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Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey
dc.creator | Jevtović, Mima | |
dc.creator | Pevec, Andrej | |
dc.creator | Turel, Iztok | |
dc.creator | Radanović, Dušanka | |
dc.creator | Milčić, Miloš | |
dc.creator | Gruden, Maja | |
dc.creator | Zlatar, Matija | |
dc.creator | Mitić, Dragana | |
dc.creator | Anđelković, Katarina | |
dc.creator | Čobeljić, Božidar | |
dc.date.accessioned | 2023-10-18T15:08:04Z | |
dc.date.available | 2025-10-17 | |
dc.date.issued | 2023 | |
dc.identifier.issn | 1387-7003 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/6766 | |
dc.description.abstract | In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions. | |
dc.publisher | Elsevier | en |
dc.relation | info:eu-repo/grantAgreement/ScienceFundRS/Ideje/7750288/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS// | |
dc.relation | Slovenian Research Agency (ARRS), grant number P1-0175 | |
dc.relation.isversionof | https://doi.org/10.1016/j.inoche.2023.111582 | |
dc.relation.isversionof | https://cer.ihtm.bg.ac.rs/handle/123456789/6788 | |
dc.rights | embargoedAccess | |
dc.source | Inorganic Chemistry Communications | en |
dc.subject | Schiff base ligands | |
dc.subject | nickel(II) | |
dc.subject | nickel(III) | |
dc.subject | complexes | |
dc.subject | synthesis | |
dc.subject | X-ray structure | |
dc.subject | DFT | |
dc.subject | syngle crystal | |
dc.subject | EPR | |
dc.title | Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey | en |
dc.type | article | en |
dc.rights.license | ARR | en |
dc.citation.volume | 158 | |
dc.citation.spage | 111582 | |
dc.citation.rank | M21~ | |
dc.description.other | This is the accepted version of the manuscript: M. Jevtović, A. Pevec, I. Turel, D. Radanović, M. Milčić, M. Gruden, M. Zlatar, D. Mitić, K. Anđelković, B. Čobeljić, Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey, Inorganic Chemistry Communications (2023), doi: [https://doi.org/10.1016/j.inoche.2023.111582] | |
dc.description.other | Published version: [https://cer.ihtm.bg.ac.rs/handle/123456789/6788] | |
dc.identifier.doi | 10.1016/j.inoche.2023.111582 | |
dc.identifier.scopus | 2-s2.0-85174714656 | |
dc.type.version | acceptedVersion |
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TMMagCat
Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes -
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