.Negative  shift  of  peak  potential  well  correlated  with  the  appearance  of  high-temperature  TPR  peak  and  could  be  ascribed  to  the cobalt phase which has lower tendency to get reduced. These findings encourage the idea of using the CV as low cost and rapid assay for distinguishing the cobalt phases onto alumina.",
publisher = "Belgrade: Serbian Ceramic Society",
journal = "Program and the Book of Abstracts - The 9th Serbian Ceramics Society Conference ''Advanced Ceramics and Application'', Belgrade",
title = "Electrochemical characterization of cobalt phases onto alumina supported cobalt catalyst",
pages = "85-85",
url = "https://hdl.handle.net/21.15107/rcub_cer_4780"
}

Mudrinić, T., Petrović, S., Krstić, J., Milovanović, B., Pavlović, S., Milutinović Nikolić, A.,& Banković, P.. (2021). Electrochemical characterization of cobalt phases onto alumina supported cobalt catalyst. in Program and the Book of Abstracts - The 9th Serbian Ceramics Society Conference ''Advanced Ceramics and Application'', Belgrade
Belgrade: Serbian Ceramic Society., 85-85.
https://hdl.handle.net/21.15107/rcub_cer_4780

Mudrinić T, Petrović S, Krstić J, Milovanović B, Pavlović S, Milutinović Nikolić A, Banković P. Electrochemical characterization of cobalt phases onto alumina supported cobalt catalyst. in Program and the Book of Abstracts - The 9th Serbian Ceramics Society Conference ''Advanced Ceramics and Application'', Belgrade. 2021;:85-85.
https://hdl.handle.net/21.15107/rcub_cer_4780 .

Mudrinić, Tihana, Petrović, Srđan, Krstić, Jugoslav, Milovanović, Biljana, Pavlović, Stefan, Milutinović Nikolić, Aleksandra, Banković, Predrag, "Electrochemical characterization of cobalt phases onto alumina supported cobalt catalyst" in Program and the Book of Abstracts - The 9th Serbian Ceramics Society Conference ''Advanced Ceramics and Application'', Belgrade (2021):85-85,
https://hdl.handle.net/21.15107/rcub_cer_4780 .

TY  - JOUR
AU  - Mojović, Zorica
AU  - Petrović, Srđan
AU  - Mojović, Miloš
AU  - Pavlović, Stefan
AU  - Rožić, Ljiljana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3702
AB  - In this paper, the relationship of structure, type of oxygen defects, valence states of Cr and Ru, and electro-
chemical properties of La0.7Sr0.3Cr1-XRuXO3 (0 < x < 0.1) perovskite-type oxides were studied. The samples were 
synthesized by a conventional solid-state reaction method and characterized by powder X-ray diffraction, X-ray 
fluorescence spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and electron 
paramagnetic resonance spectroscopy. The electrochemical performance of these samples was evaluated towards 
the detection of 4-nitrophenol and strongly depends on the concentration of ruthenium incorporated in the 
crystal lattice. A new La0.7Sr0.3Cr0.925Ru0.075O3 electrocatalyst with a wide linear concentration range (25–5000 
mM) and a detection limit of 8 mM was obtained. These results provide an opportunity for its application in the 
analysis of real water samples.
PB  - Elsevier
T2  - Journal of Physics and Chemistry of Solids
T1  - Ruthenium containing perovskites as electrode materials for  4-nitrophenol detection
VL  - 148
SP  - 109649
DO  - 10.1016/j.jpcs.2020.109649
ER  - 

@article{
author = "Mojović, Zorica and Petrović, Srđan and Mojović, Miloš and Pavlović, Stefan and Rožić, Ljiljana",
year = "2021",
abstract = "In this paper, the relationship of structure, type of oxygen defects, valence states of Cr and Ru, and electro-
chemical properties of La0.7Sr0.3Cr1-XRuXO3 (0 < x < 0.1) perovskite-type oxides were studied. The samples were 
synthesized by a conventional solid-state reaction method and characterized by powder X-ray diffraction, X-ray 
fluorescence spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and electron 
paramagnetic resonance spectroscopy. The electrochemical performance of these samples was evaluated towards 
the detection of 4-nitrophenol and strongly depends on the concentration of ruthenium incorporated in the 
crystal lattice. A new La0.7Sr0.3Cr0.925Ru0.075O3 electrocatalyst with a wide linear concentration range (25–5000 
mM) and a detection limit of 8 mM was obtained. These results provide an opportunity for its application in the 
analysis of real water samples.",
publisher = "Elsevier",
journal = "Journal of Physics and Chemistry of Solids",
title = "Ruthenium containing perovskites as electrode materials for  4-nitrophenol detection",
volume = "148",
pages = "109649",
doi = "10.1016/j.jpcs.2020.109649"
}

Mojović, Z., Petrović, S., Mojović, M., Pavlović, S.,& Rožić, L.. (2021). Ruthenium containing perovskites as electrode materials for  4-nitrophenol detection. in Journal of Physics and Chemistry of Solids
Elsevier., 148, 109649.
https://doi.org/10.1016/j.jpcs.2020.109649

Mojović Z, Petrović S, Mojović M, Pavlović S, Rožić L. Ruthenium containing perovskites as electrode materials for  4-nitrophenol detection. in Journal of Physics and Chemistry of Solids. 2021;148:109649.
doi:10.1016/j.jpcs.2020.109649 .

Mojović, Zorica, Petrović, Srđan, Mojović, Miloš, Pavlović, Stefan, Rožić, Ljiljana, "Ruthenium containing perovskites as electrode materials for  4-nitrophenol detection" in Journal of Physics and Chemistry of Solids, 148 (2021):109649,
https://doi.org/10.1016/j.jpcs.2020.109649 . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Stanković, Miroslav
AU  - Pavlović, Stefan
AU  - Mojović, Zorica
AU  - Radić, Nenad
AU  - Mojović, Miloš
AU  - Rožić, Ljiljana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4722
AB  - This paper presents a new two-step method for the synthesis of NiO/TiO2–CeO2 semiconductors, which implies, the first, the mechanochemical synthesis of TiO2–CeO2 support, and the second is the doping of different NiO contents by chemical precipitation in an aqueous medium in an ambient atmosphere. Structural, optical, electrochemical and photocatalytic properties of NiO/TiO2–CeO2 semiconductors were examined. The influence of different NiO contents on the electrocatalytic activity of NiO/TiO2–CeO2 samples was investigated in the oxygen evolution reaction and the results showed that the samples with the lowest NiO content have the highest electroactivity. The photocatalytic activity was determined during the phenol decomposition process over the samples with different NiO:TiO2–CeO2 ratios and the best photocatalytic activity is observed for the sample with 4.1 mol% NiO. The sample with the lowest NiO content obtained by a relatively simple method is suitable for use both as an electrode material in the oxygen evolution reaction and as a photocatalyst in the phenol decomposition process.
PB  - Springer
T2  - Reaction Kinetics, Mechanisms and Catalysis
T1  - Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity
VL  - 133
SP  - 1097
EP  - 1110
DO  - 10.1007/s11144-021-02014-8
ER  - 

@article{
author = "Petrović, Srđan and Stanković, Miroslav and Pavlović, Stefan and Mojović, Zorica and Radić, Nenad and Mojović, Miloš and Rožić, Ljiljana",
year = "2021",
abstract = "This paper presents a new two-step method for the synthesis of NiO/TiO2–CeO2 semiconductors, which implies, the first, the mechanochemical synthesis of TiO2–CeO2 support, and the second is the doping of different NiO contents by chemical precipitation in an aqueous medium in an ambient atmosphere. Structural, optical, electrochemical and photocatalytic properties of NiO/TiO2–CeO2 semiconductors were examined. The influence of different NiO contents on the electrocatalytic activity of NiO/TiO2–CeO2 samples was investigated in the oxygen evolution reaction and the results showed that the samples with the lowest NiO content have the highest electroactivity. The photocatalytic activity was determined during the phenol decomposition process over the samples with different NiO:TiO2–CeO2 ratios and the best photocatalytic activity is observed for the sample with 4.1 mol% NiO. The sample with the lowest NiO content obtained by a relatively simple method is suitable for use both as an electrode material in the oxygen evolution reaction and as a photocatalyst in the phenol decomposition process.",
publisher = "Springer",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
title = "Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity",
volume = "133",
pages = "1097-1110",
doi = "10.1007/s11144-021-02014-8"
}

Petrović, S., Stanković, M., Pavlović, S., Mojović, Z., Radić, N., Mojović, M.,& Rožić, L.. (2021). Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity. in Reaction Kinetics, Mechanisms and Catalysis
Springer., 133, 1097-1110.
https://doi.org/10.1007/s11144-021-02014-8

Petrović S, Stanković M, Pavlović S, Mojović Z, Radić N, Mojović M, Rožić L. Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity. in Reaction Kinetics, Mechanisms and Catalysis. 2021;133:1097-1110.
doi:10.1007/s11144-021-02014-8 .

