Strukturna i funkcionalna hemija nekih prelaznih i postprelaznih elemenata

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Strukturna i funkcionalna hemija nekih prelaznih i postprelaznih elemenata (en)
Структурна и функционална хемија неких прелазних и постпрелазних елемената (sr)
Strukturna i funkcionalna hemija nekih prelaznih i postprelaznih elemenata (sr_RS)
Authors

Publications

Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones

Popov-Pergal, Katarina M.; Poleti, Dejan; Rancic, Milica P.; Meden, Antun; Pergal, Marija

(Wiley-Blackwell Publishing, Inc, Malden, 2010)

TY  - JOUR
AU  - Popov-Pergal, Katarina M.
AU  - Poleti, Dejan
AU  - Rancic, Milica P.
AU  - Meden, Antun
AU  - Pergal, Marija
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/737
AB  - The derivatives of 5-substituted-2,4-thiazolidinedione have a broad spectrum of biological activities. In this article, new 5-(arylidene)-3-(4-methylbenzoyl)thiayolidine-2,4-diones 3a-k, with arylidene groups such as 4-phenylbenzylidene 3a, 3,4-dimethoxybenzylidene 3b, 2-hydroxybenzylidene 3c, 4-ethoxybenzylidene 3d, 5-methyl-2-furfurylidene 3e, 4-dimethylaminobenzylidene 3f, 1-naphthylidene 3g, 3,4-methylenedioxybenzylidene 3h, 4-benzyloxybenzylidene 3i, benzylidene 3j, and 4-methoxybenzylidene 3k, were synthesized by direct acylation of alkali metal salts of 5-arylidene-2,4-thiazolidinediones with 4-methylbenzoylchloride. Their structures were confirmed by elemental analysis, IR, (1)H NMR and MS spectroscopy. In addition, crystal structure of the compound 3d was determined using single-crystal X-ray diffraction data.
PB  - Wiley-Blackwell Publishing, Inc, Malden
T2  - Journal of Heterocyclic Chemistry
T1  - Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones
VL  - 47
IS  - 1
SP  - 224
EP  - 228
DO  - 10.1002/jhet.288
ER  - 
@article{
author = "Popov-Pergal, Katarina M. and Poleti, Dejan and Rancic, Milica P. and Meden, Antun and Pergal, Marija",
year = "2010",
abstract = "The derivatives of 5-substituted-2,4-thiazolidinedione have a broad spectrum of biological activities. In this article, new 5-(arylidene)-3-(4-methylbenzoyl)thiayolidine-2,4-diones 3a-k, with arylidene groups such as 4-phenylbenzylidene 3a, 3,4-dimethoxybenzylidene 3b, 2-hydroxybenzylidene 3c, 4-ethoxybenzylidene 3d, 5-methyl-2-furfurylidene 3e, 4-dimethylaminobenzylidene 3f, 1-naphthylidene 3g, 3,4-methylenedioxybenzylidene 3h, 4-benzyloxybenzylidene 3i, benzylidene 3j, and 4-methoxybenzylidene 3k, were synthesized by direct acylation of alkali metal salts of 5-arylidene-2,4-thiazolidinediones with 4-methylbenzoylchloride. Their structures were confirmed by elemental analysis, IR, (1)H NMR and MS spectroscopy. In addition, crystal structure of the compound 3d was determined using single-crystal X-ray diffraction data.",
publisher = "Wiley-Blackwell Publishing, Inc, Malden",
journal = "Journal of Heterocyclic Chemistry",
title = "Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones",
volume = "47",
number = "1",
pages = "224-228",
doi = "10.1002/jhet.288"
}
Popov-Pergal, K. M., Poleti, D., Rancic, M. P., Meden, A.,& Pergal, M.. (2010). Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones. in Journal of Heterocyclic Chemistry
Wiley-Blackwell Publishing, Inc, Malden., 47(1), 224-228.
https://doi.org/10.1002/jhet.288
Popov-Pergal KM, Poleti D, Rancic MP, Meden A, Pergal M. Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones. in Journal of Heterocyclic Chemistry. 2010;47(1):224-228.
doi:10.1002/jhet.288 .
Popov-Pergal, Katarina M., Poleti, Dejan, Rancic, Milica P., Meden, Antun, Pergal, Marija, "Synthesis and Structure of New 5-(Arylidene)-3-(4-methylbenzoyl)thiazolidine-2,4-diones" in Journal of Heterocyclic Chemistry, 47, no. 1 (2010):224-228,
https://doi.org/10.1002/jhet.288 . .
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Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts

Khristova, M.S.; Petrović, Srđan; Terlecki-Baričević, Ana V.; Mehandjiev, D.R.