Petrović, Srđan, Stanković, Miroslav, Pavlović, Stefan, Mojović, Zorica, Radić, Nenad, Mojović, Miloš, Rožić, Ljiljana, "Nickel oxide on mechanochemically synthesized TiO2–CeO2: photocatalytic and electrochemical activity" in Reaction Kinetics, Mechanisms and Catalysis, 133 (2021):1097-1110,
https://doi.org/10.1007/s11144-021-02014-8 . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Cherkezova-Zheleva, Zara
AU  - Stojadinović, Stevan
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5688
AB  - The LaTi0.4Mg0.4Fe0.2O3 perovskite was synthesized using a mechanochemical process followed by high-temperature annealing at 600 and 800 ​°C. The effects of milling time and annealing temperature on structural, microstructural changes and optical properties were examined. The photocatalytic activity of LaTi0.4Mg0.4Fe0.2O3 perovskite was evaluated through the photodegradation of methyl orange and methylene blue dyes under UV light irradiation. The results showed that the annealing temperature performed an important role in the crystallite size, crystalline degree, photoluminescence, and band gaps of the LaTi0.4Mg0.4Fe0.2O3 samples. The temperature of annealing had a profound influence on the photocatalytic activities of the LaTi0.4Mg0.4Fe0.2O3 perovskite in the single and binary dye system. The highest photocatalytic activity for methyl orange degradation showed the LaTi0.4Mg0.4Fe0.2O3 annealed at 800 ​°C, while not annealed sample, show the highest activity for degradation of methylene blue. The maximum efficiency of methylene blue photodegradation in individual and binary mixtures was observed over non-annealed perovskite at the same irradiation times. The photodegradation of methylene blue and methyl orange on the LaTi0.4Mg0.4Fe0.2O3 followed a pseudo-first-order kinetic process.
PB  - Elsevier
T2  - Journal of Solid State Chemistry
T1  - Structural, optical and photocatalytic properties of LaTi0.4Mg0.4Fe0.2O3 perovskite prepared by high-energy ball milling
VL  - 297
SP  - 122085
DO  - 10.1016/j.jssc.2021.122085
ER  - 

@article{
author = "Petrović, Srđan and Rožić, Ljiljana and Grbić, Boško and Radić, Nenad and Cherkezova-Zheleva, Zara and Stojadinović, Stevan",
year = "2021",
abstract = "The LaTi0.4Mg0.4Fe0.2O3 perovskite was synthesized using a mechanochemical process followed by high-temperature annealing at 600 and 800 ​°C. The effects of milling time and annealing temperature on structural, microstructural changes and optical properties were examined. The photocatalytic activity of LaTi0.4Mg0.4Fe0.2O3 perovskite was evaluated through the photodegradation of methyl orange and methylene blue dyes under UV light irradiation. The results showed that the annealing temperature performed an important role in the crystallite size, crystalline degree, photoluminescence, and band gaps of the LaTi0.4Mg0.4Fe0.2O3 samples. The temperature of annealing had a profound influence on the photocatalytic activities of the LaTi0.4Mg0.4Fe0.2O3 perovskite in the single and binary dye system. The highest photocatalytic activity for methyl orange degradation showed the LaTi0.4Mg0.4Fe0.2O3 annealed at 800 ​°C, while not annealed sample, show the highest activity for degradation of methylene blue. The maximum efficiency of methylene blue photodegradation in individual and binary mixtures was observed over non-annealed perovskite at the same irradiation times. The photodegradation of methylene blue and methyl orange on the LaTi0.4Mg0.4Fe0.2O3 followed a pseudo-first-order kinetic process.",
publisher = "Elsevier",
journal = "Journal of Solid State Chemistry",
title = "Structural, optical and photocatalytic properties of LaTi0.4Mg0.4Fe0.2O3 perovskite prepared by high-energy ball milling",
volume = "297",
pages = "122085",
doi = "10.1016/j.jssc.2021.122085"
}

Petrović, S., Rožić, L., Grbić, B., Radić, N., Cherkezova-Zheleva, Z.,& Stojadinović, S.. (2021). Structural, optical and photocatalytic properties of LaTi0.4Mg0.4Fe0.2O3 perovskite prepared by high-energy ball milling. in Journal of Solid State Chemistry
Elsevier., 297, 122085.
https://doi.org/10.1016/j.jssc.2021.122085

Petrović S, Rožić L, Grbić B, Radić N, Cherkezova-Zheleva Z, Stojadinović S. Structural, optical and photocatalytic properties of LaTi0.4Mg0.4Fe0.2O3 perovskite prepared by high-energy ball milling. in Journal of Solid State Chemistry. 2021;297:122085.
doi:10.1016/j.jssc.2021.122085 .

Petrović, Srđan, Rožić, Ljiljana, Grbić, Boško, Radić, Nenad, Cherkezova-Zheleva, Zara, Stojadinović, Stevan, "Structural, optical and photocatalytic properties of LaTi0.4Mg0.4Fe0.2O3 perovskite prepared by high-energy ball milling" in Journal of Solid State Chemistry, 297 (2021):122085,
https://doi.org/10.1016/j.jssc.2021.122085 . .

TY  - JOUR
AU  - Radić, Nenad
AU  - Grbić, Boško
AU  - Petrović, Srđan
AU  - Stojadinović, Stevan
AU  - Tadić, Nenad
AU  - Stefanov, Plamen
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3782
AB  - The spray pyrolysis is fast and simple method for deposition of CeO2 – rutile TiO2 coatings on stainless steel substrate. The coatings were deposited on stainless steel substrate and characterized by XRD, AFM, XPS, Raman, DRS and photoactivity test for methyl orange decolorization. Photoactivity of CeO2 – rutile TiO2 coatings increase with increasing CeO2 content up to 5 wt% and further increase of CeO2 content leads to decrease of photoactivity. Improvements of photoactivity originate from close contact between CeO2 and rutile TiO2 particles which create numerous centers able to produce very reactive radical species. Besides, the close contact between the CeO2 and rutile TiO2 provides easier charge transfer facilitating the formation of electron/hole pairs that is a necessary step in the overall photocatalytic process.
PB  - Elsevier
T2  - Physica B: Physics of Condensed Matter
T1  - Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis
VL  - 599
SP  - 412544
DO  - 10.1016/j.physb.2020.412544
ER  - 

@article{
author = "Radić, Nenad and Grbić, Boško and Petrović, Srđan and Stojadinović, Stevan and Tadić, Nenad and Stefanov, Plamen",
year = "2020",
abstract = "The spray pyrolysis is fast and simple method for deposition of CeO2 – rutile TiO2 coatings on stainless steel substrate. The coatings were deposited on stainless steel substrate and characterized by XRD, AFM, XPS, Raman, DRS and photoactivity test for methyl orange decolorization. Photoactivity of CeO2 – rutile TiO2 coatings increase with increasing CeO2 content up to 5 wt% and further increase of CeO2 content leads to decrease of photoactivity. Improvements of photoactivity originate from close contact between CeO2 and rutile TiO2 particles which create numerous centers able to produce very reactive radical species. Besides, the close contact between the CeO2 and rutile TiO2 provides easier charge transfer facilitating the formation of electron/hole pairs that is a necessary step in the overall photocatalytic process.",
publisher = "Elsevier",
journal = "Physica B: Physics of Condensed Matter",
title = "Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis",
volume = "599",
pages = "412544",
doi = "10.1016/j.physb.2020.412544"
}

Radić, N., Grbić, B., Petrović, S., Stojadinović, S., Tadić, N.,& Stefanov, P.. (2020). Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis. in Physica B: Physics of Condensed Matter
Elsevier., 599, 412544.
https://doi.org/10.1016/j.physb.2020.412544

Radić N, Grbić B, Petrović S, Stojadinović S, Tadić N, Stefanov P. Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis. in Physica B: Physics of Condensed Matter. 2020;599:412544.
doi:10.1016/j.physb.2020.412544 .

Radić, Nenad, Grbić, Boško, Petrović, Srđan, Stojadinović, Stevan, Tadić, Nenad, Stefanov, Plamen, "Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis" in Physica B: Physics of Condensed Matter, 599 (2020):412544,
https://doi.org/10.1016/j.physb.2020.412544 . .

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Đuričić-Milanković, Jelena
AU  - Pantelić, Ana
AU  - Petrović, Srđan
AU  - Gambaro, Andrea
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3350
AB  - The main aim of this work is characterization of atmospheric aerosol using 11 stage cascade impactor. The first investigation of size-segregated sub-urban aerosols from the continental part of the Balkan peninsula in 11 fractions in the range of 0.0085 < Dp < 16 μm was performed from March 2012 to December 2013. Aerosols were measured at the Zeleno Brdo observatory (ϕ = 44°48’; λ = 20°28′–243 m above sea level), the highest landmark on the eastern side of Belgrade. Zeleno Brdo is surrounded by wooded vegetation and comprises of both southern facing rural and north-west orientated urban areas. About 70% of total aerosols are fine particles, belonging especially to the PM0.53–1.06 fraction which is found to be more pronounced in winter period. In this work, we applied tests of probability function models for three distributions: normal, log-normal and three-parameter Weibull, by comparing expected and observed values. We found that these models offer the possibility to determine whether the dominant emission source was the vicinity or distance of the measuring point. Results of this test could be a significant supplement to existing multivariate mathematical models for source apportionment, providing accurate estimation of the origin of emission sources and offering information on their position relative to the investigated area (local, regional or remote). In addition, the dependence of particle concentrations for each fraction investigated versus meteorological parameters was determined.
PB  - Elsevier
T2  - Atmospheric Pollution Research
T1  - Coarse, fine and ultrafine particles of sub-urban continental aerosols measured using an 11-stage Berner cascade impactor
VL  - 11
IS  - 3
SP  - 499
EP  - 510
DO  - 10.1016/j.apr.2019.11.022
ER  - 

@article{
author = "Đorđević, Dragana and Đuričić-Milanković, Jelena and Pantelić, Ana and Petrović, Srđan and Gambaro, Andrea",
year = "2020",
abstract = "The main aim of this work is characterization of atmospheric aerosol using 11 stage cascade impactor. The first investigation of size-segregated sub-urban aerosols from the continental part of the Balkan peninsula in 11 fractions in the range of 0.0085 < Dp < 16 μm was performed from March 2012 to December 2013. Aerosols were measured at the Zeleno Brdo observatory (ϕ = 44°48’; λ = 20°28′–243 m above sea level), the highest landmark on the eastern side of Belgrade. Zeleno Brdo is surrounded by wooded vegetation and comprises of both southern facing rural and north-west orientated urban areas. About 70% of total aerosols are fine particles, belonging especially to the PM0.53–1.06 fraction which is found to be more pronounced in winter period. In this work, we applied tests of probability function models for three distributions: normal, log-normal and three-parameter Weibull, by comparing expected and observed values. We found that these models offer the possibility to determine whether the dominant emission source was the vicinity or distance of the measuring point. Results of this test could be a significant supplement to existing multivariate mathematical models for source apportionment, providing accurate estimation of the origin of emission sources and offering information on their position relative to the investigated area (local, regional or remote). In addition, the dependence of particle concentrations for each fraction investigated versus meteorological parameters was determined.",
publisher = "Elsevier",
journal = "Atmospheric Pollution Research",
title = "Coarse, fine and ultrafine particles of sub-urban continental aerosols measured using an 11-stage Berner cascade impactor",
volume = "11",
number = "3",
pages = "499-510",
doi = "10.1016/j.apr.2019.11.022"
}

Đorđević, D., Đuričić-Milanković, J., Pantelić, A., Petrović, S.,& Gambaro, A.. (2020). Coarse, fine and ultrafine particles of sub-urban continental aerosols measured using an 11-stage Berner cascade impactor. in Atmospheric Pollution Research
Elsevier., 11(3), 499-510.
https://doi.org/10.1016/j.apr.2019.11.022

Đorđević D, Đuričić-Milanković J, Pantelić A, Petrović S, Gambaro A. Coarse, fine and ultrafine particles of sub-urban continental aerosols measured using an 11-stage Berner cascade impactor. in Atmospheric Pollution Research. 2020;11(3):499-510.
doi:10.1016/j.apr.2019.11.022 .

Đorđević, Dragana, Đuričić-Milanković, Jelena, Pantelić, Ana, Petrović, Srđan, Gambaro, Andrea, "Coarse, fine and ultrafine particles of sub-urban continental aerosols measured using an 11-stage Berner cascade impactor" in Atmospheric Pollution Research, 11, no. 3 (2020):499-510,
https://doi.org/10.1016/j.apr.2019.11.022 . .

TY  - JOUR
AU  - Mojović, Zorica
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4086
AB  - U ovom radu su okarakterisani novi elektrodni materijali na bazi perovskita za detekciju 4-nitrofenola.
Mešoviti oksidi perovskitnog tipa hemijske formule La0.7Sr0.3Cr1-XRuXO3 (X= 0; 0.05) su sintetisani
konvencionalnim keramičkim postupkom. Rezultati rendgenske difrakcione analize su pokazali da je
sintetizovani sistem dvofazan, i da pored dominantne perovskitne faze sadrži udeo stroncijum hromata.
Ugljenična pasta elektroda je modifikovana sintetisanim perovskitima kako bi se ispitala njihova
elektroaktivnost. Tako dobijene elektrode su primenjene za oksido-redukciju 4-nitrofenola u kiseloj
sredini. Prisustvo rutenijuma u perovskitnoj strukturi dovodi do povećane elektrohemijske aktivnosti
elektrode za redukciju 4-nitrofenola.
AB  - In this paper new perovskite-based electrode materialsfor 4-nitrophenol detection were characterized. Mixed oxides of pereovskite type with general molecular formula La0.7Sr0.3Cr1-XRuX03 (X= 0; 0.05) were synthesized by ceramic procedure. The results of X-ray diffraction analysis showed that synthesized system has two-phase structure, including strontium chromate phase beside dominant perovskite phase. Carbon paste electrode was modified with synthsized perovskites in order to study their electrochemical activity. Electrode prepared innn such manner were used for oxido-reduction of 4-nitrophenol in acidic media. The addition of ruthenium to perovskite structure lead to increased electrochemical activity of this electrode for reduction of 4-nitrophenol.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Uloga rutenijuma u mešovitom oksidu perovskitnog tipa u elektrohemijskoj degradaciji 4-nitrofenola
T1  - The role of ruthenium in perovskite-type mixed oxide in the electrochemical degradation of 4-nitrophenol
VL  - 29
IS  - 6
SP  - 695
EP  - 699
DO  - 10.5937/tehnika2006695M
ER  - 

@article{
author = "Mojović, Zorica and Petrović, Srđan and Rožić, Ljiljana",
year = "2020",
abstract = "U ovom radu su okarakterisani novi elektrodni materijali na bazi perovskita za detekciju 4-nitrofenola.
Mešoviti oksidi perovskitnog tipa hemijske formule La0.7Sr0.3Cr1-XRuXO3 (X= 0; 0.05) su sintetisani
konvencionalnim keramičkim postupkom. Rezultati rendgenske difrakcione analize su pokazali da je
sintetizovani sistem dvofazan, i da pored dominantne perovskitne faze sadrži udeo stroncijum hromata.
Ugljenična pasta elektroda je modifikovana sintetisanim perovskitima kako bi se ispitala njihova
elektroaktivnost. Tako dobijene elektrode su primenjene za oksido-redukciju 4-nitrofenola u kiseloj
sredini. Prisustvo rutenijuma u perovskitnoj strukturi dovodi do povećane elektrohemijske aktivnosti
elektrode za redukciju 4-nitrofenola., In this paper new perovskite-based electrode materialsfor 4-nitrophenol detection were characterized. Mixed oxides of pereovskite type with general molecular formula La0.7Sr0.3Cr1-XRuX03 (X= 0; 0.05) were synthesized by ceramic procedure. The results of X-ray diffraction analysis showed that synthesized system has two-phase structure, including strontium chromate phase beside dominant perovskite phase. Carbon paste electrode was modified with synthsized perovskites in order to study their electrochemical activity. Electrode prepared innn such manner were used for oxido-reduction of 4-nitrophenol in acidic media. The addition of ruthenium to perovskite structure lead to increased electrochemical activity of this electrode for reduction of 4-nitrophenol.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Uloga rutenijuma u mešovitom oksidu perovskitnog tipa u elektrohemijskoj degradaciji 4-nitrofenola, The role of ruthenium in perovskite-type mixed oxide in the electrochemical degradation of 4-nitrophenol",
volume = "29",
number = "6",
pages = "695-699",
doi = "10.5937/tehnika2006695M"
}

Mojović, Z., Petrović, S.,& Rožić, L.. (2020). Uloga rutenijuma u mešovitom oksidu perovskitnog tipa u elektrohemijskoj degradaciji 4-nitrofenola. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 29(6), 695-699.
https://doi.org/10.5937/tehnika2006695M

Mojović Z, Petrović S, Rožić L. Uloga rutenijuma u mešovitom oksidu perovskitnog tipa u elektrohemijskoj degradaciji 4-nitrofenola. in Tehnika. 2020;29(6):695-699.
doi:10.5937/tehnika2006695M .

Mojović, Zorica, Petrović, Srđan, Rožić, Ljiljana, "Uloga rutenijuma u mešovitom oksidu perovskitnog tipa u elektrohemijskoj degradaciji 4-nitrofenola" in Tehnika, 29, no. 6 (2020):695-699,
https://doi.org/10.5937/tehnika2006695M . .

TY  - JOUR
AU  - Rožić, Ljiljana
AU  - Petrović, Srđan
AU  - Lončarević, Davor
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Stojadinović, Stevan
AU  - Jović, Vesna
AU  - Lamovec, Jelena
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2486
AB  - TiO2-CeO2 nanopowders were synthesised by a ball-milling process and then annealed at temperatures from 500 degrees to 800 degrees C. X-ray diffraction and diffuse reflectance spectra were used in combination with temperature programmed desorption to determine the structural and microstructural changes of nanopowders as a the function of annealing temperature. The results of the X-ray analysis showed that the weight fraction of the cerianite phase remained unchanged with a temperature rise of 600-700 degrees C, indicating that the phase changes occur only within TiO2. The TiO2-CeO2 nanopowder showed enhanced optical properties with a red shift after the thermal treatment. Photocatalytic studies revealed that the sample annealed at 600 degrees C showed higher photocatalytic activity than samples annealed at lower or higher temperatures in the degradation of the methyl orange. The activity test of all samples is in accordance with photoluminescence measurements, proportional to the concentrations of hydroxyl radicals at the photocatalyst surfaces.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders
VL  - 45
IS  - 2
SP  - 2361
EP  - 2367
DO  - 10.1016/j.ceramint.2018.10.153
ER  - 

@article{
author = "Rožić, Ljiljana and Petrović, Srđan and Lončarević, Davor and Grbić, Boško and Radić, Nenad and Stojadinović, Stevan and Jović, Vesna and Lamovec, Jelena",
year = "2019",
abstract = "TiO2-CeO2 nanopowders were synthesised by a ball-milling process and then annealed at temperatures from 500 degrees to 800 degrees C. X-ray diffraction and diffuse reflectance spectra were used in combination with temperature programmed desorption to determine the structural and microstructural changes of nanopowders as a the function of annealing temperature. The results of the X-ray analysis showed that the weight fraction of the cerianite phase remained unchanged with a temperature rise of 600-700 degrees C, indicating that the phase changes occur only within TiO2. The TiO2-CeO2 nanopowder showed enhanced optical properties with a red shift after the thermal treatment. Photocatalytic studies revealed that the sample annealed at 600 degrees C showed higher photocatalytic activity than samples annealed at lower or higher temperatures in the degradation of the methyl orange. The activity test of all samples is in accordance with photoluminescence measurements, proportional to the concentrations of hydroxyl radicals at the photocatalyst surfaces.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders",
volume = "45",
number = "2",
pages = "2361-2367",
doi = "10.1016/j.ceramint.2018.10.153"
}

Rožić, L., Petrović, S., Lončarević, D., Grbić, B., Radić, N., Stojadinović, S., Jović, V.,& Lamovec, J.. (2019). Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(2), 2361-2367.
https://doi.org/10.1016/j.ceramint.2018.10.153

Rožić L, Petrović S, Lončarević D, Grbić B, Radić N, Stojadinović S, Jović V, Lamovec J. Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders. in Ceramics International. 2019;45(2):2361-2367.
doi:10.1016/j.ceramint.2018.10.153 .