(Versita, Warsaw, 2009)

TY  - JOUR
AU  - Khristova, M.S.
AU  - Petrović, Srđan
AU  - Terlecki-Baričević, Ana V.
AU  - Mehandjiev, D.R.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/621
AB  - The perovskite type oxides (nominal formula LaTi0.5 Mg0.5O3) with addition of Pd were prepared by annealing the ethanol solution of precursors in nitrogen flow at 1200°C and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of NO (NO-TPD). Their activity was evaluated for NO reduction by CO under stoichiometric and oxidizing conditions and for direct decomposition of NO. Pd substituted samples exhibited high NO reduction activity and selectivity towards N2. Nearly complete elimination of NO was achieved at 200°C. Two simultaneous reactions, NO reduction by CO and direct decomposition of NO as well as two forms of NO adsorption were observed on the surface of Pd substituted perovskite samples. The distribution of Pd in different catalytically active sites or complexes on at the catalyst surface may be responsible for the proceeding of two reactions: NO reduction with CO and direct NO decomposition.
PB  - Versita, Warsaw
T2  - Central European Journal of Chemistry
T1  - Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts
VL  - 7
IS  - 4
SP  - 857
EP  - 863
DO  - 10.2478/s11532-009-0065-4
ER  - 
@article{
author = "Khristova, M.S. and Petrović, Srđan and Terlecki-Baričević, Ana V. and Mehandjiev, D.R.",
year = "2009",
abstract = "The perovskite type oxides (nominal formula LaTi0.5 Mg0.5O3) with addition of Pd were prepared by annealing the ethanol solution of precursors in nitrogen flow at 1200°C and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of NO (NO-TPD). Their activity was evaluated for NO reduction by CO under stoichiometric and oxidizing conditions and for direct decomposition of NO. Pd substituted samples exhibited high NO reduction activity and selectivity towards N2. Nearly complete elimination of NO was achieved at 200°C. Two simultaneous reactions, NO reduction by CO and direct decomposition of NO as well as two forms of NO adsorption were observed on the surface of Pd substituted perovskite samples. The distribution of Pd in different catalytically active sites or complexes on at the catalyst surface may be responsible for the proceeding of two reactions: NO reduction with CO and direct NO decomposition.",
publisher = "Versita, Warsaw",
journal = "Central European Journal of Chemistry",
title = "Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts",
volume = "7",
number = "4",
pages = "857-863",
doi = "10.2478/s11532-009-0065-4"
}
Khristova, M.S., Petrović, S., Terlecki-Baričević, A. V.,& Mehandjiev, D.R.. (2009). Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts. in Central European Journal of Chemistry
Versita, Warsaw., 7(4), 857-863.
https://doi.org/10.2478/s11532-009-0065-4
Khristova M, Petrović S, Terlecki-Baričević AV, Mehandjiev D. Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts. in Central European Journal of Chemistry. 2009;7(4):857-863.
doi:10.2478/s11532-009-0065-4 .
Khristova, M.S., Petrović, Srđan, Terlecki-Baričević, Ana V., Mehandjiev, D.R., "Catalytic reduction of NO by CO over Pd-doped Perovskite-type catalysts" in Central European Journal of Chemistry, 7, no. 4 (2009):857-863,
https://doi.org/10.2478/s11532-009-0065-4 . .
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10

LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation

Petrović, Srđan; Terlecki-Baričević, Ana V.; Karanovic, Lj.; Kirilov-Stefanov, P.; Zdujić, Miodrag; Dondur, Vera; Paneva, Daniela; Mitov, I.; Rakić, Vesna M.

(Elsevier, 2008)