Rožić, Ljiljana, Petrović, Srđan, Lončarević, Davor, Grbić, Boško, Radić, Nenad, Stojadinović, Stevan, Jović, Vesna, Lamovec, Jelena, "Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders" in Ceramics International, 45, no. 2 (2019):2361-2367,
https://doi.org/10.1016/j.ceramint.2018.10.153 . .

TY  - JOUR
AU  - Rožić, Ljiljana
AU  - Petrović, Srđan
AU  - Lončarević, Davor
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Stojadinović, Stevan
AU  - Jović, Vesna
AU  - Lamovec, Jelena
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2900
AB  - TiO2-CeO2 nanopowders were synthesised by a ball-milling process and then annealed at temperatures from 500 degrees to 800 degrees C. X-ray diffraction and diffuse reflectance spectra were used in combination with temperature programmed desorption to determine the structural and microstructural changes of nanopowders as a the function of annealing temperature. The results of the X-ray analysis showed that the weight fraction of the cerianite phase remained unchanged with a temperature rise of 600-700 degrees C, indicating that the phase changes occur only within TiO2. The TiO2-CeO2 nanopowder showed enhanced optical properties with a red shift after the thermal treatment. Photocatalytic studies revealed that the sample annealed at 600 degrees C showed higher photocatalytic activity than samples annealed at lower or higher temperatures in the degradation of the methyl orange. The activity test of all samples is in accordance with photoluminescence measurements, proportional to the concentrations of hydroxyl radicals at the photocatalyst surfaces.
PB  - Oxford : Elsevier Sci Ltd.
T2  - Ceramics International
T1  - Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders
VL  - 45
IS  - 2
SP  - 2361
EP  - 2367
DO  - 10.1016/j.ceramint.2018.10.153
ER  - 

@article{
author = "Rožić, Ljiljana and Petrović, Srđan and Lončarević, Davor and Grbić, Boško and Radić, Nenad and Stojadinović, Stevan and Jović, Vesna and Lamovec, Jelena",
year = "2019",
abstract = "TiO2-CeO2 nanopowders were synthesised by a ball-milling process and then annealed at temperatures from 500 degrees to 800 degrees C. X-ray diffraction and diffuse reflectance spectra were used in combination with temperature programmed desorption to determine the structural and microstructural changes of nanopowders as a the function of annealing temperature. The results of the X-ray analysis showed that the weight fraction of the cerianite phase remained unchanged with a temperature rise of 600-700 degrees C, indicating that the phase changes occur only within TiO2. The TiO2-CeO2 nanopowder showed enhanced optical properties with a red shift after the thermal treatment. Photocatalytic studies revealed that the sample annealed at 600 degrees C showed higher photocatalytic activity than samples annealed at lower or higher temperatures in the degradation of the methyl orange. The activity test of all samples is in accordance with photoluminescence measurements, proportional to the concentrations of hydroxyl radicals at the photocatalyst surfaces.",
publisher = "Oxford : Elsevier Sci Ltd.",
journal = "Ceramics International",
title = "Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders",
volume = "45",
number = "2",
pages = "2361-2367",
doi = "10.1016/j.ceramint.2018.10.153"
}

Rožić, L., Petrović, S., Lončarević, D., Grbić, B., Radić, N., Stojadinović, S., Jović, V.,& Lamovec, J.. (2019). Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders. in Ceramics International
Oxford : Elsevier Sci Ltd.., 45(2), 2361-2367.
https://doi.org/10.1016/j.ceramint.2018.10.153

Rožić L, Petrović S, Lončarević D, Grbić B, Radić N, Stojadinović S, Jović V, Lamovec J. Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders. in Ceramics International. 2019;45(2):2361-2367.
doi:10.1016/j.ceramint.2018.10.153 .

Rožić, Ljiljana, Petrović, Srđan, Lončarević, Davor, Grbić, Boško, Radić, Nenad, Stojadinović, Stevan, Jović, Vesna, Lamovec, Jelena, "Influence of annealing temperature on structural, optical and photocatalytic properties of TiO2-CeO2 nanopowders" in Ceramics International, 45, no. 2 (2019):2361-2367,
https://doi.org/10.1016/j.ceramint.2018.10.153 . .

TY  - JOUR
AU  - Đorđević, Dragana
AU  - Tošić, Ivana
AU  - Sakan, Sanja
AU  - Petrović, Srđan
AU  - Đuričić - Milanković, Jelena
AU  - Finger, David Christian
AU  - Dagsson-Waldhauserová, Pavla
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3859
AB  - In this work we use chemical fingerprints as characteristics ratios of specific crustal elements Ca/Al, Fe/Al, K/Al, Mg/Al, Mn/Al, Ca/Fe, and Mg/Fe to investigate the long-range transport of volcanic aerosols from Iceland. Volcanic dust enters the atmosphere during suspension processes from Icelandic deserts, but mainly from the dust hot spots in remote areas in Iceland, and it is transmitted to the central Balkan area (Belgrade). For this purpose, backward trajectories from Belgrade (φ = 44°48′; λ = 20°28′) in 2012 and 2013, simultaneous with atmospheric aerosols measurements, were calculated by using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model. We found that about 17% of air masses passed over Icelandic territory and arrived to Balkan area. In almost all of these episodes ratios of some investigated elements in suburban aerosols of Balkan area corresponded to the ratios of elements investigated in surface soil of the Rangárvellir area – South Iceland in the vicinity of volcanoes. We identified several episodes, such as August 6–8, 2012; June 2–6, 2013; June 26–28, 2013; and September 18–20, 2013; with the characteristic ratios of the highest number of investigated elements in atmospheric aerosol of central Balkan corresponding to ratios from Icelandic soil material. This study provides evidence that Icelandic dust can travel long distances showing the importance of High Latitude Dust sources. © 2019 Đorđević, Tošić, Sakan, Petrović, Đuričić-Milanković, Finger and Dagsson-Waldhauserová.
PB  - Switzerland : Frontiers Media S.A.
T2  - Frontiers in Earth Science
T1  - Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?
VL  - 7
SP  - 142
DO  - 10.3389/feart.2019.00142
ER  - 

@article{
author = "Đorđević, Dragana and Tošić, Ivana and Sakan, Sanja and Petrović, Srđan and Đuričić - Milanković, Jelena and Finger, David Christian and Dagsson-Waldhauserová, Pavla",
year = "2019",
abstract = "In this work we use chemical fingerprints as characteristics ratios of specific crustal elements Ca/Al, Fe/Al, K/Al, Mg/Al, Mn/Al, Ca/Fe, and Mg/Fe to investigate the long-range transport of volcanic aerosols from Iceland. Volcanic dust enters the atmosphere during suspension processes from Icelandic deserts, but mainly from the dust hot spots in remote areas in Iceland, and it is transmitted to the central Balkan area (Belgrade). For this purpose, backward trajectories from Belgrade (φ = 44°48′; λ = 20°28′) in 2012 and 2013, simultaneous with atmospheric aerosols measurements, were calculated by using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model. We found that about 17% of air masses passed over Icelandic territory and arrived to Balkan area. In almost all of these episodes ratios of some investigated elements in suburban aerosols of Balkan area corresponded to the ratios of elements investigated in surface soil of the Rangárvellir area – South Iceland in the vicinity of volcanoes. We identified several episodes, such as August 6–8, 2012; June 2–6, 2013; June 26–28, 2013; and September 18–20, 2013; with the characteristic ratios of the highest number of investigated elements in atmospheric aerosol of central Balkan corresponding to ratios from Icelandic soil material. This study provides evidence that Icelandic dust can travel long distances showing the importance of High Latitude Dust sources. © 2019 Đorđević, Tošić, Sakan, Petrović, Đuričić-Milanković, Finger and Dagsson-Waldhauserová.",
publisher = "Switzerland : Frontiers Media S.A.",
journal = "Frontiers in Earth Science",
title = "Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?",
volume = "7",
pages = "142",
doi = "10.3389/feart.2019.00142"
}

Đorđević, D., Tošić, I., Sakan, S., Petrović, S., Đuričić - Milanković, J., Finger, D. C.,& Dagsson-Waldhauserová, P.. (2019). Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?. in Frontiers in Earth Science
Switzerland : Frontiers Media S.A.., 7, 142.
https://doi.org/10.3389/feart.2019.00142

Đorđević D, Tošić I, Sakan S, Petrović S, Đuričić - Milanković J, Finger DC, Dagsson-Waldhauserová P. Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?. in Frontiers in Earth Science. 2019;7:142.
doi:10.3389/feart.2019.00142 .

Đorđević, Dragana, Tošić, Ivana, Sakan, Sanja, Petrović, Srđan, Đuričić - Milanković, Jelena, Finger, David Christian, Dagsson-Waldhauserová, Pavla, "Can volcanic dust suspended from surface soil and deserts of Iceland be transferred to central Balkan similarly to African dust (Sahara)?" in Frontiers in Earth Science, 7 (2019):142,
https://doi.org/10.3389/feart.2019.00142 . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
AU  - Stojadinović, Stevan
AU  - Grbić, Boško
AU  - Vasilić, Rastko
AU  - Vuković, Zorica
AU  - Radić, Nenad
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2349
AB  - In this study, WO3 doped TiO2 powders were synthesized via sol-gel method combined with a hydrothermal process. The effect of sintering temperature on mesoporous structure and catalytic activities of these powders were investigated. The physical analysis via X-ray diffraction indicates that prepared samples are a mixture of anatase and rutile TiO2 phases. X-ray peak analysis is used to evaluate the crystallite size and lattice strain by the Williamson-Hall analysis. Considering all the reflections of the anatase phase the lattice strain ranging from c = 9.505 to c = 9.548 is calculated, suggesting that microstrain decreases when calcination temperature increases. N-2 adsorption-desorption analysis shows that the surface area and pore volume decrease with increasing temperature and that WOx-TiO2 powders primarily consist of mesopores. Sintering temperature induced a change in textural properties causing a systematic shift towards larger mesopores. Simultaneously, photoactivity in decolorization of methyl orange increases with increasing calcination temperature up to 700 degrees C, followed by significant decrease with its further increase.
PB  - International Institute for the Science of Sintering, Beograd
T2  - Science of Sintering
T1  - The Effect of Sintering Temperature on Mesoporous Structure of WO3 Doped Tio(2) Powders
VL  - 50
IS  - 1
SP  - 123
EP  - 132
DO  - 10.2298/SOS1801123P
ER  - 

@article{
author = "Petrović, Srđan and Rožić, Ljiljana and Stojadinović, Stevan and Grbić, Boško and Vasilić, Rastko and Vuković, Zorica and Radić, Nenad",
year = "2018",
abstract = "In this study, WO3 doped TiO2 powders were synthesized via sol-gel method combined with a hydrothermal process. The effect of sintering temperature on mesoporous structure and catalytic activities of these powders were investigated. The physical analysis via X-ray diffraction indicates that prepared samples are a mixture of anatase and rutile TiO2 phases. X-ray peak analysis is used to evaluate the crystallite size and lattice strain by the Williamson-Hall analysis. Considering all the reflections of the anatase phase the lattice strain ranging from c = 9.505 to c = 9.548 is calculated, suggesting that microstrain decreases when calcination temperature increases. N-2 adsorption-desorption analysis shows that the surface area and pore volume decrease with increasing temperature and that WOx-TiO2 powders primarily consist of mesopores. Sintering temperature induced a change in textural properties causing a systematic shift towards larger mesopores. Simultaneously, photoactivity in decolorization of methyl orange increases with increasing calcination temperature up to 700 degrees C, followed by significant decrease with its further increase.",
publisher = "International Institute for the Science of Sintering, Beograd",
journal = "Science of Sintering",
title = "The Effect of Sintering Temperature on Mesoporous Structure of WO3 Doped Tio(2) Powders",
volume = "50",
number = "1",
pages = "123-132",
doi = "10.2298/SOS1801123P"
}

Petrović, S., Rožić, L., Stojadinović, S., Grbić, B., Vasilić, R., Vuković, Z.,& Radić, N.. (2018). The Effect of Sintering Temperature on Mesoporous Structure of WO3 Doped Tio(2) Powders. in Science of Sintering
International Institute for the Science of Sintering, Beograd., 50(1), 123-132.
https://doi.org/10.2298/SOS1801123P

Petrović S, Rožić L, Stojadinović S, Grbić B, Vasilić R, Vuković Z, Radić N. The Effect of Sintering Temperature on Mesoporous Structure of WO3 Doped Tio(2) Powders. in Science of Sintering. 2018;50(1):123-132.
doi:10.2298/SOS1801123P .

Petrović, Srđan, Rožić, Ljiljana, Stojadinović, Stevan, Grbić, Boško, Vasilić, Rastko, Vuković, Zorica, Radić, Nenad, "The Effect of Sintering Temperature on Mesoporous Structure of WO3 Doped Tio(2) Powders" in Science of Sintering, 50, no. 1 (2018):123-132,
https://doi.org/10.2298/SOS1801123P . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
AU  - Jović, Vesna
AU  - Stojadinović, Stevan
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Lamovec, Jelena
AU  - Vasilić, Rastko
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2454
AB  - Nanocrystalline TiO2-CeO2 powders were synthesized from their TiO2 and CeO2 oxides using mechanical ball milling process. The response surface method is applied to identify optimal parameters for the synthesis of TiO2-CeO2 photocatalyst. Analysis of variance and main effect plot are used to determine the significant parameters and set the optimal level for each parameter. Regression analysis showed good agreement of experimental data with the second-order polynomial model with a coefficients of determination: R-2 = 0.991, R-Adj(2). = 0.940 and R-Pred(2). = 0.983. Under optimal experimental conditions of TiO2:CeO2 weight percentage ratio 71: 29, milling speed 200 rpm, and milling time 115 min the highest photodegradation efficiency was achieved. On the basis of the above statistical analysis, it was found that the band gap energy of TiO2-CeO2 nanoparticles decreases with the increase of the milling speed and milling time with constant TiO2:CeO2 weight percentage ratio. Obtained results suggest that mechanical ball milling process is a rapid, efficient and low energy consumption method to synthesize TiO2-CeO2 photocatalyst.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - Optimization of a nanoparticle ball milling process parameters using the response surface method
VL  - 29
IS  - 9
SP  - 2129
EP  - 2139
DO  - 10.1016/j.apt.2018.05.021
ER  - 

@article{
author = "Petrović, Srđan and Rožić, Ljiljana and Jović, Vesna and Stojadinović, Stevan and Grbić, Boško and Radić, Nenad and Lamovec, Jelena and Vasilić, Rastko",
year = "2018",
abstract = "Nanocrystalline TiO2-CeO2 powders were synthesized from their TiO2 and CeO2 oxides using mechanical ball milling process. The response surface method is applied to identify optimal parameters for the synthesis of TiO2-CeO2 photocatalyst. Analysis of variance and main effect plot are used to determine the significant parameters and set the optimal level for each parameter. Regression analysis showed good agreement of experimental data with the second-order polynomial model with a coefficients of determination: R-2 = 0.991, R-Adj(2). = 0.940 and R-Pred(2). = 0.983. Under optimal experimental conditions of TiO2:CeO2 weight percentage ratio 71: 29, milling speed 200 rpm, and milling time 115 min the highest photodegradation efficiency was achieved. On the basis of the above statistical analysis, it was found that the band gap energy of TiO2-CeO2 nanoparticles decreases with the increase of the milling speed and milling time with constant TiO2:CeO2 weight percentage ratio. Obtained results suggest that mechanical ball milling process is a rapid, efficient and low energy consumption method to synthesize TiO2-CeO2 photocatalyst.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "Optimization of a nanoparticle ball milling process parameters using the response surface method",
volume = "29",
number = "9",
pages = "2129-2139",
doi = "10.1016/j.apt.2018.05.021"
}

Petrović, S., Rožić, L., Jović, V., Stojadinović, S., Grbić, B., Radić, N., Lamovec, J.,& Vasilić, R.. (2018). Optimization of a nanoparticle ball milling process parameters using the response surface method. in Advanced Powder Technology
Elsevier., 29(9), 2129-2139.
https://doi.org/10.1016/j.apt.2018.05.021

Petrović S, Rožić L, Jović V, Stojadinović S, Grbić B, Radić N, Lamovec J, Vasilić R. Optimization of a nanoparticle ball milling process parameters using the response surface method. in Advanced Powder Technology. 2018;29(9):2129-2139.
doi:10.1016/j.apt.2018.05.021 .

Petrović, Srđan, Rožić, Ljiljana, Jović, Vesna, Stojadinović, Stevan, Grbić, Boško, Radić, Nenad, Lamovec, Jelena, Vasilić, Rastko, "Optimization of a nanoparticle ball milling process parameters using the response surface method" in Advanced Powder Technology, 29, no. 9 (2018):2129-2139,
https://doi.org/10.1016/j.apt.2018.05.021 . .

TY  - JOUR
AU  - Đuričić-Milanković, Jelena
AU  - Anđelković, Ivan
AU  - Pantelić, Ana
AU  - Petrović, Srđan
AU  - Gambaro, Andrea
AU  - Đorđević, Dragana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2369
AB  - We have measured trace element contents in suburban aerosols from six size fractions in the range of PM0.27-16 from a background station in Belgrade (Serbia). The distribution and concentration of elements were determined within each of the investigated Dp fractions with emphasis on the fine and coarse modes. Fine/coarse mode ratios of element can provide information regarding their anthropogenic or natural origin. Analysis of seasonal variations of element contents in fine and coarse mode show that Cd, Co, K, and V have higher concentrations in the fine mode during heating season, while Fe contents are lower. In the coarse mode, Cu and V have higher concentrations during the heating season, while Al, Fe, Mg, Mn, and Sb contents are lower. We also apply a distribution probability model (normal, log-normal, and three-parameter Weibull) as new approach to estimate the distances of emission sources that can contribute to pollutant contents in particulate matter of the investigated location.
PB  - Springer, Dordrecht
T2  - Environmental Monitoring and Assessment
T1  - Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local, regional, and remote emission sources
VL  - 190
IS  - 10
DO  - 10.1007/s10661-018-6962-2
ER  - 

@article{
author = "Đuričić-Milanković, Jelena and Anđelković, Ivan and Pantelić, Ana and Petrović, Srđan and Gambaro, Andrea and Đorđević, Dragana",
year = "2018",
abstract = "We have measured trace element contents in suburban aerosols from six size fractions in the range of PM0.27-16 from a background station in Belgrade (Serbia). The distribution and concentration of elements were determined within each of the investigated Dp fractions with emphasis on the fine and coarse modes. Fine/coarse mode ratios of element can provide information regarding their anthropogenic or natural origin. Analysis of seasonal variations of element contents in fine and coarse mode show that Cd, Co, K, and V have higher concentrations in the fine mode during heating season, while Fe contents are lower. In the coarse mode, Cu and V have higher concentrations during the heating season, while Al, Fe, Mg, Mn, and Sb contents are lower. We also apply a distribution probability model (normal, log-normal, and three-parameter Weibull) as new approach to estimate the distances of emission sources that can contribute to pollutant contents in particulate matter of the investigated location.",
publisher = "Springer, Dordrecht",
journal = "Environmental Monitoring and Assessment",
title = "Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local, regional, and remote emission sources",
volume = "190",
number = "10",
doi = "10.1007/s10661-018-6962-2"
}

Đuričić-Milanković, J., Anđelković, I., Pantelić, A., Petrović, S., Gambaro, A.,& Đorđević, D.. (2018). Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local, regional, and remote emission sources. in Environmental Monitoring and Assessment
Springer, Dordrecht., 190(10).
https://doi.org/10.1007/s10661-018-6962-2

Đuričić-Milanković J, Anđelković I, Pantelić A, Petrović S, Gambaro A, Đorđević D. Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local, regional, and remote emission sources. in Environmental Monitoring and Assessment. 2018;190(10).
doi:10.1007/s10661-018-6962-2 .