TY  - JOUR
AU  - Petrović, Srđan
AU  - Terlecki-Baričević, Ana V.
AU  - Karanovic, Lj.
AU  - Kirilov-Stefanov, P.
AU  - Zdujić, Miodrag
AU  - Dondur, Vera
AU  - Paneva, Daniela
AU  - Mitov, I.
AU  - Rakić, Vesna M.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/399
AB  - Two new series of perovskite-type oxides LaMO3 (M = Mg, Ti, Fe) with different ratio Mg/Fe (MF) and Ti/Fe (TF) in the B cation site were prepared by annealing the precursor, obtained by the mechanochemical activation (MCA) of constituent metal oxides, at 1000 degrees C in air. In addition, two closely related perovskites LaFeO3 (LF) and LaTi0.5Mg0.5O3 (TM (50:50)) were synthesized in the similar way. Using MCA method, perovskites were obtained in rather short time and at room temperature. The samples were characterized by X-ray powder diffraction (XRPD), Xray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), temperature programmed desorption of oxygen (TPD), Mossbauer spectroscopy, BET surface area measurements and tested in methane deep oxidation. According to XRPD analysis all synthesized samples are almost single perovskite phase, with trace amounts of La2O3 phase. Data of Mossbauer spectroscopy identify Fe 31 in octahedral coordination. The activity of perovskite in methane deep oxidation increases in the order TM (50:50)  LT  MF series  LT  TF series. Higher activity of TF samples in respect to MF with similar Fe content can be related to the structural characteristic., mainly to the presence of predominantly most labile oxygen species evidenced by TPD at lowest temperature of oxygen evaluation. In used experimental conditions, the Fe substituted perovskite are thermal stable up to the temperature of 850 degrees C. The stability of Fe active sites is probably the most important parameter responsible for thermal stability of perovskite, but the atomic surface composition also should be taken into account.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation
VL  - 79
IS  - 2
SP  - 186
EP  - 198
DO  - 10.1016/j.apcatb.2007.10.022
ER  - 
@article{
author = "Petrović, Srđan and Terlecki-Baričević, Ana V. and Karanovic, Lj. and Kirilov-Stefanov, P. and Zdujić, Miodrag and Dondur, Vera and Paneva, Daniela and Mitov, I. and Rakić, Vesna M.",
year = "2008",
abstract = "Two new series of perovskite-type oxides LaMO3 (M = Mg, Ti, Fe) with different ratio Mg/Fe (MF) and Ti/Fe (TF) in the B cation site were prepared by annealing the precursor, obtained by the mechanochemical activation (MCA) of constituent metal oxides, at 1000 degrees C in air. In addition, two closely related perovskites LaFeO3 (LF) and LaTi0.5Mg0.5O3 (TM (50:50)) were synthesized in the similar way. Using MCA method, perovskites were obtained in rather short time and at room temperature. The samples were characterized by X-ray powder diffraction (XRPD), Xray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS), temperature programmed desorption of oxygen (TPD), Mossbauer spectroscopy, BET surface area measurements and tested in methane deep oxidation. According to XRPD analysis all synthesized samples are almost single perovskite phase, with trace amounts of La2O3 phase. Data of Mossbauer spectroscopy identify Fe 31 in octahedral coordination. The activity of perovskite in methane deep oxidation increases in the order TM (50:50)  LT  MF series  LT  TF series. Higher activity of TF samples in respect to MF with similar Fe content can be related to the structural characteristic., mainly to the presence of predominantly most labile oxygen species evidenced by TPD at lowest temperature of oxygen evaluation. In used experimental conditions, the Fe substituted perovskite are thermal stable up to the temperature of 850 degrees C. The stability of Fe active sites is probably the most important parameter responsible for thermal stability of perovskite, but the atomic surface composition also should be taken into account.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation",
volume = "79",
number = "2",
pages = "186-198",
doi = "10.1016/j.apcatb.2007.10.022"
}
Petrović, S., Terlecki-Baričević, A. V., Karanovic, Lj., Kirilov-Stefanov, P., Zdujić, M., Dondur, V., Paneva, D., Mitov, I.,& Rakić, V. M.. (2008). LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation. in Applied Catalysis B-Environmental
Elsevier., 79(2), 186-198.
https://doi.org/10.1016/j.apcatb.2007.10.022
Petrović S, Terlecki-Baričević AV, Karanovic L, Kirilov-Stefanov P, Zdujić M, Dondur V, Paneva D, Mitov I, Rakić VM. LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation. in Applied Catalysis B-Environmental. 2008;79(2):186-198.
doi:10.1016/j.apcatb.2007.10.022 .
Petrović, Srđan, Terlecki-Baričević, Ana V., Karanovic, Lj., Kirilov-Stefanov, P., Zdujić, Miodrag, Dondur, Vera, Paneva, Daniela, Mitov, I., Rakić, Vesna M., "LaMO3 (M = Mg, Ti, Fe) perovskite type oxides: Preparation, characterization and catalytic properties in methane deep oxidation" in Applied Catalysis B-Environmental, 79, no. 2 (2008):186-198,
https://doi.org/10.1016/j.apcatb.2007.10.022 . .
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