Đuričić-Milanković, Jelena, Anđelković, Ivan, Pantelić, Ana, Petrović, Srđan, Gambaro, Andrea, Đorđević, Dragana, "Size-segregated trace elements in continental suburban aerosols: seasonal variation and estimation of local, regional, and remote emission sources" in Environmental Monitoring and Assessment, 190, no. 10 (2018),
https://doi.org/10.1007/s10661-018-6962-2 . .

TY  - JOUR
AU  - Đuričić-Milanković, Jelena
AU  - Anđelković, Ivan
AU  - Pantelić, Ana
AU  - Petrović, Srđan
AU  - Gambaro, Andrea
AU  - Antonovic, Dusan
AU  - Đorđević, Dragana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2449
AB  - The results presented in this work demonstrate for the first time a distribution of elements in the spectral analysis of aerosols in the suburban continental Balkan Peninsula. Samples were collected in the suburban area of Belgrade (Serbia) in the period from March 2012 till December 2013. Results presented here are from long-term measurements of masses of size-segregated aerosols and macro- and microelements in the range of PM0.27-16. The following elements were analyzed: Al, Ag, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sb, Ti, Tl, V, and Zn; levels of Be, Hg, and Se were under the detection limits in all samples. Average concentrations and time and seasonal variations of particulate matter (PM) as well as element contents and their percentage shares are given. The results showed the domination of particle content around the accumulation mode in the range of 0.53  LT  Dp  LT  1.06 mu m, but the fractional distribution of elements showed maximal average concentrations in different fractions depending on the origin of each element. Crustal elements (Al, Ca, Fe, Mg, Mn, Ti, etc.) dominated in coarse mode, while anthropogenic elements (As, Cd, Cu, Pb, Sb, etc.) were mainly distributed in fine mode fractions. Some elements, such are As and Ni, were detected in investigated aerosols only occasionally, while others, such as Ca, Fe, and Mg, were detected in all analyzed samples. The application of multivariate analysis (PCA) demonstrated the connection between the elements of similar origin, in fine fractions mainly of anthropogenic origin, while in coarse mode of crustal origin, indicating the resuspension with contribution of about 40%. The contents of some measured elements were compared with their contents in aerosols in some European suburban areas.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes
VL  - 25
IS  - 21
SP  - 20841
EP  - 20853
DO  - 10.1007/s11356-018-2037-8
ER  - 

@article{
author = "Đuričić-Milanković, Jelena and Anđelković, Ivan and Pantelić, Ana and Petrović, Srđan and Gambaro, Andrea and Antonovic, Dusan and Đorđević, Dragana",
year = "2018",
abstract = "The results presented in this work demonstrate for the first time a distribution of elements in the spectral analysis of aerosols in the suburban continental Balkan Peninsula. Samples were collected in the suburban area of Belgrade (Serbia) in the period from March 2012 till December 2013. Results presented here are from long-term measurements of masses of size-segregated aerosols and macro- and microelements in the range of PM0.27-16. The following elements were analyzed: Al, Ag, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, Sb, Ti, Tl, V, and Zn; levels of Be, Hg, and Se were under the detection limits in all samples. Average concentrations and time and seasonal variations of particulate matter (PM) as well as element contents and their percentage shares are given. The results showed the domination of particle content around the accumulation mode in the range of 0.53  LT  Dp  LT  1.06 mu m, but the fractional distribution of elements showed maximal average concentrations in different fractions depending on the origin of each element. Crustal elements (Al, Ca, Fe, Mg, Mn, Ti, etc.) dominated in coarse mode, while anthropogenic elements (As, Cd, Cu, Pb, Sb, etc.) were mainly distributed in fine mode fractions. Some elements, such are As and Ni, were detected in investigated aerosols only occasionally, while others, such as Ca, Fe, and Mg, were detected in all analyzed samples. The application of multivariate analysis (PCA) demonstrated the connection between the elements of similar origin, in fine fractions mainly of anthropogenic origin, while in coarse mode of crustal origin, indicating the resuspension with contribution of about 40%. The contents of some measured elements were compared with their contents in aerosols in some European suburban areas.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes",
volume = "25",
number = "21",
pages = "20841-20853",
doi = "10.1007/s11356-018-2037-8"
}

Đuričić-Milanković, J., Anđelković, I., Pantelić, A., Petrović, S., Gambaro, A., Antonovic, D.,& Đorđević, D.. (2018). Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 25(21), 20841-20853.
https://doi.org/10.1007/s11356-018-2037-8

Đuričić-Milanković J, Anđelković I, Pantelić A, Petrović S, Gambaro A, Antonovic D, Đorđević D. Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes. in Environmental Science and Pollution Research. 2018;25(21):20841-20853.
doi:10.1007/s11356-018-2037-8 .

Đuričić-Milanković, Jelena, Anđelković, Ivan, Pantelić, Ana, Petrović, Srđan, Gambaro, Andrea, Antonovic, Dusan, Đorđević, Dragana, "Partitioning of particulate matter and elements of suburban continental aerosols between fine and coarse modes" in Environmental Science and Pollution Research, 25, no. 21 (2018):20841-20853,
https://doi.org/10.1007/s11356-018-2037-8 . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
AU  - Vuković, Zorica
AU  - Grbić, Boško
AU  - Radić, Nenad
AU  - Stojadinović, Stevan
AU  - Vasilić, Rastko
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2078
AB  - This article presents the comparison of structural and fractal properties of nanocrystalline titanium dioxide (TiO2) and TiO2 modified with tungstophosphoric acid (TiO2/HPW) and their impact on the photocatalytic degradation of hazardous water pollutants. TiO2 and TiO2/HPW samples were synthesized by a combined solgel and hydrothermal processing. The XRD analysis of pure TiO2 samples revealed that phase composition was mainly dependent on the calcination temperature, changing from amorphous TiO2 to crystalline anatase and rutile by increasing the temperature. On the other hand, the XRD of TiO2/HPW samples calcined at temperatures above 600 degrees C showed crystalline peaks associated to formation of WO3 and WO2.92 crystalline domains. The N-2 adsorption-desorption isotherm and pore size distribution of TiO2/HPW samples detected the existence of mesoporous characteristic with very narrow bimodal pores in the mesoporous region. The structural heterogeneity of samples was analyzed by means of pore size distribution functions, while the variation in fractal dimension were determined from the nitrogen adsorption isotherms, using the modified Frenkel-Halsey-Hill method. The results demonstrate that the approach is capable of characterizing complex textures such as those present in the TiO2 and TiO2/HPW photocatalysts. Besides, the effect of calcinations condition on photocatalytic properties of the samples was also investigated. The highest efficiency with respect to methyl orange photodecomposition was observed for TiO2/HPW photocatalysts calcined at 700 degrees C.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Journal of Physics and Chemistry of Solids
T1  - Structural and fractal characterization of tungstophosphoric acid modified titanium dioxide photocatalyst
VL  - 103
SP  - 95
EP  - 102
DO  - 10.1016/j.jpcs.2016.12.002
ER  - 

@article{
author = "Petrović, Srđan and Rožić, Ljiljana and Vuković, Zorica and Grbić, Boško and Radić, Nenad and Stojadinović, Stevan and Vasilić, Rastko",
year = "2017",
abstract = "This article presents the comparison of structural and fractal properties of nanocrystalline titanium dioxide (TiO2) and TiO2 modified with tungstophosphoric acid (TiO2/HPW) and their impact on the photocatalytic degradation of hazardous water pollutants. TiO2 and TiO2/HPW samples were synthesized by a combined solgel and hydrothermal processing. The XRD analysis of pure TiO2 samples revealed that phase composition was mainly dependent on the calcination temperature, changing from amorphous TiO2 to crystalline anatase and rutile by increasing the temperature. On the other hand, the XRD of TiO2/HPW samples calcined at temperatures above 600 degrees C showed crystalline peaks associated to formation of WO3 and WO2.92 crystalline domains. The N-2 adsorption-desorption isotherm and pore size distribution of TiO2/HPW samples detected the existence of mesoporous characteristic with very narrow bimodal pores in the mesoporous region. The structural heterogeneity of samples was analyzed by means of pore size distribution functions, while the variation in fractal dimension were determined from the nitrogen adsorption isotherms, using the modified Frenkel-Halsey-Hill method. The results demonstrate that the approach is capable of characterizing complex textures such as those present in the TiO2 and TiO2/HPW photocatalysts. Besides, the effect of calcinations condition on photocatalytic properties of the samples was also investigated. The highest efficiency with respect to methyl orange photodecomposition was observed for TiO2/HPW photocatalysts calcined at 700 degrees C.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Journal of Physics and Chemistry of Solids",
title = "Structural and fractal characterization of tungstophosphoric acid modified titanium dioxide photocatalyst",
volume = "103",
pages = "95-102",
doi = "10.1016/j.jpcs.2016.12.002"
}

Petrović, S., Rožić, L., Vuković, Z., Grbić, B., Radić, N., Stojadinović, S.,& Vasilić, R.. (2017). Structural and fractal characterization of tungstophosphoric acid modified titanium dioxide photocatalyst. in Journal of Physics and Chemistry of Solids
Oxford : Pergamon-Elsevier Science Ltd., 103, 95-102.
https://doi.org/10.1016/j.jpcs.2016.12.002

Petrović S, Rožić L, Vuković Z, Grbić B, Radić N, Stojadinović S, Vasilić R. Structural and fractal characterization of tungstophosphoric acid modified titanium dioxide photocatalyst. in Journal of Physics and Chemistry of Solids. 2017;103:95-102.
doi:10.1016/j.jpcs.2016.12.002 .

Petrović, Srđan, Rožić, Ljiljana, Vuković, Zorica, Grbić, Boško, Radić, Nenad, Stojadinović, Stevan, Vasilić, Rastko, "Structural and fractal characterization of tungstophosphoric acid modified titanium dioxide photocatalyst" in Journal of Physics and Chemistry of Solids, 103 (2017):95-102,
https://doi.org/10.1016/j.jpcs.2016.12.002 . .

TY  - JOUR
AU  - Radić, Nenad
AU  - Grbić, Boško
AU  - Stojadinović, Stevan
AU  - Vasilić, Rastko
AU  - Petrović, Srđan
AU  - Rožić, Ljiljana
AU  - Stefanov, Plamen
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2259
AB  - Pt-Ba-Al2O3 coatings were obtained by spray pyrolysis deposition on stainless steel foil. The XRD results showed that the coatings consisted from Ba carbonate and Pt (fcc) phases. SEM micrographs demonstrated that the coatings are smooth and compact. The XPS data confirmed that Ba and Pt are in close contact. Pt crystallite size is only slightly influenced by the order of Pt and Ba deposition and the dispersion of Pt is in the narrow range from 28 to 33% for all samples. Catalyst component deposition order affects NOx storage capacity. Simultaneous deposition of Ba and Pt on already formed Al2O3 substrate produces the most efficient catalyst. Pt deposited on top of the Ba layer results in slightly reduced NOx storage capacity, while deposition of Pt on the separated layer with Ba layer on top significantly reduces the ability for NOx storage.
PB  - Elsevier Science Sa, Lausanne
T2  - Thin Solid Films
T1  - Preparation and characterization of Pt-Ba-Al2O3 coatings obtained by spray pyrolysis
VL  - 628
SP  - 7
EP  - 12
DO  - 10.1016/j.tsf.2017.03.007
ER  - 

@article{
author = "Radić, Nenad and Grbić, Boško and Stojadinović, Stevan and Vasilić, Rastko and Petrović, Srđan and Rožić, Ljiljana and Stefanov, Plamen",
year = "2017",
abstract = "Pt-Ba-Al2O3 coatings were obtained by spray pyrolysis deposition on stainless steel foil. The XRD results showed that the coatings consisted from Ba carbonate and Pt (fcc) phases. SEM micrographs demonstrated that the coatings are smooth and compact. The XPS data confirmed that Ba and Pt are in close contact. Pt crystallite size is only slightly influenced by the order of Pt and Ba deposition and the dispersion of Pt is in the narrow range from 28 to 33% for all samples. Catalyst component deposition order affects NOx storage capacity. Simultaneous deposition of Ba and Pt on already formed Al2O3 substrate produces the most efficient catalyst. Pt deposited on top of the Ba layer results in slightly reduced NOx storage capacity, while deposition of Pt on the separated layer with Ba layer on top significantly reduces the ability for NOx storage.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Thin Solid Films",
title = "Preparation and characterization of Pt-Ba-Al2O3 coatings obtained by spray pyrolysis",
volume = "628",
pages = "7-12",
doi = "10.1016/j.tsf.2017.03.007"
}

Radić, N., Grbić, B., Stojadinović, S., Vasilić, R., Petrović, S., Rožić, L.,& Stefanov, P.. (2017). Preparation and characterization of Pt-Ba-Al2O3 coatings obtained by spray pyrolysis. in Thin Solid Films
Elsevier Science Sa, Lausanne., 628, 7-12.
https://doi.org/10.1016/j.tsf.2017.03.007

Radić N, Grbić B, Stojadinović S, Vasilić R, Petrović S, Rožić L, Stefanov P. Preparation and characterization of Pt-Ba-Al2O3 coatings obtained by spray pyrolysis. in Thin Solid Films. 2017;628:7-12.
doi:10.1016/j.tsf.2017.03.007 .

Radić, Nenad, Grbić, Boško, Stojadinović, Stevan, Vasilić, Rastko, Petrović, Srđan, Rožić, Ljiljana, Stefanov, Plamen, "Preparation and characterization of Pt-Ba-Al2O3 coatings obtained by spray pyrolysis" in Thin Solid Films, 628 (2017):7-12,
https://doi.org/10.1016/j.tsf.2017.03.007 . .

TY  - JOUR
AU  - Petrović, Srđan
AU  - Stojadinović, Stevan D.J.
AU  - Rožić, Ljiljana
AU  - Radić, Nenad
AU  - Grbić, Boško
AU  - Vasilić, Rastko
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1752
AB  - Plasma electrolytic oxidation of titanium in 12-tungstosilicic acid solution was investigated as a model reaction. The influence of the process parameters (concentration of 12-tungstosilicic acid solution, current density, and time) on the selected process response (efficiency of the methyl orange photodecolorization on the TiO2/WO3 coatings) was studied. A mathematical model was developed using a second-order response surface model with a central composite design incorporating the above-mentioned process parameters. The statistical analysis of experimental data indicates that a concentration of 12-tungstosilicic acid solution; process time, interaction between concentration and process time, and interaction between concentration and quadratic of process time have a significant effect on the methyl orange photodecolorization. Besides, the results show that obtained data were adequately fitted into the second-order polynomial model, since the calculated model F value (39.28) is higher than the critical F value. The values of coefficient of determination (R-2 = 0.960) and adjusted coefficient of determination (R-Adj.(2) = 0.937) are close to 1, indicating a high correlation between the observed and the predicted values. This model can also be useful for setting an optimum value of the process parameters for achieving the maximum efficiency of the methyl orange photodecolorization. Under the optimum conditions established in the region of experimentation (C = 1.14 . 10(-3) M, j = 153 mA/cm(2), and t = 58.9 s), a 38.6% (test duration of 8 h) efficiency of the methyl orange photodecolorization is obtained.
PB  - Elsevier
T2  - Surface and Coatings Technology
T1  - Process modelling and analysis of plasma electrolytic oxidation of titanium for TiO2/WO3 thin film photocatalysts by response surface methodology
VL  - 269
SP  - 250
EP  - 257
DO  - 10.1016/j.surfcoat.2014.12.026
ER  - 

@article{
author = "Petrović, Srđan and Stojadinović, Stevan D.J. and Rožić, Ljiljana and Radić, Nenad and Grbić, Boško and Vasilić, Rastko",
year = "2015",
abstract = "Plasma electrolytic oxidation of titanium in 12-tungstosilicic acid solution was investigated as a model reaction. The influence of the process parameters (concentration of 12-tungstosilicic acid solution, current density, and time) on the selected process response (efficiency of the methyl orange photodecolorization on the TiO2/WO3 coatings) was studied. A mathematical model was developed using a second-order response surface model with a central composite design incorporating the above-mentioned process parameters. The statistical analysis of experimental data indicates that a concentration of 12-tungstosilicic acid solution; process time, interaction between concentration and process time, and interaction between concentration and quadratic of process time have a significant effect on the methyl orange photodecolorization. Besides, the results show that obtained data were adequately fitted into the second-order polynomial model, since the calculated model F value (39.28) is higher than the critical F value. The values of coefficient of determination (R-2 = 0.960) and adjusted coefficient of determination (R-Adj.(2) = 0.937) are close to 1, indicating a high correlation between the observed and the predicted values. This model can also be useful for setting an optimum value of the process parameters for achieving the maximum efficiency of the methyl orange photodecolorization. Under the optimum conditions established in the region of experimentation (C = 1.14 . 10(-3) M, j = 153 mA/cm(2), and t = 58.9 s), a 38.6% (test duration of 8 h) efficiency of the methyl orange photodecolorization is obtained.",
publisher = "Elsevier",
journal = "Surface and Coatings Technology",
title = "Process modelling and analysis of plasma electrolytic oxidation of titanium for TiO2/WO3 thin film photocatalysts by response surface methodology",
volume = "269",
pages = "250-257",
doi = "10.1016/j.surfcoat.2014.12.026"
}

Petrović, S., Stojadinović, S. D.J., Rožić, L., Radić, N., Grbić, B.,& Vasilić, R.. (2015). Process modelling and analysis of plasma electrolytic oxidation of titanium for TiO2/WO3 thin film photocatalysts by response surface methodology. in Surface and Coatings Technology
Elsevier., 269, 250-257.
https://doi.org/10.1016/j.surfcoat.2014.12.026

Petrović S, Stojadinović SD, Rožić L, Radić N, Grbić B, Vasilić R. Process modelling and analysis of plasma electrolytic oxidation of titanium for TiO2/WO3 thin film photocatalysts by response surface methodology. in Surface and Coatings Technology. 2015;269:250-257.
doi:10.1016/j.surfcoat.2014.12.026 .

Petrović, Srđan, Stojadinović, Stevan D.J., Rožić, Ljiljana, Radić, Nenad, Grbić, Boško, Vasilić, Rastko, "Process modelling and analysis of plasma electrolytic oxidation of titanium for TiO2/WO3 thin film photocatalysts by response surface methodology" in Surface and Coatings Technology, 269 (2015):250-257,
https://doi.org/10.1016/j.surfcoat.2014.12.026 . .

TY  - JOUR
AU  - Rožić, Ljiljana
AU  - Grbić, Boško
AU  - Petrović, Srđan
AU  - Radić, Nenad
AU  - Damjanović, Ljiljana
AU  - Vuković, Zorica
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1788
AB  - This paper provides the correlation between the catalytic activity and selectivity of catalysts with various loadings of heteropolyacids over bentonite in the vapour phase 2-propanol oxidation. The catalysts are characterised by energy dispersive spectroscopy, differential scanning calorimeter, ammonia temperature programmed desorption, infrared spectroscopy and a nitrogen adsorption/desorption method. Energy dispersive spectroscopy results have shown satisfactory agreement regarding chemical composition that corresponds to the desired content of heteropolyacids on bentonite. Thermal analysis confirmed the thermal stability of catalysts under the investigated region of oxidation reaction. NH3-TPD spectra demonstrated that all catalysts include two types of acidic sites: weak adsorption centres up to 390 K and a broad distribution of stronger acidic sites at higher temperatures. The catalysts were active in the vapour-phase conversion of 2-propanol to acetone in the temperature region of 343-553 K. An increase of HPW loading improves selectivity towards acetone formation.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - The tungsten heteropolyacid supported on activated bentonites as catalyst for selective oxidation of 2-propanol
VL  - 167
SP  - 42
EP  - 48
DO  - 10.1016/j.matchemphys.2015.09.040
ER  - 

@article{
author = "Rožić, Ljiljana and Grbić, Boško and Petrović, Srđan and Radić, Nenad and Damjanović, Ljiljana and Vuković, Zorica",
year = "2015",
abstract = "This paper provides the correlation between the catalytic activity and selectivity of catalysts with various loadings of heteropolyacids over bentonite in the vapour phase 2-propanol oxidation. The catalysts are characterised by energy dispersive spectroscopy, differential scanning calorimeter, ammonia temperature programmed desorption, infrared spectroscopy and a nitrogen adsorption/desorption method. Energy dispersive spectroscopy results have shown satisfactory agreement regarding chemical composition that corresponds to the desired content of heteropolyacids on bentonite. Thermal analysis confirmed the thermal stability of catalysts under the investigated region of oxidation reaction. NH3-TPD spectra demonstrated that all catalysts include two types of acidic sites: weak adsorption centres up to 390 K and a broad distribution of stronger acidic sites at higher temperatures. The catalysts were active in the vapour-phase conversion of 2-propanol to acetone in the temperature region of 343-553 K. An increase of HPW loading improves selectivity towards acetone formation.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "The tungsten heteropolyacid supported on activated bentonites as catalyst for selective oxidation of 2-propanol",
volume = "167",
pages = "42-48",
doi = "10.1016/j.matchemphys.2015.09.040"
}

Rožić, L., Grbić, B., Petrović, S., Radić, N., Damjanović, L.,& Vuković, Z.. (2015). The tungsten heteropolyacid supported on activated bentonites as catalyst for selective oxidation of 2-propanol. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 167, 42-48.
https://doi.org/10.1016/j.matchemphys.2015.09.040

Rožić L, Grbić B, Petrović S, Radić N, Damjanović L, Vuković Z. The tungsten heteropolyacid supported on activated bentonites as catalyst for selective oxidation of 2-propanol. in Materials Chemistry and Physics. 2015;167:42-48.
doi:10.1016/j.matchemphys.2015.09.040 .

Rožić, Ljiljana, Grbić, Boško, Petrović, Srđan, Radić, Nenad, Damjanović, Ljiljana, Vuković, Zorica, "The tungsten heteropolyacid supported on activated bentonites as catalyst for selective oxidation of 2-propanol" in Materials Chemistry and Physics, 167 (2015):42-48,
https://doi.org/10.1016/j.matchemphys.2015.09.040 . .

TY  - JOUR
AU  - Novaković, Tatjana
AU  - Rožić, Ljiljana
AU  - Petrović, Srđan
AU  - Stanisavljev, Dragomir
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1839
AB  - The desorption behavior of β-carotene from a bentonite adsorbent under microwave irradiation in isopropanol was studied as a function of temperature and different initial loading concentrations. A first-order, two-component, three-parameter model described the desorption kinetics with a coefficient of de-termination R2 > 0.9932, and the β-carotene desorption process under microwave irradiation was con-trolled by both rapid and slow desorption. The activation energies of β-carotene desorption for the rapid and slow desorption processes were 19.61 and 53.04 kJ mol-1, respectively. It was observed that the de-sorption equilibrium data fitted well to both the Freundlich and Langmuir isotherms. The data obtained from the desorption-isotherm model were used to determine the thermodynamic parameters. The positive value of free energy indicates the non-spontaneity of β-carotene desorption. The change in entropy rela-tive to the enthalpy of desorption reveals that the reaction is physical in nature.
AB  - Десорпциското однесување на β-каротенот од бентонитски атсорбент беше истражувано во
услови на микробранова ирадијација како функција на температурата и различни концентрации на
полнењето. Кинтетички двокомпонентен модел од прв ред со три параметри ја опишува
десорпциската кинетика со коефицинет на корелација R
2
> 0.9932. Десорпцискиот процес на βкаротенот во услови на микробранова ирадијација е контролиран и со брза и со бавна десорпција.
Активациските енергии на десорпцијата на β-каротенот за брзата и за бавната десорпција
соодветно изнесуваат 19,61 kJ mol–1
и 53,04 kJ mol–1
. Забележано е дека десорпциската рамнотежа
добро се вклопува во изотермите на Freundlich и на Langmuir. Добиените податоци на моделот на
десорпциската изотерма се употребени за определување на термодинамички параметри.
Позитивната вредност на слободната енергија укажува на неспонтаност на десорпцијата на βкаротенот. Промената на ентропијата во однос на енталпијата укажува дека десопцијата по
природа е физичка.
PB  - Macedonian Journal of Chemistry and Chemical Engineering
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - Desorption of β-carotene from bentonite adsorbent under microwave irradiation
T1  - ДЕСОРПЦИЈА НА β-КАРОТЕН ОД БЕНТОНИТСКИ АТСОРБЕНТ ВО УСЛОВИ НА МИКРОБРАНОВА ИРАДИЈАЦИЈА
VL  - 34
IS  - 2
SP  - 363
EP  - 371
UR  - https://hdl.handle.net/21.15107/rcub_cer_1839
ER  - 

@article{
author = "Novaković, Tatjana and Rožić, Ljiljana and Petrović, Srđan and Stanisavljev, Dragomir",
year = "2015",
abstract = "The desorption behavior of β-carotene from a bentonite adsorbent under microwave irradiation in isopropanol was studied as a function of temperature and different initial loading concentrations. A first-order, two-component, three-parameter model described the desorption kinetics with a coefficient of de-termination R2 > 0.9932, and the β-carotene desorption process under microwave irradiation was con-trolled by both rapid and slow desorption. The activation energies of β-carotene desorption for the rapid and slow desorption processes were 19.61 and 53.04 kJ mol-1, respectively. It was observed that the de-sorption equilibrium data fitted well to both the Freundlich and Langmuir isotherms. The data obtained from the desorption-isotherm model were used to determine the thermodynamic parameters. The positive value of free energy indicates the non-spontaneity of β-carotene desorption. The change in entropy rela-tive to the enthalpy of desorption reveals that the reaction is physical in nature., Десорпциското однесување на β-каротенот од бентонитски атсорбент беше истражувано во
услови на микробранова ирадијација како функција на температурата и различни концентрации на
полнењето. Кинтетички двокомпонентен модел од прв ред со три параметри ја опишува
десорпциската кинетика со коефицинет на корелација R
2
> 0.9932. Десорпцискиот процес на βкаротенот во услови на микробранова ирадијација е контролиран и со брза и со бавна десорпција.
Активациските енергии на десорпцијата на β-каротенот за брзата и за бавната десорпција
соодветно изнесуваат 19,61 kJ mol–1
и 53,04 kJ mol–1
. Забележано е дека десорпциската рамнотежа
добро се вклопува во изотермите на Freundlich и на Langmuir. Добиените податоци на моделот на
десорпциската изотерма се употребени за определување на термодинамички параметри.
Позитивната вредност на слободната енергија укажува на неспонтаност на десорпцијата на βкаротенот. Промената на ентропијата во однос на енталпијата укажува дека десопцијата по
природа е физичка.",
publisher = "Macedonian Journal of Chemistry and Chemical Engineering",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "Desorption of β-carotene from bentonite adsorbent under microwave irradiation, ДЕСОРПЦИЈА НА β-КАРОТЕН ОД БЕНТОНИТСКИ АТСОРБЕНТ ВО УСЛОВИ НА МИКРОБРАНОВА ИРАДИЈАЦИЈА",
volume = "34",
number = "2",
pages = "363-371",
url = "https://hdl.handle.net/21.15107/rcub_cer_1839"
}

Novaković, T., Rožić, L., Petrović, S.,& Stanisavljev, D.. (2015). Desorption of β-carotene from bentonite adsorbent under microwave irradiation. in Macedonian Journal of Chemistry and Chemical Engineering
Macedonian Journal of Chemistry and Chemical Engineering., 34(2), 363-371.
https://hdl.handle.net/21.15107/rcub_cer_1839

Novaković T, Rožić L, Petrović S, Stanisavljev D. Desorption of β-carotene from bentonite adsorbent under microwave irradiation. in Macedonian Journal of Chemistry and Chemical Engineering. 2015;34(2):363-371.
https://hdl.handle.net/21.15107/rcub_cer_1839 .

Novaković, Tatjana, Rožić, Ljiljana, Petrović, Srđan, Stanisavljev, Dragomir, "Desorption of β-carotene from bentonite adsorbent under microwave irradiation" in Macedonian Journal of Chemistry and Chemical Engineering, 34, no. 2 (2015):363-371,
https://hdl.handle.net/21.15107/rcub_cer_1839 .